Biosperse 244 Ibc 1000l Us
Biosperse 244 Ibc 1000l Us
Biosperse 244 Ibc 1000l Us
SECTION 1. IDENTIFICATION
Product identifier
Trade name : Biosperse™ 244 MICROBIOCIDE
™ Trademark, Solenis or its subsidiaries or affiliates,
registered in various countries
EHSProductSafetyTeam@solenis.com
GHS classification in accordance with the OSHA Hazard Communication Standard (29 CFR
1910.1200)
Corrosive to metals : Category 1
1 / 18
Page: 2
Hazard pictograms :
Precautionary statements :
Prevention:
P234 Keep only in original container.
P260 Do not breathe mist or vapours.
P264 Wash skin thoroughly after handling.
P270 Do not eat, drink or smoke when using this product.
P271 Use only outdoors or in a well-ventilated area.
P272 Contaminated work clothing must not be allowed out of
the workplace.
P280 Wear protective gloves/ protective clothing/ eye protection/
face protection.
Response:
P301 + P312 + P330 IF SWALLOWED: Call a POISON
CENTER/ doctor if you feel unwell. Rinse mouth.
P301 + P330 + P331 IF SWALLOWED: Rinse mouth. Do NOT
induce vomiting.
P303 + P361 + P353 IF ON SKIN (or hair): Take off immediately
all contaminated clothing. Rinse skin with water/ shower.
P304 + P340 + P310 IF INHALED: Remove person to fresh air
and keep comfortable for breathing. Immediately call a POISON
CENTER/ doctor.
P305 + P351 + P338 + P310 IF IN EYES: Rinse cautiously with
water for several minutes. Remove contact lenses, if present
and easy to do. Continue rinsing. Immediately call a POISON
CENTER/ doctor.
P314 Get medical advice/ attention if you feel unwell.
P333 + P313 If skin irritation or rash occurs: Get medical advice/
attention.
P363 Wash contaminated clothing before reuse.
P370 + P378 In case of fire: Use dry sand, dry chemical or
alcohol-resistant foam to extinguish.
P390 Absorb spillage to prevent material damage.
Storage:
P405 Store locked up.
P406 Store in corrosive resistant container with a resistant inner
liner.
2 / 18
Page: 3
Disposal:
P501 Dispose of contents/ container to an approved waste
disposal plant.
Other hazards
None known.
Components
Chemical name CAS-No. Classification Concentration (%)
POLYETHYLENE GLYCOL 25322-68-3 Not a hazardous >= 50 - < 60
substance or mixture.
In case of eye contact : In the case of contact with eyes, rinse immediately with plenty
of water and seek medical advice.
Continue rinsing eyes during transport to hospital.
Remove contact lenses.
3 / 18
Page: 4
Most important symptoms : Signs and symptoms of exposure to this material through
and effects, both acute and breathing, swallowing, and/or passage of the material through
delayed the skin may include:
stomach or intestinal upset (nausea, vomiting, diarrhea)
irritation (nose, throat, airways)
Headache
Harmful if swallowed or if inhaled.
May cause an allergic skin reaction.
Causes serious eye damage.
Causes damage to organs through prolonged or repeated
exposure if inhaled.
Causes severe burns.
Suitable extinguishing media : Use extinguishing measures that are appropriate to local
circumstances and the surrounding environment.
Water spray
Foam
Carbon dioxide (CO2)
Dry chemical
Specific hazards during : If product is heated above its flash point it will produce vapors
firefighting sufficient to support combustion. Vapors are heavier than air
and may travel along the ground and be ignited by heat, pilot
lights, other flames and ignition sources at locations near the
point of release.
Do not allow run-off from fire fighting to enter drains or water
courses.
Alcohols
ethers
Ketones
Bromine
Nitrogen oxides (NOx)
hydrogen bromide
Sodium oxides
Further information : Fire residues and contaminated fire extinguishing water must
be disposed of in accordance with local regulations.
Special protective equipment : In the event of fire, wear self-contained breathing apparatus.
for firefighters
Methods and materials for : Soak up with inert absorbent material (e.g. sand, silica gel,
containment and cleaning up acid binder, universal binder, sawdust).
Keep in suitable, closed containers for disposal.
5 / 18
Page: 6
Conditions for safe storage : Keep container tightly closed in a dry and well-ventilated
place.
Containers which are opened must be carefully resealed and
kept upright to prevent leakage.
Observe label precautions.
Electrical installations / working materials must comply with
the technological safety standards.
C 5 mg/m3 ACGIH
(Cyanide)
TWA 5 mg/m3 OSHA P0
(Cyanide)
C 4.7 ppm NIOSH REL
5 mg/m3
(Cyanide)
Engineering measures : Provide sufficient mechanical (general and/or local exhaust)
ventilation to maintain exposure below exposure guidelines (if
applicable) or below levels that cause known, suspected or
apparent adverse effects.
6 / 18
Page: 7
Hand protection
Material : Nitrile rubber
Eye protection : Wear chemical splash goggles and face shield when there is
potential for exposure of the eyes or face to liquid, vapor or
mist.
Maintain eye wash station in immediate work area.
Hygiene measures : Wash hands before breaks and at the end of workday.
When using do not eat or drink.
Ensure that eyewash stations and safety showers are close
to the workstation location.
When using do not smoke.
Appearance : liquid
pH : 1.5 - 5.0
Method: ASTM D 93
7 / 18
Page: 8
Solubility(ies)
Water solubility : soluble
Viscosity
Viscosity, dynamic : 20 cps (77 °F / 25 °C)
Method: Brookfield
Acute toxicity
Harmful if swallowed or if inhaled.
Product:
Acute oral toxicity : LD50 (Rat): 510 mg/kg
Components:
POLYETHYLENE GLYCOL:
Acute oral toxicity : LD50 (Rat): > 20 g/kg
2,2 DIBROMO-3-NITRILOPROPIONAMIDE:
Acute oral toxicity : LD50 (Rat, female): 167 mg/kg
Acute inhalation toxicity : LC50 (Rat, male and female): 0.275 mg/l
Exposure time: 4 h
Test atmosphere: dust/mist
Method: OECD Test Guideline 403
9 / 18
Page: 10
GLP: yes
Skin corrosion/irritation
Causes severe burns.
Product:
Remarks : May cause skin irritation in susceptible persons.
Causes severe skin burns and eye damage.
Components:
POLYETHYLENE GLYCOL:
Result : Not irritating to skin
2,2 DIBROMO-3-NITRILOPROPIONAMIDE:
Species : Rabbit
Method : OECD Test Guideline 404
Result : Irritating to skin
GLP : yes
Components:
POLYETHYLENE GLYCOL:
Result : Not irritating to eyes
2,2 DIBROMO-3-NITRILOPROPIONAMIDE:
Species : Rabbit
Result : Risk of serious damage to eyes.
Method : OECD Test Guideline 405
Skin sensitisation
May cause an allergic skin reaction.
Respiratory sensitisation
Not classified based on available information.
10 / 18
Page: 11
Product:
Remarks : May cause allergic skin reaction.
Components:
2,2 DIBROMO-3-NITRILOPROPIONAMIDE:
Result : May cause sensitisation by skin contact.
2,2 DIBROMO-3-NITRILOPROPIONAMIDE:
Genotoxicity in vitro : Test Type: In vitro mammalian cell gene mutation test
Test system: Chinese hamster ovary cells
Metabolic activation: with and without metabolic activation
Result: negative
Carcinogenicity
Not classified based on available information.
Components:
2,2 DIBROMO-3-NITRILOPROPIONAMIDE:
Species : Rat
Application Route : Ingestion
Method : OECD Test Guideline 453
Result : no increase in tumors observed
IARC No component of this product present at levels greater than or equal to 0.1% is
identified as probable, possible or confirmed human carcinogen by IARC.
OSHA No component of this product present at levels greater than or equal to 0.1% is
on OSHA’s list of regulated carcinogens.
11 / 18
Page: 12
NTP No component of this product present at levels greater than or equal to 0.1% is
identified as a known or anticipated carcinogen by NTP.
Reproductive toxicity
Not classified based on available information.
STOT - single exposure
Not classified based on available information.
STOT - repeated exposure
Causes damage to organs (Respiratory Tract) through prolonged or repeated exposure if inhaled.
Components:
2,2 DIBROMO-3-NITRILOPROPIONAMIDE:
Exposure routes : Inhalation
Target Organs : Respiratory Tract
Assessment : Causes damage to organs through prolonged or repeated
exposure.
Aspiration toxicity
Not classified based on available information.
Further information
Product:
Remarks : No data available
Ecotoxicity
Product:
Toxicity to fish : LC50 (Oncorhynchus mykiss (rainbow trout)): 3.6 mg/l
Exposure time: 96 h
Toxicity to daphnia and other : EC50 (Daphnia magna (Water flea)): 2.5 mg/l
aquatic invertebrates Exposure time: 48 h
Test Type: static test
Ecotoxicology Assessment
12 / 18
Page: 13
Acute aquatic toxicity : Acute aquatic toxicity Category 2; Toxic to aquatic life.
Chronic aquatic toxicity : Chronic aquatic toxicity Category 2; Toxic to aquatic life with
long lasting effects.
Components:
POLYETHYLENE GLYCOL:
Toxicity to fish : LC50 (Oncorhynchus mykiss (rainbow trout)): > 20,000 mg/l
Exposure time: 96 h
Test Type: static test
2,2 DIBROMO-3-NITRILOPROPIONAMIDE:
Toxicity to fish : LC50 (Cyprinodon variegatus (sheepshead minnow)): 3.4 mg/l
Exposure time: 96 h
Toxicity to daphnia and other : EC50 (Mysidopsis bahia (opossum shrimp)): 0.72 mg/l
aquatic invertebrates Exposure time: 96 h
GLP: yes
Toxicity to fish (Chronic : (Oncorhynchus mykiss (rainbow trout)): 0.47 - 0.98 mg/l
toxicity)
Toxicity to daphnia and other : NOEC (Daphnia magna (Water flea)): 0.06 mg/l
aquatic invertebrates End point: Growth
(Chronic toxicity) Exposure time: 21 d
Method: OECD Test Guideline 211
Product:
Biodegradability : Remarks: Readily biodegradable
Components:
POLYETHYLENE GLYCOL:
Biodegradability : Result: Readily biodegradable.
2,2 DIBROMO-3-NITRILOPROPIONAMIDE:
13 / 18
Page: 14
Bioaccumulative potential
Components:
2,2 DIBROMO-3-NITRILOPROPIONAMIDE:
Partition coefficient: n- : Pow: 6.31
octanol/water pH: 7
Mobility in soil
No data available
Other adverse effects
Product:
Additional ecological : An environmental hazard cannot be excluded in the event of
information unprofessional handling or disposal.
Toxic to aquatic life with long lasting effects.
Disposal methods
Waste from residues : The product should not be allowed to enter drains, water
courses or the soil.
Do not contaminate ponds, waterways or ditches with
chemical or used container.
Send to a licensed waste management company.
International Regulations
IATA-DGR
UN number : UN 3265
Proper shipping name : Corrosive liquid, acidic, organic, n.o.s. (2,2 DIBROMO-3-
NITRILOPROPIONAMIDE)
Class : 8
Packing group : III
Marine pollutant : yes
14 / 18
Page: 15
IMDG-Code
UN number : UN 3265
Proper shipping name : Corrosive liquid, acidic, organic, n.o.s. (2,2 DIBROMO-3-
NITRILOPROPIONAMIDE)
Class : 8
Packing group : III
EmS Code : F-A, S-B
Marine pollutant : yes
Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code
Not applicable for product as supplied.
National Regulations
49 CFR
UN number : UN 3265
Proper shipping name : CORROSIVE LIQUID, ACIDIC, ORGANIC, N.O.S. (2,2
DIBROMO-3-NITRILOPROPIONAMIDE)
Class : 8
Packing group : III
ERG Code : 153
Marine pollutant : no
15 / 18
Page: 16
SARA 313 : This material does not contain any chemical components with
known CAS numbers that exceed the threshold (De Minimis)
reporting levels established by SARA Title III, Section 313.
California Prop. 65
This product does not contain any chemicals known to State of California to cause cancer, birth
defects, or any other reproductive harm.
The components of this product are reported in the following inventories:
TCSI : On the inventory, or in compliance with the inventory
TSCA : Exempt
DSL : Exempt
TSCA list
Exempt- This product is exempt from Significant New Use Rule requirements. See information
under Biocides for product registration information.”
Exempt-This product is exempt from TSCA 12(b) requirements. See information under Biocides
for product registration information.”
Biocides
EPA Reg. # 74655-21
This chemical is a pesticide product registered by the Environmental Protection Agency and is
subject to certain labeling requirements under federal pesticide law. These requirements differ
from the classification criteria and hazard information required for safety data sheets, and for
workplace labels of non-pesticide chemicals. Following is the hazard information as required on
the pesticide label:
Danger, Corrosive., Causes irreversible eye damage., May be fatal if inhaled., May be fatal if
swallowed., Causes skin irritation., Do not get in eyes, on skin or on clothing., Do not breathe
dust., Prolonged or frequently repeated skin contact may cause allergic reactions in some
individuals.
16 / 18
Page: 17
Further information
Revision Date : 09/30/2022
AIIC - Australian Inventory of Industrial Chemicals; ASTM - American Society for the Testing of
Materials; bw - Body weight; CERCLA - Comprehensive Environmental Response,
Compensation, and Liability Act; CMR - Carcinogen, Mutagen or Reproductive Toxicant; DIN -
Standard of the German Institute for Standardisation; DOT - Department of Transportation; DSL -
Domestic Substances List (Canada); ECx - Concentration associated with x% response; EHS -
Extremely Hazardous Substance; ELx - Loading rate associated with x% response; EmS -
Emergency Schedule; ENCS - Existing and New Chemical Substances (Japan); ErCx -
Concentration associated with x% growth rate response; ERG - Emergency Response Guide;
GHS - Globally Harmonized System; GLP - Good Laboratory Practice; HMIS - Hazardous
Materials Identification System; IARC - International Agency for Research on Cancer; IATA -
International Air Transport Association; IBC - International Code for the Construction and
Equipment of Ships carrying Dangerous Chemicals in Bulk; IC50 - Half maximal inhibitory
concentration; ICAO - International Civil Aviation Organization; IECSC - Inventory of Existing
Chemical Substances in China; IMDG - International Maritime Dangerous Goods; IMO -
International Maritime Organization; ISHL - Industrial Safety and Health Law (Japan); ISO -
International Organisation for Standardization; KECI - Korea Existing Chemicals Inventory; LC50
- Lethal Concentration to 50 % of a test population; LD50 - Lethal Dose to 50% of a test
17 / 18
Page: 18
population (Median Lethal Dose); MARPOL - International Convention for the Prevention of
Pollution from Ships; MSHA - Mine Safety and Health Administration; n.o.s. - Not Otherwise
Specified; NFPA - National Fire Protection Association; NO(A)EC - No Observed (Adverse) Effect
Concentration; NO(A)EL - No Observed (Adverse) Effect Level; NOELR - No Observable Effect
Loading Rate; NTP - National Toxicology Program; NZIoC - New Zealand Inventory of Chemicals;
OECD - Organization for Economic Co-operation and Development; OPPTS - Office of Chemical
Safety and Pollution Prevention; PBT - Persistent, Bioaccumulative and Toxic substance; PICCS
- Philippines Inventory of Chemicals and Chemical Substances; (Q)SAR - (Quantitative) Structure
Activity Relationship; RCRA - Resource Conservation and Recovery Act; REACH - Regulation
(EC) No 1907/2006 of the European Parliament and of the Council concerning the Registration,
Evaluation, Authorisation and Restriction of Chemicals; RQ - Reportable Quantity; SADT - Self-
Accelerating Decomposition Temperature; SARA - Superfund Amendments and Reauthorization
Act; SDS - Safety Data Sheet; TCSI - Taiwan Chemical Substance Inventory; TECI - Thailand
Existing Chemicals Inventory; TSCA - Toxic Substances Control Act (United States); UN - United
Nations; UNRTDG - United Nations Recommendations on the Transport of Dangerous Goods;
vPvB - Very Persistent and Very Bioaccumulative
The information provided in this Safety Data Sheet is correct to the best of our knowledge,
information and belief at the date of its publication. The information given is designed only as a
guidance for safe handling, use, processing, storage, transportation, disposal and release and is
not to be considered a warranty or quality specification. The information relates only to the
specific material designated and may not be valid for such material used in combination with any
other materials or in any process, unless specified in the text. This SDS has been prepared by
the Solenis Environmental Health and Safety Department.
US / EN
18 / 18