Activator 0613 2Lt

Conforms to Regulation (EC) No.
1907/2006 (REACH), Annex II, as amended by UK REACH Regulation SI

2019/758
SAFETY DATA SHEET

Date of issue/Date of revision : 12 July 2023 Version : 1.02
SECTION 1: Identification of the substance/mixture and of the company/

undertaking
1.1 Product identifier
Product name : Activator 0613 2Lt
Product code : 06139000-GQK0
Product description :
Product type : Liquid.
Other means of : Not available.
identification
1.2 Relevant identified uses of the substance or mixture and uses advised against
Product use : Industrial applications, Used by spraying.
Use of the substance/ : Hardener.
mixture
Uses advised against : Product is not intended, labelled or packaged for consumer use.
1.3 Details of the supplier of the safety data sheet

PPG Coatings S.A., 7, Allée de la Plaine, Gonfreville l'Orcher, 76700 HARFLEUR,France,+33 (0)2 3553 5400
PPG Industries (UK) Ltd,3 Darlington Road,Shildon,Co Durham DL4 2QP, England,+44 (0) 1388 772 541
e-mail address of person : Product.Stewardship.EMEA@ppg.com

responsible for this SDS
1.4 Emergency telephone number
Supplier
+33 (0)2 3553 5400
SECTION 2: Hazards identification

2.1 Classification of the substance or mixture
Product definition : Mixture
Classification according to UK CLP/GHS
Flam. Liq. 2, H225
Acute Tox. 4, H302
Skin Irrit. 2, H315
Eye Dam. 1, H318
Skin Sens. 1, H317
STOT SE 3, H335
STOT SE 3, H336
The product is classified as hazardous according to UK CLP Regulation SI 2019/720 as amended.
See Section 16 for the full text of the H statements declared above.
See Section 11 for more detailed information on health effects and symptoms.
2.2 Label elements

Hazard pictograms :
Signal word : Danger
English (GB) United Kingdom (UK) 1/18

Conforms to Regulation (EC) No. 1907/2006 (REACH), Annex II, as amended by UK REACH Regulation SI 2019/758
Code : 06139000-GQK0 Date of issue/Date of revision : 12 July 2023
Activator 0613 2Lt
SECTION 2: Hazards identification

Hazard statements : Highly flammable liquid and vapour.
Harmful if swallowed.
Causes skin irritation.
May cause an allergic skin reaction.
Causes serious eye damage.
May cause respiratory irritation.
May cause drowsiness or dizziness.
Precautionary statements
Prevention : Wear protective gloves. Wear eye or face protection. Keep away from heat, hot
surfaces, sparks, open flames and other ignition sources. No smoking. Avoid
breathing vapour.
Response : IF IN EYES: Rinse cautiously with water for several minutes. Remove contact
lenses, if present and easy to do. Continue rinsing. Immediately call a POISON
CENTER or doctor.
Storage : Not applicable.
Disposal : Dispose of contents and container in accordance with all local, regional, national
and international regulations.
P280, P210, P261, P305 + P351 + P338, P310, P501
Supplemental label : Not applicable.
elements
Annex XVII - Restrictions : Not applicable.
on the manufacture,
placing on the market and
use of certain dangerous
substances, mixtures and
articles
Special packaging requirements
Containers to be fitted : Not applicable.
with child-resistant
fastenings
Tactile warning of danger : Not applicable.
2.3 Other hazards
Product meets the criteria : This mixture does not contain any substances that are assessed to be a PBT or a
for PBT or vPvB according vPvB.
to Regulation (EC) No.
1907/2006, Annex XIII
Other hazards which do : Prolonged or repeated contact may dry skin and cause irritation.
not result in classification
SECTION 3: Composition/information on ingredients

Mixture
3.2 Mixtures :
Product/ingredient name Identifiers % Classification Type
butan-1-ol REACH #: ≥25 - ≤50 Flam. Liq. 3, H226 [1] [2]
01-2119484630-38 Acute Tox. 4, H302
EC: 200-751-6 Skin Irrit. 2, H315
CAS: 71-36-3 Eye Dam. 1, H318
Index: 603-004-00-6 STOT SE 3, H335
STOT SE 3, H336
xylene REACH #: ≥25 - ≤48 Flam. Liq. 3, H226 [1] [2]
01-2119488216-32 Acute Tox. 4, H312
EC: 215-535-7 Acute Tox. 4, H332
CAS: 1330-20-7 Skin Irrit. 2, H315
Index: 601-022-00-9 Eye Irrit. 2, H319
STOT SE 3, H335
Asp. Tox. 1, H304

Activator 0613 2Lt
SECTION 3: Composition/information on ingredients

N-(3-(trimethoxysilyl)propyl) EC: 217-164-6 ≥10 - ≤25 Eye Dam. 1, H318 [1]
ethylenediamine CAS: 1760-24-3 Skin Sens. 1B, H317
STOT SE 3, H335
Polyaminoamide EC: Polymer ≥1.0 - ≤5.0 Eye Dam. 1, H318 [1]
CAS: 68082-29-1
ethylbenzene REACH #: ≥1.0 - ≤5.0 Flam. Liq. 2, H225 [1] [2]
01-2119489370-35 Acute Tox. 4, H332
EC: 202-849-4 STOT RE 2, H373
CAS: 100-41-4 (hearing organs)
Index: 601-023-00-4 Asp. Tox. 1, H304
Aquatic Chronic 3,
H412
2,4,6-tris(dimethylaminomethyl) REACH #: ≥1.0 - <5.0 Acute Tox. 4, H302 [1]
phenol 01-2119560597-27 Acute Tox. 4, H312
EC: 202-013-9 Skin Corr. 1C, H314
CAS: 90-72-2 Eye Dam. 1, H318
Index: 603-069-00-0
3,6-diazaoctanethylenediamin EC: 203-950-6 <1.0 Acute Tox. 4, H302 [1]
CAS: 112-24-3 Acute Tox. 4, H312
Index: 612-059-00-5 Skin Corr. 1B, H314
Eye Dam. 1, H318
Skin Sens. 1, H317
Aquatic Chronic 3,
H412
methanol REACH #: ≤0.30 Flam. Liq. 2, H225 [1] [2]
01-2119433307-44 Acute Tox. 3, H301
EC: 200-659-6 Acute Tox. 3, H311
CAS: 67-56-1 Acute Tox. 3, H331
Index: 603-001-00-X STOT SE 1, H370
toluene REACH #: ≤0.30 Flam. Liq. 2, H225 [1] [2]
01-2119471310-51 Skin Irrit. 2, H315
EC: 203-625-9 Repr. 2, H361d
CAS: 108-88-3 STOT SE 3, H336
Index: 601-021-00-3 STOT RE 2, H373
Asp. Tox. 1, H304
See Section 16 for
the full text of the H
statements declared
above.
There are no additional ingredients present which, within the current knowledge of the supplier and in the
concentrations applicable, are classified as hazardous to health or the environment, are PBTs, vPvBs or Substances of
equivalent concern, or have been assigned a workplace exposure limit and hence require reporting in this section.
Xylene: Several REACH registrations cover the REACH registered substance with xylene isomers, ethylbenzene (and
toluene). The other REACH Registrations include: 01-2119555267-33 reaction mass of ethylbenzene and m-xylene and p-
xylene, 01-2119486136-34 Aromatic hydrocarbons, C8, 01-2119539452-40 reaction mass of ethylbenzene and xylene.
Type
[1] Substance classified with a health or environmental hazard
[2] Substance with a workplace exposure limit
Occupational exposure limits, if available, are listed in Section 8.
SUB codes represent substances without registered CAS Numbers.
SECTION 4: First aid measures

4.1 Description of first aid measures
Eye contact : Check for and remove any contact lenses. Immediately flush eyes with running water for
at least 15 minutes, keeping eyelids open. Seek immediate medical attention.
Inhalation : Remove to fresh air. Keep person warm and at rest. If not breathing, if breathing is
irregular or if respiratory arrest occurs, provide artificial respiration or oxygen by trained
personnel.

Activator 0613 2Lt
SECTION 4: First aid measures

Skin contact : Remove contaminated clothing and shoes. Wash skin thoroughly with soap and water
or use recognised skin cleanser. Do NOT use solvents or thinners.
Ingestion : If swallowed, seek medical advice immediately and show the container or label. Keep
person warm and at rest. Do NOT induce vomiting.
Protection of first-aiders : No action shall be taken involving any personal risk or without suitable training. If it
is suspected that fumes are still present, the rescuer should wear an appropriate
mask or self-contained breathing apparatus. It may be dangerous to the person
providing aid to give mouth-to-mouth resuscitation. Wash contaminated clothing
thoroughly with water before removing it, or wear gloves.
4.2 Most important symptoms and effects, both acute and delayed
Potential acute health effects
Eye contact : Causes serious eye damage.
Inhalation : Can cause central nervous system (CNS) depression. May cause drowsiness or
dizziness. May cause respiratory irritation.
Skin contact : Causes skin irritation. Defatting to the skin. May cause an allergic skin reaction.
Ingestion : Harmful if swallowed. Can cause central nervous system (CNS) depression.
Over-exposure signs/symptoms
Eye contact : Adverse symptoms may include the following:
pain
watering
redness
Inhalation : Adverse symptoms may include the following:
respiratory tract irritation
coughing
nausea or vomiting
headache
drowsiness/fatigue
dizziness/vertigo
unconsciousness
Skin contact : Adverse symptoms may include the following:
pain or irritation
redness
dryness
cracking
blistering may occur
Ingestion : Adverse symptoms may include the following:
stomach pains
4.3 Indication of any immediate medical attention and special treatment needed
Notes to physician : In case of inhalation of decomposition products in a fire, symptoms may be delayed.
The exposed person may need to be kept under medical surveillance for 48 hours.
Specific treatments : No specific treatment.
SECTION 5: Firefighting measures

5.1 Extinguishing media
Suitable extinguishing : Use dry chemical, CO₂, water spray (fog) or foam.
media
Unsuitable extinguishing : Do not use water jet.
media
5.2 Special hazards arising from the substance or mixture

Hazards from the : Highly flammable liquid and vapour. Runoff to sewer may create fire or explosion
substance or mixture hazard. In a fire or if heated, a pressure increase will occur and the container may
burst, with the risk of a subsequent explosion.

Activator 0613 2Lt
SECTION 5: Firefighting measures

Hazardous combustion : Decomposition products may include the following materials:
products carbon oxides
nitrogen oxides
metal oxide/oxides
Formaldehyde.
5.3 Advice for firefighters

Special protective actions : Promptly isolate the scene by removing all persons from the vicinity of the incident if
for fire-fighters there is a fire. No action shall be taken involving any personal risk or without
suitable training. Move containers from fire area if this can be done without risk.
Use water spray to keep fire-exposed containers cool.
Special protective : Fire-fighters should wear appropriate protective equipment and self-contained
equipment for fire-fighters breathing apparatus (SCBA) with a full face-piece operated in positive pressure
mode.
SECTION 6: Accidental release measures

6.1 Personal precautions, protective equipment and emergency procedures
For non-emergency : No action shall be taken involving any personal risk or without suitable training.
personnel Evacuate surrounding areas. Keep unnecessary and unprotected personnel from
entering. Do not touch or walk through spilt material. Shut off all ignition sources.
No flares, smoking or flames in hazard area. Do not breathe vapour or mist.
Provide adequate ventilation. Wear appropriate respirator when ventilation is
inadequate. Put on appropriate personal protective equipment.
For emergency responders : If specialised clothing is required to deal with the spillage, take note of any
information in Section 8 on suitable and unsuitable materials. See also the
information in "For non-emergency personnel".
6.2 Environmental : Avoid dispersal of spilt material and runoff and contact with soil, waterways, drains
precautions and sewers. Inform the relevant authorities if the product has caused environmental
pollution (sewers, waterways, soil or air).
6.3 Methods and material for containment and cleaning up

Small spill : Stop leak if without risk. Move containers from spill area. Use spark-proof tools and
explosion-proof equipment. Dilute with water and mop up if water-soluble.
Alternatively, or if water-insoluble, absorb with an inert dry material and place in an
appropriate waste disposal container. Dispose of via a licensed waste disposal
contractor.
Large spill : Stop leak if without risk. Move containers from spill area. Use spark-proof tools and
explosion-proof equipment. Approach the release from upwind. Prevent entry into
sewers, water courses, basements or confined areas. Wash spillages into an
effluent treatment plant or proceed as follows. Contain and collect spillage with non-
combustible, absorbent material e.g. sand, earth, vermiculite or diatomaceous earth
and place in container for disposal according to local regulations (see Section 13).
Dispose of via a licensed waste disposal contractor. Contaminated absorbent
material may pose the same hazard as the spilt product. Note: see Section 1 for
emergency contact information and Section 13 for waste disposal.
6.4 Reference to other : See Section 1 for emergency contact information.

sections See Section 8 for information on appropriate personal protective equipment.
See Section 13 for additional waste treatment information.

Activator 0613 2Lt
SECTION 7: Handling and storage

The information in this section contains generic advice and guidance. The list of Identified Uses in Section 1 should be
consulted for any available use-specific information provided in the Exposure Scenario(s).
7.1 Precautions for safe handling
Protective measures : Put on appropriate personal protective equipment (see Section 8). Persons with a
history of skin sensitization problems should not be employed in any process in
which this product is used. Do not get in eyes or on skin or clothing. Do not breathe
vapour or mist. Do not ingest. Use only with adequate ventilation. Wear
appropriate respirator when ventilation is inadequate. Do not enter storage areas
and confined spaces unless adequately ventilated. Keep in the original container or
an approved alternative made from a compatible material, kept tightly closed when
not in use. Store and use away from heat, sparks, open flame or any other ignition
source. Use explosion-proof electrical (ventilating, lighting and material handling)
equipment. Use only non-sparking tools. Take precautionary measures against
electrostatic discharges. Empty containers retain product residue and can be
hazardous. Do not reuse container.
Advice on general : Eating, drinking and smoking should be prohibited in areas where this material is
occupational hygiene handled, stored and processed. Workers should wash hands and face before
eating, drinking and smoking. Remove contaminated clothing and protective
equipment before entering eating areas. See also Section 8 for additional
information on hygiene measures.
7.2 Conditions for safe storage, including any incompatibilities

Store between the following temperatures: 5 to 35°C (41 to 95°F). Store in accordance with local regulations. Store
in a segregated and approved area. Store in original container protected from direct sunlight in a dry, cool and well-
ventilated area, away from incompatible materials (see Section 10) and food and drink. Store locked up. Eliminate all
ignition sources. Separate from oxidising materials. Keep container tightly closed and sealed until ready for use.
Containers that have been opened must be carefully resealed and kept upright to prevent leakage. Do not store in
unlabelled containers. Use appropriate containment to avoid environmental contamination. See Section 10 for
incompatible materials before handling or use.
7.3 Specific end use(s)

See Section 1.2 for Identified uses.
SECTION 8: Exposure controls/personal protection

8.1 Control parameters
Occupational exposure limits
Product/ingredient name Exposure limit values
butan-1-ol EH40/2005 WELs (United Kingdom (UK), 1/2020). Absorbed
through skin.
STEL: 154 mg/m³ 15 minutes.
STEL: 50 ppm 15 minutes.
xylene EH40/2005 WELs (United Kingdom (UK), 1/2020). [xylene, o-,m-,p-
or mixed isomers] Absorbed through skin.
TWA: 220 mg/m³ 8 hours.
TWA: 50 ppm 8 hours.
ethylbenzene EH40/2005 WELs (United Kingdom (UK), 1/2020). Absorbed
through skin.

Activator 0613 2Lt

methanol EH40/2005 WELs (United Kingdom (UK), 1/2020). Absorbed
through skin.
toluene EH40/2005 WELs (United Kingdom (UK), 1/2020). Absorbed
through skin.
Biological exposure indices
Product/ingredient name Exposure indices
xylene XYLENES
Recommended monitoring : Reference should be made to appropriate monitoring standards. Reference to

procedures national guidance documents for methods for the determination of hazardous
substances will also be required.
DNELs/DMELs
Product/ingredient name Type Exposure Value Population Effects
butan-1-ol DNEL Long term Oral 1.5625 mg/kg bw/day General population Systemic
DNEL Long term Dermal 3.125 mg/kg bw/day General population Systemic
DNEL Long term Inhalation 55.357 mg/m³ General population Systemic
DNEL Long term Inhalation 155 mg/m³ General population Local
DNEL Long term Inhalation 310 mg/m³ Workers Local
xylene DNEL Short term Inhalation 260 mg/m³ General population Systemic
DNEL Short term Inhalation 260 mg/m³ General population Local
DNEL Long term Dermal 125 mg/kg bw/day General population Systemic
DNEL Long term Oral 12.5 mg/kg bw/day General population Systemic
DNEL Long term Inhalation 221 mg/m³ Workers Systemic
DNEL Short term Inhalation 442 mg/m³ Workers Systemic
DNEL Short term Inhalation 442 mg/m³ Workers Local
DNEL Long term Dermal 212 mg/kg bw/day Workers Systemic
DNEL Long term Inhalation 65.3 mg/m³ General population Local
DNEL Short term Inhalation 260 mg/m³ General population Systemic
DNEL Long term Oral 12.5 mg/kg bw/day General population Systemic
N-(3-(trimethoxysilyl)propyl) DNEL Long term Inhalation 0.1 mg/m³ General population Local
ethylenediamine
DNEL Long term Inhalation 0.6 mg/m³ Workers Local
DNEL Short term Inhalation 5.36 mg/m³ Workers Local
DNEL Long term Oral 8 mg/kg bw/day General population Systemic
DNEL Long term Inhalation 50 mg/m³ General population Systemic
ethylbenzene DNEL Long term Oral 1.6 mg/kg bw/day General population Systemic

Activator 0613 2Lt

DMEL Long term Inhalation 442 mg/m³ Workers Local
DMEL Short term Inhalation 884 mg/m³ Workers Systemic
2,4,6-tris DNEL Long term Oral 0.075 mg/kg bw/day General population Systemic
(dimethylaminomethyl)phenol
DNEL Short term Dermal 0.075 mg/kg bw/day General population Systemic
DNEL Long term Dermal 0.075 mg/kg bw/day General population Systemic
DNEL Short term Inhalation 0.13 mg/m³ General population Systemic
DNEL Long term Dermal 0.15 mg/kg bw/day Workers Systemic
DNEL Long term Inhalation 0.53 mg/m³ Workers Systemic
DNEL Short term Dermal 0.6 mg/kg bw/day Workers Systemic
DNEL Short term Inhalation 2.1 mg/m³ Workers Systemic
methanol DNEL Short term Oral 4 mg/kg bw/day General population Systemic
DNEL Long term Oral 4 mg/kg bw/day General population Systemic
DNEL Short term Dermal 4 mg/kg bw/day General population Systemic
DNEL Short term Dermal 20 mg/kg bw/day Workers Systemic
DNEL Long term Inhalation 26 mg/m³ General population Local
toluene DNEL Long term Oral 8.13 mg/kg bw/day General population Systemic
DNEL Long term Inhalation 56.5 mg/m³ General population Local
PNECs
Product/ingredient name Compartment Detail Value Method Detail
butan-1-ol Fresh water 0.082 mg/l -
Marine water 0.0082 mg/l -
Fresh water sediment 0.178 mg/kg -
Marine water sediment 0.0178 mg/kg -
Soil 0.015 mg/kg -
Sewage Treatment Plant 2476 mg/l -
xylene Fresh water 0.327 mg/l -
Marine water 0.327 mg/l -
Sewage Treatment Plant 6.58 mg/l -
Fresh water sediment 12.46 mg/kg dwt -
Marine water sediment 12.46 mg/kg dwt -
Soil 2.31 mg/kg -
ethylbenzene Fresh water 0.1 mg/l Assessment Factors
Marine water 0.01 mg/l Assessment Factors
Sewage Treatment Plant 9.6 mg/l Assessment Factors
Fresh water sediment 13.7 mg/kg dwt Equilibrium Partitioning
Marine water sediment 1.37 mg/kg dwt Equilibrium Partitioning
Soil 2.68 mg/kg dwt Equilibrium Partitioning
Activator 0613 2Lt

Secondary Poisoning 20 mg/kg -
methanol Fresh water 20.8 mg/l Assessment Factors
Marine water 2.08 mg/l Assessment Factors
Sewage Treatment Plant 100 mg/l Assessment Factors
Fresh water sediment 77 mg/kg Equilibrium Partitioning
Marine water sediment 7.7 mg/kg Equilibrium Partitioning
Soil 100 mg/kg Assessment Factors
toluene Fresh water 0.68 mg/l Sensitivity Distribution
Marine water 0.68 mg/l Sensitivity Distribution
Sewage Treatment Plant 13.61 mg/l Sensitivity Distribution
Fresh water sediment 16.39 mg/kg dwt Equilibrium Partitioning
Marine water sediment 16.39 mg/kg dwt -
8.2 Exposure controls

Appropriate engineering : Use only with adequate ventilation. Use process enclosures, local exhaust ventilation
controls or other engineering controls to keep worker exposure to airborne contaminants below
any recommended or statutory limits. The engineering controls also need to keep gas,
vapour or dust concentrations below any lower explosive limits. Use explosion-proof
ventilation equipment.
Individual protection measures
Hygiene measures : Wash hands, forearms and face thoroughly after handling chemical products, before
eating, smoking and using the lavatory and at the end of the working period.
Appropriate techniques should be used to remove potentially contaminated clothing.
Contaminated work clothing should not be allowed out of the workplace. Wash
contaminated clothing before reusing. Ensure that eyewash stations and safety
showers are close to the workstation location.
Eye/face protection : Chemical splash goggles and face shield.
Skin protection
Hand protection : Chemical-resistant, impervious gloves complying with an approved standard should be
worn at all times when handling chemical products if a risk assessment indicates this is
necessary. Considering the parameters specified by the glove manufacturer, check
during use that the gloves are still retaining their protective properties. It should be
noted that the time to breakthrough for any glove material may be different for different
glove manufacturers. In the case of mixtures, consisting of several substances, the
protection time of the gloves cannot be accurately estimated. When prolonged or
frequently repeated contact may occur, a glove with a protection class of 6
(breakthrough time greater than 480 minutes according to EN 374) is recommended.
When only brief contact is expected, a glove with a protection class of 2 or higher
(breakthrough time greater than 30 minutes according to EN 374) is recommended.
The user must check that the final choice of type of glove selected for handling this
product is the most appropriate and takes into account the particular conditions of use,
as included in the user's risk assessment.
butyl rubber
Body protection : Personal protective equipment for the body should be selected based on the task being
performed and the risks involved and should be approved by a specialist before
handling this product. When there is a risk of ignition from static electricity, wear anti-
static protective clothing. For the greatest protection from static discharges, clothing
should include anti-static overalls, boots and gloves.
Other skin protection : Appropriate footwear and any additional skin protection measures should be selected
based on the task being performed and the risks involved and should be approved by a
specialist before handling this product.
Respiratory protection : Respirator selection must be based on known or anticipated exposure levels, the
hazards of the product and the safe working limits of the selected respirator. If workers
are exposed to concentrations above the exposure limit, they must use appropriate,
certified respirators. Use a properly fitted, air-purifying or air-fed respirator complying
with an approved standard if a risk assessment indicates this is necessary. Wear a
respirator conforming to EN140. Filter type: organic vapour (Type A) and particulate
filter P3

Activator 0613 2Lt

Environmental exposure : Emissions from ventilation or work process equipment should be checked to ensure
controls they comply with the requirements of environmental protection legislation. In some
cases, fume scrubbers, filters or engineering modifications to the process equipment
will be necessary to reduce emissions to acceptable levels.
SECTION 9: Physical and chemical properties

The conditions of measurement of all properties are at standard temperature and pressure unless otherwise indicated.
9.1 Information on basic physical and chemical properties

Appearance
Physical state : Liquid.
Colour : Straw.
Odour : Not available.
Odour threshold : Not available.
Melting point/freezing point : May start to solidify at the following temperature: <-20.15°C (<-4.3°F) This is based
on data for the following ingredient: 2,4,6-tris(dimethylaminomethyl)phenol.
Weighted average: -95.77°C (-140.4°F)
Initial boiling point and : >37.78°C (>100°F)
boiling range
Flammability (solid, gas) : liquid
Upper/lower flammability or : Greatest known range: Lower: 1.4% Upper: 11.3% (butan-1-ol)
explosive limits
Flash point : Closed cup: 21°C (69.8°F)
Auto-ignition temperature :
Ingredient name °C °F Method
butan-1-ol 355 671 EU A.15
Decomposition temperature :
pH : Not applicable.
Not applicable. insoluble in water.
Viscosity : Kinematic (40°C): >21 mm2/s
Solubility(ies) :
Media Result
cold water Not soluble
Miscible with water : No.

Partition coefficient: n-octanol/ : Not applicable.
water
Vapour pressure :
Vapour Pressure at 20˚C Vapour pressure at 50˚C
Ingredient name mm Hg kPa Method mm Hg kPa Method
ethylbenzene 9.3 1.2
Relative density : 0.87

Vapour density : Highest known value: 3.7 (Air = 1) (xylene). Weighted average: 3.02 (Air = 1)
Explosive properties : The product itself is not explosive, but the formation of an explosible mixture of
vapour or dust with air is possible.
Oxidising properties : Product does not present an oxidizing hazard.
Particle characteristics
Median particle size : Not applicable.

Activator 0613 2Lt
SECTION 10: Stability and reactivity

10.1 Reactivity : No specific test data related to reactivity available for this product or its ingredients.
10.2 Chemical stability : The product is stable.
10.3 Possibility of : Under normal conditions of storage and use, hazardous reactions will not occur.
hazardous reactions
10.4 Conditions to avoid : When exposed to high temperatures may produce hazardous decomposition products.
Refer to protective measures listed in sections 7 and 8.
10.5 Incompatible materials : Keep away from the following materials to prevent strong exothermic reactions:
oxidising agents, strong alkalis, strong acids.
10.6 Hazardous : Depending on conditions, decomposition products may include the following
decomposition products materials: carbon oxides nitrogen oxides Formaldehyde. metal oxide/oxides
SECTION 11: Toxicological information

11.1 Information on toxicological effects
Acute toxicity
Product/ingredient name Result Species Dose Exposure
butan-1-ol LC50 Inhalation Vapour Rat 24000 mg/m³ 4 hours
LD50 Dermal Rabbit 3400 mg/kg -
LD50 Oral Rat 790 mg/kg -
xylene LD50 Dermal Rabbit 1.7 g/kg -
LD50 Oral Rat 4.3 g/kg -
N-(3-(trimethoxysilyl)propyl) LD50 Dermal Rabbit >2000 mg/kg -
ethylenediamine
ethylbenzene LC50 Inhalation Vapour Rat 17.8 mg/l 4 hours
LD50 Dermal Rabbit 17.8 g/kg -
LD50 Oral Rat 3.5 g/kg -
2,4,6-tris LD50 Dermal Rabbit 1.28 g/kg -
(dimethylaminomethyl)
phenol
LD50 Dermal Rat 1280 mg/kg -
3,6-diazaoctanethylenediamin LD50 Dermal Rabbit 1465 mg/kg -
methanol LC50 Inhalation Vapour Rat 64000 ppm 4 hours
LD50 Dermal Rabbit 15800 mg/kg -
toluene LC50 Inhalation Vapour Rat 49 g/m³ 4 hours
LD50 Dermal Rabbit 8.39 g/kg -
Conclusion/Summary : There are no data available on the mixture itself.
Acute toxicity estimates
Product/ingredient name Oral (mg/ Dermal Inhalation Inhalation Inhalation
kg) (mg/kg) (gases) (vapours) (dusts
(ppm) (mg/l) and mists)
(mg/l)

Activator 0613 2Lt

Activator 0613 2Lt 1550.6 5997.7 N/A 38.8 N/A
butan-1-ol 790 3400 N/A 24 N/A
xylene 4300 1700 N/A 11 N/A
N-(3-(trimethoxysilyl)propyl)ethylenediamine 2413 N/A N/A N/A N/A
ethylbenzene 3500 17800 N/A 17.8 N/A
2,4,6-tris(dimethylaminomethyl)phenol 1200 1280 N/A N/A N/A
3,6-diazaoctanethylenediamin 1716 1465 N/A N/A N/A
methanol 100 300 64000 3 N/A
toluene 5580 8390 N/A 49 N/A
Irritation/Corrosion
Product/ingredient name Result Species Score Exposure Observation
xylene Skin - Moderate irritant Rabbit - 24 hours 500 -
mg
2,4,6-tris Skin - Visible necrosis Rabbit - 4 hours 7 days
(dimethylaminomethyl)phenol
Conclusion/Summary : Not available.
Skin : There are no data available on the mixture itself.
Eyes : There are no data available on the mixture itself.
Respiratory : There are no data available on the mixture itself.
Sensitisation
Product/ingredient name Route of Species Result
exposure
3,6-diazaoctanethylenediamin skin Guinea pig Sensitising
Conclusion/Summary
Skin : There are no data available on the mixture itself.
Respiratory : There are no data available on the mixture itself.
Mutagenicity
Carcinogenicity
Reproductive toxicity
Teratogenicity
Conclusion/Summary :
There are no data available on the mixture itself.
Specific target organ toxicity (single exposure)
Product/ingredient name Category Route of Target organs
exposure
butan-1-ol Category 3 - Respiratory tract
irritation
Category 3 Narcotic effects
xylene Category 3 - Respiratory tract
irritation
N-(3-(trimethoxysilyl)propyl)ethylenediamine Category 3 - Respiratory tract
irritation
methanol Category 1 - -
toluene Category 3 - Narcotic effects
Specific target organ toxicity (repeated exposure)
Product/ingredient name Category Route of Target organs
exposure
ethylbenzene Category 2 - hearing organs
toluene Category 2 - -

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Aspiration hazard
Product/ingredient name Result
xylene ASPIRATION HAZARD - Category 1
ethylbenzene ASPIRATION HAZARD - Category 1
toluene ASPIRATION HAZARD - Category 1
Information on likely routes : Not available.

of exposure
Potential acute health effects
Eye contact : Causes serious eye damage.
Inhalation : Can cause central nervous system (CNS) depression. May cause drowsiness or
dizziness. May cause respiratory irritation.
Skin contact : Causes skin irritation. Defatting to the skin. May cause an allergic skin reaction.
Ingestion : Harmful if swallowed. Can cause central nervous system (CNS) depression.
Symptoms related to the physical, chemical and toxicological characteristics

Eye contact : Adverse symptoms may include the following:
pain
watering
redness
Inhalation : Adverse symptoms may include the following:
respiratory tract irritation
coughing
nausea or vomiting
headache
drowsiness/fatigue
dizziness/vertigo
unconsciousness
Skin contact : Adverse symptoms may include the following:
pain or irritation
redness
dryness
cracking
blistering may occur
Ingestion : Adverse symptoms may include the following:
stomach pains
Delayed and immediate effects as well as chronic effects from short and long-term exposure
Short term exposure
Potential immediate : Not available.
effects
Potential delayed effects : Not available.
Long term exposure
Potential immediate : Not available.
effects
Potential delayed effects : Not available.
Potential chronic health effects
Not available.
General : Prolonged or repeated contact can defat the skin and lead to irritation, cracking and/
or dermatitis. Once sensitized, a severe allergic reaction may occur when
subsequently exposed to very low levels.
Carcinogenicity : No known significant effects or critical hazards.

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Mutagenicity : No known significant effects or critical hazards.
Reproductive toxicity : No known significant effects or critical hazards.
Other information : Not available.
SECTION 12: Ecological information

12.1 Toxicity
Product/ingredient name Result Species Exposure
butan-1-ol Acute LC50 1376 mg/l Fish 96 hours
N-(3-(trimethoxysilyl)propyl) EC50 597 mg/l Fish 96 hours
ethylenediamine
ethylbenzene Acute EC50 1.8 mg/l Fresh water Daphnia 48 hours
Chronic NOEC 1 mg/l Fresh water Daphnia - Ceriodaphnia dubia -
2,4,6-tris Acute LC50 175 mg/l Fish 96 hours
phenol
methanol Acute LC50 13 mg/l Fresh water Fish - Trout 96 hours
12.2 Persistence and degradability

Product/ingredient name Test Result Dose Inoculum
ethylbenzene - 79 % - Readily - 10 days - -
Product/ingredient name Aquatic half-life Photolysis Biodegradability
xylene - - Readily
ethylbenzene - - Readily
toluene - - Readily
12.3 Bioaccumulative potential

Product/ingredient name LogPow BCF Potential
butan-1-ol 1 - Low
xylene 3.12 7.4 to 18.5 Low
ethylbenzene 3.6 79.43 Low
2,4,6-tris 0.219 - Low
phenol
3,6-diazaoctanethylenediamin -1.66 to -1.4 - Low
methanol -0.77 - Low
toluene 2.73 8.32 Low
12.4 Mobility in soil

Soil/water partition : Not available.
coefficient (KOC)
Mobility : Not available.
12.5 Results of PBT and vPvB assessment

This mixture does not contain any substances that are assessed to be a PBT or a vPvB.
12.6 Other adverse effects : No known significant effects or critical hazards.

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SECTION 13: Disposal considerations

13.1 Waste treatment methods
Product
Methods of disposal : The generation of waste should be avoided or minimised wherever possible.
Disposal of this product, solutions and any by-products should at all times comply
with the requirements of environmental protection and waste disposal legislation
and any regional local authority requirements. Dispose of surplus and non-
recyclable products via a licensed waste disposal contractor. Waste should not be
disposed of untreated to the sewer unless fully compliant with the requirements of
all authorities with jurisdiction.
Hazardous waste : Yes.
Waste catalogue
Waste code Waste designation
08 01 11* waste paint and varnish containing organic solvents or other hazardous substances
Packaging
Methods of disposal : The generation of waste should be avoided or minimised wherever possible. Waste
packaging should be recycled. Incineration or landfill should only be considered
when recycling is not feasible.
Type of packaging Waste catalogue
Container 15 01 10* packaging containing residues of or contaminated by
hazardous substances
Special precautions : This material and its container must be disposed of in a safe way. Care should be
taken when handling emptied containers that have not been cleaned or rinsed out.
Empty containers or liners may retain some product residues. Vapour from product
residues may create a highly flammable or explosive atmosphere inside the
container. Do not cut, weld or grind used containers unless they have been cleaned
thoroughly internally. Avoid dispersal of spilt material and runoff and contact with
soil, waterways, drains and sewers.
SECTION 14: Transport information

ADR/RID ADN IMDG IATA
14.1 UN number UN1263 UN1263 UN1263 UN1263
14.2 UN proper PAINT RELATED PAINT RELATED PAINT RELATED PAINT RELATED
shipping name MATERIAL MATERIAL MATERIAL MATERIAL
14.3 Transport 3 3 3 3
hazard class(es)
14.4 Packing II II II II
group
14.5 No. Yes. No. No.
Environmental
hazards
Marine pollutant Not applicable. Not applicable. Not applicable. Not applicable.
substances
ADR/RID : None identified.
Tunnel code : (D/E)
ADN : The product is only regulated as an environmentally hazardous substance when transported in tank
vessels.
IMDG : None identified.
IATA : None identified.

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SECTION 14: Transport information
14.6 Special precautions for : Transport within user’s premises: always transport in closed containers that are
user upright and secure. Ensure that persons transporting the product know what to do in
the event of an accident or spillage.
14.7 Transport in bulk : Not available.

according to IMO
instruments
SECTION 15: Regulatory information

15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture
UK (GB)/REACH
Annex XIV - List of substances subject to authorisation
Annex XIV
None of the components are listed.
Substances of very high concern
None of the components are listed.
Ozone depleting substances
Not listed.
Annex XVII - Restrictions : Not applicable.
on the manufacture,
placing on the market
and use of certain
dangerous substances,
mixtures and articles
Seveso Directive
This product is controlled under the Seveso Directive.
Danger criteria
Category
P5c
SECTION 16: Other information

Indicates information that has changed from previously issued version.
Abbreviations and : ATE = Acute Toxicity Estimate
acronyms GB CLP = UK CLP (EC No 1272/2008) on the Classification, Labelling and
Packaging of Substances and Mixtures as amended by (EU Exit) Regulations 2019
No. 720 and amendments
DMEL = Derived Minimal Effect Level
DNEL = Derived No Effect Level
EUH statement = GB CLP-specific Hazard statement
N/A = Not available
PBT = Persistent, Bioaccumulative and Toxic
PNEC = Predicted No Effect Concentration
RRN = REACH Registration Number
SGG = Segregation Group
vPvB = Very Persistent and Very Bioaccumulative
Procedure used to derive the classification

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Classification Justification
Flam. Liq. 2, H225 On basis of test data
Acute Tox. 4, H302 Calculation method
Skin Irrit. 2, H315 Calculation method
Eye Dam. 1, H318 Calculation method
Skin Sens. 1, H317 Calculation method
STOT SE 3, H335 Calculation method
STOT SE 3, H336 Calculation method
Full text of abbreviated H statements
H225 Highly flammable liquid and vapour.
H226 Flammable liquid and vapour.
H301 Toxic if swallowed.
H302 Harmful if swallowed.
H304 May be fatal if swallowed and enters airways.
H311 Toxic in contact with skin.
H312 Harmful in contact with skin.
H314 Causes severe skin burns and eye damage.
H315 Causes skin irritation.
H317 May cause an allergic skin reaction.
H318 Causes serious eye damage.
H319 Causes serious eye irritation.
H331 Toxic if inhaled.
H332 Harmful if inhaled.
H335 May cause respiratory irritation.
H336 May cause drowsiness or dizziness.
H361d Suspected of damaging the unborn child.
H370 Causes damage to organs.
H373 May cause damage to organs through prolonged or repeated exposure.
H412 Harmful to aquatic life with long lasting effects.
Full text of classifications
Acute Tox. 3 ACUTE TOXICITY - Category 3
Acute Tox. 4 ACUTE TOXICITY - Category 4
Aquatic Chronic 3 LONG-TERM (CHRONIC) AQUATIC HAZARD - Category 3
Asp. Tox. 1 ASPIRATION HAZARD - Category 1
Eye Dam. 1 SERIOUS EYE DAMAGE/EYE IRRITATION - Category 1
Eye Irrit. 2 SERIOUS EYE DAMAGE/EYE IRRITATION - Category 2
Flam. Liq. 2 FLAMMABLE LIQUIDS - Category 2
Flam. Liq. 3 FLAMMABLE LIQUIDS - Category 3
Repr. 2 REPRODUCTIVE TOXICITY - Category 2
Skin Corr. 1B SKIN CORROSION/IRRITATION - Category 1B
Skin Corr. 1C SKIN CORROSION/IRRITATION - Category 1C
Skin Irrit. 2 SKIN CORROSION/IRRITATION - Category 2
Skin Sens. 1 SKIN SENSITISATION - Category 1
Skin Sens. 1B SKIN SENSITISATION - Category 1B
STOT RE 2 SPECIFIC TARGET ORGAN TOXICITY - REPEATED EXPOSURE - Category 2
STOT SE 1 SPECIFIC TARGET ORGAN TOXICITY - SINGLE EXPOSURE - Category 1
STOT SE 3 SPECIFIC TARGET ORGAN TOXICITY - SINGLE EXPOSURE - Category 3
History
Date of issue/ Date of : 12 July 2023
revision
Date of previous issue : 9 November 2022
Prepared by : EHS
Version : 1.02
Disclaimer

Activator 0613 2Lt

The information contained in this data sheet is based on present scientific and technical knowledge. The purpose of this
information is to draw attention to the health and safety aspects concerning the products supplied by us, and to
recommend precautionary measures for the storage and handling of the products. No warranty or guarantee is given in
respect of the properties of the products. No liability can be accepted for any failure to observe the precautionary
measures described in this data sheet or for any misuse of the products.

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Conforms to Regulation (EC) No.

1907/2006 (REACH), Annex II, as amended by UK REACH Regulation SI

SAFETY DATA SHEET

SECTION 1: Identification of the substance/mixture and of the company/

1.3 Details of the supplier of the safety data sheet

e-mail address of person : Product.Stewardship.EMEA@ppg.com

SECTION 2: Hazards identification

2.2 Label elements

Signal word : Danger

English (GB) United Kingdom (UK) 1/18

SECTION 2: Hazards identification

SECTION 3: Composition/information on ingredients

English (GB) United Kingdom (UK) 2/18

SECTION 3: Composition/information on ingredients

SECTION 4: First aid measures

English (GB) United Kingdom (UK) 3/18

SECTION 4: First aid measures

SECTION 5: Firefighting measures

5.2 Special hazards arising from the substance or mixture

English (GB) United Kingdom (UK) 4/18

SECTION 5: Firefighting measures

5.3 Advice for firefighters

SECTION 6: Accidental release measures

6.3 Methods and material for containment and cleaning up

6.4 Reference to other : See Section 1 for emergency contact information.

English (GB) United Kingdom (UK) 5/18

SECTION 7: Handling and storage

7.2 Conditions for safe storage, including any incompatibilities

7.3 Specific end use(s)

SECTION 8: Exposure controls/personal protection

English (GB) United Kingdom (UK) 6/18

SECTION 8: Exposure controls/personal protection

Recommended monitoring : Reference should be made to appropriate monitoring standards. Reference to

English (GB) United Kingdom (UK) 7/18

SECTION 8: Exposure controls/personal protection

SECTION 8: Exposure controls/personal protection

8.2 Exposure controls

English (GB) United Kingdom (UK) 9/18

SECTION 8: Exposure controls/personal protection

SECTION 9: Physical and chemical properties

9.1 Information on basic physical and chemical properties

Miscible with water : No.

Relative density : 0.87

English (GB) United Kingdom (UK) 10/18

SECTION 10: Stability and reactivity

10.2 Chemical stability : The product is stable.

SECTION 11: Toxicological information

English (GB) United Kingdom (UK) 11/18

SECTION 11: Toxicological information

English (GB) United Kingdom (UK) 12/18

SECTION 11: Toxicological information

Information on likely routes : Not available.

Symptoms related to the physical, chemical and toxicological characteristics

English (GB) United Kingdom (UK) 13/18

SECTION 11: Toxicological information

Other information : Not available.

SECTION 12: Ecological information

12.2 Persistence and degradability

12.3 Bioaccumulative potential

12.4 Mobility in soil