Chemistry

Practice Quiz
Target NEET/JEE 2022
XIII AMINES Time : 1hr.

SINGLE CORRECT CHOICE TYPE

1. The product (A) of the reaction

3 NaN
CH2COOH 
H SO , heat
A
2 4

(A) CH2CH2NH2 (B) CH2CONH2

(C) CH2NH2 (D) NH2

2. The reaction of RCONH2 with a mixture of Br2 and aqueous KOH gives RNH2 as the main
product. The intermediate(s) involved in this reaction is(are):

(A) RCONHBr (B) RCONBrK 
(C) R – N = C = O (D) all of these

3. Amphetamine, a CNS(Central Nervous System) stimulant, has the structural formula

C6H5CH2CH(NH2)CH3. Which of the following sets of reactants should be hydrogenated in
the presence of nickel catalyst to prepare amphetamine?
(A) C6H5CH2CHO and CH3NH2 (B) C6H5CH2COCH3 and NH3
(C) C6H5CH2NH2 and CH3CHO (D) C6H5CH = CHCH3 and NH3

4. Consider the following reaction sequence

H2 ,Ni HNO2
A   B   C2H5OH
The starting compound (A) is:
(A) CH3CN (B) CH3NC
(C) C2H5CN (D) CH3NO2

5. How many maximum number of CH3I molecules can be absorbed by one molecule of the
following compound?
NH2

(A) 3 (B) 4
(C) 2 (D) 5

6. Which of the following compounds gives a secondary amine on reduction?

(A) Nitromethane (B) Nitrobenzene
(C) Methyl isocyanide (D) Methyl cyanide

7. Which one of the following compounds will produce a water-insoluble yellow oily liquid of
nitrosamine on reaction with NaNO2 and dilute HCl at 0oC?
(A) Ethylamine (B) Methylamine
(C) Diethylamine (D) Triethylamine

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 8. Among the compounds
O
(I) ( II ) ( III ) ( IV )
N N N N
H H H H
The order of basicity is:
(A) IV > I > III > IV (B) III > I > IV > II
(C) II > I > III > IV (D) I > III > II > IV
9. The major product of the reaction
CN
H2 is:
 
Pt
O

NH2
(A) (B)
N
O
H

(C) (D)
N
N
H

10. The compound that will react most readily with NaOH to form methanol is:
 
(A)  CH3  4 NI (B) CH3OCH3 (C)  CH3 3 SI (D) (CH3)3CCI
POCl3
11. HCONHR 
Pyridine
  A   H2O : (A) in the reaction is:
 
(A) RCN = NOH (B) R – N = C = O (C) R – C  N (D) R  N  C

12. Reaction of cyclohexanone with dimethylamine in the presence of catalytic amount of an

acid forms a compound if water during the reaction is continuously removed. The compound
formed is generally known as:
(A) a schiff’s base (B) an enamine
(C) an imine (D) an amine

13. In carbylamine reaction

(A) the nucleophile is RNH2 and electrophile is: CCl2
(B) the nucleophile is primary amine and electrophile is CCl3
(C) the nucleophile is CCl3 and the electrophile is primary amine
(D) the attacking reagent is electrophile

14. One mole of an amine(A) consumes two moles of methyl bromide to give a quaternary
ammonium salt. The amine (A) is:
(A) (CH3)3CCH2NH2 (B) (CH3)2NCH2CH3

(Piperidine)
(C) (D) (Pyridine)
N
N
H

15. Which among the following is amphoteric?

(A) CH3 – NH2 (B) (CH3)2 NH
(C) (CH3)3N (D) CH3CONH2

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 ASSERTION – REASONING TYPE
These questions given below consist of an Assertion (A) and the Reason (R). Use the following
keys to choose the appropriate answer
(A) If both (A) & (R) are correct and (R) is the correct explanation of (A).
(B) If both (A) & (R) are correct but (R) is not the correct explanation of (A).
(C) If (A) is correct but (R) is incorrect
(D) If (A) is incorrect but (R) is correct.
16. (A) Ammonolysis of alkyl halides is not a suitable method for the preparation of pure primary
amines.
(R) Ammonolysis of alkyl halides yields mainly secondary amines.

17. (A) Carbylamine reaction involves chemical reaction between 1o amine and chloroform in
basic medium.
(R) In carbylamine reaction, – NH2 group changes into – NC group.

18. (A) The main product of reaction of alcoholic silver nitrite and ethyl bromide is nitroethane.
(R) Silver nitrite is predominantly covalent compound.

19. (A) In strongly acidic solutions, aniline becomes more reactive towards electrophile
reagents.
(R) The amino group being completely protonated in strongly acidic solution, the lone pair of
electrons on the nitrogen is no longer available for resonance.

20. (A) CuCl2 gives a deep blue coloured solution with ethylamine.
(R) Ethylamine molecules co-ordinate with cupric ions forming a blue coloured complex.

21. (A) Amines are more basic than esters and ethers.
(R) Nitrogen is less electronegative than oxygen. It is better position to accommodate the
positive charge on the proton.

MORE THAN ONE OPTION MAY BE CORRECT

22. (i) CH I(excess)
 CH3 2 CHCH2NHCH2CH2CH3  3
(X)

(ii) OH

Heat
Product(s) 
H O

2

The end product(s) of above reaction is/are:

(A) (CH3)2CHCH2N(CH3)2 (B) CH3CH2CH2N(CH3)2
(C) CH3CH = CH2 (D) (CH3)2C = CH2

23. HNO
 CH3 2 CCH2C(CH3 )2NH2  Product(s)
2
Heat

OH
The product(s) of above reaction is/are:
(A) CH3COCH3 (B) (CH3)2C = CH2
(C) (CH3)2CHNH2 (D) CH3CHCH3

OH

24. Which of the following reaction(s) give aromatic products?

(A) HC  CH  Re d hot iron
 (B) CHO
873 K NH NH

2
H / 
2

CHO
(C) conc.H2SO4
CH3COCH3   (D) 1. CH3NH2
CH3CH2 CHO  
Heat 2. HCl

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 25. Which of the following sequence of reagent(s) is/are used to carry out the following
conversion?
CH3CH2 OH  CH3CH2NH2
(A) SOCl2, NaCN, H2/Ni (B) CrO3, NH3, H2/Ni
(C) KMnO4, SOCl2, NH3, , NaOBr (D) Cu/300°C, NH3, LiAlH4

26. CH3

H3 O
H3C C O OH    P1  P2

P2  FeCl3  Violet colour

P1  NaOI 
 P3  P4
yellow
Choose correct statements from the following regarding the above reaction.
Sodalim e Ag
(A) P4 
Heat
Benzene (B) P3   Acetylene
2,4DNP Br2 /H2O
(C) P1   Coloured compound (D) P2   White ppt. 

27. Which of the following reaction(s) produce(s) amine?

(A) CH3 (B) CH3 O
NH3
CH3 C CH2Br   CH3 C C Br2 /NaOH
NH2  
CH3
Br
(C) NO2 (D) (i) Sn/HCl
CH2 C N 
(ii) NaNO /HCl

2

(i) Sn/HCl

(ii) NaNO2 /HCl


INTEGER ANSWER TYPE

28. An organic compound (A) on reduction gives a compound(B) which on reaction with CHCl3
and KOH forms (C) which on catalytic reduction gives N – methyl aniline. How many oxygen
atoms are present in one molecule of (A)?

29. A compound(X) on treatment with PCl5 and then with NH3 gives(Y). When (Y) is treated with
Br2/KOH, (Z) is formed. (Z) on treatment with HNO2 and then boiling produces ortho cresol.
How many functional groups are present in compound (X)?

30. The molecular formula of an organic compound(A) is C9H13NO. It can be resolved into
enantiomers. (A) does not react with Br2 water. When treated with dil.H2SO4, (A) forms
another resolvable compound (B) (C9H14O3) which gives effervescence with NaHCO3. (B) on
treatment with NaBH4 yields (C) (C9H16O3) which on heating with conc.H2SO4 yields ester
(D) (C9H14O2). Compound (A) on reduction with LiAlH4 followed by treatment with H2SO4
forms the following compound.
H
N

How many pi-bond(s) is/are present in one molecule of (A)?

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 ANSWERS
Amines
1. C 2. D 3. B 4. A
5. B 6. C 7. C 8. D
9. C 10. A 11. D 12. B
13. A 14. C 15. D 16. C
17. A 18. A 19. D

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