AtoZ CHEMISTRY NITROGEN CONTAINING COMPOUNDS

NITROGEN CONTAINING COMPOUNDS

1. Alkyl Nitrites, Nitroalkane

Q 1. Which of the following is not nitrogen containing Q 10. Which of the following Nitroalkane doesn’t
Compounds? undergo hydrolysis ?
(A) R – NC (B) R – CN (A)  CH3  CNO2 (B)  CH3  CHNO2
3 2
(C) R – O – NO (D) None of these
(C) CH3CH 2 NO2 (D) All of these
Q 2. The two form of HNO2 is
Q 11. In basic medium, reduction of C2H5 NO2 with
(A) HONO,HNO2 (B) HO2 N,HNO2
SnCl2  HCl gives
(C) HNOO,HNO2 (D) NHO2 ,HNO4
(A) CH3CH 2 NHOH
Q 3. Which of the following is called ester of NO2
(B) CH3CH  N  ON
(A) Nitroalkane (B) Alkylnitrites
(C) Oxime (D) Alkyl isocynid (C) both a & b
Q 4. In the reaction (D) None of these
2C2H5OH  N2O3  product, is Q 12. In the reaction
R  CH2  NO2  R 'MgX  Product is
(A) C2H5 NO2 (B) C2H5ONO
(A) R 'CH 2 NO2 (B) R’H
(C) CH5 NOC2H5 (D) C2H5OC2H5
(C) R  CH  N  OH (D) None of these
Q 5. Which compound has characteristics smell of
Q 13. In the reaction
apple?
HCl
(A) RNO2 (B) RNC R 2CH  NO2 
 Product
(C) R  ONO (D) R  C  N  OH (A) R 2C  O (B) R 2CHO
Q 6. In the reaction (C) R 2 C  NO 2 (D) None of these
 |
Cl  CH2  COOH  NaNO2 
 Cl
The product A is
(A) O2 N  CH2COOH (B) CH3NO2
(C) Cl  CH2  CONO2 (D) None of these
2. Alkane Nitrile & Isonitrile, Amines
Q 7. In the reaction Q 1. Butanonitrile may be prepared by
Cl2 / NaOH
CH3NO2  product, is (A) propyl alcohol + KCN
(B) butyl alcohol + KCN
(A) CCl3NO2 (B) CHCl3 (C) butyl chloride + KCN
(C) CH3CN (D) None of these (D) propyl chloride + KCN
Q 8. Which of the following nitroalkanes gives red Q 2. The best method for preparation of Me3C-CN is
colour with HNO2 ? (A) to react Me3C  OH with HCN

(A)  CH3 3 CNO2 (B)  CH3 2 CHNO2 (B) to react Me3C  Br with NaCN
(C) to react Me3C  Br with ClCn
(C) CH3CH 2 NO2 (D) None of these
Q 9. Write the product in the following reactions: (D) to react Me3C  Li with NH2CN
(A) C2H5NO2 Sn + HCl Q 3. CH 3CH 2 Cl 
NaCN
  x  
Ni / H2
  Y
(B) C2H5NO2 Zn dust + NH4Cl

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
Acetic anhydride
  Z CH3
(Z) in the above reaction sequence is CH3 C NH2
(A) CH3CH2 CH2 NHCOCH3
Q 11. CH3 is a
(B) CH3CH2 CH2 NH2 (A) primary amine
(C) CH3CH2 CH2 CONHCH3 (B) secondary amine
(C) tertiary amine
(D) CH3CH2 CH2 CONHCOCH3 (D) quaternary salt
Q 4. Which of the following is obtained in Q 12. The reaction between primary amine, chloroform
carbylamine reaction ? and few drops of alcoholic KOH is known as
(A) C2 H5 NH2 (B) COCl2 (A) Hofmann’s reaction
(B) Kolbe’s reaction
(C) C6 H5CN (D) C6 H5 NC
(C) Carbylamine reaction
Q 5. Ethyl chloride on heating with AgCN forms a (D) Reimer – Tiemann’s reaction
compound (X). The functional isomer of (X) is Q 13. Gabriel phthalimide synthesis can be used to
(A) C2 H5 NC (B) C2 H5 NH2 prepare
(A) ethanamine
(C) C2 H5CN (D) None of these
(B) N-methylmethanamine
Q 6. State the product available by the following (C) N,N-dimethylmethanamine
reaction: (D) p-toluidine
CH3CH2CN  ethanol  H 2 O 
conc. H2SO4

Q 14. Primary amines are identified by
(A) Hofimann’s reaction
(A) ethyl formate + NH3
(B) Carbylamine reaction
(B) ethyl propanote + NH3 (C) Friedel-Crafts reaction
(C) ethyl butanoate + NH3 (D) Biuret reaction
Q 15. In the given reaction
(D) ethyl acetate + NH3 H2SO4
CH3 – CH2 – C – CH3 +
Q 7. CH3 NH2  CHCl3  KOH  nitrogen H 2O/H ,
NOH
containing compound is (A) and (B) are
(A) CH3  C  N (B) CH3  NH  CH3 (A) CH3COOH and C2 H5 NH 2
  
(C) CH3  N  C (D) CH3  N  C (B) CH3CH 2 COOH and CH3 NH2
Q 8. Carbylamine test is not answered by (C) CH3 NH2 and C2 H5 NH 2
(A) aprotic acid (B) neutral compound
(D) CH3COOH and CH3CH 2 COOH
(C) Lewis acid (D) Lewis base
Q 9. Write the products in the following reactions: Q 16. Hinsberg’s reagent is
(A). CH3 – C ≡N + H2O (A) benzene sulphonamide
(B). CH3 – C ≡N + Ni/H2 (B) benzene sulphonic acid
(C) benzene sulphuryl chloride
(C). CH3 – C ≡N + SnCl2/HCl
(D) benzene sulphonyl chloride
(D). CH3 – C ≡N + CH3MgCl
Q 17. Which one ofthe following on reduction with
Q 10: (A). R –N≡C + S8 ?
(B). R –N≡C + 2HgO ?
LiAlH 4 yields a secondary amine ?
(C). R –N≡C + O3 ? (A) Methyl cyanide (B) Nitroethane
(C) Methyl isocyanide (D) Acetamide
Q 18. By passing the mixture of the vapours of alcohol

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and excess of ammonia over heated alumina at (B) CH3CH2 NHCH3

623K, the main product obtained is CH3 – CH – NH2
(A) primary amine
(B) secondary amine (C) CH 3
(C) tertiary amine CH3 – N – CH3
(D) a mixture of pri- sec- & tert-amines CH 3
(D)
Q 6. Ethyl isocyanide on hydrolysis in acidic medium
gives :
(A) ethanoic acid and ammonium salt
(B) propanoic acid and ammonium salt
(C) ethylamine salt and methanoic acid
3. Test of Amines, Reaction of Amines (D) methylamine salt and ethanoic acid
Q 1. Secondary amine forms yellow oily liquid with Q 7. In the following sequence of reaction, the major
nitrous acid, which on warming with phenol and product (C) is
  A 

conc. H 2SO4 gives a brown or red colour and CH3CH2 I 
NaCN OH
Partial hydrolysis

which at once changes into blue – green. This
reaction is called as
 B 
Br / NaOH
2
  C
(A) Carbylamine reaction (A) CH3CH 2 NH 2
(B) Liebermann’s nitroso reaction O
(C) Gabriel phthalimide reaction
(B) CH3CH2 C NHBr
(D) Hofmann’s mustard oil reaction
Q 2. Tertiary amines dissolve in cold nitrous acid to (C) CH3CH 2COONH 4
form salt, which on warming decomposes to give O
(A) R 3 N.HNO2 (B) R 2 N.NO (D) CH3 CH2 C NHBr2
(C) ROH (D) R 2 N.NO  ROH Q 8. The major organic product formmed from the
following reaction,
Q 3. Acetamide reacts with NaOBr in alkaline O
medium to form: (i) CH NH3 2
(ii) LiAIH4 (iii) H2O Is
(A) NH3 (B) CH3 NH2
O – NHCH 3
(C) CH3 CN (D) R 2 N.NO  ROH (A) (B) NHCH 3
Q 4. The compound that will react most readily with NHCH 3 NHCH 3
NaOH to form methanol is (C) OH (D) OH

(A)  CH3  4 N I

(B) CH3OCH3

Q 9. In order to distinguish between C2 H5 NH 2 and
(C)  CH3 3 SI (D)  CH3 3 CCl

C6 H5 NH 2 , which of the following reagents is
Q 5. An organic compound, C3 H 9 N (A) when treated useful ?
with nitrous acid gave an alcohol and N 2 gas (A) Hinsberg reagent (B)   naphthol

was evolved. (A) on warming with CHCl3 and (C) CHCl3 / KOH (D) NaOH

caustic potash gave (C) which on reduction gave Q 10. An organic compound ‘A’ containing nitrogen,
isopropyl methylamine. on acid catalysed hydrolysis produces a water
Predict the structure of (A). soluble organic compound ‘B’ and a gaseous
compound ‘C’ When methyl magnesium bromide
(A) CH3CH2 CH2 NH2

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is slowly added to ‘A’ in 1 : 1 ratio and The end product B of the above reaction is
hydrolysed, it produces a compound which can
be obtained by dry distillation of calcium salt of
‘B’. The compound ‘A’ is (A) (B)
(A) N-methyl methanamide
(B) N-ethyl methanamide
(C) N,N-dimethyl methanamide
(D) methyl isocyanide (C) (D)
Q 11. The rate Hofmann’s bromamide degradation with
following amide will follow the order

Q 15.
The correct route for the above transformation is
(A) (i) Br2/KOH (ii) H 2 / Pt (iii) CH3COOH
III  I  IV  II
(B) (i)P2O5/Heat (ii) H2/Pt (iii)  CH3CO2 2 O
(A)
(B) II  IV  I  III
(C) I  II  III  IV (C) (i)  CH3CO 2 O (ii) H2/Pt (iii) Br2 / KOH
(D) I  III  IV  II (D) (i) Br2 / KOH ; (ii) CH3COCl
Q 12. The amines that will give off N 2 upon treatment
with NaNO2 and dil. H 2SO4 is/are at 0 to 5°C
Q 16.
The final product (Y) is

(A) (B)
(A) (B)

(C) (D) None of these (C) (D)

HNO
Q 13. 
2  A (major)

(A) (B)

(C) (D)

Q 14.

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Answer Key
1. Alkyl Nitrites, Nitroalkane
(1). B (2). A (3). B
(4). B (5). C (6). B
(7). A (8). C
(9). (A). C2H5NH2 (B). C2H5NHOH
(10). C (11). C (12). B
(13). A

2. Alkane Nitrile & Isonitrile, Amines

(1). D (2). C (3). A
(4). D (5). C (6). B
(7). D (8). B
(9). (A). CH3COOH (B). CH3CH2NH2
(C). CH3CHO (D). CH3COCH3
(10). (A). R–N=C=O (B). R–N=C=O
(C). R–N=C=O
(11). A (12). C (13). A
(14). B (15). A (16). D
(17). C (18). A

3. Test of Amines, Reaction of Amines

(1). B (2). D (3). B
(4). A (5). C (6). C
(7). A (8). B (9). B
(10). A (11). A (12). D
(13). A (14). D (15). B

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