Chemistry Notes Abd17

SOLUTIONS
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PYQs-Solutions
CBSE 2022
Q: The vapour pressure of pure liquid X and pure liquid Y
at 25°C are 120 mm Hg and 160 mm Hg respectively. If
equal moles of X and Y are mixed to form an ideal
solution, calculate the vapour pressure of the solution.
Solution
pTotal = p°x χx + p°Y χB
χx = XB = 0.5
pTotal = (120 × 0.5) + (160 × 0.5)
= 140 mm Hg
CBSE 2023
Q: Answer the following questions :
(a) State Henry's law and explain why are the tanks used
by scuba divers filled with air diluted with helium (11.7%
helium, 56.2% nitrogen and 32.1% oxygen) ?
(b) Assume that argon exerts a partial pressure of 6 bar.
Calculate the solubility of argon gas in water. (Given
Henry's law constant for argon dissolved in water,
ΚΗ = 40 kbar)
Solution
(a) Henry's law: The partial pressure of the gas in vapour
phase (p) is proportional to the mole fraction of the gas
(x) in the solution.
The pressure underwater is high, so the solubility of
gases in blood increases. When the diver comes to
surface the pressure decreases so does the solubility
causing bubbles of nitrogen in blood, to avoid this
situation and maintain the same partial pressure of
nitrogen underwater too, the dilution is done.
Solution
(b) p = KH X
mole fraction of argon in water
x = p/KH
= 6/40 × 103 = 1.5 × 10-4
CBSE 2023
Q: When 19.5 g of F - CH2 - COOH (Molar mass = 78 g
mol-1), is dissolved in 500 g of water, the depression in
freezing point is observed to be 1°C. Calculate the degree of
dissociation of F - CH2 - COOH.
[Given: K for water = 1.86 K kg mol-1]
Solution
Electrochemistry
CBSE 2022
Solution
CBSE 2022
Solution
Solution
Solution
CBSE 2022
Solution
PYQ - Electrochemistry
CBSE 2022
Q:
(a) The standard Gibbs energy (ΔrG°) for the following cell
reaction is -300 kJ mol-1:
Zn(s) + 2Ag+(aq) → Zn2+ (aq) + 2Ag(s)
Calculate Ecell° for the reaction. (Given: IF = 96500
mol-1)
(b) Calculate λm° for MgCl2 if λ° values for Mg2+ ion and Cl-
ion are 106 S cm² mol-1 and 76.3 S cm2 mol-1
respectively.
Solution
(a)
(b)
CBSE 2023
Q: Rahul set-up an experiment to find resistance of aqueous KCl
solution for different concentrations at 298 K using a conductivity cell
connected to a Wheatstone bridge. He fed the Wheatstone bridge
with a.c. power in the audio frequency range 550 to 5000 cycles per
second. Once the resistance was calculated from null point he also
calculated the conductivity K and molar conductivity m and recorded
his readings in tabular form.
S. No. Conc.(M) k S cm-1 λm S cm2 mol-1
1. 1.00 111.3 × 10-3 111.3
2. 0.10 12.9 × 10-3 129.0
3. 0.01 1.41 × 10-3 141.0

CBSE 2023
Q: (a) Why does conductivity decrease with dilution?
Solution
The number of ions per unit volume decreases on dilution.
CBSE 2023
Q: (b) If λm° of KCl is 150.0 S cm2 mol-1, calculate the degree
of dissociation of 0.01 M KCl.
Solution
CBSE 2023
Q: (c) Amit, a classmate of Rahul repeated the same
experiment with CH3COOH solution instead of KCl solution.
Give one point that would be similar and one that would be
different in his observations as compared to Rahul.
Solution
Similarity: λm increases with dilution for both electrolytes.
Difference: For KCl the λm increases gradually whereas for
CH3COOH, Am increases steeply on dilution / In case of
CH3COOH, λm° cannot be obtained by extrapolation of λm° to
zero concentration whereas for KCl it can be obtained/
graphical explanation.
CBSE 2022
Q: In a plot of Am against the square root of concentration
(C1/2) for strong and weak electrolyte, the value of limiting
molar conductivity of a weak electrolyte cannot be obtained
graphically. Suggest a way to obtain this value. Also state the
related law, if any.
Solution
Limiting molar conductivity for weak electrolyte can be
obtained by using Kohlrausch law.
It states that limiting molar conductivity of an electrolyte is
the sum of conductivity of constituent ions.
CBSE
Q: Write the Nernst equation and calculate emf of the 2022
following cell at 298 K:
Cr | Cr3+ (0.1 M) || Fe2+ (0.01 M) | Fe
Solution
CHEMICAL KINETICS
Solution
Q: Calculate the overall order of a reaction which has the
rate expression
(a) Rate = k [A]1/2 [B]3/2
(b) Rate = k [A]3/2 [B]-1
Solution
Solution
Solution
Solution
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Solution
PYQ CHEMICAL KINETICS
CBSE 2022
Q: In the given reaction
N2(g) + 3H2(g) → 2NH3(g)
the rate of formation of NH3 is 3.6 × 10-4 mol L-1 s-1.
Calculate the
(i) rate of reaction, and
(ii) rate of disappearance of H2 (g).
Solution
(i)
(ii)
CBSE 2022
Q: Read the passage given below and answer the questions that follow:
The rate law for a chemical reaction relates the reaction rate with the
concentrations or partial pressures of the reactants. For a general reaction
aA + bB → C with no intermediate steps in its reaction mechanism,
meaning that it is an elementary reaction, the rate law is given by k[A]x [B]x,
where [A] and [B] express the concentrations of A and B in moles per litre.
Exponents x and y vary for each reaction and are determined
experimentally. The value of k varies with conditions that affect reaction
rate, such as temperature, pressure, surface area, etc.
The sum of these exponents is known as overall reaction order. A zero
order reaction has a constant rate that is independent of the concentration
of the reactants. A first order reaction depends on the concentration of only
one reactant. A reaction is said to be second order when the overall order
is two. Once we have determined the order of the reaction, we can go back
and plug in one set of our initial values and solve for k.
CBSE 2022
Q: (i) Calculate the overall order of a reaction which has the
following rate expression:
Rate = k[A]½ [B]3/2
Solution
CBSE 2022
Q: (ii) What is the effect of temperature on rate of reaction?
Solution
The rate of a reaction increases with the increase in
temperature.
CBSE 2022
Q: A first order reaction takes 77·78 minutes for 50%
completion. Calculate the time required for 30% completion
of this reaction. (log 10 = 1, log 7 = 0·8450)
Solution
CBSE 2023
Q: A first order reaction is 50% complete in 30 minutes at
300 K and in 10 minutes at 320 K. Calculate activation
energy (Ea) for the reaction.
[R= 8.314 J K-1 mol-1]
[Given: log 2 = 0.3010, log 30.4771, log 40.6021]
Solution
Solution
CBSE 2023
Q: The rate of a reaction doubles when temperature changes
from 27°C to 37°C. Calculate energy of activation for the
reaction. (R = 8.314 J K-1 mol-1)
(Given: log 2 = 0.3010, log 3 = 0.4771, log 4 0.6021)
Solution

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SOLUTIONS

S. No. Conc.(M) k S cm-1 λm S cm2 mol-1

1. 1.00 111.3 × 10-3 111.3

2. 0.10 12.9 × 10-3 129.0

3. 0.01 1.41 × 10-3 141.0

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