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No.

UNIT TEST – 1 (2023-2024)


Subject : 043 CHEMISTRY (SET-A) Max. Marks : 20
Class : XII Time: 45 minutes
th
Date : Mar 2023
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General Instructions:
(i) All questions are compulsory.
(ii) The question paper has FOUR sections and 9 questions. All questions are compulsory.
(iii) Section-A has 3 questions of 1 mark each; Section B has 3 questions of 2 marks each; Section-C
has 2 questions of 3 marks each; Section D has 1 question of 5 mark with internal choice.
(iv) Internal choices have been provided in some questions. A student has to attempt only one of the
alternatives in such questions.
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Section A 3 X 1= 3
1. Arrange the halogens F2, Cl2, Br2, I2 in order of their increasing reactivity with alkanes.
a. I2 < Br2 < Cl2 < F2 c. F2 < Cl2 < Br2 < I2
b. Br2 < Cl2 < F2 < I2 d. Br2 < I2 < Cl2 < F2
2. The increasing order of reduction of alkyl halides with zinc and dilute HCl is
a. R-Cl < R-I < R-Br c. R-I < R-Br < R-Cl
b. R-Cl < R-Br < R-I d. R-Br < R-I < R-Cl
3. Arrange the following in decreasing order of their boiling points
I. n-Butane III. n-Pentane
II. 2-Methylbutane IV. 2,2-Dimethylpropane
a. I > II > III > IV c. IV > III > II > I
b. II > III > IV > I d. III > II > IV > I
Section B 3X2=6
4. Write structures of different chain isomers of alkanes corresponding to the molecular formula C6H14.
Also, write their IUPAC names.
5. Write any two structures of different isomeric alkyl groups corresponding to the molecular formula
C5H11. Write IUPAC names of alcohols obtained by attachment of –OH groups at different carbons of
the chain.
6. Write the IUPAC names of the following compounds: a. (CH3)3CCH2C(CH3)3 b. (CH3)2C(C2H5)2

Section C 3 X 3 =9
7. Write the IUPAC names of the following compounds: a. CH2=C(CH2CH2CH3)2

b. c.

8. a. Write structures for each of the following compounds. Why are the given names incorrect? Write
correct IUPAC names. (i) 2-Ethylpentane (ii) 5-Ethyl – 3-methylheptane
b. Sodium salt of which acid will be needed for the preparation of propane? Write the chemical
equation for the reaction
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Section D 1 X 5 =5

9. a. How do you account for the formation of ethane during the chlorination of methane? [3]
b. Draw the cis and trans structures of Hex-2-ene. Which isomer will have higher b.p. and why? [2]
(OR)
c. An alkene ‘A’ on ozonolysis gives a mixture of ethanal and pentan-3-one. Write structure and
IUPAC name of ‘A’. [2]
d. An alkene ‘A’ contains three C – C, eight C – H s bonds and one C – C p bond. ‘A’ on ozonolysis
gives two moles of an aldehyde of molar mass 44 u. Write IUPAC name of ‘A’. [3]

 ……………………………….. All the Best ………………………………… 

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