PA CK SIZ ES AVAILA BLE 20 LITRES 200 LITRES 1000 LITRES 10,000 LITRES 20,000 LITRES TECH NICAL SUPPORT

Chemiphase will off er on- site technical support during all stage s of production. Technical support includes o n-site testi ng and results. PRODU CT SAFETY All Chemiphase products are thoroughly researched and tested. All products are also COSHH registered and come complete with delivery. For more information on any of our products or services please visit us on the Web at:
www.chemiphase.co.uk

Information Technology Solutions

Coldflow 402

Biodiesel Pour Point Additive for PME, SME Biodiesel Blends

PRODUCT DESCRIPTION
Chemiphase are proud to launch our latest development in biodiesel technology, a cold flow improver designed for biodiesels produced from blends of Palm Methyl Esters, Tallow Methyl Esters and other heavy oils. Coldflow 402 will provide cold weather When it becomes colder still, the biodiesel will form into a gel that will eventually set solid in the fuel tank. To achieve the best results possible with Coldflow 402 we recommend in house testing. Depending on the type of oils used to make your biodiesel the pour point of the biodiesel will vary due to quality of the produced fuel, i.e. virgin vegetable oils have a lower pourpoint than used cooking oil mixtures.

protection and improve performance of storage and stability in biodiesels produced from blends of all ester based fuels. Coldflow 402 will significantly improve the point at which biodiesel made from Palm / Tallow based blends start to cloud and then gel causing serious fuel problems such as fuel gelling

For Marine Oil enquiries please contact:

Phone :
(08456) 432900

up completely and engine not starting / fuel filters blocking / fuel pump failure etc. It is well documented Biodiesel will cloud like petroleum diesel fuel when the weather gets cold and gel. Initially we see little crystals of wax forming and these crystals will begin to clog fuel filters.

Julian Beach

Email :
sales@chemiphase.co.uk Manufactured by :

PRODUCT RANGE :
BIODIESEL ADDITIVES

Coldflow 402

ALLKLEAR 400
Biodiesel antioxidant to control oxidation levels in biodiesel which can cause degradation and damage to tank storage.

BIO-CONTROL 41
Biodiesel biocide to control micro-biological growth in biodiesel.

BIOBOOST 1000
Biodiesel cetane enhancing product which increase performance and efficiency.

PH CORRECT
pH correction agent to control the pH of the biodiesel after the reaction stage.

COLDFLOW 402
Pour point additive designed for heavy oils like Rapeseed, Used Cooking Oils etc.

CITRACLEAN
Excellent cleaning detergent for areas where oil staining and greasy floors are a problem.

Coldflow 402 Application Coldflow 402 is mixed into solution after the distillation of the biodiesel occurs. For maximum results the biodiesel must be 5C above the cloud point (point at which the biodiesel begins to cloud up in cold temperatures) of the fuel before the Coldflow 402 is added. One the correct dosage rate has been added the solution must then be thoroughly mixed to ensure product effectiveness. For best practices a re-circulation pump is sufficient to turn the tank round and mix the product into solution. For customers who resin wash instead of water washing: - The Coldflow 402 can be added before the biodiesel is passed through the resin towers. Again the temperature must be 5C above the cloud point of the fuel.

Coldflow 402
Coldflow 402 - CFPP Test + Pour Point Test on Rapeseed Methyl Esters
Degree's Centigrade C

Test Methods : Pour Point ASTM D5950 (Deg C) CFPP ASTM D6371 (Deg C) PACK SIZES AVAILABLE 20 LITRES

0 -5 -10 -15 -20 -25

Un-Treated 3000 ppm 4000 ppm 5000 ppm 10000 ppm

200 LITRES 1000 LITRES 10,000 Tanker 20,000 Tanker

TECHNICAL SUPP ORT Chemiph ase will

Coldflow 402 - CFPP + Pour Point Test on Soy Methyl Ester

Degrees Centigrade C

offer on- site technical support during all stages of production. Technical su pport includes on site testing.
DISCLAIMER : The information and all further technical advice are based on our present knowledge and experience. However, they imply no liability or other legal responsibility on our part, including with regards to existing third party intellectual property rights, especially patent rights. In particular, no warranty, whether express or implied of guarantee of product properties is intended or implied. We reserve the right to make any changes according to technological progress or further developments. The customer is not released from the obligation to conduct careful inspection and testing of incoming goods. Performance of the product described herein should be verified by testing, which should be carried out by qualified experts in the sole responsibility of the customer.

0 -2 -4 -6 -8 -10
Un-Treated 3000 ppm 4000 ppm 5000 ppm 10000 ppm

Coldflow 402 - CFPP Test + Pour Point Test on Used Cooking Oil Methyl Esters
Degree's Centigrade C

0 -5 -10 -15
Un-Treated 3000 ppm 4000 ppm 5000 ppm 10000 ppm

Coldflow 402 - CFPP + Pour Point Test on Palm Methyl Esters

Degree's Centigrade C

20 15 10 5 0
Un-Treated 3000 ppm 4000 ppm 5000 ppm 10000 ppm

Revision date: November 2015

CHEMIPHASE LTD

SAFETY DATA SHEET

COLDFLOW 402
1. IDENTIFICATION OF THE SUBSTANCE/PREPARATION AND COMPANY UNDERTAKING
PRODUCT NAME: PRODUCT Description: APPLICATION SUPPLIER

COLDFLOW 402
Biodiesel Additive - NEW FORMULATION NOVEMBER 2015 BIODIESEL Chemiphase International Ltd PO Box 168 Ormskirk L40 6ZX Tel: 00 44 8456 932 400 Fax: 00 44 1744 886633

EMERGENCY TELEPHONE (24 HR) 00 44 (0) 1744 886622

2. COMPOSIITON INFORMATION ON INGREDIENTS

NAME TOLUENE EU No 203-625-9 CAS No Confidential PERCENTAGE BY WEIGHT 2% CLASSIFICATION R11 R38 R48/20 R63 R65 R67

The Full Text for all R- Phrases are displayed in Section 16

3. HAZARDS IDENTIFICATION
Symbol(s) Product Classification Not applicable Not applicable

4. FIRST AID MEASURES

GENERAL INFORMATION Move the exposed person to fresh air at once. Get medical attention if any discomfort continues. INHALATION Remove exposed person to fresh air if adverse effects are observed. If breathing is laboured administer oxygen. If breathing has stopped, Apply artificial respiration. If irritation persists or if toxic symptoms are observed, get medical attention. INGESTION DO NOT INDUCE VOMITTING. If conscious, give 2 glasses of water. Get immediate medical attention. SKIN CONTACT Wash with soap and water. Remove contaminated clothing. Get medical attention if irritation develops. Launder contaminated clothing before reuse. EYE CONTACT Make sure to remove any contact lenses from the eyes before rinsing. Promptly wash eyes with plenty of water while lifting the eyelids. Continue to rinse for at least 15 minutes and get medical attention.

5. FIRE FIGHTING MEASURES

EXTINGUISHING MEDIA Use: Dry chemical, Carbon dioxide (CO2) or foam. Water can be used to cool and protect exposed material. FLASH POINT >61 OC, 141.8 OF PMCC (Minimum) FIRE FIGHTING PROCEDURES Recommend wearing self-contained breathing apparatus. Water may cause splattering. UNUSUAL FIRE & EXPOSURE HAZARDS Vapours may be heavier than air and may travel along the ground to a distant ignition sources and flash back. Container may rupture on heating.

6. ACCIDENTAL RELEASE MEASURES

SPILL PROCEDURES Evacuate all non-essential personnel. Personal Protective Equipment must be worn, see Personal Protection Section for PPE recommendations. Remove sources of ignition. Ventilate spill area. Prevent entry into sewers and waterways. Pick up free liquid for recycle and/or disposal. Residual liquid can be absorbed on inert material. Check under Transportation and Labelling (DOT/CERCLA) and other Regulatory Information Section (SARA) for hazardous substances to determine regulatory reporting requirements for spills.

7. HANDLING AND STORAGE

PUMPING TEMPERATURE Not determined. MAXIMUM HANDLING TEMPERATURE 55 OC, 131 OF HANDLING PROCEDURES Keep away from potential sources of ignition. Open container in a well ventilated area. Avoid breathing vapours. Keep containers closed when not in use. Wash thoroughly after handling. Empty containers retain material residue. Do not cut, weld, braze, solder, drill, grind or expose containers to heat, flames, spark or other sources of ignition. MAXIMUM STORAGE TEMPERATURE 45 O C, 113 O F STORAGE PROCEDURES Do not store near potential sources of ignition. Store in well ventilated place. LOADING TEMPERATURE 110 O C, 230 O F

8. EXPOSURE CONTROL/PERSONAL PROTECTION

EXPOSURE LIMITS - EU Name TOLUENE CAS No. 108-88-3 LONG TERM Hours T.W.A.) 50 ppm (s) (8 SHORT TERM (15 mins.) N/E

UK Not applicable. (s) Skin exposure (p) Proposed limit (c) Ceiling exposure (l) Recommended exposure limit (u) Supplier recommended exposure limit (N/E) None established OTHER EXPOSURE LIMITS: Contains mineral oil. Under conditions which may generate mists, observe the OSHA PEL of 5 mg per cubic meter, ACGIH STEL of 10 mg per cubic metre ENGINEERING CONTROLS: Use local exhaust ventilation to control mists or vapours. Additional ventilation or exhaust may be required to maintain air concentrations below recommended exposure limits. HAND PROTECTION: Nitrile EYE PROTECTION: Safety glasses. If potential for splash or mist exists, wear chemical goggles or faceshield. RESPIRATORY PROTECTION: Use full face respirator with a combination organic vapour and high efficiency filter cartridge if the recommended exposure limit is exceeded. Use self-contained breathing apparatus for entry into confined space, for other poorly ventilated areas and for large spill clean-up sites. CLOTHING RECOMMENDATION: Long sleeve shirt is recommended. Wear either a chemical protective suit or apron when potential for contact with material exists. Launder contaminated clothing before reuse.

9. PHYSICAL AND CHEMICAL PROPERTIES

Flash Point Upper Flammable Limit Lower Flammable Limit Autoignition Point Explosion Data Vapour Pressure pH Specific Gravity Bulk Density Water Solubility Percent Solid Percent Volatile Percent VOC Vapour Density Evaporation Rate >61 O C, 141.8 O F PMCC (Minimum) Not determined Not determined Not determined Material does not have explosive properties 0.0001 mm Hg (20 o C) 0.0046 mm Hg (77 o C) Not Determined 0.92 (15.6 o C) Not Determined Insoluble Not Determined Unknown Not Determined Not Determined Not Determined

Odour Appearance Viscosity Odour Threshold Boiling Point Pour Point Temperature Melting/freezing Point

Mild Amber coloured liquid 6000 Centistokes (40 o C) 660 Centistokes (100 o C) Unknown Not Determined Not Determined Not Determined

The above data are typical values and do not constitute a specification

10. STABILITY AND REACTIVITY

STABILITY DECOMPOSITION TEMPERATURE INCOMPATIBILITY THERMAL DECOMPOSITION Material is normally stable at moderately elevated temperatures and pressures. Not Determined Strong oxidising agents Smoke, carbon monoxide, carbon dioxide, aldehydes and other products of incomplete combustion.

11. TOXICOLOGICAL INFORMATION

-ACUTE EXPOSUREWeak to moderate eye irritant. Does not meet EU R36 criteria. Based on data from components and similar materials. May cause skin irritation, based on data from components or similar materials. Not expected to meet EU R38 criteria. Prolonged or repeated skin contact as from clothing wet with material may cause dermatitis. Symptoms may include redness, edema, drying, and cracking of the skin. RESPIRATORY IRRITATION Nose, throat and lung irritant. Based on data from components or similar materials. DERMAL TOXICITY The LD50 in rabbits is >5000 mg/kg. Based on data from components or similar materials. Components of this Material are absorbed through the skin. INHALATION TOXICITY High concentrations may cause headaches, dizziness, nausea, stupor, and other central nervous system effects leading to visual impairment, difficulty breathing and convulsions. ORAL TOXICITY The LD50 in rats is > 5000 mg/kg. Based on data from components or similar materials. DERMAL SENSITISATION No data available to indicate product or components may be a skin sensitisers. INHALATION SENSITISATION No data available to indicate product or components may be respiratory sensitisers. -CHRONIC EXPOSURECHRONIC TOXICITY CARCINOGENICITY Repeated overexposure to toluene may cause loss of appetite, liver enlargement, and kidney and lung damage. Repeated inhalation of hydrocarbon solvents such as toluene can cause chronic neurological disturbances. This product is formulated with mineral oils which are considered to be severely refined and not considered to be carcinogenic under IARC. All of the oils in this product have been demonstrated to contain less than 3% extractables by the IP 346 test. No data available to indicate product or any components present at greater than 0.1% are mutagenic or genotoxic. No data available to indicate either product or components present at greater than 0.1% that may cause reproductive toxicity. Prolonged and repeated exposure of pregnant animals to toluene by inhalation has been reported to cause adverse fetal development effects. No other health hazards known. EYE IRRITATION SKIN IRRITATION

MUTAGENICITY REPRODUCTIVE TOXICITY TERATOGENICITY OTHER

12. ECOLOGICAL INFORMATION

-ENVIRONMENTAL TOXICITYFRESHWATER FISH TOXICITY FRESHWATER INVERTEBRATES TOXICITY ALGAE TOXICITY SALTWATER FISH TOXICITY SALTWATER INVERTEBRATES TOXICITY BACTERIA TOXICITY MISCELLANEOUS TOXICITY The acute LC50 is > 1000 mg/L based on similar products Not Determined. Not Determined. Not Determined. Not Determined. The acute EC50 is >1000 mg/L based on similar products Not Determined.

13. DISPOSAL CONSIDERATIONS

WASTE DISPOSAL This material, if discarded, should not be considered a European hazardous waste.

14. TRANSPORT INFORMATION

Harmonised Code ICAO/IATA (International) IMDG IMDG EMS Fire IMDG EMS Spill IMDG MFAG IMO Marine Vessel USCG Compatability ADR/RID ADR/RID Hazard ID No.

270730 Not regulated Not regulated Not applicable Not applicable Not applicable DO NOT TRANSPORT ADDITIONAL INFORMATION REQUIRED Not determined Not regulated Not applicable

Review classicification requirements before shipping materials at elevated temperatures

15. REGULATORY INFORMATION

SYMBOL(s) INDICATION OF DANGER PRECAUTIONARY LABLES OTHER LABEL INFORMATION RELEVANT R PHRASES Not applicable Not applicable Not applicable None R11 Highly flammable R38 - Irritating to skin R48/20 Harmful: danger of serious damage to health by prolonged exposure through inhalation R63 Possible risk of harm to the unborn child R65 Harmful: may cause lung damage if swallowed R67 Vapours may cause drowsiness or dizziness

UK REGULATORY REFERENCES Approved Supply List STATUTORY INSTRUMENTS Chemicals (Hazard Information and Packaging) Regulations APPROVED CODE OF PRACTICE Classification and Labelling of Substances and Preparations Dangerous for Supply. Safety Data Sheets for Substances and Preparations. GUIDANCE NOTES Occupational Exposure Limits EH40. Approved guide to the classification and labelling of substances and preparations dangerous for supply.

16. OTHER INFORMATION

REVISION COMMENTS General revision ISSUED BY CES REVISION DATE REVISED SDS GENERATED MARCH 2015 NOVEMBER 2010

DISCLAIMER The information provided in this SDS is correct to the best of our knowledge, information and belief at the date of its publication. The information given is designed only as guidance for safe handling, use, processing, storage, transportation, disposal, and release and is not being considered a warranty or quality specification. The information relates only to the specific material designated and may not be valid for such material used in combination with any other materials or in any process unless specified in the text.