Thermoelectric Handbook 060222
Thermoelectric Handbook 060222
Thermoelectric Handbook 060222
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Table of Contents
Introduction to Thermoelectrics
2
Thermoelectric Cooler Series Structure and Function
CP Series is a standard thermoelectric cooler for refrigeration A thermoelectric cooler is composed of semiconductor material,
applications commonly found in the medical and analytical ceramic substrates and solder. It is considered a heat pump or
markets. Cooling capacity ranges from 2 to 118 watts. This solid-state device with no moving parts. The semiconductor
product series has many configurations and is available in material is unique in its properties as it is one of the few materials
numerous heat pumping capacities, geometric shapes, and input that is highly electrically conductive yet thermally insulating.
power ranges. These modules are often grouped together in an The high thermal resistance properties allow for a temperature
array to support refrigeration applications in lab environments at differential to be achieved across the module. Thermoelectric
room temperature. The maximum operating temperature of this material is grown into semiconductor rods and sliced and diced
series is 80°C. into P and N elements and then soldered in series between
two ceramic substrates. At the cold junction, energy (heat) is
absorbed by electrons as they pass from a low energy state in the
OptoTEC™ OTX/HTX Series is a premium miniature p-type semiconductor element, to a higher energy state in the
thermoelectric cooler product series using advanced n-type semiconductor element. The power supply provides the
thermoelectric materials to boost cooling performance. It is energy to move the electrons through the electric circuit. At the
commonly used to temperature stabilize small optoelectronic hot junction, energy is expelled to a heat sink as electrons move
devices such as laser diodes and image sensors, while ambient from a high energy state (n-type element) to a lower energy state
temperatures may fluctuate greatly. It offers the smallest sizes (p-type element).
with footprints less than 13 x 13 mm, while cooling capacities
are typically low ranging from 0.4 to 9.5 Watts. This Series is An analogy often used to help comprehend a thermoelectric
available in two solder constructions. The OTX Series has a cooling system is that of a standard thermocouple used to
maximum operating temperature of 120°C and HTX Series has a measure temperature. Thermocouples of this type are made by
maximum operating temperature of 150°C. connecting two wires of dissimilar metal, typically copper and
constantan, in such a manner that two junctions are formed. One
junction is kept at some reference temperature and the other is
HiTemp ETX Series is a premium thermoelectric cooler designed attached to the control device measurement. The system is used
for high temperature applications. The construction of this when the circuit is opened at some point and the generated
product series is designed to survive in temperatures up to voltage is measured. Reversing this train of thought, imagine
150°C. It features advanced thermoelectric materials to boost a pair of fixed junctions into which electrical energy is applied
performance and robust construction to prevent degradation causing one junction to become cold while the other becomes
in high temperature environments. This product series can be hot.
used in all markets, but is commonly found in analytical, telecom,
automotive (autonomous systems) and industrial (machine Thermoelectric cooling couples (Fig. 2) are made from two
vision) applications. elements of semiconductor, primarily Bismuth Telluride, heavily
doped to create either an excess (n-type) or deficiency (p-type)
of electrons. Heat absorbed at the cold junction is pumped to the
Multistage MS Series is a standard product series offering hot junction at a rate proportional to current passing through the
the highest temperature differential (∆T). Each stage is a circuit and the number of couples.
thermoelectric cooler stacked on top of each other creating a
multistage module. This product series is available in numerous
footprints, temperature differentials and cooling capacity ranges.
It is designed for lower heat pumping applications for image
sensing or detector cooling to minimize thermal noise.
3
The third and often most difficult parameter to accurately
quantify is the amount of heat to be removed or absorbed by the
cold surface of the thermoelectric cooler, (Qc). All thermal loads
to the thermoelectric cooler must be considered. These thermal
loads include, but are not limited to, the active heat load (I2R)
from the electronic device to be cooled and passive heat load
where heat loss can occur through any object in contact with
ambient environment (i.e., electrical leads, insulation, air or gas
surrounding objects, mechanical fasteners, etc.). In some cases,
radiant heat effects must also be considered.
4
Temperature Control and/or cooling systems where the temperature must stay constant
(with no change) regardless of the ambient temperature. For
example, a thermoelectric liquid chiller system used to control the
When designing a thermoelectric system, power supplies, temperature of a detector plate in a medical imaging system.
temperature controllers, and temperature sensors are
components that also require careful consideration. Regardless of the controller used, the easiest feedback parameter
to detect and measure is temperature. The sensors most used
Thermoelectric devices require a DC power source to operate. by temperature controllers are thermocouples, thermistors,
The power supply output should be matched to the operational and RTD’s. Depending on the system, one or more temperature
voltage of the thermoelectric modules and fans. It is not sensors may be used for the purpose of control. The temperature
recommended to operate thermoelectric devices above sensor feedback is compared by the controller to a set point or
the specified maximum voltage. Doing so will degrade the another temperature to determine the power supply output. The
performance of the thermoelectric coolers and operate less temperature feedback sensor(s) will most likely be determined by
efficiently. The power supply should also have a small ripple the controller specified. Some controllers even include a sensor
voltage with a maximum of 10% of full output power. The ripple with purchase.
voltage is a fluctuation of the power supply output voltage
and therefore is an AC component of the DC power source. To begin selection of a thermoelectric controller, consider the
AC power will degrade the operational performance of the following questions:
thermoelectric coolers. The degradation in performance due to
ripple voltage can be approximated by: 1. What is the maximum voltage & current of thermoelectric
coolers used in the application? (also needed for selecting a
power supply)
∆T / ∆Tmax = 1 / (1+N2), where N is a percentage of current 2. Does the system need to Heat, Cool or Heat & Cool?
ripple, expressed as a decimal. Laird Thermal Systems
3. Can the system tolerate a temperature swing of 3°C?
recommends no more than a 10% ripple.
Once answered, the selection of the basic functions of a
temperature controller can be identified. The controller
selected needs to be capable of handling the maximum
Temperature control can be accomplished by using one of voltage and current to properly control the thermoelectric
two control methods: Open Loop (manual) and Closed Loop cooler and power fans.
(automatic).
In the Open Loop method, an operator adjusts the output of If the answers to question 2 is “Heat” or “Cool” and the answer to
the power supply to achieve and maintain a steady control question 3 is “Yes” then the required controller is single directional
temperature. In the Closed Loop method an electronic controller and thermostatic.
runs an algorithm that utilizes feedback data from a temperature
sensor within the system to vary the output of the power supply If the answers to question 2 is “Heat” or “Cool” and the answer to
to control the temperature. question 3 is “No” then the required controller is single directional
and proportional.
Temperature controllers can have a single directional or a
bidirectional output. A temperature controller that has a single If the answers to question 2 is “Heat & Cool” and the answer to
directional output can operate only in Heating or Cooling question 3 is “Yes” then the required controller is bidirectional and
mode depending on connection polarity. Controllers with thermostatic.
a single directional output are used to maintain a constant If the answers to question 2 is “Heat & Cool” and the answer to
temperature within a system surrounded by a relatively constant question 3 is “No” then the required controller is bidirectional and
ambient temperature (i.e., refrigeration or hot food storage). A proportional.
temperature controller with a bidirectional output can operate in
both heating and cooling modes. Controllers with a bidirectional Temperature controllers also can accommodate more advanced
output are used for maintaining a constant temperature within options to trip alarms, control fan speeds and interface remotely
a system surrounded by an ambient environment with large with PC or UI, but these are beyond the scope of this handbook.
temperature fluctuations (i.e., back-up battery storage or However, some basic questions to consider for temperature
climate control enclosure during winter and summer months). controller designs are:
Temperature controllers can also have two regulation modes: 1. What alarms/indicators are required for User Interface?
thermostatic (On/Off) or proportional control. Thermostatic 2. Does the controller need to interface with a PC?
controllers operate by turning on the thermoelectric coolers in
order to heat or cool to a set point. The set point temperature 3. Does the TEM controller provide fan control?
tolerance is defined by a hysteresis range. Once the set point is 4. Does the temperature set point need to be changed by the
achieved the controller shuts off the thermoelectric cooler. When end user?
the control temperature changes to outside the hysteresis range
the controller turns on power to the thermoelectric coolers
Other design considerations may exist and should be considered
and restarts the cooling or heating mode process. This cycle
during system level design.
continues until the controller is shut down. Thermostatic control
is often used in climate control or refrigeration, where narrow
Laird Thermal Systems offers a variety of Closed Loop
temperature swings can be tolerated.
Temperature Controllers. The controller offering includes single
and bidirectional output controllers that employ thermistor
Proportional controllers use proportional regulation to maintain a
temperature sensor feedback, fan controls, alarms, and a range
constant temperature with no swing in the control temperature.
of control algorithms ranging from thermostatic (ON/OFF) to
This is often accomplished by using a Proportional Integral
PID. Laird Thermal Systems also has the ability to customize
Derivative (PID) algorithm to determine the output value and a
and design temperature controllers to meet unique application
Pulse Width Modulation (PWM) output to handle the physical
requirements. Consult with a Laird Thermal Systems Sales
control. When using a controller with a PWM output, a capacitor
Engineer on available product offerings or customized solutions
can be placed (electrically) across the output to filter the voltage
that may fit your design criteria.
to the TEM. Proportional controllers are often used in heating
5
Thermal Wizard
The Thermal Wizard displays the quickest means of obtaining Figure 6: Thermal Wizard Enclosure Cooling Calculator
samples for prototyping. Whenever the Thermal Wizard displays
a product, either in a selection list or in an active datasheet, a
Buy Now >> button is always there to indicate a source with
inventory. The Thermal Wizard Request a Quote form is also
available if you require a firm quote from Laird Thermal Systems.
Figure 5: Selecting Qc and ∆T for Thermal Wizard Product Search Figure 7: Thermal Wizard Device Cooling Calculator
6
Sealant Options Thermoelectric Array
Most applications operate in a room temperature environment Wiring multiple thermoelectric coolers together is commonly
and cool to below dew point. As a result, moisture in the referred to as a TE array. The decision to wire thermoelectric
environment will condense onto the cold side heat exchanger coolers in series or in parallel is primarily based on available input
and may accumulate around mounting hardware and eventually power requirements. No additional performance benefit will be
penetrate to the thermoelectric cooler. The presence of achieved by wire arrangement. TE arrays are commonly used for
moisture will cause corrosion that will degrade the useful higher heat pumping capacities and can be more efficient than a
life of a thermoelectric module. Two perimeter sealants are single thermoelectric cooler by taking advantage of dissipating
generally used because they provide moisture protection against heat over a larger surface area. When mounting a TE array onto a
condensation, have high dielectric strength and low thermal heat exchanger, the recommended lapping tolerances are ± 0.025
conductivity. mm for two thermoelectric coolers and ± 0.0125 mm for three or
more. This is done to maximize the thermal contact between the
Silicone (RTV) is an all-purpose sealant that exhibits good thermoelectric cooler and mating heat exchangers.
sealing characteristics and retains its elastomeric properties
over a wide temperature range, -60 to 200°C. The sealant is One advantage of wiring a TE array in parallel versus in series is
non-corrosive to many chemicals and exhibits good electrical that the entire TE array will not fail if one thermoelectric cooler
properties with low thermal conductivity. It is suitable for has an open circuit. This can be beneficial for applications that
high volume applications for ease of use and is cost effective. require redundancy.
However, over time it is impervious to vapor migration that can
trap small amounts of moisture inside the thermoelectric cooler
once the vapor condenses. This may or may not be a problem
dependent on life expectancy of application and environmental
conditions. This sealant is also better suited for thermal cycling
applications
Figure 8: Thermoelectric Cooler with RTV (translucent or white) sealant. Figure 10: Thermoelectric Cooler Array
A multistage thermoelectric cooler should be used only when Laird Thermal Systems offers a line of MS Series cascades though
a single stage module does not meet temperature control there are no standard applications. Each need for a cascade is
requirements. Figure 11 depicts two graphs: the first shows unique, so too should be the device selected to fill the need. Laird
the ∆T vs. Normalized Power input (Pin/Pmax) of single and Thermal Systems has developed a proprietary computer aided
multistage modules. The second graph shows the ∆T vs. COP. design selection tool called the Thermal Wizard to help select
COP is defined as the amount of heat absorbed at the cold side a device. The three parameters listed are used as inputs to the
of the TEM (in thermal watts) divided by the input power (in programs. Other variables such as physical size, and operating
electrical watts). voltage or current can, within limits, be used to make the final
selection. More than 40,000 different cascades can be assembled
These figures should help identify when to consider cascades
utilizing available ceramic patterns. This allows near custom
since they portray the effective ∆T range of the various stages. A
design, at near “standard” prices. When the three parameters
two- stage cascade should be considered somewhere between a
have been defined, please contact a Laird Thermal Systems sales
∆T of 40°C and 65°C. Below a ∆T of 40°C, a single stage module
engineer for assistance in cascade selection.
may be used, and a ∆T above 65°C may require a 3, 4 or even 5
stage module.
Once ∆T (Th - Tc) and the heat load have been defined,
utilization of Figure 4 will yield the number of stages that
should be considered. Knowing COP and Qc, input power can
also be estimated. The values listed in Figure 11 are theoretical
maximums. Any device that is manufactured will rarely achieve
these maximums but should closely approach this value.
9
Assembly Tips
The techniques used in the assembly of a thermoelectric system In addition, we have enclosed step-by-step procedure for
can be as important as the selection of the thermoelectric assembling Laird Thermal Systems modules, Solderable or Lapped
cooler (TEC). It is imperative to keep in mind the purpose of the modules to heat-exchangers.
assembly – namely to transfer heat. Generally, a thermoelectric
cooler, in cooling mode, moves heat from an object to ambient
environment. All of the mechanical interfaces between the
If you should require any further assistance, please contact
device to be cooled and ambient are also thermal interfaces.
one of our engineers. Our many years of experience in
Similarly, all thermal interfaces tend to inhibit the transfer of heat
working with customers ensuring reliable and efficient
or add thermal resistance to system, which lowers COP. Again,
application of our products has proven to be essential to
when considering assembly techniques every reason- able effort
product success.
should be made to minimize the thermal resistance between hot
and cold surfaces.
10
Procedure For Assembling Lapped
Modules To Heat Exchangers
Step 6. Repeat Step #3 for cold side surface and cold plate.
11
Reliability & Qualification Testing Mechanical Testing
MTBF is difficult to determine and highly dependent on Mechanical testing is more commonly conducted on smaller
application conditions. Thermoelectric devices can be highly OptoTEC™ or Multistage parts used in various optoelectronic
reliable if design considerations for application have been fully applications where the cold side surface is used to mount
vetted and proper qualification testing has been conducted an optical component or thermistor. Larger form factor
to assure worst case attributes. Most customers create their thermoelectric coolers generally do not conduct mechanical
own qualification requirements based on accelerated or severe testing unless they are used for aerospace or automotive
environmental testing that goes beyond worst case application applications. Common mechanical testing is vibration and shear
conditions. force testing.
To ensure proper long-term performance of a thermoelectric
cooler in an application, performance measurements and
qualification testing must be conducted to validate full Vibration Testing
compliance in an application:
• Functional testing – verifies that the thermoelectric cooler Assures thermoelectric coolers are not affected by careless
meets expected performance specifications handling during transportation. It is typically required for
• Reliability testing – determines the thermoelectric cooler’s miniature thermoelectric coolers used in telecom and aerospace
mechanical integrity and ability to survive in extreme applications due to their sensitive module construction.
environmental conditions
• Compliance –ensures that the product meets applicable How is the test performed?
industry standards • The thermoelectric cooler is mounted on the test fixture
which is then mounted on the test equipment platform in one
of three axes.
Functional Performance Testing • The thermoelectric cooler is subjected to vibrations during
multiple sequences.
Thermoelectric coolers undergo performance testing to
ensure they deliver the expected cooling capacity. A vacuum
temperature difference tester is used to measure electrical Shear Force Testing
current and voltage input.
12
High Temperature Storage HALT/HASS Testing
Will determine the effect of long-term storage of thermoelectric HALT-Highly Accelerated Life Test aims to identify the operating
coolers at a specific condition. This testing induces thermal limits of the thermoelectric cooler. By identifying weaknesses
stress on the thermoelectric cooler in a non-operation state. early in the product development process, HALT can reduce cost
and time-to-market. This type of test is typically performed when
assessing failure modes or estimating MTBF of a thermoelectric
How is the test performed?
cooler.
The thermoelectric cooler is placed in a storage chamber at
a temperature and time specified by a certain standard or
HASS-Highly Accelerated Stress Test will detect flawed
customer application requirement. There is typically a low or
thermoelectric coolers caused by poor manufacturing processes.
high temperature storage requirement
The testing procedure is similar to HALT but stress levels are less
• Low temperature storage testing is commonly conducted at a extreme.
temperature between 80 to 100°C
• High temperature storage testing is commonly conducted at
How is the test performed?
a temperature between 120 to 150°C
• The thermoelectric cooler is powered on and placed in a
hot oven.
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