PW 10a - Sweets

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SWEETS

CONTENT

Classification
Consumption forms
The nutritional value
The advantages of consuming sweets
The disadvantages of consuming sweets
Contamination (contamination) of sweets
Quality control of sweets
Alteration (aging) of sweets
CLASIFICATION
The composition of this products contain carbohydrates with
small molecules in varying quantities between 20-100%

They are divided into four categories:


⚫ Predominantly carbohydrate products;

⚫ Carbohydrate and fruit products;


⚫ Preparations from carbohydrates and oleaginous seeds;

⚫ Complex products.
CONSUMPTION FORMS
1. Predominantly carbohydrate preparations (refined
carbohydrates):
sugar (100% sucrose), invert sugar (sucrose enzymatically hydrolyzed
into glucose and fructose which is about 70% sweeter than sucrose),
fructose, caramel (2 parts sugar + 1 part glucose), nougat, sorbet, delight

2. Sugar and fruit products:


jams, marmalades, jellies, glazed fruits

3. Sugar and oilseed products:


halva (sunflower seeds + sugar), chocolate (cocoa seeds + sugar)

4. Complex preparations or mixtures:


wafers, checks, cakes, confectionery and pastries
NUTRITIONAL VALUE
● concentrated foods rich in carbohydrates that are an
important source of energy
● sugar provides 410 calories per 100g

Recommended daily ration


● 7-8% of the caloric requirement for children, pregnant
women
● 10% of the caloric requirement for adolescents, adults
and the elderly
NUTRITIONAL VALUE
Nutritional value Proteins Fats Carbohydrates Calories (kcal/
(g%) (g%) (g%) 100g)
Sugar - - 99,9 410

Glucose - - 77,7 319

Honey 0,4 - 81,3 335

Candies 3,1 9,1 78,7 420

Plum jam 0,62 - 72,5 300

Marmalade 0,46 - 72,5 289

House chocolate 6,5 27,5 61,6 536

Milk chocolate 6,9 29,9 49,8 603

Marzipan 9,3 28,5 46,7 495

Halvah 18,8 31,5 43 546


1. PREDOMINANTLY CARBOHYDRATE
PREPARATIONS
1. Sugar – a refined product obtained from sugar beet or sugar
cane; contains approx. 99.7-99.9% crystallized sucrose, 0.05%
water, 0.05% ash, 0.05% other substances (invert sugar, etc.)

2. Inverted sugar syrup is prepared from sucrose by acid or


enzymatic hydrolysis; contains glucose, fructose and small
amounts of sucrose and acid; it is used for preparing sweets, in
food industry, being sweeter than sugar

3. Glucose (starch sugar) is obtained in industry from potato or


corn starch.
1. PREDOMINANTLY CARBOHYDRATE
PREPARATIONS

4. Candies are obtained from a mass of caramel prepared from 2/3


sugar and 1/3 glucose in which dyes, flavors, citric acid are
incorporated

5. Sorbet is obtained from sugar and a small percentage of


glucose, dyes, flavors, citric acid

6. Nougat is obtained by stirring the caramel mass (prepared from


sugar and glucose) with an extract from the root of a plant called
soapwort (contains saponins).

7. The delight is starch gelled by boiling in sugar syrup and


glucose to which flavors, dyes, citric or tartaric acid, nuts, butter,
cocoa are added.
1. PREDOMINANTLY
CARBOHYDRATE PREPARATIONS
8. Bee honey - is a natural product, made by bees from
floral and extrafloral nectar or other sweet liquid existing in
different parts of plants, is rich in carbohydrates, with
variable content of vitamins, mineral elements, antiseptic
substances

antibiotics, hormones, protein substances, steric oils, wax


etc. (more than 70 existing substances in honey have been
identified)
2. SUGAR AND FRUIT PRODUCTS
Depending on the preparation method: jam, marmalade, jelly, glazed
fruits, compote and syrup

The carbohydrate content varies between 65-75%

The nutritional value is more complex than the preparations in the first
category, because they are, rich in digestible and non-digestible
carbohydrates (cellulose, pectin's), vitamins, mineral substances
(alkaline mini-equivalents predominate), macro- and microelements
(K, Ca, Fe, Cu, etc.), organic acids.

They have a high caloric value (240-300 calories per 100 grams)
3.SUGAR AND OILSEED PRODUCTS
Chocolate is obtained from roasted, shelled, ground cocoa seeds
that are mixed with sugar and lecithin as an emulsifier.

Milk, nuts, hazelnuts, almonds, coffee, raisins, sugary fruits can


be added to the hot chocolate mass (approx. 35°C)
Contains 50-60% sugar, 20-40% fat
The caloric value varies between 450-600 calories per 100
grams
It also contains protein substances, tannins, theobromine and
caffeine 1-2%, mineral salts, depending on the added substances
3. SUGAR AND OILSEED PRODUCTS

Halva is obtained mainly from sunflower and sesame seeds


(although other oleaginous seeds can also be used). For some
varieties, hazelnuts, nuts, cocoa, chocolate, candied fruits, flavors
are added

Complex nutritional value: 35-40% carbohydrates, 26-30% fats,


~12% proteins, ~3-4% mineral salts, vitamins (complex B, E),
cellulose, etc.

Caloric value: 440-500 calories / 100 grams


4. COMPLEX PRODUCTS

This category includes cakes (cakes, cookies, gingerbread,


muffins, tarts, pancakes, etc.) and ice cream

Many ingredients are used to make these preparations: flour,


starch, eggs, milk, butter, oil, cream, sugar, honey, cocoa,
fruits, flavors, dyes, etc.

Generally high nutritional value

They are often consumed in excess

It presents a high degree of perishability


ADVANTAGES OF CONSUMING
SWEETS

1. caloric intake less important than dietary fats


2. increase the satiety power of the menu
3. honey has a laxative effect
4. chocolate has a stimulating effect on the nervous
system due to the content of theobromine
DISADVANTAGES OF CONSUMING
SWEETS
1. excessive consumption increases the risk of obesity, dyslipidemia,
atheromatosis due to hypercaloric intake

2. excessive consumption of sugary products leads to diabetes due to the overload


of the pancreas

3. they do not contain vitamins, but they increase the body's need for vitamin B1
(thiamine), generating a thiamine-carbohydrate imbalance that determines
a.central neurological syndrome: nervousness, inability to concentrate, memory loss,
apathy, noise intolerance
b.peripheral neurological syndrome: skin hyperesthesia , burning sensation in the
fingers, muscle cramps
c.digestive syndrome: ana- or hypochlorhydria, constipation
d.cardiovascular syndrome: tachycardia, palpitations, dyspnea

4. they do not contain minerals and cover the teeth with a fermentable film of
carbohydrates, generating tooth decay
CONTAMINATION OF SWEETS
Pathogenic and conditionally pathogenic germs for humans
- confectionery and pastry products present favorable
environments for the development of germs that produce food
poisoning (e.g. staphylococci, salmonella, shigella, E.coli,
Clostridium perfringens, Proteus mirabilis, Proteus vulgaris,
Bacillus cereus, etc.)

Harmful chemical substances - Cu, Pb, Al are oxidized and


produce the verdigris that passes through equipment and
packaging - non-permitted additives (e.g. aniline or Pb dyes,
toxic flavors, synthetic sweeteners)
ALTERATION OF SWEETS
● fermentation of carbohydrates produces acids, alcohols,
aldehydes, ketones

● deamination, decarboxylation and desulfation of


proteins produces amines (such as putrescine,
cadaverine and other amines), ammonia, smelling acids
(such as butyric acid, aldehydes, ketones, peroxides,
hydrogen sulfide, mercaptan)

● β-oxidation of fatty acids produces the specific rancid


smell and taste through the accumulation of amines and
ammonia and alkalinization of the pH
QUALITY CONTROL OF SWEETS

The organoleptic examination


appearance, color, consistency, taste, smell

Chemical examinations
⚫ determination of sugar and water content
⚫ determination of acidity
⚫ identification of fraudulently added substances (e.g. the addition of
starch, flour…..)
⚫ qualitative determination of synthetic dyes
⚫ determination of fat alteration (Kreis reaction)
QUALITY CONTROL OF
CARBOHYDRATES
gives clues about the nature of honey and some
forgeries:

nectar honey contains up to 5% sucrose;


hand honey contains up to 10% sucrose;
honey prepared by bees fed with sugar syrup = 25% sucrose;
adulterated honey with invert sugar = between 10-45%
sucrose (identification with the resorcinol test)
QUANTITATIVE DETERMINATION
OF CARBOHYDRATES
1. physical method - polarimetry

2. chemical method - based on the reducing property of carbohydrates

IODOMETRICAL METHOD

1. an alkaline solution of cupric salt is reduced under heat with the help of reducing sugars.
Titrate indirectly with sodium thiosulfate solution, the cuprous oxide resulting from the
reaction.

2. the difference between no. of ml of thiosulphate used to titrate the sample and those used to
titrate the control (the control sample has the same reagents, replacing the 20 ml of sugar solution
with distilled water) represents the amount of copper reduced by the carbohydrates in the sample;

3. the amount of carbohydrate in the sample is established with the help of a table (the equivalent in
Cu for various carbohydrates of Na thiosulphate)
DETERMINATION OF SACCHARIN

Principle:
it is based on the extraction of saccharin with a mixture of
ether and ethyl petroleum ether and, then, its transformation
into salicylic acid which is identified in the presence of ferric
chloride

In the presence of salicylic acid, a purple color is obtained


due to the iron salicylate formed
DETERMINATION OF ACIDITY
indicator of changes produced by alteration

Procedure:
the sample to be analyzed is dissolved in warm water and 1-2
drops of phenolphthalein are added and titrated with NaOH 0.1n
until a persistent pink color appears;

acidity is expressed in citric acid for candies and in malic


acid
QUALITATIVE DETERMINATION
OF SYNTHETIC DYES

Food dyes are organic, natural or synthetic substances, with a


well-established physiological role in nature, but also with the role
of normalizing the color of some foods and drinks, or
improving the appearance of food products.

The determination of the dyes in these products is carried out by


following methods:
by fixing the synthetic dye on the textile fiber (wool);
using two extraction systems (ethyl alcohol and phosphate buffer) and
spectrophotometric analysis of the obtained extracts.
EXERCISES
1. Food: milk chocolate
Ex. organoleptic:
⚫ appearance – 100 g tablets, packed in foil and waxed paper
⚫ content - whole tablet, not fogged, not stained, without
mold colonies
⚫ taste, smell - specific to milk chocolate

Ex. physico-chemical:
⚫ Kreiss reaction – negative
⚫ pH – 5.7
Conclusions: the sample meets hygiene and health standards
EXERCISES
2. Food: candy - drops
Ex. organoleptic:
⚫ pieces of regular shape, dry, non-sticky to the touch, not agglomerated
⚫ inside glassy, brittle mass
⚫ light yellow color
⚫ pleasant taste, sweet-sour, pleasant aroma.

Ex. physico-chemical:
⚫ total sugar (invert sugar): 85%
⚫ toxic metals: lead, arsenic - absent
⚫ dye – synthetic (tartrazine)

Conclusions: the sample meets hygiene and health standards


THANK YOU!!

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