Caustic Soda Liquid 50
Caustic Soda Liquid 50
Caustic Soda Liquid 50
Olin Corporation (OCAP) encourages and expects you to read and understand the entire (M)SDS, as
there is important information throughout the document. We expect you to follow the precautions iden-
tified in this document unless your use conditions would necessitate other appropriate methods or
actions.
SECTION 1. IDENTIFICATION
GHS classification in accordance with the OSHA Hazard Communication Standard (29 CFR
1910.1200)
Corrosive to Metals : Category 1
1 / 16
SAFETY DATA SHEET
Precautionary Statements :
Prevention:
P234 Keep only in original container.
P264 Wash skin thoroughly after handling.
P270 Do not eat, drink or smoke when using this product.
P280 Wear protective gloves/ protective clothing/ eye protection/
face protection.
Response:
P301 + P312 + P330 IF SWALLOWED: Call a POISON
CENTER/ doctor if you feel unwell. Rinse mouth.
P301 + P330 + P331 IF SWALLOWED: Rinse mouth. Do NOT
induce vomiting.
P303 + P361 + P353 IF ON SKIN (or hair): Take off immediately
all contaminated clothing. Rinse skin with water/ shower.
P304 + P340 + P310 IF INHALED: Remove person to fresh air
and keep comfortable for breathing. Immediately call a POISON
CENTER/ doctor.
P305 + P351 + P338 + P310 IF IN EYES: Rinse cautiously with
water for several minutes. Remove contact lenses, if present
and easy to do. Continue rinsing. Immediately call a POISON
CENTER/ doctor.
P363 Wash contaminated clothing before reuse.
P390 Absorb spillage to prevent material damage.
Storage:
P405 Store locked up.
P406 Store in corrosive resistant container with a resistant inner
liner.
Disposal:
P501 Dispose of contents/ container to an approved waste dis-
posal plant.
Other hazards
None known.
CAS-No. : 1310-73-2
Components
Chemical name CAS-No. Concentration (% w/w)
Sodium hydroxide 1310-73-2 >= 30 - <= 54
Water 7732-18-5 >= 46 - <= 70
2 / 16
SAFETY DATA SHEET
Suitable extinguishing media : This material does not burn. If exposed to fire from another
source, use suitable extinguishing agent for that fire.
Unsuitable extinguishing : Do not use water.
media
Specific hazards during fire : Product reacts with water. Reaction may produce heat and/or
fighting gases.
This reaction may be violent.
Violent steam generation or eruption may occur upon
application of direct water stream to hot liquids.
3 / 16
SAFETY DATA SHEET
ucts
Further information : Keep people away. Isolate fire and deny unnecessary entry.
Water is not recommended, but may be applied in large
quantities as a fine spray when other extinguishing agents are
not available.
This material does not burn. Fight fire for other material that is
burning.
Special protective equipment : Wear positive-pressure self-contained breathing apparatus
for fire-fighters (SCBA) and protective fire fighting clothing (includes fire
fighting helmet, coat, trousers, boots, and gloves).
Avoid contact with this material during fire fighting operations.
If contact is likely, change to full chemical resistant fire fighting
clothing with self-contained breathing apparatus. If this is not
available, wear full chemical resistant clothing with self-
contained breathing apparatus and fight fire from a remote
location.
For protective equipment in post-fire or non-fire clean-up
situations, refer to the relevant sections.
Environmental precautions : Prevent from entering into soil, ditches, sewers, waterways
and/or groundwater. See Section 12, Ecological Information.
4 / 16
SAFETY DATA SHEET
5 / 16
SAFETY DATA SHEET
Color : Colorless
Odor : Odorless
pH : 14
Method: Literature
Pour point :
Softening point
Boiling point/boiling range : Method: ASTM D1120
6 / 16
SAFETY DATA SHEET
Solubility(ies)
Water solubility : completely miscible
Viscosity
Viscosity, dynamic : No data available
Explosive properties : No
Oxidizing properties : No
Note: These are the Reference Points for these Physical Properties listed above, unless otherwise
noted in their respective Physical Property value information: Boiling Point at 760 mmHg; Evaporation
Rate Butyl Acetate = 1; Relative Vapor Density Air = 1; and Relative Density Water = 1.
NOTE: The physical data presented above are typical values and should not be construed as a
specification.
7 / 16
SAFETY DATA SHEET
Acute toxicity
Product:
Acute oral toxicity : Remarks: Moderate toxicity if swallowed.
Swallowing may result in burns of the mouth and throat.
Swallowing may result in gastrointestinal irritation or ulceration.
Acute inhalation toxicity : Remarks: Mist may cause severe irritation of upper respiratory tract
(nose and throat).
Remarks: As product:
The LC50 has not been determined.
Acute dermal toxicity : Remarks: Prolonged skin contact is unlikely to result in absorption
of harmful amounts.
Components:
Sodium hydroxide:
Acute oral toxicity : LD50 (Rabbit): 336 mg/kg
Method: Estimated.
Acute inhalation toxicity : Remarks: The LC50 has not been determined.
Acute dermal toxicity : Remarks: The dermal LD50 has not been determined.
Skin corrosion/irritation
Product:
Result : Causes burns.
Remarks : Brief contact may cause skin burns. Symptoms may include pain,
severe local redness and tissue damage.
Components:
Sodium hydroxide:
Result : Causes severe burns.
Remarks : Brief contact may cause severe skin burns. Symptoms may include
pain, severe local redness and tissue damage.
8 / 16
SAFETY DATA SHEET
Product:
Remarks : Due to the pH of the material, it is assumed that exposure
may cause severe irritation with corneal injury which may re-
sult in permanent impairment of vision, even blindness.
Mist may cause eye irritation.
Components:
Sodium hydroxide:
Result : Corrosive
Remarks : May cause severe irritation with corneal injury which may re-
sult in permanent impairment of vision, even blindness. Chem-
ical burns may occur.
Dust may irritate eyes.
Product:
Remarks : For skin sensitization:
No relevant data found.
Components:
Sodium hydroxide:
Assessment : Does not cause skin sensitization.
Remarks : Did not cause allergic skin reactions when tested in humans.
Product:
Genotoxicity in vitro : Remarks: For the major component(s):
In vitro genetic toxicity studies were negative.
Components:
Sodium hydroxide:
Genotoxicity in vitro : Remarks: In vitro genetic toxicity studies were negative.
Carcinogenicity
Product:
Remarks : No relevant data found.
9 / 16
SAFETY DATA SHEET
Components:
Sodium hydroxide:
Remarks : No relevant data found.
IARC No ingredient of this product present at levels greater than or equal to 0.1% is
identified as probable, possible or confirmed human carcinogen by IARC.
OSHA No component of this product present at levels greater than or equal to 0.1% is
on OSHA’s list of regulated carcinogens.
NTP No ingredient of this product present at levels greater than or equal to 0.1% is
identified as a known or anticipated carcinogen by NTP.
Reproductive toxicity
Product:
Effects on fertility : Remarks: No relevant data found.
Components:
Sodium hydroxide:
Effects on fertility : Remarks: No relevant data found.
STOT-single exposure
Product:
Assessment : Material is corrosive. Material is not classified as a respiratory
irritant; however, upper respiratory tract irritation or corrosivity
may be expected.
Components:
Sodium hydroxide:
Assessment : Available data are inadequate to determine single exposure
specific target organ toxicity.
Product:
Remarks : Based on available data, repeated exposures are not anticipated to
cause additional significant adverse effects.
Components:
Sodium hydroxide:
Remarks : Based on available data, repeated exposures are not anticipated to
cause additional significant adverse effects.
10 / 16
SAFETY DATA SHEET
Aspiration toxicity
Product:
Aspiration into the lungs may occur during ingestion or vomiting, causing tissue damage or lung
injury.
Components:
Sodium hydroxide:
Aspiration into the lungs may occur during ingestion or vomiting, causing tissue damage or lung
injury.
Ecotoxicity
Components:
Sodium hydroxide:
Toxicity to fish : Remarks: May increase pH of aquatic systems to > pH 10 which
may be toxic to aquatic organisms.
Components:
Sodium hydroxide:
Biodegradability : Remarks: Biodegradability is not applicable to inorganic substances.
Bioaccumulative potential
Components:
Sodium hydroxide:
Partition coefficient: n- : Remarks: No bioconcentration is expected because of the relatively
octanol/water high water solubility.
Mobility in soil
Components:
Sodium hydroxide:
Distribution among environ- : Koc: 14
mental compartments Method: Estimated.
Remarks: Potential for mobility in soil is very high (Koc between 0
and 50).
11 / 16
SAFETY DATA SHEET
Components:
Sodium hydroxide:
Results of PBT and vPvB as- : This substance is not considered to be persistent, bioaccumulating
sessment and toxic (PBT). This substance is not considered to be very persis-
tent and very bioaccumulating (vPvB).
Disposal methods
Waste from residues : AS YOUR SUPPLIER, WE HAVE NO CONTROL OVER THE
MANAGEMENT PRACTICES OR MANUFACTURING
PROCESSES OF PARTIES HANDLING OR USING THIS
MATERIAL.
THE INFORMATION PRESENTED HERE PERTAINS ONLY
TO THE PRODUCT AS SHIPPED IN ITS INTENDED
CONDITION AS DESCRIBED IN MSDS SECTION:
Composition Information.
All disposal practices must be in compliance with all Federal,
State/Provincial and local laws and regulations.
Regulations may vary in different locations.
Waste characterizations and compliance with applicable laws
are the responsibility solely of the waste generator.
DO NOT DUMP INTO ANY SEWERS, ON THE GROUND,
OR INTO ANY BODY OF WATER.
International Regulations
UNRTDG
UN number : UN 1824
Proper shipping name : SODIUM HYDROXIDE SOLUTION
Class : 8
Packing group : II
Labels : 8
IATA-DGR
UN/ID No. : UN 1824
Proper shipping name : Sodium hydroxide solution
Class : 8
Packing group : II
Labels : Corrosive
Packing instruction (cargo air- : 855
craft)
Packing instruction (passenger : 851
aircraft)
IMDG-Code
UN number : UN 1824
Proper shipping name : SODIUM HYDROXIDE SOLUTION
Class : 8
12 / 16
SAFETY DATA SHEET
Packing group : II
Labels : 8
EmS Code : F-A, S-B
Marine pollutant : no
Remarks : Stowage category AAlkalis
Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code
Not applicable for product as supplied.
Domestic regulation
49 CFR
UN/ID/NA number : UN 1824
Proper shipping name : Sodium hydroxide solution
Class : 8
Packing group : II
Labels : CORROSIVE
ERG Code : 154
Marine pollutant : no
Special precautions for user
The transport classification(s) provided herein are for informational purposes only, and solely
based upon the properties of the unpackaged material as it is described within this Safety Data
Sheet. Transportation classifications may vary by mode of transportation, package sizes, and
variations in regional or country regulations.
SARA 313 : This material does not contain any chemical components with
known CAS numbers that exceed the threshold (De Minimis)
reporting levels established by SARA Title III, Section 313.
US State Regulations
13 / 16
SAFETY DATA SHEET
Further information
14 / 16
SAFETY DATA SHEET
NFPA 704:
Flammability
0
Health Instability
3 1
Special hazard
AIIC - Australian Inventory of Industrial Chemicals; ASTM - American Society for the Testing of
Materials; bw - Body weight; CERCLA - Comprehensive Environmental Response, Compensation,
and Liability Act; CMR - Carcinogen, Mutagen or Reproductive Toxicant; DIN - Standard of the
German Institute for Standardisation; DOT - Department of Transportation; DSL - Domestic Sub-
stances List (Canada); ECx - Concentration associated with x% response; EHS - Extremely Haz-
ardous Substance; ELx - Loading rate associated with x% response; EmS - Emergency Schedule;
ENCS - Existing and New Chemical Substances (Japan); ErCx - Concentration associated with
x% growth rate response; ERG - Emergency Response Guide; GHS - Globally Harmonized Sys-
tem; GLP - Good Laboratory Practice; HMIS - Hazardous Materials Identification System; IARC -
International Agency for Research on Cancer; IATA - International Air Transport Association; IBC
- International Code for the Construction and Equipment of Ships carrying Dangerous Chemicals
in Bulk; IC50 - Half maximal inhibitory concentration; ICAO - International Civil Aviation Organiza-
tion; IECSC - Inventory of Existing Chemical Substances in China; IMDG - International Maritime
Dangerous Goods; IMO - International Maritime Organization; ISHL - Industrial Safety and Health
Law (Japan); ISO - International Organisation for Standardization; KECI - Korea Existing Chemi-
cals Inventory; LC50 - Lethal Concentration to 50 % of a test population; LD50 - Lethal Dose to
50% of a test population (Median Lethal Dose); MARPOL - International Convention for the Pre-
vention of Pollution from Ships; MSHA - Mine Safety and Health Administration; n.o.s. - Not Oth-
erwise Specified; NFPA - National Fire Protection Association; NO(A)EC - No Observed (Adverse)
Effect Concentration; NO(A)EL - No Observed (Adverse) Effect Level; NOELR - No Observable
Effect Loading Rate; NTP - National Toxicology Program; NZIoC - New Zealand Inventory of
Chemicals; OECD - Organization for Economic Co-operation and Development; OPPTS - Office
of Chemical Safety and Pollution Prevention; PBT - Persistent, Bioaccumulative and Toxic sub-
stance; PICCS - Philippines Inventory of Chemicals and Chemical Substances; (Q)SAR - (Quanti-
15 / 16
SAFETY DATA SHEET
tative) Structure Activity Relationship; RCRA - Resource Conservation and Recovery Act;
REACH - Regulation (EC) No 1907/2006 of the European Parliament and of the Council concern-
ing the Registration, Evaluation, Authorisation and Restriction of Chemicals; RQ - Reportable
Quantity; SADT - Self-Accelerating Decomposition Temperature; SARA - Superfund Amend-
ments and Reauthorization Act; SDS - Safety Data Sheet; TCSI - Taiwan Chemical Substance
Inventory; TECI - Thailand Existing Chemicals Inventory; TSCA - Toxic Substances Control Act
(United States); UN - United Nations; UNRTDG - United Nations Recommendations on the
Transport of Dangerous Goods; vPvB - Very Persistent and Very Bioaccumulative
Olin Corporation (OCAP) urges each customer or recipient of this (M)SDS to study it carefully
and consult appropriate expertise, as necessary or appropriate, to become aware of and under-
stand the data contained in this (M)SDS and any hazards associated with the product. The in-
formation herein is provided in good faith and believed to be accurate as of the effective date
shown above. However, no warranty, express or implied, is given.Regulatory requirements are
subject to change and may differ between various locations. It is the buyer's/user's responsibility
to ensure that his activities comply with all federal, state, provincial or local laws. The information
presented here pertains only to the product as shipped. Since conditions for use of the product
are not under the control of the manufacturer, it is the buyer's/user's duty to determine the condi-
tions necessary for the safe use of this product. Due to the proliferation of sources for information
such as manufacturer-specific (M)SDSs, we are not and cannot be responsible for (M)SDSs ob-
tained from any source other than ourselves. If you have obtained an (M)SDS from another
source or if you are not sure that the (M)SDS you have is current, please contact us for the most
current version.
US / Z8
16 / 16