SAFETY DATA SHEET

1. Identification
Product identifier Dykem® High Purity Action Marker - Red
Other means of identification
Part Number 44301
Synonyms Hi Purity AM 33- Fine, and 44-Medium * FORMULA CODE: * T301 (Red)
Recommended use Solvent based marker
Recommended restrictions None known.
Manufacturer/Importer/Supplier/Distributor information
Manufacturer
Company name ITW Pro Brands
Address 805 E. Old 56 Highway
Olathe, KS 66061
Country (U.S.A.)
Tel: +1 800-443-9536
In Case of Emergency 1-800-535-5053 (Infotrac)

2. Hazard(s) identification
Physical hazards Flammable liquids Category 3
Health hazards Skin corrosion/irritation Category 2
Serious eye damage/eye irritation Category 2A
Carcinogenicity Category 2
Specific target organ toxicity, single exposure Category 3 respiratory tract irritation
Specific target organ toxicity, single exposure Category 3 narcotic effects
Environmental hazards Not classified.
OSHA defined hazards Not classified.

Label elements

Signal word Warning

Hazard statement Flammable liquid and vapor. Causes skin irritation. Causes serious eye irritation. May cause
respiratory irritation. May cause drowsiness or dizziness. Suspected of causing cancer.
Precautionary statement
Prevention Obtain special instructions before use. Do not handle until all safety precautions have been read
and understood. Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Keep
container tightly closed. Ground/bond container and receiving equipment. Use explosion-proof
electrical/ventilating/lighting equipment. Use only non-sparking tools. Take precautionary
measures against static discharge. Avoid breathing mist/vapors. Wash thoroughly after handling.
Use only outdoors or in a well-ventilated area. Wear protective gloves/protective clothing/eye
protection/face protection.
Response If on skin (or hair): Take off immediately all contaminated clothing. Rinse skin with water/shower.
If inhaled: Remove person to fresh air and keep comfortable for breathing. If in eyes: Rinse
cautiously with water for several minutes. Remove contact lenses, if present and easy to do.
Continue rinsing. If exposed or concerned: Get medical advice/attention. If skin irritation occurs:
Get medical advice/attention. If eye irritation persists: Get medical advice/attention. Take off
contaminated clothing and wash it before reuse. In case of fire: Use appropriate media to
extinguish.
Storage Keep cool. Store in a well-ventilated place. Keep container tightly closed. Store locked up.
Disposal Dispose of contents/container in accordance with local/regional/national/international regulations.

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Hazard(s) not otherwise None known.
classified (HNOC)
Supplemental information None.

3. Composition/information on ingredients
Mixtures
Chemical name Common name and synonyms CAS number %
Aromatic Solvent 64742-95-6 30 - 40
1,2,4-Trimethylbenzene 95-63-6 15 - 20
Solvent Naptha 64741-65-7 1-5
Xylene 1330-20-7 1-2
Cumene 98-82-8 0.1 - 1

4. First-aid measures
Inhalation Remove victim to fresh air and keep at rest in a position comfortable for breathing. Call a poison
center or doctor/physician if you feel unwell.
Skin contact Take off immediately all contaminated clothing. Rinse skin with water/shower. If skin irritation
occurs: Get medical advice/attention. Wash contaminated clothing before reuse.
Eye contact Immediately flush eyes with plenty of water for at least 15 minutes. Remove contact lenses, if
present and easy to do. Continue rinsing. Get medical attention if irritation develops and persists.
Ingestion Rinse mouth. Get medical attention if symptoms occur.
Most important May cause drowsiness or dizziness. Headache. Nausea, vomiting. Severe eye irritation.
symptoms/effects, acute and Symptoms may include stinging, tearing, redness, swelling, and blurred vision. May cause
delayed respiratory irritation. Skin irritation. May cause redness and pain.
Indication of immediate Provide general supportive measures and treat symptomatically. Thermal burns: Flush with water
medical attention and special immediately. While flushing, remove clothes which do not adhere to affected area. Call an
treatment needed ambulance. Continue flushing during transport to hospital. Keep victim under observation.
Symptoms may be delayed.
General information Take off all contaminated clothing immediately. IF exposed or concerned: Get medical
advice/attention. If you feel unwell, seek medical advice (show the label where possible). Ensure
that medical personnel are aware of the material(s) involved, and take precautions to protect
themselves. Wash contaminated clothing before reuse.

5. Fire-fighting measures
Suitable extinguishing media Water fog. Alcohol resistant foam. Dry chemical powder. Carbon dioxide (CO2).
Unsuitable extinguishing Do not use water jet as an extinguisher, as this will spread the fire.
media
Specific hazards arising from Vapors may form explosive mixtures with air. Vapors may travel considerable distance to a source
the chemical of ignition and flash back. During fire, gases hazardous to health may be formed.
Special protective equipment Self-contained breathing apparatus and full protective clothing must be worn in case of fire.
and precautions for firefighters
Fire fighting In case of fire and/or explosion do not breathe fumes. Move containers from fire area if you can do
equipment/instructions so without risk.
Specific methods Use standard firefighting procedures and consider the hazards of other involved materials.
General fire hazards Flammable liquid and vapor.

6. Accidental release measures

Personal precautions, Keep unnecessary personnel away. Keep people away from and upwind of spill/leak. Eliminate all
protective equipment and ignition sources (no smoking, flares, sparks, or flames in immediate area). Wear appropriate
emergency procedures protective equipment and clothing during clean-up. Avoid breathing mist/vapors. Do not touch
damaged containers or spilled material unless wearing appropriate protective clothing. Ventilate
closed spaces before entering them. Local authorities should be advised if significant spillages
cannot be contained. For personal protection, see section 8 of the SDS.

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Methods and materials for Eliminate all ignition sources (no smoking, flares, sparks, or flames in immediate area). Keep
containment and cleaning up combustibles (wood, paper, oil, etc.) away from spilled material. Take precautionary measures
against static discharge. Use only non-sparking tools.

Large Spills: Stop the flow of material, if this is without risk. Dike the spilled material, where this is
possible. Use a non-combustible material like vermiculite, sand or earth to soak up the product
and place into a container for later disposal. Following product recovery, flush area with water.

Small Spills: Absorb with earth, sand or other non-combustible material and transfer to containers
for later disposal. Wipe up with absorbent material (e.g. cloth, fleece). Clean surface thoroughly to
remove residual contamination.

Never return spills to original containers for re-use. Put material in suitable, covered, labeled
containers. For waste disposal, see section 13 of the SDS.
Environmental precautions Avoid discharge into drains, water courses or onto the ground.

7. Handling and storage

Precautions for safe handling Obtain special instructions before use. Do not handle until all safety precautions have been read
and understood. Do not handle, store or open near an open flame, sources of heat or sources of
ignition. Protect material from direct sunlight. When using do not smoke. Explosion-proof general
and local exhaust ventilation. Take precautionary measures against static discharges. All
equipment used when handling the product must be grounded. Use non-sparking tools and
explosion-proof equipment. Avoid breathing mist/vapors. Avoid contact with eyes, skin, and
clothing. Avoid prolonged exposure. Should be handled in closed systems, if possible. Wear
appropriate personal protective equipment. Observe good industrial hygiene practices.
Conditions for safe storage, Store locked up. Keep away from heat, sparks and open flame. Prevent electrostatic charge
including any incompatibilities build-up by using common bonding and grounding techniques. Store in a cool, dry place out of
direct sunlight. Store in tightly closed container. Store in a well-ventilated place. Keep in an area
equipped with sprinklers. Store away from incompatible materials (see Section 10 of the SDS).

8. Exposure controls/personal protection

Occupational exposure limits
The following constituents are the only constituents of the product which have a PEL, TLV or other recommended exposure limit.
At this time, the other constituents have no known exposure limits.
US. OSHA Table Z-1 Limits for Air Contaminants (29 CFR 1910.1000)
Components Type Value
Cumene (CAS 98-82-8) PEL 245 mg/m3
50 ppm
Xylene (CAS 1330-20-7) PEL 435 mg/m3
100 ppm

US. ACGIH Threshold Limit Values

Components Type Value
Cumene (CAS 98-82-8) TWA 50 ppm
Xylene (CAS 1330-20-7) STEL 150 ppm
TWA 100 ppm

US. NIOSH: Pocket Guide to Chemical Hazards

Components Type Value
1,2,4-Trimethylbenzene TWA 125 mg/m3
(CAS 95-63-6)
25 ppm
Cumene (CAS 98-82-8) TWA 245 mg/m3
50 ppm
Xylene (CAS 1330-20-7) STEL 655 mg/m3
150 ppm
TWA 435 mg/m3
100 ppm

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Biological limit values
ACGIH Biological Exposure Indices
Components Value Determinant Specimen Sampling Time
Xylene (CAS 1330-20-7) 1.5 g/g Methylhippuric Creatinine in *
acids urine
* - For sampling details, please see the source document.
Exposure guidelines
US - California OELs: Skin designation
Cumene (CAS 98-82-8) Can be absorbed through the skin.
US - Minnesota Haz Subs: Skin designation applies
Cumene (CAS 98-82-8) Skin designation applies.
US - Tennessee OELs: Skin designation
Cumene (CAS 98-82-8) Can be absorbed through the skin.
US NIOSH Pocket Guide to Chemical Hazards: Skin designation
Cumene (CAS 98-82-8) Can be absorbed through the skin.
US. OSHA Table Z-1 Limits for Air Contaminants (29 CFR 1910.1000)
Cumene (CAS 98-82-8) Can be absorbed through the skin.
Appropriate engineering Explosion-proof general and local exhaust ventilation. Good general ventilation should be used.
controls Ventilation rates should be matched to conditions. If applicable, use process enclosures, local
exhaust ventilation, or other engineering controls to maintain airborne levels below recommended
exposure limits. If exposure limits have not been established, maintain airborne levels to an
acceptable level. Provide eyewash station and safety shower.
Individual protection measures, such as personal protective equipment
Eye/face protection Not normally needed. If contact is likely, safety glasses with side shields are recommended.

Skin protection
Hand protection Wear appropriate chemical resistant gloves.
Other Wear appropriate chemical resistant clothing. Use of an impervious apron is recommended.
Respiratory protection If engineering controls do not maintain airborne concentrations below recommended exposure
limits (where applicable) or to an acceptable level (in countries where exposure limits have not
been established), an approved respirator must be worn.
Thermal hazards Wear appropriate thermal protective clothing, when necessary.

General hygiene Observe any medical surveillance requirements. When using do not smoke. Always observe good
considerations personal hygiene measures, such as washing after handling the material and before eating,
drinking, and/or smoking. Routinely wash work clothing and protective equipment to remove
contaminants.

9. Physical and chemical properties

Appearance
Physical state Liquid.
Form Liquid.
Color Red.
Odor Aromatic.
Odor threshold Not available.
pH Not available.
Melting point/freezing point Not available.
Initial boiling point and boiling 248 - 338 °F (120 - 170 °C)
range
Flash point 89.0 - 108.0 °F (31.7 - 42.2 °C)
Evaporation rate < 1 (BuAc = 1)
Flammability (solid, gas) Not applicable.
Upper/lower flammability or explosive limits
Flammability limit - lower 1%
(%)
Flammability limit - upper 12.6 %
(%)

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 Explosive limit - lower (%) Not available.
Explosive limit - upper (%) Not available.
Vapor pressure Not available.
Vapor density > 1 (air = 1)
Relative density > 1 @ 70°F
Solubility(ies)
Solubility (water) Not available.
Partition coefficient Not available.
(n-octanol/water)
Auto-ignition temperature Not available.
Decomposition temperature Not available.
Viscosity Not available.
Other information
Explosive properties Not explosive.
Oxidizing properties Not oxidizing.
VOC 71.9%, 669 g/L

10. Stability and reactivity

Reactivity The product is stable and non-reactive under normal conditions of use, storage and transport.
Chemical stability Material is stable under normal conditions.
Possibility of hazardous Hazardous polymerization does not occur.
reactions
Conditions to avoid Avoid heat, sparks, open flames and other ignition sources. Avoid temperatures exceeding the
decomposition temperature. Avoid temperatures exceeding the flash point. Contact with
incompatible materials.
Incompatible materials Strong oxidizing agents.
Hazardous decomposition Carbon oxides.
products

11. Toxicological information

Information on likely routes of exposure
Inhalation May cause drowsiness or dizziness. Headache. Nausea, vomiting. May cause irritation to the
respiratory system. Prolonged inhalation may be harmful.
Skin contact Causes skin irritation.
Eye contact Causes serious eye irritation.
Ingestion Expected to be a low ingestion hazard.
Symptoms related to the May cause drowsiness or dizziness. Headache. Nausea, vomiting. Severe eye irritation.
physical, chemical and Symptoms may include stinging, tearing, redness, swelling, and blurred vision. May cause
toxicological characteristics respiratory irritation. Skin irritation. May cause redness and pain.
Information on toxicological effects
Acute toxicity Not expected to be acutely toxic.
Components Species Test Results
1,2,4-Trimethylbenzene (CAS 95-63-6)
Acute
Dermal
LD50 Rabbit > 3200 mg/kg
Inhalation
LC50 Rat 10000 mg/m3, 4 Hours
Oral
LD50 Rat 3300 mg/kg

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Components Species Test Results
Aromatic Solvent (CAS 64742-95-6)
Acute
Dermal
LD50 Rabbit > 1900 mg/kg, 24 Hours
Inhalation
Vapor
LC50 Rat > 5 mg/l, 4 Hours
Oral
LD50 Rat 4800 mg/kg
Cumene (CAS 98-82-8)
Acute
Dermal
LD50 Rabbit > 3200 mg/kg, 24 Hours
Inhalation
Vapor
LC50 Mouse 10 mg/l, 7 Hours
Fully Dimerized Resin (CAS 65997-05-9)
Acute
Dermal
LD50 Rat > 2000 mg/kg, 24 Hours
Oral
LD50 Rat 1000 - 2000 mg/kg
Xylene (CAS 1330-20-7)
Acute
Dermal
LD50 Rabbit 12000 mg/kg, 24 Hours
Inhalation
LC50 Rat 6400 mg/l, 4 Hours
Oral
LD50 Rat 3500 mg/kg
Skin corrosion/irritation Causes skin irritation.
Serious eye damage/eye Causes serious eye irritation.
irritation
Respiratory or skin sensitization
Respiratory sensitization Not a respiratory sensitizer.
Skin sensitization This product is not expected to cause skin sensitization.
Germ cell mutagenicity No data available to indicate product or any components present at greater than 0.1% are
mutagenic or genotoxic.
Carcinogenicity Suspected of causing cancer.
ACGIH Carcinogens
Xylene (CAS 1330-20-7) A4 Not classifiable as a human carcinogen.
IARC Monographs. Overall Evaluation of Carcinogenicity
Cumene (CAS 98-82-8) 2B Possibly carcinogenic to humans.
Xylene (CAS 1330-20-7) 3 Not classifiable as to carcinogenicity to humans.
OSHA Specifically Regulated Substances (29 CFR 1910.1001-1053)
Not listed.
US. National Toxicology Program (NTP) Report on Carcinogens
Cumene (CAS 98-82-8) Reasonably Anticipated to be a Human Carcinogen.
Reproductive toxicity This product is not expected to cause reproductive or developmental effects.
Specific target organ toxicity - May cause respiratory irritation. May cause drowsiness or dizziness.
single exposure

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Specific target organ toxicity - Not classified.
repeated exposure
Aspiration hazard Not likely, due to the form of the product.
Chronic effects Prolonged inhalation may be harmful. Prolonged exposure may cause chronic effects.

12. Ecological information

Ecotoxicity The product is not classified as environmentally hazardous. However, this does not exclude the
possibility that large or frequent spills can have a harmful or damaging effect on the environment.
Components Species Test Results
1,2,4-Trimethylbenzene (CAS 95-63-6)
Aquatic
Fish LC50 Fathead minnow (Pimephales promelas) 7.19 - 8.28 mg/l, 96 hours
Cumene (CAS 98-82-8)
Aquatic
Crustacea EC50 Brine shrimp (Artemia sp.) 3.55 - 11.29 mg/l, 48 hours
Fish LC50 Rainbow trout,donaldson trout 2.7 mg/l, 96 hours
(Oncorhynchus mykiss)
Xylene (CAS 1330-20-7)
Aquatic
Fish LC50 Bluegill (Lepomis macrochirus) 7.711 - 9.591 mg/l, 96 hours
Persistence and degradability No data is available on the degradability of any ingredients in the mixture.
Bioaccumulative potential
Partition coefficient n-octanol / water (log Kow)
Cumene 3.66
Xylene 3.12 - 3.2
Mobility in soil Not established.
Other adverse effects None known.

13. Disposal considerations

Disposal instructions Collect and reclaim or dispose in sealed containers at licensed waste disposal site. Incinerate the
material under controlled conditions in an approved incinerator. Do not incinerate sealed
containers. If discarded, this product is considered a RCRA ignitable waste, D001. Dispose of
contents/container in accordance with local/regional/national/international regulations.
Local disposal regulations Dispose in accordance with all applicable regulations.
Hazardous waste code D001: Waste Flammable material with a flash point <140 F
The waste code should be assigned in discussion between the user, the producer and the waste
disposal company.
Waste from residues / unused Dispose of in accordance with local regulations. Empty containers or liners may retain some
products product residues. This material and its container must be disposed of in a safe manner (see:
Disposal instructions).
Contaminated packaging Since emptied containers may retain product residue, follow label warnings even after container is
emptied. Empty containers should be taken to an approved waste handling site for recycling or
disposal.

14. Transport information

DOT
UN number UN1263
UN proper shipping name Paint related material including paint thinning, drying, removing, or reducing compound
Transport hazard class(es)
Class 3
Subsidiary risk -
Label(s) 3
Packing group III
Special precautions for user Read safety instructions, SDS and emergency procedures before handling.
Special provisions B1, B52, IB3, T2, TP1, TP29
Packaging exceptions 150
Packaging non bulk 173
Packaging bulk 242
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IATA
UN number UN1263
UN proper shipping name Paint related material (including paint thinning or reducing compounds)
Transport hazard class(es)
Class 3
Subsidiary risk -
Packing group III
Environmental hazards No.
ERG Code 3L
Special precautions for user Read safety instructions, SDS and emergency procedures before handling.
Other information
Passenger and cargo Allowed with restrictions.
aircraft
Cargo aircraft only Allowed with restrictions.
IMDG
UN number UN1263
UN proper shipping name PAINT (including paint, lacquer, enamel, stain, shellac, varnish, polish, liquid filler and liquid
lacquer base) or PAINT RELATED MATERIAL (including paint thinning or reducing compound)
Transport hazard class(es)
Class 3
Subsidiary risk -
Packing group III
Environmental hazards
Marine pollutant No.
EmS F-E, S̲ -E̲
Special precautions for user Read safety instructions, SDS and emergency procedures before handling.
Transport in bulk according to Not applicable.
Annex II of MARPOL 73/78 and
the IBC Code
DOT

IATA; IMDG

15. Regulatory information

US federal regulations This product is a "Hazardous Chemical" as defined by the OSHA Hazard Communication
Standard, 29 CFR 1910.1200.
Toxic Substances Control Act (TSCA)
TSCA Section 12(b) Export Notification (40 CFR 707, Subpt. D)
Not regulated.

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 CERCLA Hazardous Substance List (40 CFR 302.4)
Cumene (CAS 98-82-8) Listed.
Xylene (CAS 1330-20-7) Listed.
SARA 304 Emergency release notification
Not regulated.
OSHA Specifically Regulated Substances (29 CFR 1910.1001-1053)
Not listed.
Superfund Amendments and Reauthorization Act of 1986 (SARA)
SARA 302 Extremely hazardous substance
Not listed.
SARA 311/312 Hazardous Yes
chemical
Classified hazard Flammable (gases, aerosols, liquids, or solids)
categories Skin corrosion or irritation
Serious eye damage or eye irritation
Carcinogenicity
Specific target organ toxicity (single or repeated exposure)
SARA 313 (TRI reporting)
Chemical name CAS number % by wt.
1,2,4-TRIMETHYLBENZENE 95-63-6 15 - 20
CUMENE 98-82-8 0.1 - 1
Xylene (mixed isomers) 1330-20-7 1-2
Other federal regulations
Clean Air Act (CAA) Section 112 Hazardous Air Pollutants (HAPs) List
Cumene (CAS 98-82-8)
Xylene (CAS 1330-20-7)
Clean Air Act (CAA) Section 112(r) Accidental Release Prevention (40 CFR 68.130)
Not regulated.
Safe Drinking Water Act Not regulated.
(SDWA)
US state regulations
US. New Jersey Worker and Community Right-to-Know Act
1,2,4-Trimethylbenzene (CAS 95-63-6)
Cumene (CAS 98-82-8)
Xylene (CAS 1330-20-7)
California Proposition 65
WARNING: This product can expose you to chemicals including Cumene, which is known to the State of
California to cause cancer. For more information go to www.P65Warnings.ca.gov.

California Proposition 65 - CRT: Listed date/Carcinogenic substance

Cumene (CAS 98-82-8) Listed: April 6, 2010
US. California. Candidate Chemicals List. Safer Consumer Products Regulations (Cal. Code Regs, tit. 22, 69502.3,
subd. (a))
1,2,4-Trimethylbenzene (CAS 95-63-6)
Aromatic Solvent (CAS 64742-95-6)
Cumene (CAS 98-82-8)
Solvent Naptha (CAS 64741-65-7)
Xylene (CAS 1330-20-7)
International Inventories
Country(s) or region Inventory name On inventory (yes/no)*
Australia Australian Inventory of Chemical Substances (AICS) Yes
Canada Domestic Substances List (DSL) Yes
Canada Non-Domestic Substances List (NDSL) No
China Inventory of Existing Chemical Substances in China (IECSC) Yes
Europe European Inventory of Existing Commercial Chemical No
Substances (EINECS)
Europe European List of Notified Chemical Substances (ELINCS) No

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 Country(s) or region Inventory name On inventory (yes/no)*
Japan Inventory of Existing and New Chemical Substances (ENCS) No
Korea Existing Chemicals List (ECL) Yes
New Zealand New Zealand Inventory Yes
Philippines Philippine Inventory of Chemicals and Chemical Substances Yes
(PICCS)
Taiwan Taiwan Chemical Substance Inventory (TCSI) Yes
United States & Puerto Rico Toxic Substances Control Act (TSCA) Inventory Yes
*A "Yes" indicates that all components of this product comply with the inventory requirements administered by the governing country(s)
A "No" indicates that one or more components of the product are not listed or exempt from listing on the inventory administered by the governing
country(s).

16. Other information, including date of preparation or last revision

Issue date 11-13-2020
Version # 01
Disclaimer The information provided in this Safety Data Sheet is correct to the best of our knowledge,
information and belief at the date of its publication. The information given is designed only as a
guidance for safe handling, use, processing, storage, transportation, disposal and release and is
not to be considered a warranty or quality specification. The information relates only to the specific
material designated and may not be valid for such material used in combination with any other
materials or in any process, unless specified in the text. ITW Pro Brands cannot anticipate all
conditions under which this information and its product, or the products of other manufacturers in
combination with its product, may be used. It is the user’s responsibility to ensure safe conditions
for handling, storage and disposal of the product, and to assume liability for loss, injury, damage or
expense due to improper use.

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