SAFETY DATA SHEET

1. Identification
Product identifier Irathane 155 Gray - Side B
Other means of identification
SKU# FW55121B
Recommended use Not available.
Recommended restrictions None known.
Manufacturer/Importer/Supplier/Distributor information
Manufacturer
Company name ITW Engineered Polymers
Address 130 Commerce Drive
Montgomeryville, PA 18936
United States
Telephone Customer Service 215-855-8450
Website www.itwengineeredpolymers.com
E-mail orders.na@itwep.com
Contact person EHS Department
Emergency phone number CHEMTREC 800-424-9300
International 703-527-3887

2. Hazard(s) identification
Physical hazards Flammable liquids Category 2
Health hazards Acute toxicity, dermal Category 4
Acute toxicity, inhalation Category 4
Serious eye damage/eye irritation Category 2A
Specific target organ toxicity, single exposure Category 3 narcotic effects
Specific target organ toxicity, repeated Category 2
exposure
Environmental hazards Hazardous to the aquatic environment, acute Category 2
hazard
Hazardous to the aquatic environment, Category 2
long-term hazard
OSHA defined hazards Not classified.

Label elements

Signal word Danger

Hazard statement Highly flammable liquid and vapor. Harmful in contact with skin. Causes serious eye irritation.
Harmful if inhaled. May cause drowsiness or dizziness. May cause damage to organs through
prolonged or repeated exposure. Toxic to aquatic life. Toxic to aquatic life with long lasting effects.
Precautionary statement
Prevention Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Keep container tightly
closed. Ground/bond container and receiving equipment. Use explosion-proof
electrical/ventilating/lighting equipment. Use only non-sparking tools. Take precautionary
measures against static discharge. Do not breathe mist or vapor. Wash thoroughly after handling.
Use only outdoors or in a well-ventilated area. Avoid release to the environment. Wear protective
gloves/protective clothing. Wear protective gloves/eye protection/face protection.

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 Response If on skin (or hair): Take off immediately all contaminated clothing. Rinse skin with water/shower.
If inhaled: Remove person to fresh air and keep comfortable for breathing. If in eyes: Rinse
cautiously with water for several minutes. Remove contact lenses, if present and easy to do.
Continue rinsing. Get medical advice/attention if you feel unwell. If eye irritation persists: Get
medical advice/attention. Take off contaminated clothing and wash before reuse. In case of fire:
Use appropriate media to extinguish. Collect spillage.
Storage Store in a well-ventilated place. Keep container tightly closed. Store in a well-ventilated place.
Keep cool. Store locked up.
Disposal Dispose of contents/container in accordance with local/regional/national/international regulations.
Hazard(s) not otherwise Static accumulating flammable liquid can become electrostatically charged even in bonded and
classified (HNOC) grounded equipment. Sparks may ignite liquid and vapor. May cause flash fire or explosion.
Supplemental information 87.97% of the mixture consists of component(s) of unknown acute hazards to the aquatic
environment. 87.97% of the mixture consists of component(s) of unknown long-term hazards to
the aquatic environment.

3. Composition/information on ingredients
Mixtures
Chemical name Common name and synonyms CAS number %
ETHYL ACETATE 141-78-6 60 - 100
Silicon Dioxide 112945-52-5 1-5
Titanium Dioxide 13463-67-7 1-5
Zeolites 1318-02-1 1-5
Other components below reportable levels 15 - 40
*Designates that a specific chemical identity and/or percentage of composition has been withheld as a trade secret.

4. First-aid measures
Inhalation Remove victim to fresh air and keep at rest in a position comfortable for breathing. Oxygen or
artificial respiration if needed. Call a physician if symptoms develop or persist.
Skin contact Take off immediately all contaminated clothing. Rinse skin with water/shower. Get medical
advice/attention if you feel unwell. Get medical attention if irritation develops and persists. Wash
contaminated clothing before reuse.
Eye contact Immediately flush eyes with plenty of water for at least 15 minutes. Remove contact lenses, if
present and easy to do. Continue rinsing. Get medical attention if irritation develops and persists.
Ingestion Rinse mouth. Get medical advice/attention if you feel unwell.
Most important May cause drowsiness and dizziness. Headache. Nausea, vomiting. Severe eye irritation.
symptoms/effects, acute and Symptoms may include stinging, tearing, redness, swelling, and blurred vision. Prolonged
delayed exposure may cause chronic effects.
Indication of immediate Provide general supportive measures and treat symptomatically. Thermal burns: Flush with water
medical attention and special immediately. While flushing, remove clothes which do not adhere to affected area. Call an
treatment needed ambulance. Continue flushing during transport to hospital. Keep victim warm. Keep victim under
observation. Symptoms may be delayed.
General information Take off all contaminated clothing immediately. If you feel unwell, seek medical advice (show the
label where possible). Ensure that medical personnel are aware of the material(s) involved, and
take precautions to protect themselves. Show this safety data sheet to the doctor in attendance.
Wash contaminated clothing before reuse.

5. Fire-fighting measures
Suitable extinguishing media Water fog. Alcohol resistant foam. Carbon dioxide (CO2). Dry chemical powder, carbon dioxide,
sand or earth may be used for small fires only.
Unsuitable extinguishing Do not use water jet as an extinguisher, as this will spread the fire.
media
Specific hazards arising from Vapors may form explosive mixtures with air. Vapors may travel considerable distance to a source
the chemical of ignition and flash back. This product is a poor conductor of electricity and can become
electrostatically charged. If sufficient charge is accumulated, ignition of flammable mixtures can
occur. To reduce potential for static discharge, use proper bonding and grounding procedures.
This liquid may accumulate static electricity when filling properly grounded containers. Static
electricity accumulation may be significantly increased by the presence of small quantities of water
or other contaminants. Material will float and may ignite on surface of water. During fire, gases
hazardous to health may be formed.

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Special protective equipment Self-contained breathing apparatus and full protective clothing must be worn in case of fire.
and precautions for firefighters
Fire fighting In case of fire and/or explosion do not breathe fumes. Move containers from fire area if you can do
equipment/instructions so without risk.
Specific methods Use standard firefighting procedures and consider the hazards of other involved materials.
General fire hazards Highly flammable liquid and vapor.

6. Accidental release measures

Personal precautions, Keep unnecessary personnel away. Keep people away from and upwind of spill/leak. Eliminate all
protective equipment and ignition sources (no smoking, flares, sparks, or flames in immediate area). Wear appropriate
emergency procedures protective equipment and clothing during clean-up. Do not breathe mist or vapor. Do not touch
damaged containers or spilled material unless wearing appropriate protective clothing. Ventilate
closed spaces before entering them. Use appropriate containment to avoid environmental
contamination. Transfer by mechanical means such as vacuum truck to a salvage tank or other
suitable container for recovery or safe disposal. Local authorities should be advised if significant
spillages cannot be contained. For personal protection, see section 8 of the SDS.
Methods and materials for Eliminate all ignition sources (no smoking, flares, sparks, or flames in immediate area). Keep
containment and cleaning up combustibles (wood, paper, oil, etc.) away from spilled material. Take precautionary measures
against static discharge. Use only non-sparking tools. Prevent entry into waterways, sewer,
basements or confined areas.

Large Spills: Stop the flow of material, if this is without risk. Dike the spilled material, where this is
possible. Use a non-combustible material like vermiculite, sand or earth to soak up the product
and place into a container for later disposal. Following product recovery, flush area with water.

Small Spills: Absorb with earth, sand or other non-combustible material and transfer to containers
for later disposal. Wipe up with absorbent material (e.g. cloth, fleece). Clean surface thoroughly to
remove residual contamination.

Never return spills to original containers for re-use. For waste disposal, see section 13 of the SDS.
Environmental precautions Avoid release to the environment. Inform appropriate managerial or supervisory personnel of all
environmental releases. Prevent further leakage or spillage if safe to do so. Avoid discharge into
drains, water courses or onto the ground. Use appropriate containment to avoid environmental
contamination.

7. Handling and storage

Precautions for safe handling Do not handle, store or open near an open flame, sources of heat or sources of ignition. Protect
material from direct sunlight. Explosion-proof general and local exhaust ventilation. Minimize fire
risks from flammable and combustible materials (including combustible dust and static
accumulating liquids) or dangerous reactions with incompatible materials. Handling operations that
can promote accumulation of static charges include but are not limited to: mixing, filtering,
pumping at high flow rates, splash filling, creating mists or sprays, tank and container filling, tank
cleaning, sampling, gauging, switch loading, vacuum truck operations. Take precautionary
measures against static discharges. All equipment used when handling the product must be
grounded. Use non-sparking tools and explosion-proof equipment. Do not breathe mist or vapor.
Avoid contact with eyes, skin, and clothing. Avoid prolonged exposure. When using, do not eat,
drink or smoke. Use only outdoors or in a well-ventilated area. Wear appropriate personal
protective equipment. Wash hands thoroughly after handling. Avoid release to the environment.
Wash contaminated clothing before reuse. Observe good industrial hygiene practices.

For additional information on equipment bonding and grounding, refer to the Canadian Electrical
Code in Canada, (CSA C22.1), or the American Petroleum Institute (API) Recommended Practice
2003, "Protection Against Ignitions Arising out of Static, Lightning, and Stray Currents" or National
Fire Protection Association (NFPA) 77, "Recommended Practice on Static Electricity" or National
Fire Protection Association (NFPA) 70, "National Electrical Code".

Conditions for safe storage, Store locked up. Keep away from heat, sparks and open flame. Prevent electrostatic charge
including any incompatibilities build-up by using common bonding and grounding techniques. Eliminate sources of ignition. Avoid
spark promoters. Ground/bond container and equipment. These alone may be insufficient to
remove static electricity. Store in a cool, dry place out of direct sunlight. Store in original tightly
closed container. Store in a well-ventilated place. Keep in an area equipped with sprinklers. Store
away from incompatible materials (see Section 10 of the SDS).

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8. Exposure controls/personal protection
Occupational exposure limits
US. OSHA Table Z-1 Limits for Air Contaminants (29 CFR 1910.1000)
Components Type Value Form

ETHYL ACETATE (CAS PEL 1400 mg/m3

141-78-6)
400 ppm
Titanium Dioxide (CAS PEL 15 mg/m3 Total dust.
13463-67-7)
US. OSHA Table Z-3 (29 CFR 1910.1000)
Components Type Value
Silicon Dioxide (CAS TWA 0.8 mg/m3
112945-52-5)
20 mppcf
US. ACGIH Threshold Limit Values
Components Type Value Form

ETHYL ACETATE (CAS TWA 400 ppm

141-78-6)
Titanium Dioxide (CAS TWA 10 mg/m3
13463-67-7)
Zeolites (CAS 1318-02-1) TWA 1 mg/m3 Respirable fraction.
US. NIOSH: Pocket Guide to Chemical Hazards
Components Type Value
ETHYL ACETATE (CAS TWA 1400 mg/m3
141-78-6)
400 ppm
Silicon Dioxide (CAS TWA 6 mg/m3
112945-52-5)
Biological limit values No biological exposure limits noted for the ingredient(s).
Appropriate engineering Explosion-proof general and local exhaust ventilation. Good general ventilation (typically 10 air
controls changes per hour) should be used. Ventilation rates should be matched to conditions. If
applicable, use process enclosures, local exhaust ventilation, or other engineering controls to
maintain airborne levels below recommended exposure limits. If exposure limits have not been
established, maintain airborne levels to an acceptable level. Provide eyewash station. Eye wash
fountain and emergency showers are recommended.
Individual protection measures, such as personal protective equipment
Eye/face protection Chemical respirator with organic vapor cartridge and full facepiece.
Skin protection
Hand protection Wear appropriate chemical resistant gloves. Suitable gloves can be recommended by the glove
supplier.
Other Wear appropriate chemical resistant clothing. Use of an impervious apron is recommended.
Respiratory protection Chemical respirator with organic vapor cartridge and full facepiece.
Thermal hazards Wear appropriate thermal protective clothing, when necessary.
General hygiene When using do not smoke. Always observe good personal hygiene measures, such as washing
considerations after handling the material and before eating, drinking, and/or smoking. Routinely wash work
clothing and protective equipment to remove contaminants.

9. Physical and chemical properties

Appearance Liquid.
Physical state Liquid.
Form Liquid.
Color Gray or Orange
Odor Strong. Solvent.
Odor threshold Not available.
pH 7 - 8 @ 5 Percent Solution

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Melting point/freezing point Not available.
Initial boiling point and boiling > 170 °F (> 76.67 °C)
range
Flash point 24.0 °F (-4.4 °C)
Evaporation rate > 1 BuAc
Flammability (solid, gas) Not applicable.
Upper/lower flammability or explosive limits
Flammability limit - lower Not available.
(%)
Flammability limit - upper Not available.
(%)
Explosive limit - lower (%) Not available.
Explosive limit - upper (%) Not available.
Vapor pressure Not available.
Vapor density >1
Relative density Not available.
Solubility(ies)
Solubility (water) Not available.
Partition coefficient Not available.
(n-octanol/water)
Auto-ignition temperature Not available.
Decomposition temperature Not available.
Viscosity Not available.
Other information
Density 8.45 lb/gal
Explosive properties Not explosive.
Flammability class Flammable IB estimated
Oxidizing properties Not oxidizing.
Specific gravity 1.01
VOC 653 g/l

10. Stability and reactivity

Reactivity The product is stable and non-reactive under normal conditions of use, storage and transport.
Chemical stability Material is stable under normal conditions.
Possibility of hazardous Hazardous polymerization does not occur.
reactions
Conditions to avoid Avoid heat, sparks, open flames and other ignition sources. Avoid temperatures exceeding the
flash point. Contact with incompatible materials.
Incompatible materials Nitrates.
Hazardous decomposition No hazardous decomposition products are known.
products

11. Toxicological information

Information on likely routes of exposure
Inhalation Harmful if inhaled. May cause damage to organs through prolonged or repeated exposure by
inhalation. May cause drowsiness and dizziness. Headache. Nausea, vomiting.
Skin contact Harmful in contact with skin.
Eye contact Causes serious eye irritation.
Ingestion Expected to be a low ingestion hazard.
Symptoms related to the May cause drowsiness and dizziness. Headache. Nausea, vomiting. Severe eye irritation.
physical, chemical and Symptoms may include stinging, tearing, redness, swelling, and blurred vision.
toxicological
characteristics

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Information on toxicological effects
Acute toxicity Harmful if inhaled. Harmful in contact with skin. Narcotic effects.
Skin corrosion/irritation Prolonged skin contact may cause temporary irritation.
Serious eye damage/eye Causes serious eye irritation.
irritation
Respiratory or skin sensitization
Respiratory sensitization Not a respiratory sensitizer.
Skin sensitization This product is not expected to cause skin sensitization.
Germ cell mutagenicity No data available to indicate product or any components present at greater than 0.1% are
mutagenic or genotoxic.
Carcinogenicity This product is not considered to be a carcinogen by IARC, ACGIH, NTP, or OSHA.
IARC Monographs. Overall Evaluation of Carcinogenicity
Silicon Dioxide (CAS 112945-52-5) 3 Not classifiable as to carcinogenicity to humans.
Titanium Dioxide (CAS 13463-67-7) 2B Possibly carcinogenic to humans.
Zeolites (CAS 1318-02-1) 3 Not classifiable as to carcinogenicity to humans.
OSHA Specifically Regulated Substances (29 CFR 1910.1001-1050)
Not regulated.
US. National Toxicology Program (NTP) Report on Carcinogens
Not listed.
Reproductive toxicity This product is not expected to cause reproductive or developmental effects.
Specific target organ May cause drowsiness and dizziness.
toxicity - single exposure
Specific target organ May cause damage to organs through prolonged or repeated exposure.
toxicity - repeated
exposure
Aspiration hazard Not an aspiration hazard.
Chronic effects May cause damage to organs through prolonged or repeated exposure. Prolonged inhalation may
be harmful.

12. Ecological information

Ecotoxicity Toxic to aquatic life with long lasting effects.
Persistence and degradability No data is available on the degradability of this product.
Bioaccumulative potential
Mobility in soil No data available.
Other adverse effects No other adverse environmental effects (e.g. ozone depletion, photochemical ozone creation
potential, endocrine disruption, global warming potential) are expected from this component.

13. Disposal considerations

Disposal instructions Collect and reclaim or dispose in sealed containers at licensed waste disposal site. Do not allow
this material to drain into sewers/water supplies. Do not contaminate ponds, waterways or ditches
with chemical or used container. Dispose of contents/container in accordance with
local/regional/national/international regulations.
Local disposal regulations Dispose in accordance with all applicable regulations.
Hazardous waste code The waste code should be assigned in discussion between the user, the producer and the waste
disposal company.
Waste from residues / unused Dispose of in accordance with local regulations. Empty containers or liners may retain some
products product residues. This material and its container must be disposed of in a safe manner (see:
Disposal instructions).
Contaminated packaging Since emptied containers may retain product residue, follow label warnings even after container is
emptied. Empty containers should be taken to an approved waste handling site for recycling or
disposal.

14. Transport information

DOT
UN number UN1139
UN proper shipping name Coating Solution

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 Transport hazard class(es)
Class 3
Subsidiary risk -
Label(s) 3
Packing group II
Special precautions for user Read safety instructions, SDS and emergency procedures before handling.
Special provisions 149, IB2, T2, TP1, TP8
Packaging exceptions 150
Packaging non bulk 202
Packaging bulk 242
IATA
UN number UN1139
UN proper shipping name Coating Solution
Transport hazard class(es)
Class 3
Subsidiary risk -
Packing group II
Environmental hazards Yes
ERG Code 3H
Special precautions for user Read safety instructions, SDS and emergency procedures before handling.
Other information
Passenger and cargo Allowed with restrictions.
aircraft
Cargo aircraft only Allowed with restrictions.
IMDG
UN number UN1139
UN proper shipping name Coating Solution, MARINE POLLUTANT
Transport hazard class(es)
Class 3
Subsidiary risk -
Packing group II
Environmental hazards
Marine pollutant Yes
EmS F-E, S̲ -E̲
Special precautions for user Read safety instructions, SDS and emergency procedures before handling.
Transport in bulk according to Not established.
Annex II of MARPOL 73/78 and
the IBC Code
DOT

IATA; IMDG

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Marine pollutant

General information IMDG Regulated Marine Pollutant.

15. Regulatory information

US federal regulations This product is a "Hazardous Chemical" as defined by the OSHA Hazard Communication
Standard, 29 CFR 1910.1200.
TSCA Section 12(b) Export Notification (40 CFR 707, Subpt. D)
Not regulated.
CERCLA Hazardous Substance List (40 CFR 302.4)
ETHYL ACETATE (CAS 141-78-6) Listed.
SARA 304 Emergency release notification
Not regulated.
OSHA Specifically Regulated Substances (29 CFR 1910.1001-1050)
Not regulated.
Superfund Amendments and Reauthorization Act of 1986 (SARA)
Hazard categories Immediate Hazard - Yes
Delayed Hazard - Yes
Fire Hazard - Yes
Pressure Hazard - No
Reactivity Hazard - No
SARA 302 Extremely hazardous substance
Not listed.
SARA 311/312 Hazardous No
chemical
SARA 313 (TRI reporting)
Not regulated.

Other federal regulations

Clean Air Act (CAA) Section 112 Hazardous Air Pollutants (HAPs) List
Not regulated.
Clean Air Act (CAA) Section 112(r) Accidental Release Prevention (40 CFR 68.130)
Not regulated.
Safe Drinking Water Act Not regulated.
(SDWA)
FEMA Priority Substances Respiratory Health and Safety in the Flavor Manufacturing Workplace
ETHYL ACETATE (CAS 141-78-6) Low priority
US state regulations
US. California Controlled Substances. CA Department of Justice (California Health and Safety Code Section 11100)
Not listed.
US. California. Candidate Chemicals List. Safer Consumer Products Regulations (Cal. Code Regs, tit. 22, 69502.3, subd.
(a))
Titanium Dioxide (CAS 13463-67-7)
US. Massachusetts RTK - Substance List
ETHYL ACETATE (CAS 141-78-6)
Silicon Dioxide (CAS 112945-52-5)
Titanium Dioxide (CAS 13463-67-7)
US. New Jersey Worker and Community Right-to-Know Act
ETHYL ACETATE (CAS 141-78-6)
Titanium Dioxide (CAS 13463-67-7)
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 US. Pennsylvania Worker and Community Right-to-Know Law
ETHYL ACETATE (CAS 141-78-6)
Silicon Dioxide (CAS 112945-52-5)
Titanium Dioxide (CAS 13463-67-7)
US. Rhode Island RTK
ETHYL ACETATE (CAS 141-78-6)
US. California Proposition 65
WARNING: This product contains a chemical known to the State of California to cause cancer and birth defects or other
reproductive harm.
US - California Proposition 65 - CRT: Listed date/Carcinogenic substance
Benzene (CAS 71-43-2) Listed: February 27, 1987
Carbon Black (CAS 1333-86-4) Listed: February 21, 2003
Ethyl Benzene (CAS 100-41-4) Listed: June 11, 2004
Titanium Dioxide (CAS 13463-67-7) Listed: September 2, 2011
US - California Proposition 65 - CRT: Listed date/Developmental toxin
Benzene (CAS 71-43-2) Listed: December 26, 1997
Toluene (CAS 108-88-3) Listed: January 1, 1991
US - California Proposition 65 - CRT: Listed date/Male reproductive toxin
Benzene (CAS 71-43-2) Listed: December 26, 1997
International Inventories
Country(s) or region Inventory name On inventory (yes/no)*
Australia Australian Inventory of Chemical Substances (AICS) No
Canada Domestic Substances List (DSL) No
Canada Non-Domestic Substances List (NDSL) No
China Inventory of Existing Chemical Substances in China (IECSC) Yes
Europe European Inventory of Existing Commercial Chemical No
Substances (EINECS)
Europe European List of Notified Chemical Substances (ELINCS) No
Japan Inventory of Existing and New Chemical Substances (ENCS) No
Korea Existing Chemicals List (ECL) No
New Zealand New Zealand Inventory No
Philippines Philippine Inventory of Chemicals and Chemical Substances No
(PICCS)
United States & Puerto Rico Toxic Substances Control Act (TSCA) Inventory Yes
*A "Yes" indicates that all components of this product comply with the inventory requirements administered by the governing country(s)
A "No" indicates that one or more components of the product are not listed or exempt from listing on the inventory administered by the governing
country(s).

16. Other information, including date of preparation or last revision

Issue date 09-11-2013
Revision date 08-16-2016
Version # 03
HMIS® ratings Health: 2*
Flammability: 3
Physical hazard: 0
NFPA ratings Health: 2
Flammability: 3
Instability: 0
Disclaimer ITW Engineered Polymers cannot anticipate all conditions under which this information and its
product, or the products of other manufacturers in combination with its product, may be used. It is
the user’s responsibility to ensure safe conditions for handling, storage and disposal of the
product, and to assume liability for loss, injury, damage or expense due to improper use. The
information in the sheet was written based on the best knowledge and experience currently
available.

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Revision information Composition/information on ingredients: Component information
Fire-fighting measures: Suitable extinguishing media
Fire-fighting measures: Specific methods
Accidental release measures: Methods and materials for containment and cleaning up
Handling and storage: Precautions for safe handling
Handling and storage: Conditions for safe storage, including any incompatibilities
Physical & Chemical Properties: Multiple Properties
Toxicological information: Carcinogenicity
HazReg Data: International Inventories

Material name: Irathane 155 Gray - Side B SDS US

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