Aromatity (4n42) -o.

4 De' n

the orgaii compouds ivded into

stabil;y
D Aromate Complete delocallsatinn, (ons, tutkel
lomplete delocalisqka - 4NT nStte
) Antf -Nomttc 10 an ti
3) HorD - arormatte
Aronaty
4) Bishono -a1onatte
BT non- anomtte net tompk delocaliaEv
nan- somat
1) Aromat de'es
- The conplete deloalisatton T)1D0)h Jdoalicatin deba'hgh, ho
Nor-ca
(4n2)= ne
-Sbey 4n)N eule n0,y23
507.rorrg'

Huchel stabili aromatc

(whele number )
(antf- aroco
Intenal

-Complete delbcalartn E Total aYOmabeity Sams

4nT ule a unstable
B) Homo-qmatic -
Conplete delocalesa ien?by Fasstn ône sato1ated atom
6oloued
-(4n +2)1eRule as
4) Bshomo - aoYnatii
Comjere
- (4 n42)T) eKule sfotloueel More
5) least
Non -atomath i
deeern
-There ho complete delalisaton. g eleton Ka- acidiy
c tw
atilty
Chyed donse elg Beshomo Dxomti
romati/Anríaruma fe /Homo-arometic/
Tdentiby tAe compounct 6i'oufr chaged irgs ?
Or non- aromabe 6rom te

ydopropent carion.
(4n2)

tn 2
4ns0
qle adefotlouel
nzo tudhelCompete localisation
Arometic

A
 Andestawdn
2.

not
Theae &a conplete ylt delaalzsatim Boloutng lan1T| e rs le
These s comple de locataa t'om not allos t4nne

4n
n 2l

i)

(4n42)=
4n 2H-n

noly
n=o - Aromee
-Dbey He ckule yule:

No deloalisaion nbn -oomic

V)

. no futhoy delocalssatin."non-atrn

Vi)

cyci'e deloalisatm
(mte)ne6n

aromate compound.
7)

Comdet delo«atsatun
AnH atom ati

complered

Ayomatte

JelocaluaHm
4)
move
t o canbecahm
no non - romati

Monaromattc ( no
Aeloealisatiun

An b-2
(4nt21 Alowed
Aromatre

delbeal 0satn

Anti-a omate
in )

Complere deloealtateon
C4n +2)TI & nof follos L

Anti - Avomatte

Comglee debalsaken

AYOmat' fshse namben)

n
A
tonlety conjuated Exocyelle double bon n) ohey onmat
Snot bßeys antf a omatie
(Dten the ring 4n+2 4
4n 2
Anh-atomatc
b)

A Conpound h oill shus the dkpoter, stu rwe s

r yclie deloialia Jelocalsan
CAn +21 ) =41
4n = 2-2 4n4&
50Y.
ayomah.
nonaomte

The compouno 6 no-aromate

Antt-ar oratic

(o1
antt-aaont ant-aongtie
d)
en
(on

Qromgt c
antal amat c

La'gear
becaall anomahe vesall ut atomate

caracten

e)

anomatie

(mee stable)

aromaic
9)

Ju.aromQtie

han-Aomehe

6)

Meo
non-aDmat'e
oomR
Eroyclee double trmd ll shoo eiThen
Cenplerg cenjuested
Oa nom- anomat

Out comne '

1) wheaten ?
2) Aromahe ? No - a1umatte?
3) compaw'son E anonte chaaltey (Whtuh chows lases t aromattc
4) Conyatson los Ce Aotatfonal éregy velue baraten ?
 (Pesorura fy

Arematie.
A ..
Aromatte hanat eustiu (rig ige
B
D>c>BA
M Varus as
"De>B>A oposs
ite
(-c leugth
D.
c=c otaional Sny
ASBC>D

wtl be the anomatle choacte

dpstemomentu Greoter
? Greate the
and long wPl be the c-c bondl lensth
moment
’ Greates the dipste
ant low în the rot attonal Eneng

Annulene! mono-ycll poyenes io called the annulencs

A
Conpietty oycated
I4J annulere annuleñe

delocalsaNm
yli delocal'satt on Cqn+ 41

Antj-ionaic fn nat1e nrb lyattenal)

AnaAYOm atie
L6J Annlene

Delocalisatm
yelte Delocalisatten

=b2

n=lconote numben )
Dbey (AnT4) nule
Aromatc
 b t
Plemas
plaraity
- Deloultsaton
nd plann
[8j annulene
tycloccta tetraene
- Non planot comrl n2
o Do not have delocalisawer Arumake
It wfll be a non- anomati
elelocalisa tom
- Complete delocaltattn
(4n+a2n -8ne [12] Annulenes
=8-2

repaltofach
nzb not he
-plaai
h= /(not -vbep(40421 ) mWe.
- Non aNomatt zintetnal H wân not nopel to
The deveated
Lech otie & wiu not
ioj ennulenesth
nepel toSach
NAotpknag
|non-romatie
from planai
Complete delócaisahu
yco deapantaene Faflo ws 4mT1 Tule
- Anti~atomatfe chesactes
- complete delocalisaa
-l4n+) = lo e
4]Annulenes;

NR shste numbet)

Angnatic
The ojannalere,Snteinal H planan
Kepel strngy.Ir dweate trom
delocaaaten

the planasy delocaltsafon ardl - Anta)=t4T)

ho
ThoBore
a non dsumatc caructe
- Aromti
Conside asas
f s ] . ]notplanar

(16)

A & Ínnen Hwl be brtdgel thol shous

Pbraxity
 [l67 annulene Arematiag n furd qoten;
ETher l! be a1omehi lor) to be
non. planan non aNomat
- No -delocatsattm Fsed
- Non-aromatie chasacte

Antianpmate

18] anulene non- aromatte (Stmahy fued

Extenal Hydrgon
=45 PP (2 outeg H)

Totcma'
Jrternal tydogen (bt)
H = -6 to -8 NonatOmat'L

-plana
-delealsan
-(4nta)T =1 e
4n42 = 1&2
n=bly
n=y (Whae numbey)
- Aromati
6 înternal H: The
profon NMR VaL Non -omatic (symmeh'e tonideata)
f= -6 to -8 PPm
SntnaH!
9s PP

L90]- An-aNoatfe
agulene
[22J Aronmatic tighy momase in natue

othen System
ano cntt-oette Pn natuse
 Avomatt)y fos
tes ehe syster
en

ph
ph

bromahe An

Identity hih of thu fefloorg a1matii o non -7ornatfu (or)

homo aromate (ot) Bishonmo asomaHe ?
ph -ph ph ph
a) b) d
Ph

Cenplete elocalhed
No-delocahsetn
-delocalitatin elocab Nbn-homatt
obeylaneay6
4n b-2
AromatHe
-Aromaie
a tcscasbDos

e) 6) Planas
Armeh

B e defient ss it
is Equaleney cchoige ~ l4 annulene
shoufng anti-axomaie
- chaiged stngs ae planan
- Arematt

n: (kat)
 g)

- roytium
-Tt Sho us Apmati

h
HornsBypassing
One Stu aitom
ttamo aromate
Homo -anomattc
Comnplete detocaksartin gng
ene Saturated atonm

Tdentsy which oo the tollowlng

Specès ae BoTmad in a chePcal n !

sbfs
aromaHc
3bfs b a strug Lewis acbdt t be take p ,the halgen atem rem
Spo hybridied CaTbon ator
ereatrg a pos He eharge.

b) SbFs.
aromatfc

c) Sbls

aNomatfe

d) 2L

aromatc
 Sathsociem

e)
+&Na
nenplanat
Also knon
non-atomatie
w
Me
Planar
aromae

satwruted atorm
By Eypass
spe abshaet
Homo-anomatfe
3) DD
aromatc

DDe, become Hfrom cUtomaste

Bhoung

’To tonpase the Cutty conpauols

Al the phenomena I wtl inplain through the aomase

tompowrds
’ T8 compane the acelby ob the
Grearer ka valhe qreater wil be the adity
G1seate Pha vahe lowen wl be the aidey
cfs
1 avomaty
CA) 8)
BSe
eompari n9 the aciity ob A
cF

B) c)
(A) arOmae
Comatic
ahtt

Pka
 LALe B
AgNog preipitattom
with
Ant;
fgel +
+
prectpiatfon
stabihrahm) haore
dfbk Ant
trgChnore
laye
ptsm.
thanSetvely esy lise3°Aböeabm
Atabi A
State
",o) resona More
aromah'e mate ro CUnDmatte Ant-omate
+
Bascity basbiay greter theauovdorg
to Arange
(A)
ph Ph
ph
Ph
ph
species tetlootng the adey
ob the (ompase