JEE ADV Chemistry Unit Wise Tests & Sol

JEE Advanced
Unit wise
Practice Tests
CHEMISTRY
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Preface
Competitive examination preparation takes enormous efforts & time on the part of a
student to learn, practice and master each unit of the syllabus.
To check proficiency level in each unit, student must take self-assessment to identify
his/her weak areas to work upon, that eventually builds confidence to win. Also
performance of a student in exam improves significantly if student is familiar with the
exact nature, type and difficulty level of the questions being asked in the Exam .
With this objective in mind, we are presenting before you this book containing unit
tests. Some features of the book are -
a) The complete syllabus is divided into logical units and there is a self-assessment
tests for each unit
b) Tests are prepared by subject experts who have decade of experience to prepare
students for competitive exams
c) Tests are as per the latest pattern of the examination
d) Detailed explanatory solution of each test paper s also given
Student is advised to attempt these Tests once they complete the

preparation/revision of unit. They should attempt these Test in exam like
environment in a specified time. Student is advised to properly analyze the
solutions and think of alternative methods & linkage to the solutions of identical
problems also. We firmly believe that the book in this form will definitely help a
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errors. We would appreciate if the same is brought to our notice.
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JEE Advanced
Syllabus: Chemistry
Physical chemistry
General topics: Concept of atoms and molecules; Dalton's atomic theory; Mole concept; Chemical formulae;
Balanced chemical equations; Calculations (based on mole concept) involving common oxidation-reduction,
neutralisation , and displacement reactions; Concentration in terms of mole fraction , molarity, molality and
normality.
Gaseous and liquid states: Absolute scale of temperature, ideal gas equation; Deviation from ideality, van der
Waals equation; Kinetic theory of gases, average, root mean square and most probable velocities and their
relation with temperature; Law of partial pressures; Vapour pressure; Diffusion of gases.
Atomic structure and chemical bonding: Bohr model , spectrum of hydrogen atom, quantum numbers; Wave-
particle duality, de Broglie hypothesis; Uncertainty principle; Qualitative quantum mechanical picture of
hydrogen atom, shapes of s, p and d orbitals; Electronic configurations of elements (up to atomic number 36);
Aufbau principle; Pauli's exclusion principle and Hund's rule; Orbital overlap and covalent bond; Hybridisation
involving s, p and d orbitals only; Orbital energy diagrams for homonuclear diatomic species; Hydrogen bond;
Polarity in molecules, dipole moment (qualitative aspects only); VSEPR model and shapes of molecules (linear,
angular, triangular, square planar, pyramidal , square pyramidal, trigonal bipyramidal , tetrahedral and
octahedral).
Energetics: First law of thermodynamics; Internal energy, work and heat, pressurevolume work; Enthalpy,
Hess's law; Heat of reaction, fusion and vapourization; Second law of thermodynamics; Entropy; Free energy;
Criterion of spontaneity.
Chemical equilibrium: Law of mass action; Equilibrium constant, Le Chatelier's principle (effect of
concentration, temperature and pressure); Significance of llG and llGO in chemical equilibrium; Solubility
product, common ion effect, pH and buffer solutions; Acids and bases (Bronsted and Lewis concepts);
Hydrolysis of salts.
Electrochemistry: Electrochemical cells and cell reactions; Standard electrode potentials; Nernst equation and
its relation to llG ; Electrochemical series, emf of galvanic cells; Faraday's laws of electrolysis; Electrolytic
conductance, specific, equivalent and molar conductivity, Kohlrausch's law; Concentration cells.
Chemical kinetics: Rates of chemical reactions; Order of reactions; Rate constant; First order reactions;
Temperature dependence of rate constant (Arrhenius equation).
Solid state: Classification of solids, crystalline state, seven crystal systems (cell parameters a, b, C, a, 13, V),
close packed structure of solids (cubic), packing in fcc, bcc and hcp lattices; Nearest neighbours, ionic radii,
simple ionic compounds, point defects.
Solutions: Raoult's law; Molecular weight determination from lowering of vapour pressure, elevation of boiling
point and depression of freezing point.
Surface chemistry: Elementary concepts of adsorption (exduding adsorption isotherms); Colloids: types,
methods of preparation and general properties; Elementary ideas of emulSions, surfactants and micelles (only
definitions and examples).
Nuclear chemistry: Radioactivity: isotopes and isobars; Properties of a, 13 and y rays; Kinetics of radioactive
decay (decay series excluded), carbon dating; Stability of nuclei with respect to proton-neutron ratio; Brief
discussion on fission and fusion reactions.
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Inorganic chemistry
Isolation/preparation and properties of the following non-metals: Boron, silicon, nitrogen, phosphorus,
oxygen, sulphur and halogens; Properties of allotropes of carbon (only diamond and graphite), phosphorus and
sulphur.
Preparation and properties of the following compounds: Oxides, peroxides, hydroxides, carbonates,
bicarbonates, chlorides and sulphates of sodium, potassium, magnesium and calcium; Boron: diborane, boric
acid and borax; Aluminium: alumina, aluminium chloride and alums; Carbon: oxides and oxyacid (carbonic acid);
Silicon: silicones, silicates and silicon carbide; Nitrogen: oxides, oxyacids and ammonia; Phosphorus: oxides,
oxyacids (phosphorus acid, phosphoric acid) and phosphine; Oxygen: ozone and hydrogen peroxide; Sulphur:
hydrogen sulphide, oxides, sulphurous acid, sulphuric acid and sodium thiosulphate; Halogens: hydrohalic
acids, oxides and oxyacids of chlOrine, bleaching powder; Xenon fluorides.
Transition elements (3d series): Definition, general characteristics, oxidation states and their stabilities, colour
(excluding the details of electronic transitions) and calculation of spin-only magnetic moment; Coordination
compounds:nomenclature of mononuclear coordination compounds, cis-trans and ionisation isomerisms,
hybridization and geometries of mononuclear coordination compounds (linear, tetrahedral, square planar and
octahedral ).
Preparation and properties of the following compounds: Oxides and chlorides of tin and lead; Oxides,
chlorides and sulphates of Fe2+, Cu 2+ and Zn 2+; Potassium permanganate, potassium dichromate, silver oxide,
silver nitrate, silver thiosulphate.
Ores and minerals: Commonly occurring ores and minerals of iron, copper, tin, lead, magnesium, aluminium,
zinc and silver.
Extractive metallurgy: Chemical principles and reactions only (industrial details excluded); Carbon reduction
method (iron and tin); Self reduction method (copper and lead); Electrolytic reduction method (magnesium and
aluminium); Cyanide process (silver and gold).
Principles of qualitative analysis: Groups I to V (only Ag+, Hg2+, Cu 2+, Pb2+, Bi 3 +, Fe 3+, Cr3+, AI 3+, Ca 2+, Ba2+,
Zn 2+, Mn2+ and Mg2+); Nitrate, halides (excluding fluoride), sulphate and sulphide.
Organic chemistry
Concepts: Hybridisation of carbon; C1 and TT-bonds; Shapes of simple organic molecules; Structural and
geometrical isomerism; Optical isomerism of compounds containing up to two asymmetric centres, (R,S and E,Z
nomenclature excluded); IUPAC nomenclature of simple organic compounds (only hydrocarbons, mono-
functional and bi-functional compounds); Conformations of ethane and butane (Newman projections);
Resonance and hyperconjugation; Keto enoltautomerism; Determination of empirical and molecular formulae of
simple compounds (only combustion method); Hydrogen bonds: definition and their effects on physical
properties of alcohols and carboxylic acids; Inductive and resonance effects on acidity and basicity of organic
acids and bases; Polarity and inductive effects in alkyl halides; Reactive intermediates produced during
homolytic and heterolytic bond cleavage; Formation, structure and stability of carbocations, carbanions and free
radicals.
Preparation, properties and reactions of alkanes: Homologous series, physical properties of alkanes
(melting points, boiling points and density); Combustion and halogenation of alkanes; Preparation of alkanes by
Wurtz reaction and decarboxylation reactions. Preparation, properties and reactions of alkenes and alkynes:
Physical properties of alkenes and alkynes (boiling pOints, denSity and dipole moments); Acidity of alkynes; Acid
catalysed hydration of alkenes and alkynes (excluding the stereochemistry of addition and elimination);
Reactions of alkenes with KMn04 and ozone; Reduction of alkenes and alkynes; Preparation of alkenes and
alkynes by elimination reactions; Electrophilic addition reactions of alkenes with X2, HX, HOX and H20
(X=halogen); Addition reactions of alkynes; Metal acetyl ides.
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Reactions of benzene: Structure and aromaticity; Electrophilic substitution reactions: halogenation, nitration,
sui phonation, Friedel-Crafts alkylation and acylation; Effect of 0-, m- and p-directing groups in monosubstituted
benzenes.
Phenols: Acidity, electrophilic substitution reactions (halogenation, nitration and sui phonation); Reimer-Tieman
reaction, Kolbe reaction.
Characteristic reactions of the following (induding those mentioned above): Alkyl halides: rearrangement
reactions of alkyl carbocation, Grignard reactions, nucleophilic substitution reactions; Alcohols: esterification,
dehydration and oxidation, reaction with sodium, phosphorus halides, ZnCl2/concentrated HCI, conversion of
alcohols into aldehydes and ketones; Ethers: Preparation by Williamson's Synthesis; Aldehydes and Ketones:
oxidation, reduction, oxime and hydrazone formation ; aldol condensation, Perkin reaction; Cannizzaro reaction;
haloform reaction and nucleophilic addition reactions (Grignard addition); Carboxylic acids: formation of esters,
acid chlorides and amides, ester hydrolysis; Amines: basicity of substituted anilines and aliphatic amines,
preparation from nitro compounds, reaction with nitrous acid, azo coupling reaction of diazonium salts of
aromatic amines, Sandmeyer and related reactions of diazonium salts; carbylamine reaction; Haloarenes:
nucleophilic aromatic substitution in haloarenes and substituted haloarenes (excluding Benzyne mechanism and
Cine substitution).
Carbohydrates: Classification; mono- and di-saccharides (glucose and sucrose); Oxidation , reduction , glycoside
formation and hydrolysis of sucrose.
Amino acids and peptides: General structure (only primary structure for peptides) and physical properties.
Properties and uses of some important polymers: Natural rubber, cellulose, nylon, teflon and PVC.
Practical organic chemistry: Detection of elements (N, S, halogens); Detection and identification of the following
functional groups: hydroxyl (alcoholic and phenolic),carbonyl (aldehyde and ketone), carboxyl, amino and nitro;
Chemical methods of separation of mono-functional organic compounds from binary mixtures.
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Practice Test Syllabus
CHEMISTRY
Test No, Chapters
Unit Test-1 Atomic Structure, Periodic Table, Chemical Bonding
Basic concept of chemistry ,Redox & Volumetric Analysis, Hydrogen

Unit Test-2
and its Compound
Unit Test-3 Chemical Equilibrium, Ionic Equilibrium , s-Block Element
Unit Test-4 Gaseous State, Chemical EnergetiC
Unit Test-5 IUPAC and Nomenclature, GOC , Isomerism
Revision Test -1 Units 1 to 5
Unit Test-6 Solution and Colligative Properties, Solid state, Surface Chemistry
Unit Test-7 Electro Chemistry, Chemical Kinetics
Unit Test-S Hydrocarbon, Aromatic Chemistry, Halogen Derivative,
Alcohol,Phenol ,Ether, Carbonyl Compound, Carboxylic Acid and

Unit Test-9 Derivatives, Nitrogen containing Compound, Carbohydrate and
Protein (Biomolecule)
Co-ordination Compound, d and f-Block Elements, p-Block,

Unit Test-10
Metaliurgy,Salt Analysis
Revision Test -2 Units 6 to 10
Major Test Full Syllabus
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CONTENTS
Test Paper Page No. Test Paper Page No.
12. Revision Test-2 159-174
1. Unit Test-l 1-14
• Paper-1 159
• Paper-2
Paper-1 1
•MajorPaper-2 167
• 9 13. Test 175-188
2. Unit Test-2 15-28
• Paper-2
Paper-1 175
• Paper-1 15
• 181
3.
•UnitPaper-2
Test-3
21
29-42
14. Answer Key 191-196
• Paper-2
Paper-1 29 15. Solution Unit Test-l 197-200
4.
•
Unit Test-4
35
43-58 16. Solution Unit Test-2 201-204
• Paper-1 43
5.
•UnitPaper-2
Test-5
51
59-74
17. Solution Unit Test-3 205-207
• Paper-1 59 18. Solution Unit Test-4 208-211
6.
• Paper-2
Revision Test-l
67
• Paper-1 75
7.
•UnitPaper-2
Test-6
81
87-100
20. Solution Revision Test-l 215-217
8.
• Paper-2
Unit Test-7
93
• Paper-1 101
9.
•UnitPaper-2
Test-8
107
115-130
23. Solution Unit Test-8 225-228
10.
• Paper-2
Unit Test-9
123
131-146 25. Solution Unit Test-l0 233-236
• Paper-1 131
11.
•UnitPaper-2
Test-l0
139
147-158
26. Solution Revision Test-2 237-240
• Paper-1 147 27. Solution Major Test 241-243

• Paper-2 153
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Practice Test for JEE Advanced
Unit Test-l
[Paper-I]
Time allowed: 1 hour Max. Marks: 61
SYLLABUS
CHEMISTRY : Atomic Structure, Periodic Table, Chemical Bonding
IMPORTANT INSTRUCTIONS
A. GENERAL:
1. Please read the instructions given for each question carefully and mark the correct answers against the question numbers on the
answer sheet in the respective subjects.
2. The answer sheet, a machine readable Optical Mark Recognition (OMR) is provided separately.
3. Do not break the seal of the question-paper booklet before being instructed to do so by the invigilators.
B. MARKING SCHEME :
Each subject in this paper consists of following types of questions:-
SECTION -I
4. Multiple choice questions with multiple correct option. 4 marks will be awarded for each correct answer and
-2 mark for each wrong answer. However, +1 mark will be awarded for darkening a bubble corresponding to each correct
option, provided NO incorrect option is darkened.
SECTION -/I
5. Numerical response type questions. 3 marks will be awarded for each correct answer and no negative marking for wrong answer
in this section. Answers to this Section are to be given in the form of single digit integer type.
SECTION - III
5. Based an Table Matching type questions (Single Correct Answer type). 3 marks will be awarded for the correct answer and
-1 markfar wrong answer.
C. FILLING THE OMR :
7. Fill your Name, Roll No., Batch, Course and Centre of Examination in the blocks of OMR sheet and darken circle properly.
8. Use only HB pencil or blue/black pen (avoid gel pen) for darking the bubbles.
9. While filling the bubbles please be careful about SECTIONS [i.e. Section-I (include single correct, reason type, multiple correct
answers), Section-II ( column matching type), Section-III (include integer answer type)]
S('ction - I S('ction-II S('ction-III

For example if only 'A' cho i ce is For examp le, if the correc t answers to question For example if Correct matc h for (A) is P ;
correct then , the correct method for numbers X, Y, Z and W (say) are 6, 0 , 9 and 2 , for (8) is R, S ; for (C) is Q ; for (D) is P, Q,
filli n g the bubbles is respectively, then the correct method for fi ll ing S the n the correct method for fi lling the
ABC 0 the bubb les is bubb les is
• 0 0 0 X Y Z W
P Q R S T
For examp le i ronly 'A & C ' choices
are correct then , the correct method
II) ® A • 0 0 0 0
:( BOO •• 0
[or filli ng the b ubb les is
ABC 0 CO . 0 0 0
• 0 • 0 o •• 0 • 0
th e wrong method for fi lli ng the
bubble are
o ® ~ G
The answer of the questions in
w rong or an y other manne r will be
treated as wrong .
"'"
Unitwise Practice Test for JEE Advanced
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CHEMISTRY
SECTION-I (Maximum Marks: 28)
• This section contains SEVEN questions.

• Each question has FOUR options (A), (B), (C) and (D). ONE OR MORE THAN ONE of these four options
is( are) correct.
• For each question, darken the bubble(s) corresponding to all the correct option(s) in the ORS.
• For each question, marks will be awarded in one of the following categories:
Full Marks :+4 If only the bubble(s) corresponding to all the correct option(s) is(are) darkened.
Partial Marks : +1 For darkening a bubble corresponding to each correct option, provided NO
incorrect option is darkened
Zero Marks :0 If none of the bubbles is darkened.
Negative Marks :- 2 In all other cases.
• For example, if (A), (C) and (D) are all the correct options for a question, darkening all these three will get
+ 4 marks; darkening only (A) and (D) will get + 2 marks; and darkening (A) and (B) will get -2 marks, as a
wrong option is also darkened.
SECTION-l (Maximum Marks: 28)

is(are) correct.
• For each question, marks will be awarded in one of the followin~ cate~ories:
Partial Marks : +I For darkening a bubble corresponding to each correct option, provided NO
Zero Marks : 0 If none of the bubbles is darkened.
Q.l I st excitation potential for the R-like (hypothetical) sample is 24 V. Then-

(A) ionisation energy of the sample is 36 eV
(B) Ionisation energy of the sample is 32 eV
(C) Binding energy OO,d excited state is 2 eV
. I f h i · 32 x 8 V
(D) 2nd eXCItatIOn
. .
potentIa 0 t e samp e IS--
9
Q.2 A hydrogen like atom in ground state absorbs 'n' photons having the same energy and it emits exactly 'n'
photons when electronic transition takes place. Then the energy of the absorbed photon may be -
(A) 91.8 eV (B) 40.8 eV (C) 48.4 eV (D) 54.4 eV
nd
Q.3 In a sample of atoms hydrogen like electron is in 2 excited state, the binding energy of 4th orbit of this atom
is 13.6 eV, then the -
(A) A 25 eV photon can set free the electron from the second excited state of this sample
(B) 3 different types of photon will be observed if electrons make transition up to ground state from the
second excited state
(C) If23 eV photon is used then K.E. of the ejected electron is I eV
(D) 2nd line of Balmer series of this sample has same energy value as 1st excitation energy ofR -atoms
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Q.4 Which of the following statements are not correct ?
(A) All C-O bonds in CO~- are equal but not in H 2C0 3
(B) All C-O bonds in HCO Z- are equal but not in HC0 2H
(C) C-O bond length in HCO Z- is longer than C-O bond length in CO~
(D) C-O bond length in HCOZ- and C-O bond length in CO~- are equal
Q.S Select the correct statements about the compound NO[BF4J :

(A) It has Sa and 21t bond
(B) Nitrogen-oxygen bond length is higher than nitric oxide (NO)
(C) It is a diamagnetic species
(D) B-F bond length in this compound is lower than in BF3
Q.6 Which of the following statements is/are not correct for following compounds ?
(I) SCIz(OCH3)2 & (II) SF 2(OCH3)z
(A) -OCH3 groups in both case occupy the same position
(B) CI-atoms occupy equatorial position in case of (I) & F-atoms occupy equatorial position in case (II)
(C) CI-atom occupy axial position in case of (I) & F-atoms occupy equatorial position in case of (II)
(D) There is one lone pair each in I & II
Q.7 Which of the following is/are electron deficient compounds ?

(A) NaBH4 (B) B2H6 (C) AlCh (D) LiAIH4
SECTION-2 (Maximum Marks: 15)

• This section contains FIVE questions
• The answer to each question is a SINGLE DIGIT INTEGER ranging from 0 to 9, both inclusive
• For each question, darken the bubble corresponding to the correct integer in the ORS
• For each question, marks will be awarded in one of the following categories :
Full Marks : +3 If only the bubble corresponding to the correct option is darkened.
Zero Marks : 0 In all other cases.
Q.8 A single electron in an ion has ionization energy equal to 217.6 eV. What is the total number of neutrons
present in one ion of it ?
Q.9 What will be the covalent radius (in A) between Hand F atom in HF ? If radius of hydrogen is lA and the
radius of fluorine is 0.5 A.
Q.I0 He+ ions in its ground state are irradiated with photons of energy 67.15 eV. Electrons ejected from He+
strikes the H -atom in its ground state.
Give the maximum number of spectral lines which can be obtained from de-excitation ofH-atoms.
Q.ll Speed of electron in 4th orbit of a hydrogen like ion is 2 .725 x 10 6 m/ sec . Give atomic
number of ion
Q.12 Determine the energy released due to formation of MgS lattice in kcallmol in nearest possible integers from
the following data.
Morm H (MgS) = - 82.2 kcallmol.
~sub H (Mg) = 36.5 kcallmol.
for Mg, IE, + IE" = 520.6 kcal/mol.
for S8 , ~atom H = 1065.6 kcallmol.
For S, ~eg H, + ~eg H" = -72.4 kcal/mol.
(Give your answer after divided by 100)
• This section contains SIX questions of matching type.
• This section contains TWO tables (each having 3 colurrms and 4 rows)
• Based on each table, there are THREE questions.
• Each question has FOUR options (A), (B), (C) and (D). Only one of these four options is correct.
• For each questions, darken the bubble corresponding to the correct option in the ORS.
Negative Marks : -1 In all other cases.
Answer Q.13, Q.14 and Q.15 by appropriately matching the information given in the three columns of the
following table.
The wave function, 'I'n ,e, m l is a mathematical function whose value depends upon spherical polar coordinates
(r, e, cp) of the electron and characterized by the quantum numbers n, e and m, Here r is distance form nucleus, e is
colatitude and cp is azimuth. In the mathematical functions given in the Table, Z is atomic number and 110 is Bohr radius
Column 1 Column 2 Column 3
(I) 1s orbital (P)
(i) 'I'n ,f, m oc ( ~a J~ J~:)
(' 'I:'f
t
o
1\
E
§
..:
-- -
C
~
0
,~. '" r / ao
(II) 2s orbital (ii) One radial node :v/ (Q) Probability density at nucleus
I
oc -
<. a 30
(III) 2pz orbital ~ (R) Probability density is maximum
(iii) 'l'n 1 m
" I
OC ( ~
a
Yre - 2a,
o
( Zr )
cose at nucleus
(IV) 3d/ orbital (iv) xy- plane is a nodal plane (S) Energy needed to excite electron from
27 .. h
r\~\
n = 2 state to n = 4 state times t e
IS -
V 32
energy needed to excite electron from
n = 2 state to n = 6 state
Q.13 For the given orbital in Colurrm 1, the only CORRECT combination for any hydrogen-like species is
(A) (III) (iii) (P) (B) (II) (ii) (P) (C) (IV) (iv) (R) (D) (I) (ii) (S)
Q.14 For He+ ion, the only INCORRECT combination is

(A) (I) (i) (R) (B) (I) (i) (S) (C) (I) (iii) (R) (D) (II) (ii) (Q)
Q.15 For hydrogen atom, the only CORRECT combination is

(A) (I) (i) (S) (B) (I) (iv) (R) (C) (I) (i) (P) (D) (II) (i) (Q)
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following table.
Column -1 Column - 2 Column - 3

(I) XeF; (i) spJd, see saw (P) Pn - Pn bonding
L
(II) SF 4 (ii) spJd , square planar (Q) no. ofL. P. = 1
3 2
(III) SF 6 (iii) sp d , distorted octahedral (R) no. of L. P. = 2
2
(iv) sp3d , octahedral
~>
(IV) XeF6 (S) no. ofB. P. = 6
(v) 90°
(""'>
Q.16 Which of the following is only incorrect option?
(A) (I) (ii) (R) (B) (III) (iv) (S) (C) (II) (i) (P) (D) (IV) (iii) (R)
Q.17 Which of the following is correct option?

(A) (I) (S) (B) (II) (R) (C) (III) (Q) (D) (IV) (S)
Q.18 Which of the following option is only correct?

(A) (I) (iii) (v) (B) (II) (Q) (v) (C) (III) (iv) (v) (D) (I) (v) (ii)
II" work
SpaC8 for roup"
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Paper-l [OMR SHEET]
Use only HB pencils Enrolment No. Test Date

to darken the ovals and I I I I I I I @::@J~l v Iv Iv Iv I
black pen for all other ® ® ® ® ®Q)
entries selection CD CD CD CD CD Course
procedure 0 10 CI 0 m
Incorrect . , (8 0 I Q) Q) IQ ) Q) IQ)
Correct
•
Do Not make any stray
marks In the form
I
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G) G) G) G) G)s
® ® ® ® ®:§>
'J) 'J) 7 'J) 'J)'J)
Paper -I
Paper -2
Medium
0
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Name of the Candidate (in Capital Letters)
Damaged form IS
liable to be rejected
® ® ® ® ®§) Hindi 0 Examination Centre (In Capital Letters)
® ® ® ® ®2> English 0
PHYSICS CHEMISTRY MATHEMATICS
Section I Section I Section I
1·0 ® © ® 1. 0 ® © @ 1·0 ® © ®
2·0 ® © ® 2·0 ® © @ 2·0 ® © ®
3·0 ® © ® 3·0 ® © @ 3·0 ® © ®
4·0 ® © ® 4·0 ® © @ 4·0 ® © ®
5·0 ® © ® 5·0 ® © @ 5·0 ® © ®
6·0 ® © ® 6·0 ® © @ 6·0 ® © ®
7·0 ® © ® 7·0 ® © @ 7·0 ® © ®
Section II Section II Section II
8. 9. 10. 11 . 12. 8. 9. 10. 11. 12. 8. 9. 10. 11. 12.
@ @ @ @ @ @ @ @ @ @ @ @ @ @ @
G) G) G) G) G) G) G) G) G) G) G) G) G) G) G)
® ® CD CD ® ® ® CD CD ® CD ® ® CD CD
® ® CD CD ® ® ® CD CD ® CD ® ® CD CD
(3)(3) 0 0 (3) (3) (3) 0 0 (3) (3) (3) 0 0
(3)
® ® ® ® ® ® ® ® ® ® ® ® ® ® ®
® ® ® ® ® ® ® ® ® ® ® ® ® ® ®
CD CD 0 CD CD CD CD 0 CD CD 0 CD CD CD CD
® ® ® ® ® ® ® ® ® ® ® ® ® ® ®
® ® ® ® ® ® ® ® ® ® ® ® ® ® ®
Section III Section III Section III

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I SIGNATURE OF CANDIDATE ISIGNATURE OF INVIGILATOR I
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Unit Test-l
[Paper-2]
Time allowed: 1 hours Max. Marks: 61
SYLLABUS
CHEMISTRY : Atomic Structure, Periodic Table, Chemical Bonding
A. GENERAL :
•
B. MARKING SCHEME :
SECTION -I
4. Multiple choice questions with only one correct answer. 3 marks will be awarded for each correct answer and
-1 mark for each wrong answer.
SECTION -/I
option, provided NO Incorrect option Is darkened.
SECTION - III
6. Passage based multiple choice questions with single correct aptian. 3 maries will be awarded for each correct answer and No negative
marking for wrong answer.
answers), Section -II (co!umn matching type), Section-III (inc!ude integer answer type)]
Scction -I Scction-ll Scction-Ill

For exam ple i f only 'A' cho ice is For examp le, if the correc t answers to question For example if Correct matc b for (A) is P ;
correct then, the correct method for numbers X. Y. Z and W (say) are 6, O. 9 an d 2 . for (8) is R. S ; for (C) is Q ; for (D) is p . Q.
filli n g tbe bubbles is respec ti ve ly, then the correct me th od for fi lli ng S the n the cor rect me thod for fi lling the
A B C D th e bubb les IS bubb les is
• 0 0 0 x Y Z W P Q R S T
For example if only 'A & C ' choices @ CD @ @ A • 0 0 0 0
a re correct then , the correct method
I CC ICD BOO •• 0
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CHEMISTRY
SECTION - 1 (Maximum Marks: 21)

• This section contains SEVEN questions
• Each question has FOUR options (A), (B), (C) and (D). ONLY ONE of these four options is correct.
• For each question, darken the bubble corresponding to the correct option in the ORS.
Q.l Which type of overlapping is not possible -
(A)O +
s
0
s
CBl 0 + ~ (C) C::X:::>+ c::x:::>
p p
s p p p
Q.2 Oxygen is more electronegative than sulphur. Yet H 2S is acidic while H 20 is neutral. This is because -
(A) Water is a highly associated compound
(B) Molecular mass ofH 2S is more than that of H 20
(C) H 2S is gaseous under ordinary conditions while H 20 is a liquid
(D) H-S bond is weaker than H-O bond
Q.3 An ion with mass number 56 contains 3 units of positive charge if ion contains 30.4 % more neutrons than
electrons. Identify the symbol of the ion -
(A) i~Al+3 (B) ~~SC +3 (C) ~~Fe+3 (D) i~Ti +3
Q.4 Which element is represented by the following electronic configuration -

2p
2s H H
Is H
H
(A) Nitrogen (B) Oxygen (C) Fluorine (D) Neon
Q.5 An electron is accelerated from a very low velocity (- zero speed) by the application of a potential difference
of V volts. If the de Broglie wavelength should change (i.e., decrease) by 1.0% what percent increase in V
causes it-
(A) 0.5% (B) 1% (C) 1.5% (D) 2%
Q.6 Correct order of second ionization potential of

C, Li Be, B is -
(A) B > C > Li > Be (B) C > Be > B > Li (C) Li > B > C > Be (D) Be > B > C > Li
Q.7 Choose the incorrect relations on the basis of Bohr's theory

. I . 1
(A) VelOCity of an electron oc - (B) Frequency of revolutIOns oc -3
n n
2 I
(C) Radius of orbit oc n Z (D) Force on an electron oc 4
n
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• The section contains SEVEN questions
• Each question has FOUR options (A), (B), (C) and (D). ONE OR MORE THAN ONE of these four option(s)
is( are) correct.
Full Marks: +4 If only the bubble(s) corresponding to all the correct option(s) is(are) darkened.
Partial Marks + 1 For darkening a bubble corresponding to each correct option, provided NO incorrect
option is darkened
Zero Marks o If none of the bubble is darkened.
Negative Marks -2 In all other cases.
• For example, if (A), (C) and (D) are all the correct options for a question, darkening all these three will get +4
marks; darkening only (A) and (D) will get +2 marks; and darkening (A) and (B) will get -2 marks, as a wrong
option is also darkened.
Q.S CO 2 molecule is not isostructural with:

(A) HgClz (B) SnCIz
Q.9 Which is wrong statement about (SiH 3hN is -

(A) (SiH3hN is planar
(B) (SiH3)3N is linear
(C) In (SiH3)3N lone pair is present on N does not under back bonding
(D) There are 9 sigma bond in the above molecule
Q.I0 An element M forms M2+ ion which has the electronic configuration Is2 2s2 p6 3s2 p6 d3 it is-
(A) That of an element in III group of periodic table (B) That of an element ofiV group of periodic table.
(C) That ofan element of V group of periodic table (D) That ofa transition metal
Q.ll Which of the following statement (s) is (are) correct?
(A) The electronic configuration ofCr is [Ar]3d5 4s'.(Atomic No. ofCr = 24)
(B) The magnetic quantum number may have a negative value
(C) In silver atom, 23 electrons have a spin of one type and 24 of the opposite type. (Atomic No. of Ag = 47)
(D) The oxidationstateofnitrogeninHN3is -3
Q.12 n= 3 -1r------r1--
31
n=2--+----.1-2~--~~
n=I--~--~--------
For above transitions in hydrogen like atoms, select the correct relation( s) -
(A) V3 = VI + V2 (B) V3 = I 2
V V (C) 1..3 = AI + 1..2
VI +V2
Q.13 Choose the correct statement(s) -

(A) The shape of an atomic orbital depends upon azimuthal quantum number
(B) The orientation of an atomic orbital depends upon the magnetic quantum number
(C) The energy of an electron in an atomic orbital of multi-electron atom depends upon principal quantum
number only
(D) The number of degenerate atomic orbitals of one type depends upon the value of azimuthal and magnetic
quantum number
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Q.l4 The angular momentum of electron can have the value(s) :
(A) O.S.!: (B) .!: (C) ~ (D) 2.S~
1t 1t O.S1t 21t

• This section contains TWO paragraphs
• Based on each paragraph, there are TWO questions
• Each question has FOUR options (A), (B), (C) and (D). ONLY ONE of these four options is correct
• For each question, darken the bubble corresponding to the correct option in the ORS
Zero Marks : 0 In all other cases
PARAGRAPHl
Consider the following two electronic transitions possibilities in a hydrogen atom
_ _.I.
t-
---r--,---- n = 3
---+--t
_ _L_ _ _ _
n= 2
n= I
Q.lS The ratio of 8E3 ... 2 to 8E3 ... I [8E x ... y = energy change for transition from x to y]
W~ ~)~ ~)12.1 ~~
12.1 12.2 1.9 1.2
Q.l6 What is true about wavelength & frequencies for the emitted radiation
(A) Frequency & wavelength are additive of emitted spectrum
(B) Frequency are additive but not wavelength
(C) Neither frequency nor wavelengths are additive
(D) Wavelength are additive but not frequency
PARAGRAPH 2
Four elements P, Q, Rand S have ground state electronic configuration as-
p ~ 1s2 2S2 2l3s 2 3p3
Q ~ Is2 2S2 2p6 3s2 3p'
R ~ Is2 2S2 2p6 3s 23p6 3dlO 4s2 4p3
S ~ Is2 2S2 2p6 3s23p6 3plO 4s2 4pl
Q.l7 Comment which of the following option represent the correct order of true (T) & false (F) statement.
I size ofP < size ofQ
II size of R < size of S
III size ofP < size ofR (appreciable difference)
IV size ofQ < size ofS (appreciable difference)
(A) TTTT (B) TTTF (C) FFTT (D) TIFF
Q.l8 Order of lEI values among the following is -

(A) P> R> S> Q (B) P < R < S < Q (C) R> S > P>Q (D) P> S> R> Q
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Unit Test-2
[Paper-I]
SYLLABUS
CHEMISTRY Basic concept of chemistry, Redox & Volumatric Analysis, Hydrogen and its Compound
A. GENERAL:
B. MARKING SCHEME :
SECTION -I
SECTION -/I
SECTION - 11/
5. Bosed on Table Matching type questions (Single Correct Answer type). 3 marks will be awarded for the correct answer and
answers), Section-II (column matching type), Section-III (include integer answer type)]

For example if only 'A' cho i ce is For examp le, if the correc t answers to question For example if Correct match for (A) is P ;
filli n g the bubbles is respectively, then the correct method for filling S the n the correct method for filling the
ABC 0 the bubbles is bubb les is
• 0 0 0 X Y Z W
P Q R S T
For examp le ir only 'A & C ' choices
II) ® A • 0 0 0 0
:( BOO •• 0
ABC 0 CO . 0 0 0
• 0 • 0 o •• 0 • 0
th e wrong method for filling the
bubble are
o ® ~ G
w rong or an y other manne r wi ll be
treated as wrong .
"'"
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CHEMISTRY

is( are) correct.
Q.l A sample of H20 2 solution labelled as "28 volume" has density of 26.5 giL. Mark the correct option(s)
representing concentration of same solution in other units:
w
(A) MH 0
2 2
= 2.5 (B) %-=17
v
(C) Mole fraction ofH20 2 = 0.2 (D) m H20 2 = 13.88
Q.2 Dichromate ion in acidic medium oxidizes stannous ion as:

xSn 2+ + yCr20~- + zH+ --t aSn4+ + bCr3+ + cH 20
(A) The value ofx : y is I : 3 (B) The value ofx + y + z is 18
(C) a : b is 3 : 2 (D) The value of z - cis 7
Q.3 Two bulbs A & B contains 16 gram 02 and 16 gram 0 3 respectively. Which of the following statements are true-
(A) Both bulbs contains same number of atoms
(B) Both bulbs contains different number of atoms
(C) Both bulbs contain same number of molecule
(D) Bulbs A contains N A molecules while bulb B contain N B molecules [NA = Avogadro's number]
2 3
Q.4 Which of the following is/are correct
CS 2 + 3Cb ~ CCI 4 + S2Cb
(S = 32, ce
= 35.5, C = 12)
I gram of CS 2 and 2 gm Cb reacts -
(A) 0.714 g ofCS 2 is used in reaction (B) 0.286 g CS 2 is in excess
(C) 1.45 g ofCCI 4 is formed (D) 0.8 g Cb is in excess
Q.S Mass of one mole of CO 2 is -

(A) 44 gram (B) 7.304 x 1024 u (C) 44 u
Q.6 Which of the following is a disproportionation reaction -

CHO CH 20H COO-
(A) I + OW ----+ I +I (B) P2H4----+ PH3 + P4H 2
COOH COO- COO-
(C) P4 + NaOH----+ NaH2P02 + PH 3 (D) CaOCb----+ CaCI 2+ Ca(C10 3h
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Q.7 1.2 kg of iron pyrites (FeS2) are roasted to convert sulphur in (FeS2) to S02 with 80% efficiency. It is then
oxidised to S03 which is then absorbed in H20 to give H2S04. If the maximum & minimum possible
efficiencies are 60% & 30% respectively for any of these two steps, which of the following amounts of
H2S04 could possibly be obtained? (Fe = 56, S = 32)
(A) 1.44 (B) 2.88 (C) 5.76 (D) 9.6

Q.8 The ratio of concentration of NH3 in H20 to the concentration of NH3 in CHCI3 at 290 K is 24 at any
pressure. Through one litre of pure water ammonia gas was passed , the concentration ofNH3 was measured
2
to be 0.38 (M). To this solution 0.025 moles of CUS04 was added. In NH3 solution all Cu + ions form the
complex Cu (NH3);+ . Now over this solution one litre of CHCb was added , thoroughly shaken and
equilibrated. In CHCh layer, Cu(NH 3);+ was absent but in CHCb the concentration ofNH 3 was reduced to
0.0112 (M) at 290 K. Determine the value ofx in nearest possible integers.
Q.9 An acid 'A' is 0.4 N. In a neutralization process 50 ml of 'A' is mixed with 30 ml of sodium carbonate
solution (42.49/litre) and 10 mL of the resulting solution is diluted to 50 mL and then 5 mL of this solution
(B) is completely neutralised with certain volume of 40 times diluted solution of (A). find the volume of
diluted solution. of (A) required for the neutralization ofB (in mL)
Q.IO 0.7 g of a sample of Na2C0 3·xH 20 were dissolved in water and the volume was made to 100 m!. 20 ml of
this solution required 19.8 ml of Nil 0 HCI for complete neutralization. The value ofx is.
Q.ll One mole of N2H4 loses ten moles of electrons to form a new compound Y. Assuming that all the nitrogen
appears in the new compound, what is the oxidation state of nitrogen in Y ? (There is no change in the
oxidation state of hydrogen).
Q.12 Atomic weight of Al on a non-conventional scale is found to be 18 while on conventional scale, it is 27. On
the new scale an amu is defined as (~) lh part by weight of C-12. Here x is.
• This section contains TWO tables (each having 3 columns and 4 rows)
Negative Marks : -I In all other cases.
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Answer Q.13, Q.14 and Q.lS by appropriately matching the information given in the three columns of the
following table.
Column-l (Molecule) Column-2 (O.S) Column-3 (Act as)

(I) 0 3 (i) +5 (P) OA & RA both
(II) HN0 4 (ii) +6 (Q) OA only
(III) H 2S2OS (iii) 0 (R) RA only
(IV) H 3P0 2 (iv) + I (S) Neither OA Nor R.A
;
Q.13 Which of the followmg IS correctly match
(A) I (i) R (B) I (iii) P (C) I (ii) S (D) I (iv) Q
Q.14 Which of the following is correctly match for H2S 20 S

(A) III (ii) Q (B) III (iv) R (C) III (i) P (D) III (iii) S
Q.lS Which is incorrect match

(A) II (i) Q (B) I (iii) S (C) III (ii) Q (D) IV (iv) P
following table.
, -
Column-l Column-2 .' Column-3
(1) KMn04 in acidic medium (i) 10 \ (P) Always oxidizing agent

(II) Ba(Mn04)2 in acidic medium (ii) 6 In '1'--;: (Q) Always reducing agent
(III) S203-2 in alkaline medium (iii) 5 . 'J / (R) Oxidizing as well as reducing agent
(IV) K2Cr207 in acidic medium (iv) 8 ~' (S) Maximum oxidizing state
Q.16 Which of the following option is the only correct combination?

(A) (I) (ii) (P) (B) (IV) (ii) (R) (C) (IV) (ii) (P) (D) (II) (i) (R)
Q.17 Which of the following is the only incorrect combination?

(A) (I) (iii) (P) (B) (IV) (ii) (Q) (C) (I) (iii) (P) (D) (II) (iii) (P)
Q.18 Oxidation state of both the sulphur in S203-2 is

(A) (+2, +2) (B) (+2, +4) (C) (+4, 0) (D) (+4, +4)
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Unit Test-2
[Paper-2]
SYLLABUS
CHEMISTRY Basic concept of chemistry ,Redox & Volumatric Analysis, Hydrogen and its Compound
A. GENERAL:
B. MARKING SCHEME :
SECTION -I
4. Multiple choice questions with only one correct answer. 3 maries will be awarded for each correct answer and
SECTION -/I
-2 mark for each wrong answer. However, +1 marie will be awarded for darkening a bubble corresponding to each correct
SECTION - III
6. Passage based multiple choice questions with single correct option. 3 mat1<S will be awarded for each correct answer and No negative
answers), Section -II ( column matching type), Section-III (include integer answer type)]
Section -I Section-II Section-III

For example if only 'A' cho ice is Fo r exam pl e, if the correc t answers to que st ion For example if Correct matc h fo r (A) is P;
correct th en, the correcl me th od for numb ers X. Y. Z and W (say) are 6.0,9 an d 2 , for (8) is R, S ; fo r (C) is Q ; for (D) is P , Q.
filling the bubbles is respect ive ly, then the correct method fo r fi lli ng S then the correct me thod [or fil ling the
ABC D the bubb les is bubb les is
• 0 0 0 X Y Z IV P Q R S T
For exa mp le if only 'A & C ' choices
are correct then , the correct me thod
® CD @ @ A • 0 0 0 0
l eI I I BOO •• 0
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ABC
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treated as wrong.
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CHEMISTRY
SECTION -1 (Maximum Marks: 21)

•
Q.l The oxidation number ofS in H 2S20 S is-

(A) + 2 (B) +4 (C) + 6
Q.2 What is the coefficient of oxalate ion in the following reaction?

MnO:; + C20~- + H+ -+ Mn2+ + CO 2 + H 20
(A) 4 (B)2 (C) 3 (D) 5
Q.3 Of the following reactions, only one is a redox reaction, IdentifY it-
(A) Ca(OH)z + 2HCI -+ CaCh + 2H 20
(B) BaCh + MgS04 -+ BaS04 + MgCh
(C) 2S20~- + 2H 20 -+ 4S0~- + 4H+
(D) Cu2S + 2FeO -+ 2Cu + 2Fe + S02
Q.4 Old lead paintings regain their original colour by washing with hydrogen peroxide solution. It is because -
(A) Hydrogen peroxide oxidise the dye
(B) Hydrogen peroxide reduce the oxidised coloured compounds
(C) Hydrogen peroxide oxidise black coloured PbS to white PbS04
(D) Hydrogen peroxide dissolves the blackened layer by virtue of its acidic nature
Q.5 Calgon is an industrial name given to -

(A) normal sodium phosphate (B) sodium meta-aluminate
(C) sodium hexametaphosphate (D) hydrated sodium aluminium silicate
Q.6 Which of the following operation would cause removal of temporary hardness of water ?
(A) passing CO 2 gas through it (B) passing S02 gas through it
(C) adding calculated amount ofCa(OH)z (D) adding calculated amount of sodium hypophosphate
Q.7 Which of the following pairs of compound does not illustrate the law of multiple proportion?
(A) S02 & S03 (B) N0 2 & N 20 (C) MgO & Mg (OH)z (D) NO & N 20 s and CO 2
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is( are) correct.
option is darkened
Q.8 If 100 mI of 1M H2S0 4 solution is mixed with 100 mI of98% (W/W) H 2S0 4 solution (d = 0.1 g I ml) then-
(A) Concentration of solution remains same (B) Volume of solution become 200 ml
(C) Mass of H 2S04 in the solution is 98 gram (D) Mass of H2S0 4 in the solution is 19.6. gram
Q.9 A sample of a mixture of CaCI 2 & NaCi weighing 4.44 gm was treated to precipitate all the Ca as CaC0 3
which was then heated and quantitatively converted to 1.12 gm of CaO Calculate the % of CaCh in the
mixture-
(Ca = 40, Na = 23, CI = 35.5)
(A) Mixture Contains 50% NaCI (B) Mixture Contains 60% CaCh
(C) Mass ofCaCh is 2.22 g (D) Mass ofCaCh 1.11 gm
Q.I0 For the given reaction

CH 3COOH + C2HsOH --+ CH 3COOC2Hs + H 20
When 72 gram acetic acid is made to react with 2.77x 102s u of ethanol.
(A) acetic acid will be limiting reagent (B) alcohol will be limiting reagent
(C) acetic acid will be excess reagent (D) alcohol will be excess reagent
Q.ll Amount oflime that can be produced by heating 100 g of90% pure lime stone-
(A) 50.4 gm (B) 0.98 gm (C) 0.9g molecule (D) 56 gm
Q.12 The first chemical compound of a rare gas element was prepared in 1962. since then several such compounds have
been prepared and characterized. What can be the formula of the compound ofXe(131). Which is 67.2% Xe and
32.8% 0 by mass.
(A) Xe 20s (B) Xe03 (D) XeOs
Q.13 In which of the following pairs do I gram of each have an equal number of molecule?
(A) N 20 and CO (B) N2 and C 30 2 (C) N2 and CO (D) N 20 and CO 2
Q.14 Which concentration can be calculated if mass fraction and density of an aqueous solution ofNaOH are known?
(A) Molality (B) Molarity (C) Percent by mass (D) ppm (mass by mass)
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PARAGRAPHl
Ascorbic acid, C6HS06, also known as vitamin C is a dibasic acid undergoes dissociation as:
C6H s06 -="" C 6H 70 6 + H+; Kl = 8 x 10-5
C 6H 70 6 -="" C6H60~- + H+; K2 = 1 x 10- 12
The ascorbic acid is readily oxidized to dehydroascorbic acid as:
C6HS06 -+ C~606 + 2H+ + 2e
OCHO 9~'r={ol1 ~HO~ + 2H+ +2e

~oAo 0 0
The estimation of ascorbic acid in a sample is made by titrating its solution with KI03 solution which acts as
an intermediate and in presence of I M HCI solution, the first excess of iodate gives blue colour with starch
due to the redox change given below:
C6H s06 + 103-+ 3C6H60 6 + r + 3H20
103 + 5r + 6H+ -+ 31z + 3H 20
excess (generate~ in
reaction)
However, if 5 M HCI is used, the redox change occurs as follows:

4Hs06 + 103 + W + cr -="" ~6 + ICI + 2H20
The acid is heat and light sensitive and deactivated at higher temperature and thus placed in cold and dark
place. It is found in fruit juice, green vegetables and its deficiency in human body develops scurvy, brittling
of bone, teething trouble, etc.
Q.l5 A given 1 litre solution of KI0 3 of unknown molarity is titrated by taking its 50 mL solution against KI
solution in strong acid medium of excess HC!. The equivalence point was detected when 10 mL to 0.1 M KI
was consumed. The molarity ofKI0 3 solution is:
(A) 4 x 10-3 M (B) 2 x 10-3 M (C) 8 x 10-3 M
Q.16 The 250 mL sample of fruit juice collected by crushing a fruit is supposed to have only one ingradient which
can react with KI0 3 is taken in 500 mL measuring flask and 250 mL of 1 M HCI is added. A 50 mL solution
is now pipette out and titrated against intermediate KI0 3 of concentration as reported in past problem [11]. It
was found that 1 mL ofKI0 3 were used. The molarity and strength of ascorbic acid are:
(A) 4.8 x 10-4 M, 84.5 mg/litre (B) 9.6 x 10-4 M, 169 mg/litre
(C) 2.4 x 10-4 M, 42.25 mg/litre (D) None of these
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PARAGRAPH 2
2.5 g sample of copper is dissolved in excess of H 2S04 to prepare 100 mL of 0.02 M CuS04(aq). 10mL of
0.02 M solution ofCuS04 (aq) is mixed with excess ofKI to show the following changes.
CUS04 + 2KI ~ K2S04 + Cuh
2CuI2 ~ CU2h + h
The liberated iodine is titrated with hypo (Na2S203) and requires V mL of 0.1 M hypo solution for its
complete reduction.
Q.17 Percentage of purity of sample is:

(A) 10.16 (B) 5.08 (C) 2.54 (D) 1.27
Q.18 The amount ofI2 liberated in the reaction of 10 mL ofO.2M solution with KIexcess is:
(A) 0.051 g (B) 0.0254 g (C) 0.102 g (D) 0.204 g
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Unit Test-3
[Paper-I]
SYLLABUS
CHEMISTRY Chemical Equilibrium, Ionic Equilibrium, s-Block Element
A. GENERAL:
B. MARKING SCHEME :
SECTION -I
SECTION -/I
SECTION - 11/

• 0 0 0 X Y Z W
P Q R S T
II) ® A • 0 0 0 0
:( BOO •• 0
ABC 0 CO . 0 0 0
• 0 • 0 D •• 0 • 0
bubble are
o ® ~ G
treated as wrong .
"'"
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CHEMISTRY
SECTION-I (Maximum Marks: 28)

is( are) correct.
Q.l In 2HI(g) ~ H2(g) + 12 (g), 2mole HI, 4mole H2 and 4 mole of h are found at equilibrium. If some
hydrogen is now introduced into the container such that at equilibrium concentration of HI and h become
equal. Find the Number of mole ofH 2 added.
(A) 10 mole (B) 20 mole (C) I mole (D) None of these
Q.2 Increase in the pressure for the following equilibrium: H 20( e) ~ H20(g), result in the -
Q.3
(A) formation of more H 20(e)
(C) increase in b.p. of H 20 (C)
When ice melts at IOC :

{(f (B) formation of more H 20(g)
(D) decrease in b.p. ofH 20(f)
(A) an increases in entropy (B) a decrease in enthalpy

(C) a decrease in free energy (D) process is spontaneous
Q.4 Which of the following properties of the elements of group II (alkaline earth metals) increase (s) with
increasing atomic number?
(A) Stability of carbonate (B) Solubility of hydroxide
(C) Reactivity with water (D) First ionization energy
Q.S Sodium sulphate is soluble in water but BaS04 is sparingly soluble because -
(A) the hydration energy ofNa2S04 is more than its lattice energy
(B) the lattice energy of BaS04 is more than its hydration energy
(C) the lattice energy has no role to play in solubility
(D) the lattice energy ofNa 2S04 is more than its hydration energy
Q.6 Which of the following statements about LiCI and NaCI is wrong?
(A) LiCI has lower melting point than NaCI
(B) LiCI dissolves more in organic solvents whereas NaCI does not
(C) LiCI would ionise in water more than NaCI
(D) Fused LiCI would be less conducting than fused NaCi
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Q.7 Select the correct statements about Na2S203.5H20 ;
(A) It is also called as hypo (B) It is used in photography to form complex with AgBr
(C) It can be used as antichlor (D) It is used to remove stains of h

Q.8 If 50 ml of 0.2 M NaCN is mixed with 50 ml of 0.2 M HCl then (Kb for CW = 2 x 10- 5) Calculate
concentration Of[H30J in terms of molarity x 10-6.
Q.9 Calculate the pH at which Mg(OH)2 begins to precipitate from a solution containing 0.1 M Mg+2 ions (Ksp
Mg(OHh = 10- ")
Q.IO Calculate pH of a solution of given mixture (0.1 mole CH 3COOH + 0.2mole CH 3COONa) in 100 ml of
mixture. Ka = 2x lO-5
Q.ll Determine degree of dissociation of 0.05 M NH3 at 25°C in a solution of pH = 11.
Q.12 0.1 mole of each C2H 50H and CH 3COOH when allowed to react in 100 ml of non aqueous solution, it is seen
10 ml of the equilibrium mixture require 80 ml of 0.1 (N) NaOH for complete neutralisation. The equilibrium
constant,
For the reaction
CH3COOH+C2HsOH .~. CH3COOC2Hs+ H20 is expressed as ICc and the value of 32 ICc is

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following table.
Column-l Column-2 Column-3

(P) No effect on reducing volume of
(I) N 2(g) + 3 H 2(g) ~ 2NH 3(g) l1H = -ve (i) kp > kc
container
(Q) On increasing temperature
(II) 2S0 2(g) + 02(g) ~ 2S0 3(g) l1H + = -ve (ii) kp < kc
forward shift is observed
(iii) enk / K=Eq.
Constant (R) On decreasing pressure
(III) CuS04(s) + 5H 20(g) ~ CuS04.5H 2O(s) l backward shift is observed
I
-
T ~ , I'
(iV)enkl ~ (S) On addition of inert gas backward

(IV) H 20(s) ~ H 2O(e) shift is observed
I [at constant pressure]
-
T <
Q.13 Which of the following is correct
(A) (I) (1) (S)
..
(B) (II) (11) (P)
..
(C) (I) (11) (P)
.\' ...
(D) (I) (111) (R)
Q.14 Which of the following is incorrect
(A) (III) (ii) (R) (B) (III) (iii) (R) (C) (II) (ii) (S) (D) (IV) (iv) (S)
Q.lS Which of the following is correct
(A) (IV) (i) (P) (B) (IV) (iii) (S) (C) (IV) (iv) (P) (D) (IV) (iv) (R)
following table.
Column-l /// Column-2 Column-3
Flame colour of underlined atom
(I) Used as source of O 2 in (i) .Mg(CI04)2 (P) Brick Red
submarines, space shuttles and
oxygen masks
(II) Used in obtained the X-ray of the (ii) CaH 2 (Q) Crimson
stomach
(III) Used as a drying agent (iii) K02 (R) Voilet
(IV) React with water to produce H2 (iv) BaS04 (S) Colorless
Q.16 Which of the following is correct combination-

(A) I, ii, R (B) II, i, Q (C) II, i, P (D) IV, ii, P
Q.17 Which of the following is incorrect combination -

(A) I, iii, R (B) II, iv, Q (C) III, ii, S (D) IV, ii, P
Q.18 Which of the following is correct combination-

(A) IV, ii, Q (B) III, ii, S (C) I, iv, Q (D) II, iv, Q
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Unit Test 3
[Paper-2]
SYLLABUS
CHEMISTRY Chemical Equilibrium, Ionic Equilibrium, s·Block Element
A. GENERAL:
•
B. MARKING SCHEME :
Each subject in this paper consists of fOllowing types of questions:-
SECTION -I
SECTION -/I
SECTION - III
answers). Section -II ( co!umn matching type), Section-III (inc!ude integer answer type)]
Section -I Section-II Section-Ill

For example if only 'A' cho i ce is For examp le, if the correc t answers to question For example if Correct matcb for (A) is P ;
correct then , the correct method for numbers X. Y. Z and W (sa y) are 6,0 , 9 an d 2 , for (8) is R, S ; for (C) is Q ; for (D) is P, Q,
filli n g the bubbles is respectively, then the correct me thod for fi lli ng S the n the cor rect method for fi ll ing the
• 0 0 0 x Y Z W P Q R S T
For exam pl e ifonly 'A & C' choices @ CJ) @ @ A • 0 0 0 0
are correct then , the correct method 1 ([ CD CD BOO •• 0
(J) CD CD 8 CO . 0 0 0
ABC D
• 0 • 0 <D <D <D <D D •• 0 • 0
th e wrong method for fi lli ng the @) @) @) @)
bubble are ~ <Il ~ 5
<0 ® ~ G (it ® ® ®
T he a n swer of the que stions in ('j) Q) (j) ('j)
wrong or an y other manner wi ll be
treated as wrong.
®®®®
® CI) (§)
(§)
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CHEMISTRY

Q.l The reaction of sodium is highly exothermic with water. The rate of reaction is lowered by -
(A) Lowering the temperature (B) Mixing with alcohol
(C) Mixing with acetic acid (D) Making an amalgam
Q.2 The solubility of alkali metal hydroxides follows the order -

(A) LiOH < NaOH < KOH < RbOH < CsOH (B) LiOH > NaOH > KOH > RbOH > CsOH
(C) LiOH > CsOH > RbOH > NaOH > KOH (D) None of the above
Q.3 In the following reactions P, Q, R are respectively

(i) Mg3N 2+ 6H 20 -+ Mg(OHh + P (ii) AlN + 3H20 -+ Al(OH)3 + Q
(iii) Na 202 + 2H 20 -+ 2NaOH + R
(A) N0 2, NH 3, H20 (B) NH 3, N02, H 20
Q.4 Correct order of solubility of sulphates of alkaline earth metals are -

(A) BeS04 > CaS04 > SrS04 > MgS04 (B) BeS04 > SrS04 > CaS04 > MgS04
(C) BeS04 > MgS04 > CaS04 > SrS04 (D) None of these
Q.S Alkali metal dissolve in liquid ammonia to give blue coloured solution due to formation of-
(A) Ammoniated electron (B) Ammoniated cation
(C) Both (A) and (B) (D) None of these
Q.6 There sparingly soluble salts A2X, AX and AX3 have the same solubility product. Their solubilities will be in
the order
(A) AX3 > AX > A2X (B) AX3 > A2X > AX (C) AX > AX3 > A2X (D) AX > A2X > AX3
Q.7 The equilibrium constant for the reaction CO(g) + H20 (g) ~ CO 2(g) + H 2(g) is 5. How many moles of
CO 2 must be added to 1 litre container already containing 3 moles each of CO and H20 to make 2M
equilibrium concentration of CO ?
(A) 15 (B) 19 (C) 5 (D) 20
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is( are) correct.
option is darkened
Zero Marks 0 If none ofthe bubble is darkened.
Q.S Select correct statements -

(A) Ca3(P04h is part of bones and 3Ca3(P04h. CaF2 is part of enamel in teeth
(B) Ca2+ ions are important in blood clotting
(C) BeH2 and MgH2 are covalent and polymeric. while CaH2 , SrH2 and BaH 2 are ionic
(D) BeH 2 contain three-centre two-electron bonds
Q.9 The hydrolytic constants are expressed as K hydr . At 25°C, pKhydr of the following cations are as given
Cations Mg"' Ca-" At>' Fe'"
pKhydr 11.4 12.6 5.1 9.5
(A) Smaller the value of ionisation constant of base, greater is the extent of hydrolysis
(B) Greater the polarisation power of the cation stronger the hydrolysis
(C) pKhydr for Fe3+ is expected to be lesser than 9.5
(D) pKhydr for Ba2+ is expected to be greater than 12.6
Q.I0 Select the correct statement (s) from the following-

(A) For the the weak acid HA, if a « 1 then a is inversely proportional to concentration HA, where a stands for degree of
dissociation of HA
(B) For the weak acid HA, If a «1, then a is inversely proportional to square root of concentration ofHA,
where a stands for degree of dissociation ofHA
(C) For the iso hydric solution of two weak acids HA and HB the initial concentrations before mixing must be
equal
(D) In acid buffer solution containing weak acid HA & salt of A-, excess ofHA present in the system reduces
the extent of hydrolysis of A-
Q.ll A solution contains a mixture of 0.01 M Zn2+ and 0.01 M Mn2+ ions and is saturated with H 2S (a saturated
solution ofH 2S being 0.1 M). From the following statements, indicate the correct one-
(Given: ksp ofZnS = 1.0 x 10- 22 , ks p ofMnS = 5.6 x 10- 16 , [H+f [S-2] in saturated solution = 1.0 x 10- 22 )
(A) The pH at which MnS just starts precipitating is 4.38
(B) Zn2+ ions concentration in solution at above pH is 1.8 x 10-9 M
2 27
(C) IfCd + ions are also present at 0.01 M (Ksp of CdS = 8 x 10- ) the ease of precipitations of all these ions
2 2
increases in the order Cd + < Zn + < Mn2+
(D) The H+ concentration just required to precipitate each of these ions in the decreasing order is Mn2+ >
Zn2+ > Cd 2+ (Given: log 4.2 = 0.62)
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Q.12 An acid-base indicator has a Ka 00.0 x 10-5 The acid form of the indicator is red and the basic form is blue.
Then-
(A) pH is 4.05 when indicator is 75% red (B) pH is 5.00 when indicator is 75% blue
(C) pH is 5.00 when indicator is 75% red (D) pH is 4.05 when indicator is 75% blue
Q.l3 The equilibrium

CO(g) + H 20(g) ~ CO 2(g) + H 2(g)
at a given temperature equilibrium amount of CO2 can be increased by -
(A) Adding a suitable catalyst (B) Adding an inert gas
(C) decreasing the conc. ofH 2 (D) increasing the concentration of CO.
Q.l4 In the given question Ka values of five weak acids are given:
I Acids
Ka
I 10
HA I 8 HB
10""
I 2xl0
HC I HD I HE I
8
10 10
10 I
Select the correct statement (s) as per the above information. Given 10g2 = 0.3
(A) Among NaA. NaB, NaC, NaD and NaE, the NaD is most extensively hydrolysed
(B) Among NaA, NaB, NaC, NaD and NaE, NaB is most extensively hydrolysed.
(C) pH of 0.1 (M) aqueous solution of NaB is approximately 9.5
(D) 0.1(M) solution of HE and O.OI(M) solution ofHB are isohydric to each other approximately

PARAGRAPHl
Any acid or base can be classified as hard or soft by its apparent preference for the hard and soft reactants.
For example, a base B may be classified as hard or soft depending on the equilibrium constant, Keq for the
reaction
BH+ + CH3Hg+ ~ CH3HgB+ + H+·

is less than unity or more than unity.
= [ CH 3H gB +] x [W][B]
K~ ~x~
[CH3Hg+][B] [BW]
or log Keq = log Ks + log Ka
or log K~ = log Ks - pKa
Ks is the equilibrium constant of the reaction:
Ks
CH3Hg+ + B;::::::::::! CH3HgB+
Ka is the equilibrium constant of the reaction:
K
BW~ B+W
For hard base, pKa > log Ks, while for soft base, pKa is less than log Ks.
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For the three anions pKa and log Ks are as given:
Anions. pK. logKs
A- 14.2 21.2
B- 15.2 9.2
C- 3.2 1.2
Q.15 The relative softness of A-, B- and C- are-

(A)A- > B- > C- (B) C- > B- > A-
Q.16 Which of the following is not correct-

(A) [H+] = [OHl = .JK:: for a neutral solution at all temperature
7
(B) [H+] = [OIr] = 10- for a neutral solution at all temperature
(C) [H+] > ~Kw and [OH-] < ~Kw for an acidic solution
(D)W < ~Kw and [OHl > ~Kw foranalkalinesolution
PARAGRAPH 2
Mass action ratio or reaction quotient Q for a reaction can be calculated using the law of mass action
A(g) + B(g) ~ C(g) + D(g)
Q = [C] [D]
[A] [N]
The value of Q decides whether the reaction is at equilibrium or not.
At equilibrium, Q=K
For non equilibrium process, Q"* K
When Q > K, reaction will favour backward direction and when Q < K, it will favour forward direction.
Answer the following questions:
Q.17 The reaction quotient Q for:

N 2(g) + 3H2(g) ~ 2NH3(g)
is given by Q = (NH 3f 3 . The reaction will proceed in backward direction, when:

(N2][H 2]
(A) Q = Kc (B) Q < Kc (C) Q > Kc (D) Q = 0
Q.18 For the reaction:

2A+B ~ 3Cat298K,Kc=49
A 3L vessel contains 2, 1 and 3 moles of A, Band C respectively. The reaction at the same temperature:
(A) must proceed in forward direction (B) must proceed in back direction
(C) must be in equilibrium (D) cannot be predicted
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Unit Test-4
[Paper-I]
SYLLABUS
CHEMISTRY Gaseous State, Chemical Energetics
A. GENERAL:
B. MARKING SCHEME:
SECTION -I
SECTION -/I
SECTION - III
5. Based an Table Matching type questians (Single Correct Answer type). 3 marks will be awarded for the correct answer and
-1 markfor wrong answer.
answ ers), Section-II ( column matching type), Section-III (include integer answer type)]
S('ction -I Section-II Section-II'

For example if only 'A' cho ice is Fo r examp le , i f t he correct answers to que stion For example i f Correct matc h [or (A) is P ;
correct then , the correct met hod for numbers X, Y, Z and W (say) are 6 , 0 , 9 and 2 , for (B) is R, S ; for (C) is Q ; for (0) is P , Q,
filli n g t he bubbles is respect ive ly, then the correct me thod fo r fi lli ng S the n the correct method for fi ll ing the
• 0 0 0 x Y Z W P Q R S T
For examp le if only 'A & C' choices
® CD ® ® A • 0 0 0 0
I (1 Q) Q) BOO •• 0
for filli ng the b ubb les is
(b (b Q; 18 CO . 0 0 0
ABC 0
• 0 • 0 Q) <D Q) Q) o •• 0 • 0
th e w rong method for fi lli ng the @) @) @) @)
bubble a re CD W 5 5
o ® ~ C. CIt 6 6 6
T h e an swer of the ques ti ons in (j) (j) (j) (j)
wrong or an y other manne r will be
t reated as wrong .
®®®®
<9: <9: 0) <9:
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CHEMISTRY

is( are) correct.
Q.l The pressure of an ideal gas is increased isothermally at 298 K in a 5 L vessal from 1 bar to 2 bar. The
correct option (s) is /are-
(A) ~G = 2.7 kJ/mol (B) ~G = 1.7 kJ/mol (C) ~Sgas < 0 (D) ~SsuIToun<lings = 0
Q.2 A study of automobile speeds on a highway yielded the following data for a 1 hour period-
Speed in kmlhr Number of cars (n)
(i) 40 10
(ii) 45 8
(iii) 50 15
(iv) 55 10
(v) 60 12
Which of the following is/are correct-
(A) The most probable speed of the automobile is 50 kmlhr
(B) The root mean square speed 51 kmlhr (approximately)
(C) The value of u

avg
urrns
is not equal to Is
V};
(D) None
Q.3
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Q.4 The radial distribution function [P(r)] is used to determine the most probable radius, which is used to find the
electron in a given orbital dP(r) for Is-orbital of hydrogen like atom having atomic number Z, is
dr
dP = 4~3 l2r _ 2Zr2 e -2Zr lao :
J
dr ao ao
Then which of the following statement is/are correct?
(A) At the point of maximum value of radial distribution function dP(r) = 0 ; one antinode is present
dr
(B) Most probable radius of Li 2+ is ~ pm
3
(C) Most probable radius ofHe+ is ~ pm
2
(D) Most probable radius of hydrogen atom is ao pm
Q.S Following represents the Maxwell distribution curve for an ideal gas at two temperature T\ and T 2. Which of
the following option(s) are true?
A \ = Area of small
rectangle I
A2 = Area of small
rectangle II
I dN
- x-
N dU
(A) Total area under the two curves is independent of moles of gas
(B) IfdU\ = JUmps , and dU 2 = JUmps, thenA\ =A2
(C) T\ > T2 and hence higher the temperature, sharper the curve
(D) The fraction of molecules having speed = Umps decreases as temperature increases
Q.6 A open ended mercury manometer is used to measure the pressure exerted by a trapped gas as shown in the
figure. Initially manometer shows no difference in mercury level in both columns as shown in diagram
P = 76 cm
!
gas A
After sparking' A' dissociates according to following reaction

A(g) ----+ B(g) + 3C(g)
If pressure of Gas "A" decreases to 0.9 atm Then (Assume temperature to be constant and is 300 K)
(A) Total pressure increased to 1.3 atm (B) Total pressure increased by 0.3 atm
(C) Total pressure increased by 22.3 cm ofHg (D) Difference in mercury level is 228 mm
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Porous plate
(II)
Q.7
Insulation
The given system is completely thermally insulated. P 2 < PI and T2 < TI consider molar volume at PI , TI is
VI and molar volume at P 2, T 2 is V2 . 1 mole of gas is transferred from piston (I) to piston (II) As per the
gi ven figure -
(A) Work done on the gas in piston (I) is PI VI and work done by the gas in piston (II) is P2V2
(B) Net work done, t':!.w = PI VI - P2V2
(C) The given process is constant enthalpy process.
(D) For the given process the change in internal energy, t':!.E *- 0

Q.8 Two vessels of equal volume are connected to each other by a value of negligible volume. One of the
containers has 2.8 g ofN2 12.7 g OfI2 at a temperature T I. The other container is completely evacuated. The
container that has N2 and h is heated to temperature T2 while the evacuated container is heated T2/3. The
value is now opened. Calculate the mass of N2 in container (B) after a very long time 12 sublimes at T 2.
(report your answer in nearst integer form in grams)
23 3
Q.9 In a container of volume 1 litre 10 gas molecules are present at the r. m . s. speed equal to 10 mls.
Determine the total kinetic energies of the gas molecules in kJ in nearest possible integers.
23 22
Given: N A = 6 x 10 and mass of one molecule = 10- gm
Q.I0 An ideal gas is taken through the cycle A ~ B ~ C ~ A as shown in the figure. If net heat supplied
to the gas in the cycle is 5J, the work done on the gas in the process C ~ A is ......... J-
t 2 ~B
----~ A
V
in m3 1
10
P ~ inN/m2
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Q.ll A person takes 20 breaths lmin. The amount of air inhaled per breath is 500 mi. The inhaled air contains 5%
by volume of oxygen. If enthalpy of combustion of sugar is -3690 J/mol and all the oxygen taken in is used
for combustion of sugar (CI2H22011), find out amount of heat energy liberated (in KJ) per day by combustion
of sugar. (air is inhaled at 1 atm and 27°C)
Q.12 A glass bulb containing a fine orifice was filled with oxygen gas at pressure of 2 atm. It was seen in
50 mins 0.1 gm of oxygen gas was effused out.
Now the glass bulb is completely evacuated and filled with a gas mixture containing oxygen and another gas
(x) (mol wt = 162) in the mole ratio of3:2 at the total pressure of 10 atm. In 100 mins howmany mg ofx will
be effused out of bulb in nearest possible integers?

following table.
Column-l Column-2 Column-3 (Titration Indicator)
(I) Salt ofWA + WB (i) pH = pKw +pKw +logC (P) Methyl orange
2
pK +pK -pK
(II) Salt ofWA + SB C)
11 pH = W a b (Q) Methyl Red
/ 2
(III) Salt of SA + SB ~~ C) H
111 P = pKw -pKb -logC (R) Phenolphthalien
............. 2
(IV) Salt of SA + WB '\ . I

(IV) pH = -pKw (S) No general Indicator is suitable
~ / 2
Q.13 Which of is following is correct combination as given data?

(A) I, ii, P (B) II, ii, R (C) IV, i, P (D) I, ii, S
Q.14 Which of the following is incorrect combination?

(A) IV, iii, Q (B) III, iv, R (C) II, i, P (D) I, ii, S
Q.lS Correct combination is -

(A) III, iv, Q (B) IV, ii, Q (C) II, i, P (D) I, ii, S
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following table.
(I) Root mean square velocity (i) ~RT (P) 1.085 x average velocity
2
~
(II) Most probable velocity (ii)
ltd
(Q) 0.816 rms
~~~",
(III) Average velocity C)ff
III - (R) ~kt ~~-j
(IV) KE of gas mor
i
(iv) r~T
d
(S)
2
ff ,
~/
.V
Q.16 Which of the following is incorrect combination as above data -
(A) IV, i, R (B) II, ii, P (C) I, iii, S (D) II, i, Q
Q.17 Which of the following correct reletion among three columns -

(A) I, ii, S (B) III, iv, Q (C) II, ii, P (D) IV, i, R
Q.18 Which is following is correct set -

(A) III, iv, Q (B) I, iv, Q (C) I, iv, P (D) II, iv, Q
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Unit Test-4
[Paper-2]
SYLLABUS
CHEMISTRY Gaseous State, Chemical Energetics
A. GENERAL:
3. Do not break the seal of the question·paper booklet before being instructed to do so by the invigilators.
B. MARKING SCHEME :
SECTION -I
SECTION -II
SECTION - III
6. Passage based multiple choice questions with single correct option. 3 maries will be awarded for each correct answer and No negative
answers), Section -II (column matching type), Section-III (include integer answer type)]

For example if only 'A' cho i ce is For examp le , if the correc t answers to question For example if Correct matcb for (A) is P ;
correct t hen , the correct method for numbers X, Y, Z and W (say) are 6.0 , 9 an d 2 , for (8) is R, S ; for (C) is Q ; for (D) is P, Q,
filli n g the bubbles is respectively, then the correct method for fi ll ing S the n the cor rect method for fi ll ing the
• 0 0 0 x Y Z W P Q R S T
For examp le i f only 'A & C' choices @ CJ) @ @ A • 0 0 0 0
a re correct tben, the correct method 1 ([ leD BOO •• 0
ABC D
CD CD CD 8 CO . 0 0 0
• 0 • 0 <D <D <D <D D •• 0 • 0
t he wrong method for fi lli ng the @) @) @) @
bubble are ~ <Il ~ 5
<0 ® ~ G 0 ®®®
The a n swer of the questions in (]) (]) (]) (])
treated as wrong.
®®®®
® CI) (§)
(§)
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CHEMISTRY
Q.l In the cyclic process shown in P-V diagram, the magnitude of the work done is-
V
--"'01-~
--,- ,
1 1
'---:!----:!--p
Q.2 What entropy change is involved in the isothermal expansion of5 mol of ideal gas from a volume of 10 L to
100 L at 300 K ?
(A) - 95.7 JK- I (B) + 95.7 JK- I (C) 28.72 kJK- I (D) - 28.72 kJK- I
Q.3 The direct conversion of A to B is difficult. Hence, it is carried out by the following shown path:
8S(A .... C) = 50 e.u., 8S(c .... 0) = 30 e.u.,
8S(B .... 0) = 20 e.u.
where e.u. is entropy unit, then 8S(A .... B) is-
(A) + 100 e.u. (B) + 60 e.u. (C) - 100 e.u. (D) - 60 e.u.
Q.4 Which of the following reperesents a plot of compressibility factor (Z) vs P at room temperature for helium?
(A)<t::=. (B)'~~ (C)'~~ (D)<~

p p p p
Q.S A bulb of constant volume is attached to as manometer tube open at other end as shown in figure. The
manometer is filled with a liquid of density (1I3)rd that of mercury. Initially h was 228 cm.
Through a small hole in the bulb gas leaked assuming pressure decreases as dp/dt = - kP. If value of h is 114
cm after 14 minutes. What is the value ofk (in hour-I)?
[Use: In( 4/3) = 0.28 and density of
Hg = 13.6g1mL.]
(A) 0.6 hr- I (B) 1.2 hr- I (C) 2.4 hr- I (D) 7.2 hr- I
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Q.6 At low pressure the vander Waal equation can be written as (p+ : 2 ) V = RT. The compressibility factor of
the gas is-
(A) (1-~) (C) (I __a )

RTV
Q.7 A particular amount of an ideal gas is filled in boxes of volume, V, V, V , V & so on connected in series
248
through tube of negligible volumes at pressure P & temperature T. This whole sample is now made to
confine in a volume V. The final res sure at the temperature T is -
V
(A) P (B) 2P (C) 3P (D) Infinite

is( are) correct.
option is darkened
Q.S The work involved in a reversible adiabatic process of expansion of an ideal gas from P I and V I to P2 and V2
is given by-
(A)W= P2 V2 -PI VI
'Y -I
(C) W = nCv (T2 - T I) (D) W = [efficiency of camot cycle x aabsorbed]
Q.9 180 gm of water are evaporated slowly under isothermal conditions at 100°C. Assuming water vapour to
behave ideally (~Hv = 2260 Jig) then
(A) ~U = 375.8 kJ (B) ~S = 177.5 JIK (C) ~G = 0 (D) Q = 406.8 kJ
Q.I0 In a reversible camot cycle an ideal gas undergoes following changes.

Step I isothermal reversible expansion PI ,VITI ~ P2, V2, TI
Step II Adiabatic reversible expansion P2, V2 TI ~ P3, V3, T2
Step III isothermal reversible compression P3 , V 3 , T2 ~ P4 , V4 , T2
Step IV Adiabatic reversible comperssion P4 , V4 , T2 ~ PI, VI, TI
Which of the following plot represent the changes in the camot cycle.
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()I,b,
T-
1,2
rLH
(B)T 4
S-
3
1 1
(C)
H
/3,4
T-
(D)
H
\" T-
Q.ll For the reaction N 2(g) + 3H2(g) --+ 2NH 3(g) , standard enthalpy change and standard entropy change at 298 K
are -92 KJ and -198 JIK respectively. Identify the correct statement (s) regarding the reaction -
(A) The ~Go of the reaction is -33KJ
(B) The Kp value of the reaction is 6.03 x 105
(C) The optimum condition for maximum yield of ammonia is high temperature and high pressure
(D) The Kc value of the reaction is 0.098 (Given: --+ Antilog 0.78 = 6.03)
Q.12 203(g) ~ 302(g) , Kp = 109 atm

If at equilibrium total pressure = 10 atm then -
(A) Po, = 10 atm (B) Po, = 10 atm (C) Po, = 10- 3 atm (D) Po, = 10- 3 atm
Q.13 One mole of an ideal gas is subjected to a two step reversible process (A-B and B--C). The pressure at A
and C is same. Mark the correct statement(s) :
,-., (1,100) B(3 600)

~ A ~ ,
i3:' ".:r-:/C(I , 300)
/
/
/
/
/
T(K)
(A) Work involved in the path AB is zero
(B) In the path AB work will be done on the gas by the surrounding
(C) Volume of gas at C = 3 x volume of gas at A
(D) Volume of gas at B is 16.42 litres
Q.14 Which of the following is correct?

(A) m = ~U + ~(PV) when P and V both changes (B) ~H = ~U + P~ V when pressure is constant
(C) ~H = ~u + V~P when volume is constant (D) ~H = ~U + P~ V + V~P when P and V both changes

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PARAGRAPH 1
v/3
On the nearly dis covered planet offound that gasses follow the relationship Pe = nCT where C is constant,
P = pressure, n = mol, V = vol. T = Temp. in Kelvin. A curve is plotted between P and V at 300 K and 3 moles of
gas as shown in figure.
1 atrn
pt
V (lit) --+
Q.15 The value ofC
(A) 1.1 x 10-3 (B) 1.1 x 10-2 (C) 2.2 x 10-4 (D) None of these
Q.16 Find the slope. of curve plotted vs T for closed container volume lit having same moles.
(A) ~ (B) ~ (C) ~ (D) ~
IOOOe IOOOe IOOOe IOOOe
PARAGRAPH 2
When a system is taken from state A to state B as shown in the figure along path ACB, 84 kJ of heat flow
into the system, and the system does 32 kJ of work-
f
p
c17l B
~~D
V-
Q.17 What is the change in internal energy along path A --+ B ?
(A) 52 kJ (B) -52 kJ (C) 116 kJ (D) -116 kJ
Q.18 When the system returned from B to A along the BA path, the work done on the system is 21 kJ. Then which of
the following conclusion is correct-
(A)8q=-3IkJ (B)8q=3JkJ (C)8q=73kJ (D)8q=-73kJ
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Unit Test-5
[Paper-I]
SYLLABUS
CHEMISTRY IUPAC and Nomenclature, GOC, Isomerism
A. GENERAL:
B. MARKING SCHEME :
SECTION -I
SECTION -/I
SECTION - III

• 0 0 0 X Y Z W
P Q R S T
II) ® A • 0 0 0 0
:( BOO •• 0
ABC 0 CO . 0 0 0
• 0 • 0 o •• 0 • 0
bubble are
o ® ~ G
treated as wrong .
"'"
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CHEMISTRY
• Each question has FOUR options (A), (8), (C) and (D). ONE OR MORE THAN ONE of these four options
is( are) correct.
+ 4 marks; darkening only (A) and (D) will get + 2 marks; and darkening (A) and (8) will get -2 marks, as a
Q.l Which of the following pair/s have same IUPAC naming :

Sr I
~
COOCH3
(A)
Sf
0
COOH
and
$COOH
0
OCOCH3
(8)
I ¢F
Sf
Cl
and
(C)~rum ~
Q.2 The correct structure of the compound 2-Amino- 5-bromocyclohexane-l-carboxylic acid is/are-
QCOO~H2
r)
Sf NH2
(8) (C) (D) A
sr~cooH
HOOC
NH2 Sr
Q.3 Select the incorrect statement for the following pair of compounds -
CH3 Cl
~
(A) Constitutional isomer (8) Stereoisomer
(C) Different conformation of same compound (D) Diastereomers
Q.4 Identity the compound which does not have any meso stereoisomer -
(A) 2-hydroxypropanoic acid (8) 2,3-dichloropentane
(C) 2-chlorobutane (D) 2,3-dichlorobutane
Q.5 Which offollowing is/are optically active?
Me H
Me
H$OH
(8) HO H (C) r-\.Me (D)~F
HO
HO
H
Me
~Me H
OH
H
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Q.6 Which is resolvable?
Me,
(A) @=C
~
'----/@ (B)
Me
}:
OHC
=a CH = CH2
o
II
(C)Me-P-Ph (D) Ethylmethylphenyl amine at pH=2
I
CH= CH2
Q.7 Identify the incorrect option according to the property given in the parenthesis-
(y~H J~
(A) ~ l ~ <
N 0
(order of anion stability)
1
H
H3
(B) ~ ~
~N-C-CH2-H
I (3 < I < 20rder of deprotonation)
12
H
(C)*
COOH
(acidic strength)
N0 2
(D) "---- < '-------

~ - - \. (Heat of Hydrogenation)
isobutene trans-2-butene

Q.S
COOH COOH
h C H3 hCl
V V
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Q.' Th, ,ompo~d ( ~ ~ ), m '~Ik ,ompo"d dore 10 001" p,,;pho'l' 01',"0' '"~ti,g ruI".
follows huckel rule i.e. 4n + 2. What is the value ofn.
Q.I0 How many are correct for stability ofresonating structure

E!) E!) E!) 0 0 E!)
(I) CH 3 -C =0 < CH 3 -C=O (II) CH 2 =N=N > CH 2 -N=N
-T- >100'<:::
E!)
(III) CH 3 CH3 > CH3i-CH3

/N- CH 3
CH3-N-CH3 CH 3 Ell
(IV) (0
1~
'<::::
~ Q Q
e
(V) CH2-~-CH3 > CH2=9-CH 3
o 00
Q.ll On reaction with 4 equivalent NaHC0 3 how many acidic hydrogen is removed
SO)H
HO-o--t-COOH
C=CH
Q.12 What is the value ofX-Y-Z+W. If
X = No. of resonating structure of benzene
Y = No. of resonating structure ofnapthalene
Z = No. of resontaing structure of anthracene
W = No. of resonating structure oftropyliumcation

following table.
(I) -N0 2 (i) - M effect (P) 0, P directing
(II) -0'" (ii) + M effect (Q) activating
(UI) - 0 - CH 3 (iii) + I effect (R) deactivating
(IV) - F (iv) - [ effect (S) meta directing
Q.13 CORRECT combination is :
(A) II (ii) R (B) II (i) P (C) II (iii) S (D) III (ii) Q
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Q.14 INCORRECT combination is :
(A) I (i) S (B) II (iii) Q (C) III (ii) P (D) None
Q.15 CORRECT combination is :

(A) II (iii) P (B) IV (iv) P (C) IV (ii) R (D) All
following table.
Column-l Column-2 Column-3 ")
(No. ofisomer)
(P) Three Isomer are soluble in
(I) Benzenoid isomer of C 7 HgO (i) 5
NaOH
(Q) Isomers are positional isomer
(II) C6H 3ClBr I Benzenoid Isomer (ii) 10
(Only)
(R) Five Isomers is cyclic other are
(III) C4H 100 (Structural Isomer) (iii) 7
open chain
(IV) CsHIO (Structural Isomer) (iv) 3 (S) It Include Alcohol & ether
Q.16 Which of the following is CORRECT combination

(A) I (iii) S (B) I (ii) Q (C) II (ii) Q (D) II (ii) P
Q.17 Which of the following is CORRECT combination

(A) III (iii) P (B) III (iii) S (C) III (i) P (D) IV (iv) P
Q.18 CORRECT combination is

(A) I (i) P (B) I (i) S (C) IV (ii) S (D) All
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Unit Test-5
[Paper-2]
SYLLABUS
CHEMISTRY IUPAC and Nomenclature, GOC, Isomerism
A. GENERAL:
B. MARKING SCHEME :
SECTION -I
SECTION -/I
S. Multiple choice questions with multiple correct option. 4 marks will be awarded for each correct answer and
SECTION - III
6. Passage based multiple choice questions with single correct option. 3 maries will be awarded for each oorrect answer and No negative
answers). Section -II ( column matching type), Section-III (include integer answer type)]
Section -, Section-II Section-II'

For example if only 'A' cho ice is For examp le, i f th e correc t answers to question For example if Correct match for (A) is P;
correct then , the correct method for numbers X . Y . Z and W (say) are 6 . O. 9 a nd 2 . for (8) is R. S; for (C) is Q; for (D) is p. Q.
filling t he bubbles IS respect ive ly, then the correct me thod fo r fill ing S the n the correct me thod for fi lling the
• 0 0 0 x Y Z W P Q R S T
® CI) ® ® A • 0 0 0 0
I e! :.L I BOO •• 0
for filli ng the bubb les is
ABC D
~ <I q; I. CO . 0 0 0
• 0 • 0 Q) Q) Q) Q) D •• 0 • 0
th e wrong method for fi ll ing the @) @) @) @)
bubble are 5 ) W 5
(2) ® ~ (J 0 ® 6 ®
T h e answer of the questions in CD CD CD (j)
treated as wrong .
®®®®
® ® 0) ®
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CHEMISTRY

CH 2 CH 3
II I
Q.l The IUP AC name of C2HS-C-CHz-CHNH2 is -
(A) 4-arnino-2-ethylpent-I-ene (B) 2-ethylpentan-4-arnine
(C) arninopent-4-ene (D) 4-ethylpent-4-en-2-arnine
Q.2 Which of the following compounds has wrong IUP AC name?
(A) CH3CH2CH2COOCH2CH3:; ethylbutanoate (B) CHr-rH-CH2-CHO; ; 3-methylbutanal
CH 3
(C) CH 3-CH-CH-CH 3 ; 2-methylbutan-3-ol

o
II
(D) CH3-CH-C-C2HS ; 2-methylpentan-3-one
I I I
OH CH 3 CH 3
Q.3 A, (CJI12) optically active compound on catalytic hydrogenation gives B, (CJI14) an optically inactive
compound. A and Bare-
(A)
H3C
A ~E
yH 3
CH 3 H3C CH 3
(B)CH 2=CH-CH-CH 2CH 3 and 3-Methyl pentane
I
CH 3
(C) CH 3CH=C-C H z-CH 3 and 3-Methylpentane

Q.4 Which statement is correct about the following structures?
CH 3 C2Hs CI
H--+-Br H--+-Br
C l i OCH3 H3COiCI
H3CO +-C2S Br
H
Hi
C2HS CH 3 CH 3
(I) (II) (III)
(A) I and III are structural isomers (B) I, II and I, III are enantiomers
(C) I, ill are enantiomers and L II are structural isomers (D) I, II and III are stereoisomers
Q.5 The correct stability order for the following species is -
Ao~AA~o~AA $
(I) (II) (III) (IV)
(A) II > IV > I > III (B) I > II > III > IV (C) II > I > IV > III (D) I > III > II > IV
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Q.6 Select the incorrect statement among the following -
(A) Benzene undergoes predominant reactions by electrophilic substitution
(B) Toluene is more easily sulphonated than benzene
(C) Benzene reacts with CCl4 in the presence of anhydrous AlCl 3 to give triphenyl methyl chloride
(D) Benzene reacts with chlorine (Cb) in presence of light to give benzyl chloride
Q.7 The structure of2-(3'-Oxobutyi) cyciohexane-l-one is-
(A) d' O-CH-CHrCH)

(8) (y"rCHi-CH;
I
CH 3
(C)
°D CHrTi-CHrCH)
° SECTION - 2 (Maximum Marks: 28)

is( are) correct.
option is darkened
Q.8 Identify the incorrect order -
(B)
(stability of carbocation) (Acidic strength)
>
CI.............. CI
CE>
I
(D) @--NH- CH 3 > 0
CI ~
(stability order of anion) (pKb) H
Q.9 NaHC0 3 can react with -
(A)
°UO
°
I
OB
H
(B)@-COOH
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a
Q.I0 The correct order of heat of combustion values are-
(B)Q ~Me
Me ..llluM e
CH
>
(y 3
(A)U < Me Me Ll....Me
(C)O > 0 (D)@-@ < @ 2-@ CH
Q.ll Which is the correct order of increasing basicity ?

(A) CH 3CH 2CH 3 < CH 3CH 2 SH < CH 3CH 20H < CH 3CH 2NH 2
(B) CH 3CH 2CH 3 < CH 3CH 20H < CH 3CH 2SH < CH 3CH 2NH 2
(C) CH 3CH 2NH 2< CH 3CH 2SH < CH 3CH 20H < CH 3CH 2CH 3
(D) CH 3CH 2CH 3< CH 3CH 20H < CH 3CH 2NH 2 < CH 3CH 2SH
Q.12 Which of the following has been arranged in order of decreasing stability?
(A) CH] > CH 3CH2 > (CH3)2CW > (CH3)3C+ (B) CH 3CH2 > (CH3)2CW > (CH 3hC+ > CH]
(C) (CH 3hCW > CH3CH~ > (CH 3hC+ > CHr (D) (CH 3 hC+ > (CH 3hCH+ > CH 3CH2 > Cm
Q.13 ChC) C=C<H

H
(I)
CCh HH
ChC)C = C<CCh
(II)
which is true for above isomeric form I & II respectively
(I) (II)
(A) Polarity more less
(B) Boiling point less more
(C) Heat of hydrogenation less more
(D) Solubility in water more less
Q.14 Which of following conformers are possible for 1 phenyl propane-
(A)H~H (C)H~H H*H

Ph
(8)H*CH'
(D)
H~H H~H H~H H H
Ph H CH 2Ph H

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PARAGRAPH 1
The following plot was obtained during conversion of chair form of cyclohexane to its boat form.
B
t
Potential
energy
A
Conformations-
Q.lS Which is correctly matched?

(A) B : Boat form (B) C : Half-chair (C) D : Twist-boat (D) C : Twist-boat
Q.16 Which conformation is optically active?

(A) A (B) B (C) C (D)D
PARAGRAPH 2
Cyclo alkanes consisting of two rings only and having two or more atoms in common are named by taking the
prefix "bicyclo" followed by the name of the alkane/alkene/alkyne. In between bicyclo and alkane/alkene/
alkyne, number of C-atoms representing the bridge (except bridgehead positions) are written within bracket.
Bridgehead positions are those which join two rings.
Q.17 Choose correct IUP AC name for-
~'----1 OR
(A) Bicyclo [3.1.1] heptan-2-ol (B) Tricyclo [3.1.1] heptan-2-ol

(C) Tricyclo [3.1.1] heptan-4-ol (D) Bicyclo [3.2.0] heptan-3-ol
OHc);
Q.18 Give IUP AC name for the following compound -
(A) 2-[2,4-dihydroxycyc1obutyl]Bicyclo[ 4.3.0] non-7-ene

(B) 5-[2,4-dihydroxycyclobutyl]Bicyclo[4.3.0] non-7-ene
(C) 1,1' cyc1ohexyl-2, 3-cyclopent-2-enyl cyclobutane-2, 4-diol
(D) 2-[2,4-cyclobutanediol]Bicyclo[4.4.3] non-2-ene
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SpaC8 for roup"
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Revision Test -1
[Paper-I]
SYLLABUS
CHEMISTRY Units 1 to 5
A. GENERAL:
B. MARKING SCHEME :
SECTION -I
SECTION -/I
SECTION - III
9. While filling the bubbles please be careful about SECTIONS [Le. Section-I (include single correct, reason type, multiple correct
answ ers), Section-II (column matching type), Section-III (include integer answer type)]

correct then , the correct met hod for numbers X. Y. Z and W (say) are 6 , 0 , 9 and 2 , for (B) is R, S ; for (C) is Q ; for (0) is P , Q,
• 0 0 0 x Y Z W P Q R S T
® CD ® ® A • 0 0 0 0
I (1 Q) Q) BOO •• 0
(b (b Q; 18 CO . 0 0 0
ABC 0
• 0 • 0 Q) <D Q) Q) o •• 0 • 0
o ® ~ C. CIt 6 6 6
T h e an swer of the que sti ons in (j) (j) (j) (j)
t reated as wrong .
®®®®
<9: <9: 0) <9:
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CHEMISTRY

is( are) correct.
Q.l I st excitation potential for the H-like (hypothetical) sample is 24 V. Then -

(A) ionisation energy of the sample is 36 eV (B) Ionisation energy of the sample is 32 eV
8V
(C) Binding energy oOrd excited state is 2 eV (D) 2nd excitatIOn
. . potentia . I 0 f th I e I' S
e samp 32-x -
9
Q.2 A hydrogen like atom in ground state absorbs 'n' photons having the same energy and it emits exactly 'n'
photons when electronic transition takes place. Then the energy of the absorbed photon may be-
(A) 91.8 eV (B) 40.8 eV (C) 48.4 eV (D) 54.4 eV
Q.3 nd
In a sample of atoms hydrogen like electron is in 2 excited state, the binding energy of 4'h orbit of this atom
is l3.6 eV, then the -
(A) A 25 eV photon can set free the electron from the second excited state of this sample
(B) 3 different types of photon will be observed if electrons make transition up to ground state from the
second excited state
(C) If23 eV photon is used then K.E. of the ejected electron is I eV
(D) 2nd line of Balmer series of this sample has same energy value as IS' excitation energy ofH -atoms
Q.4 Select the incorrect statement -

(A) When attractive forces are dominant in a real gas U internal energy increases by increasing the average
molecular separation
(B) Isothermal contraction decreases the internal energy when repulsive forces between molecules exist
(C) For an ideal gas at constant T internal energy is function of volume only.
(D) In case of attractive forces between particle, if the volume of the sample expands isothermally its dU< 0
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Q.5 203(g) ~ 302(g) , Kp = 109 atm
If at equilibrium total pressure = 10 atm then -
(A) Po 2 = 10 atm (B) Po 3 = 10 atm (C) Po 3 = 10- 3 atm (D) Po 2 = 10- 3 atm
Q.6 CO 2 molecule is not isostructural with:

(A) HgCIz (B) SnCIz (D) N0 2
Q.7 Which is wrong statement about (SiH 3hN is-
(A) (SiH 3hN is planar
(B) (SiH3)3N is linear
(C) In (SiH3)3N lone pair is present on N does not under back bonding
(D) There are 9 sigma bond in the above molecule

Q.8 If 50 ml of 0.2 M NaCN is mixed with 50 rnl of 0.2 M HCl then (Kb for C~ = 2 x 10- 5) Calculate
concentration of [H30l interrns of molarity x W·.{;.
Q.9 Calculate the pH at which Mg(OH)2 begins to precipitate from a solution containing 0.1 M Mg+2 ions (Ksp
Mg(OHh = 10- ")
Q.I0 Calculate pH of a solution of given mixture (0.1 mole CH 3COOH + 0.2mole CH 3COONa) in 100 rnl of
mixture. Ka = 2x lO- 5
Q.ll 4 mole each ofS0 2 and O2 gases are allowed to react to form S03 in a closed vessel. At equilibrium, 25% of O2
is used up. The total number of moles of all the gases at equilibrium is.
Q.I0 Under identical condition of temperature density of gas X is two times to that of gas Y while molecular mass
of gas Y is three times than of X. Calculate the ratio of pressure X and Y

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Answer Q.13, Q.14 and Q.1S by appropriately matching the information given in the three columns of the
following table.
(Charged on Carbon) (Hybridization of Charged Carbon)
(- )
(I) C6HS CH 2 (i) Pyramidal (P) Sp2
(-)
(II)
0 (ii) Resonance stabilized (Q) Sp3
(~~
~
(+)
(III) Me 3C (iii) Stabilized by Hyper conjugation (R) sp
(IV) :CH:J (iv) Anti aromatic (S) sp3d ,\ v

.'
Q.13 Which of the following is only correct option?
(A) (I, ii, Q) (B) (II, iv, R) (C) (III, i, P) (D) (IV, i, Q)
Q.9 Which of the following is only incorrect option?

(A) (II, ii, P) (B) (III, iii, P) (C) (II, iv, R) (D) (I, ii, P)
Q.I0 Which of the following is only correct option?

(A) (II, i, iv) (B) (IV, ii, P) (C) (III, i, Q) (D) (I, ii, P)
following table.
Column -1 Column - 2 Column - 3

(I) BH; (i) 2 B. P. & 3 L. P. (P) Hybridisation = spj
(II) ICI; (ii) 4 B. P. & No L. P. (Q) Hybridisation = sp' d"
(III) ICI;: (iii) 3 B. P. & I L. P. (R) Hybridisation = spj d
(IV) ICI; (iv) 2 B. P. & 2 L. P. (S) Hybridisation - sp'd'

(v) 4 B. P. & 2 L. P.
Q.16 Which of the following is only incorrect set?

(A) (I) (ii) (P) (B) (II) (iv) (P) (C) (III) (i) (R) (D) (IV) (v) (P)
Q.17 Which of the following is true set?

(A) (III) (ii) (R) (B) (IV) (v) (P) (C) (IV) (v) (Q) (D) (III) (iii) (R)
Q.18 Which of the following has (Pn - Pn) bonding.

(A) BH; (B) ICI;: (C) ICI; (D) None of these
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8. 9. 10. 11 . 12. 8. 9. 10. 11. 12. 8. 9. 10. 11. 12.
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Revision Test -1
[Paper-2]
SYLLABUS
CHEMISTRY Units 1 toS
A. GENERAL:
B. MARKING SCHEME:
SECTION-I
SECTION -/I
SECTION - 11/
S('ction -I S('ction-II S('ction-III

For exam ple if only 'A' cho i ce i s For examp le, if the correc t answers to que stion For example if Correct match for (A) is P ;
correct th en, the correct method for number s X, Y, Z and W (say) are 6, 0 , 9 and 2 , for (8) is R, S; for (C) is Q ; for (D) is P, Q ,
filli ng the bubbles is respective ly, then the correct m e thod for filling S the n the correct method for tilling the
ABC D the bubbl es is bubb les is
• 0 0 0 x Y Z W P Q R S T
For exam pl e if only 'A & C' choices
are co rrect then , the correct method
® CD ® ® A • 0 0 0 0
ICl leD BOO •• 0
[or filli ng the bubb les is
ABC D
CD <D <D 8 CO . 0 0 0
• 0 • 0 <D <D <D <D D •• 0 • 0
th e wrong method for filling th e @) ® ® ®
bubble a re G) II) G) G)
o ® ~ G (it 6 6 6
The a nswer of the que stion s in (J) (J) (J) (J)
treated as wrong.
®®®®
<2: @: 0 1<2:
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CHEMISTRY

Q.l Given enthalpy of combustion of glucose is 2870 kl/mo!. What will be the amount of glucose a man has to eat
in order to climb a height of 100 m assuming 100% efficiency of the body system (weight of man = 60 kg) -
(A) 37 g (B) 3.7 g (C) 370 g (D) 180 g
Q.2 Calculate The pH of mixture of 400 mL of _1- M Ba(OH)2 and 400 rnl of ~ M HCI and 200 mL of water -
200 50
(A) 8.4 (B) 2.4 (C) 2.8 (D) None of these
3
Q.3 A stationary mass of gas is compressed without friction from an initial state of 0.3 m and 0.105 M Pa to a
3
final state of 0.15 m and 0.105 M Pa. The pressure remaining constant. During the process there is transfer
of37.6 kI ofheat from the system. During the process the amount of internal energy change is-
(A) - 28.85 kI (B) - 21.85 kJ (C) - 21.85 MJ (D) -53.35 kI
Q.4 Which is not a correct match?

(A) Li 20 < Na20 < K 20; order of basic character (B) Be < Mg < Ca ; order of metallic character
(C) N < 0 < F ; order of oxidising character (D) K < N a < Rb ; order of reducing character
Q.5 Which of the following statements is not correct?

(A) The element with highest IE belongs to group 18
(B) In each period the element with lowest IE belongs to group 1.
(C) In each period the element with highest IE is a noble gas
(D) In the second period, as we move from left to right, ionization energy increases regularly
Q.6 The correct order of electron affinities is -

(A) CI > Si > Na > Ar (B) Si > CI > Na >Ar (C) CI > Na > Si > Ar (D) CI > Si > Ar > Na
Q.7 The compound has been named in IUP AC as -
(A) 2-carbethoxy cyclopentan-l-one (B) l-oxo-2-carbethoxy cyclopentane

(C) Carbethyoxy cycle pentanone (D) Ethyl -2-0xo-cylopentane-carboxylate
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is( are) correct.
option is darkened
Q.8 Which of the following statements are not correct?

(A) All C-O bonds in CO~- are equal but not in H 2C0 3
(B) All C-O bonds in HCOl" are equal but not in HC02H
(C) C-O bond length in HCOl" is longer than C-O bond length in CO~-
(D) C-O bond length in HCOl" and C-O bond length in CO~- are equal
Q.9 Select the correct statements about the compound NO[BF4J :

(A) It has Sa and 21t bond
(B) Nitrogen-oxygen bond length is higher than nitric oxide (NO)
(C) It is a diamagnetic species
(D) B-F bond length in this compound is lower than in BF3
Q.I0 The correct statement concerning the structures E, F and Gis/are-
H3~
C
H)C
O
CH3
C
H3~
H3C
OH
< CH 3
(E) (F) (G)
(A) E, F and G are resonance structures (B) E, F and E, G are tautomers
(C) F and G are geometrical isomers (D )F and G are diastereomers
Q.ll Identify the correct statements
~~[]ODH
I II III IV V
(A) I & III are antiaromatic (B) III & IV are non aromatic
(C) II & V are aromatic (D) Only IV is non aromatic
Q.12 For which of the following species resonating structures can not be written-
Ell Ell Ell
(A) CH2=CH-CHz-CH2 (B) CHz=C -CHz--CH3 (C) CH2=CH-O--CH 3 (D) C H =CH-CHz--CH 3
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Q.13 Which of the following are not resonating structure
~H3 ~
(A)O-lL]
Q.14 For phase transition involving 3 moles of benzene
C6H6 (l, 80°C, I atm) ~ C6H6 (g, 80°C, 0.5 atm) If 80°C is normal Boiling point of C~6.
The correct statement about the transition is-
(A) L'1E < 0 (B) L'1G = - 0.49 kcal (C) L'1H > 0 (D) L'1G = 2.3 kcal

PARAGRAPH 1
Isomers that differ in their cis-trans arrangement on a ring or double bond are known as geometrical isomers.
Geometrical isomers are subclass of diastereomers. cis-trans or E, Z nomenclature is used for geometrical
isomers. (E) form is generally more stable than (Z) form.
Q.lS Which of the following compounds will show geometrical isomerism?
(A) H><X)<
CH3 H
CH
3 (B) H)C=C=C <CH
Br C2HS
3
(C) CD (D) All of these
Q.16 Number of geometrical isomers of the given compound is :

C6H s-CH=CH-CH=CH-CH=CH-C00H
(A) 4 (B) 8 (C) 16 (D) 10
PARAGRAPH 2
Lithium only forms monoxide when heated in oxygen. Sodium forms monoxide and peroxide in excess of
oxygen. Other alkali metals form superoxide with oxygen, i.e., M0 2. The abnormal behaviour of lithium is
due to small size. The larger size of higher alkali metals also decides the role in formation of superoxides. All
the three anions abstract proton from water. The three anions are related to each other as follows :
.!.o,
0 2- 2 ) O~ ~ 20;-
oxide ion peroxide ion Superoxide ion
Q.17 Consider the following reaction:
M + O2 ~ M0 2
(M = alkali metal) (stable superoxide)
(A) M can not be Li and Na (B) M can not be Cs and Rb
(C) M can not be Li and Rb (D) None of these
Q.18 Which anion is stable towards water -
(A) 0 2- (B) O~- (C) O 2 (D) None of these
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Unit Test-6
[Paper-I]
SYLLABUS
CHEMISTRY Solution and Colligative Properties, Solid state, Surface Chemistry
A. GENERAL:
B. MARKING SCHEME :
SECTION -I
SECTION -/I
SECTION - III

correct then , the correct met hod for numbers X. Y. Z and W (say) are 6, 0, 9 and 2, for (8) is R, S ; for (C) is Q ; for (0) is P, Q,
filli ng the bubbles is respect ive ly, then the correct me thod fo r fi lli ng S the n the correct method for fi ll ing the
• 0 0 0 x Y Z W P Q R S T
® CD ® ® A • 0 0 0 0
I (1 Q) Q) BOO •• 0
(b (b Q; 18 CO . 0 0 0
ABC 0
• 0 • 0 Q) <D Q) Q) o •• 0 • 0
bubble are CD W 5 5
o ® ~ C. CIt 6 6 6
t reated as wrong .
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CHEMISTRY
is( are) correct.
Q.l In the unit cell ofNaCI, which of the following statements are correct?
(A) Na+ ions have six cr ions in its nearest neighbourhood
(B) cr ions have six Na+ ions in its nearest neighbourhood
(C) Second nearest neighbour ofNa+ ion are twelve Na+ ions
(D) NaCl has 68% of occupied space
Q.2 Select the correct statements among following -

(A) Nearest neighbour distance in NaCl = a/2
(B) Nearest neighbour distance in CaF2 = a.J3 I 4
(C) Nearest neighbour distance in Na20 = a.J3 I 4
(D) Nearest neighbour distance in CsCI = a.J3 12 (a = edge length of unit cell)
Q.3 A sample ofH 20 2 solution labelled on '28 V density of26.5 giL. Mark the correct option(s) representing the
same in other units
(A) Molarity = 2.5 (B) % wN = 17
(C) Mole fraction ofH 20 2 = 0.2 (D) Molality = 13.88
Q.4 Which one ofthe following statements is/are true ?

(A) two sucrose solutions of same molality prepared in different solvents will have the same freezing
point depression
(B) the osmotic pressure (1t) of a solution is given by the equation 1t = MRT, where M is the molarity
of the solution
(C) Raoult's law states that the vapour pressure of a component over a solution is proportional to its
mole fraction
(D) the correct order of osmotic pressure for 0.01 M aqueous solution of each compound is
BaCh > KCI > CH 3COOH > Sucrose
Q.S Consider the following arrangement and select the incorrect options -
0.2 M : 0.18 M
Na,SO, :, KCI
Semipermeable membrane
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(A) O.P. ofNa2S04 solution is higher than the O.P. ofKCI solution
(B) Water will flow from KCI solution to Na2S04 solution
(C) O.P. ofNa2S04 solution is lesser than the O.P. ofKCl solution
(D) Water will flow from Na2S04 solution to KCl solution
Q.6 Which of the following are correct about the binary homogeneous liquid mixture?
(A) H20 and C 2HsOH (B) CJf6 and CJf SCH 3
MIsoI . > 0, ~Vol . > 0 MIsol. = 0, ~V,ol. = 0
(C) CH3COCH 3 and CHCb (D) H20 and HCl
MIsoI < 0, ~Vsol. < 0 MIsol. > 0, ~V,ol. < 0
Q.7 Select the correct statements among following -
(A) Volume of mixing of ideal solution is zero
(B) Enthalpy of mixing of ideal solution is zero
(C) When mixture is less volatile, there is negative deviation from Raoult's law
(D) Entropy of mixing is zero for ideal solution

Q.8 A solution of fatty acid "X" (M = 252 gmlmol) in benzene contain 4.2 gm of acid per litre. When this
solution is dropped in a water surface the benzene evaporates and fatty acid "X" forms a monolayer film. of
solid type. Ifwe wish to cover 10 m2 area with monolayer film of fatty acid "X", what volume of solution in
2
ml should we use? Each fatty acid molecule occupy 0.2 nm area
Q.9 When a graph is plotted between log xlm and log p, it is straight line with an angle 45 0 and intercept 0.3010
on y-axis. If initial pressure is 0.3 atm, what will be the amount of gas adsorbed per gm of adsorbent. Give
your answer after multiply by 5 .
Q.I0 A solution containing 0.1 g of a non-volatile organic substance P (molecular mass 100) in 100 g of benzene
raises the boiling point of benzene by 0.2°C, while a solution containing 0.1 g of another non-volatile
substance Q in the same amount of benzene raises the boiling point of benzene by O.4°C. What is the ratio of
molecular masses ofP and Q in term ofP/Q ?
Q.ll If the vapour pressures of pure A and pure B at 298 K are 60 and 15 torr respectively, what woule be the
mole percent of A in vapour phase (at this temperature) in a solution that contains 20 mole per cent of A in
the (A + B) binary mixture in the liquid phase? Express your answer as O.x. What is x
Q.12 You are given marbles of diameter 10 mm. They are to be placed such that their centres are lying in a square
bond by four lines each of length 40 mm. What will be the arrangements of marbles can be placed inside the
2
area. Determine the number of marbles in unit cm area.
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following table.
(1) AAAA packing (i) CCP A (P) CN = 12
(II) ABABAB packing (ii) HCP
"'- (Q) CN=4
(III) ABCABC packing
(IV) body centre cubic
(iii) BCC
(iv) primitive
/,~
I ~" )
" (R) CN - 8
(S) CN = 6
?/
Q.13 Which one of the following combination is correct combination
(A) (I) (iv) (R) (B) (I) (iv) (S) (C) (I) (ii) (P) (D) (I) (i) (S)
Q.14 Which is correct for ABCABC packing

(A) (III) (i) (P) (B) (III) (i) (Q) (C) (III) (ii) (P) (D) (III) (iii) (R)
Q.lS Which of the following is incorrect combination
(A) (II) (ii) (P) (B) (IV) (iii) (R) (C) (II) (i) (P) (D) All of these
following table.
(I) Milk (i) gas dispersed in liquid (P) aerosol
(II) Dust /\" (ii) solid dispersed in liquid (Q) emulsion
(III) Cheese /<~ (iii) solid dispersed in gas (R) gel
,
(IV) Froth (iv) liquid dispersed in solid (S) foam
Q.16 Which of the following set is correct as above three colurrms -

(A) IV, iii, S (B) III, iii, S (C) II, i, P (D) II, ii, Q
Q.17 Which of the following is correct option?

(A) II, iv, R is correct set (B) I, iv, Q is correct set
(C) Both are correct (D) None of above is correct
Q.18 Which of the following is incorrect set -

(A) I, ii, Q (B) II, ii, P (C) III, iv, R (D) IV, iii, Q
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Unit Test-6
[Paper-2]
SYLLABUS
CHEMISTRY Solution and Colligative Properties, Solid state, Surface Chemistry
A. GENERAL:
B. MARKING SCHEME :
SECTION -I
SECTION -/I
S. Multiple choice questions with multiple correct option. 4 marks will be awarded for each correct answer and
SECTION - III
S('ction - I Section-II Section-III

For example i f only 'A' cho ice is For examp le , i f t he correc t answers to question For example i f Correct matc h for (A) is P ;
cor rect t hen , the correct met hod fo r numbers X , Y, Z and W (say) are 6 , 0 , 9 and 2, for (8) is R, S; for (C) is Q; for (0) is P, Q,
filli n g the bubbles is respect ive ly, then the correct me thod fo r fi ll ing S the n the correct method for fi ll ing the
• 0 0 0 x Y Z W P Q R S T
For example if only 'A & C ' choices
® CD ® ® A • 0 0 0 0
I e! CD CD BOO •• 0
(b <r Q; 18 CO . 0 0 0
ABC 0
• 0 • 0 Q) <D Q) Q) o •• 0 • 0
bubble are CD cr 5 5
o ® ~ G CJ 6 6 6
T h e answer of the questions in (j) (j) (j) (j)
t reated as wrong .
®®®®
(i (i U 1<2:
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CHEMISTRY

Q.l Ferrous oxide has a cubic structure and edge length of the unit cell is 5.0 A. Assuming the density offerrous
2 2
oxide to be 3.84 g1cm3, the no. of Fe + and 0 - ions present in each unit cell be:
23
(use NA = 6 x 10 ) :
(A) 4 Fe 2+ and 40 2- (B) 2 Fe2+ and 20 2- (C) 1 Fe2+ and 1 0 2- (D) 3 Fe 2+ and 40 2-
Q.2 A2B molecules (molar mass = 259.8 g1mol) crystallises in a hexagonal lattice as shown in figure. The lattice
constants were a = 5 A and b = 8 A. If density of crystal is 5 g1cm3 then how many molecules are contained
in given unit cell? (use NA = 6 x 1023)
1
b
J-------+-7 1
(A) 6 (B) 4 (C) 3 (D) 2
Q.3 The density of solid substance A (A = 40 g1mol) is 1.68 g1mL at 40 K. If the atom of substance A is assumed
to be a sphere of radius 1.50 x 10-8 em, what % of solid A is apparently empty space?
(use NA = 6.023 x 1023 )
(A) 35.64 (B) 64.36 (C) 74% (D) None of these
Q.4 The gold numbers of protective colloids A, B, C and Dare 0.04, 0.004, 10 and 40 respectively. The
protective powers of A, B, C and D are in the order -
(A) A > B > C > D (B) B > A > C > D (C) D > C > A > B (D) D > C > B > A
Q.5 AS 2S3 sol is -

(A) Positive colloid (B) Negative colloid (C) Neutral colloid (D) None of the above
Q.6 A graph between xlm and the pressure P of the gas at a constant temperature is called adsorption isotherm.
Where x is the no. of moles of the adsorbate and m is the mass of the adsorbent. Adsorption isotherms of
1/n
different shapes have been experimentally observed. According to Frundlich adsorption isotherm xlm = KP
Where k and n are constant parameters depend upon the nature of the solid and gas. Graph between
log (~) and log P is straight line at angle 45° with intercept OA as shown.
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1
x
logm A
Hence, (:) at a pressure of 2 atm is -
(A) 2 (B) 4 (C) 8 (D) 1
Q.7 In a planar tetraatomic molecule, AB 3, A is at the centroid of the equilateral triangle formed by the atoms, B.
If the A-B bond distance is 1 A, what is the distance between the centres of any two B atoms?
(A) 11 J3 A (B) .J2A (C) J3A (D) 1/.J2A

is( are) correct.
option is darkened
Q.S To 22 ml 1 M BaCI 2 solution 12 ml of 0.6 M K2 S04 is added, BaS04 is precipitated out-

(A) vapour pressure is decreased (B) boiling point is increased
(C) freezing point is increased (D) Freezing point is decreased
Q.9 Select the correct statement(s):

(A) A NaCI type AB crystal lattice can be interpreted to be made up of two individual fcc type unit lattice of A+
and B- fused together in such a manner that the comer of one unit lattice becomes the edge centre of the other
(B) In a fcc center unit lattice, the body centre is an octahedral void
(C) In an scc lattice, there can be no octahedral void
(D) In an scc lattice, the body center is the octahedral void
Q.I0 The density ofa certain solid AB (formula mass = 119) is 2.75 g/cm3. The edge of the unit cell is 654 pm long.
What is/are true about the solid AB ?
(A) It has bcc unit cell (B) There are four constituents per unit cell
(C) Unit cell constituted by anion is fcc (D) Structure is similar to ZnS
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Q.ll In the unit cell ofNaCl, which of the following statements are correct?
(A) Na+ ions have six cr ions in its nearest neighbourhood
(B) cr ions have six Na+ ions in its nearest neighbourhood
(C) Second nearest neighbour ofNa+ ion are twelve Na+ ions
(D) NaCl has 68% of occupied space
Q.12 Crystalline solids have:
(A) sharp melting point (B) anisotropic character
(C) the character of supercooled liquid (D) smooth cooling curve
Q.13 Which statement(s) is/are correct?

(A) Physical adsorption is multilayer, non-directional and non-specific
(B) Chemical adsorption attains equilibrium some late
(C) Physical adsorption is due to valence of atoms
(D) Chemical adsorption is more stronger than physical adsorption
Q.14 A lyophobic colloidal solution can be precipitated by-

(A) adding lyophilic colloid (B) heating
(C) adding electrolyte (D) adding oppositely charged colloid

PARAGRAPH 1
The total vapour pressure of a binary solution is given by
P = (llOX A + l25X B ) mm Hg
where X A and X B are the mole fraction of components A and B, respectively.
Q.3 The mole fraction of A in the solution is 0.3 . The mole fraction ofB in the vapour phase, YB is-
(A) 0.38 (B) 0.73 (C) 0.27 (D) 0.46
Q.4 For the equimolar solution of A and B, which of the following is a correct statement ?
(A) P > p Ao (B) P < p Ao (C) P = p Ao (D) None of these
PARAGRAPH 2
The mineral perovskite has a structure that is the prototype of many ABX 3 solids; particularly oxides. The
perovskite structure is cubic with A atoms surrounded by l2X atoms and the B atoms surrounded by 6X
atoms. The sum of charges on the cations A and B must be +6; it can be achieved in several ways (A2+ B4+
and A3+s 3+ among them).
The perovskite structure is closely related to the materials that show interesting electrical properties, such as
piezoelectricity, ferroelectricity and high temperature superconductivity.
Perovskite is the name of a mineral containing calcium, oxygen and titanium having following unit cell structure:
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,
- -- ~ ----:..
"- ,
\.l
'\,
"
"Titanium-Oxygen oCalcium
Q.16 Total number of atoms in the unit cell of perovskite is -

W2 ~)3 ~)4 (D) 5
Q.17 Which of the following does not have perovskite structure?

(A) LaNio.5 IrO.50 3 (B) BaTi03 (C) CaTi0 3
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II" work
SpaC8 for roup"
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Unit Test-7
[Paper-I]
SYLLABUS
CHEMISTRY Electro Chemistry, Chemical Kinetics
A. GENERAL:
B. MARKING SCHEME:
SECTION -I
SECTION -/I
SECTION - III
5. Based an Table Matching type questians (Single Correct Answer type). 3 marks will be awarded for the carrect answer and

correct then , the correct met hod for numbers X, Y, Z and W (say) are 6 , 0 , 9 and 2 , for (B) is R, S ; for (C) is Q ; for (0) is P , Q,
• 0 0 0 x Y Z W P Q R S T
® CD ® ® A • 0 0 0 0
I (1 Q) Q) BOO •• 0
(b (b Q; 18 CO . 0 0 0
ABC 0
• 0 • 0 Q) <D Q) Q) o •• 0 • 0
o ® ~ C. CIt 6 6 6
t reated as wrong .
®®®®
<9: <9: 0) <9:
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CHEMISTRY
is( are) correct.
Full Marks :+ 4 If only the bubble(s) corresponding to all the correct option(s) is(are) darkened.
Partial Marks :+I For darkening a bubble corresponding to each correct option, provided NO
Negative Marks : - 2 In all other cases.
Q.l A reactant (A) forrns two products:

kl./B
/ Ea
A~k2 1
E>c
E., = 2 E.,
Frequency factors for both the reaction are equal. Therefore-
(A) k2 = kl e -E" I RT (B) k2 = k~ /A (C) kl= Ak2 eE"/RT (D) Both (A) & (B) are correct
Q.2 For a first order reaction, which of following are not correct
(A) t718 = 3t3/4 (B) t3/4 = 2t1/2 (C) tJS/J6 = 4tl/2 (D) tJS/16 = 3t3/4
Q.3 Given that,

E~i" IN i = - 0.25 V, E~u" leu = + 0.34 V
E:g ' / Ag = +0.80 V, E;n"l zn =-0.76V
Which of the following redox processes will not take place in specified direction?
(A) Ni2+(aq) + Cu(s) ---+ Ni(s) + Cu2\aq) (B) Cu(s) + 2Ag+(aq) ---+ Cu2+(aq) + 2Ag(s)
2
(C) Cu(s) + 2H+(aq) ---+ Cu +(aq) + H 2(g) (D) Zn(s) + 2H+(aq) ---+ Zn2+(aq) + H 2(g)
Q.4 Standard electrode potential of two metals A and Bare E? and E1 respectively. When half cells A2+/A and
B2+/B are connected electrons flow from A to B but when A is connected with standard hydrogen electrode
electrons flow from A to standard hydrogen electrode. If magnitude of E? and E1 are 0.25 and 0.34 volt
respectively the among the following the correct statement(s) is/are-
(A) E? for A2+ + 2e ~ A is -0.25 V
(B) E1 for B2+ + 2e ~ B is -0.34 V
(C) E~ell of the cell connecting these electrodes is 0.59 V
(D) E1 for B2+ + 2e ~ B is 0.34 V
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Q.S Which of the following expression(s) represent the voltage of cell at 298 K:
Ag (s) I AgI (saturated solution) II Ag2C204 (saturated solution) I Ag(s)
(B) Ecell = 0.0592 log [Ag +]Ag 2C 20 4
[Ag +]AgI
[2K (Ag C 0 )]' /3
(D) Ecell = 0.0592 10 sp 2 2 4
g [K sp (AgI)]' /2
Q.6 Standard electrode potential of two metals A and Bare E? and Egrespectively. When half cells A 2+/A and
2
B +/B are connected electrons flow from A to B but when A is connected with standard hydrogen electrode
electrons flow from A to standard hydrogen electrode. If magnitude of E?
and Eg
are 0.25 and 0.34 volt
respectively the among the following the correct statement(s) is/are -
(A) E? for A2+ + 2e ~ A is -0.25 V
(B) Eg for B2+ + 2e ~ B is -0.34 V
(C) E~ll of the cell connecting these electrodes is 0.59 V
(D) Eg for B2++ 2e ~ B is 0.34 V
Q.7 If9 gm H 20 is electrolysed completely with the current of 50% efficiency then-
(A) 96500 charge is required (B) 2 x 96500 C charge is required
(C) 5.6 L of O2 at S.T.P. will be formed (D) 11.2 L of 02 at S.T.P. will be formed

Q.S A current of 2 amp when passed for 5 hour through a molten salt deposits 22.2 g of metal of atomic mass
177. The oxidation state of the metal in the metal salt is.
Q.9 h(s)/r (0.1 M) half cell is connected to half cell a H+ (aq) I H2(1 bar) I Pt & emffound to be 0.7714 V. If
E; n- = 0.535V. Find the pH ofH+1H 2 half cell.
2
Q.I0 The conductance of a salt solution (AB) measured by two parallel electrode of area 100 cm2 separated by 10
cm was found to be 0.00010- 1 If volume enclosed between two electrode contain 1.0 mole of salt, what is
molar conductivity (S cm2 mor') of salt at same concentration. Express your answer by multiplying by 10.
Q.ll A drug becomes ineffective after 50% decomposition. The original concentration of a drug in a sample was
10 mg/ml which becomes 4 mg/ml during 10 months. Assuming the decomposition of drug of first order,
what is the expiry time of the drug in months? Give the answer in nearest possible integer in month.
Q.12 In the reaction of NO by H2 it was observed that equimolecular mixture of gases at 500 mm was half
changed in 100 seconds. In another experiment with an initial pressure of 250 mm, the reactions was half
completed in 200 seconds. Calculate the order of reaction-
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following table.
Electrol ysis Product at Catbode Product at Anode
(I) Aq solution ofNaCI (i) Na-Hg (P) H2
(II) Fused solution ofNaCl (ii) H2 (Q) Ch
,," >
(III) Very dilute solution ofNaCI (iii) H2 \ " (R) O 2
(IV) NaCI solution in presence of Hg catbode (iv) Na .J" / (S) Hg-<
Q.13 For tbe electrolysis of aq. Solution ofNaCl which is correct combination is
(A) (I) (ii) (Q) (B) (I) (ii) (R) (C) (I) (iii) (Q) (D) (I) (iii) (S)
Q.14 For tbe electrolysis in colurrm I tbe only correct combination is

(A) (I) (ii) (P) (B) (II) (iv) (Q) (C) (II) (iv) (P) (D) (III) (iii) (P)
Q.lS For tbe electrolysis of very dilute NaCl the correct combination is
(A) (III) (ii) (R) (B) (III) (iii) (R) (C) (III) (ii) (Q) (D) (III) (ii) (P)
following table.
(Permitted coordination number) (arrangement of anion round the cation) (Example)
(I) 3 (i) Plane triangular (P) CsCI
(Il) 4 ,
/... ~....... \ ...... (ii) Cubic (body center) (Q) 8 20 3
(III) 6 _\...\~ (iii) Tetrabedral (R) ZnS
(IV) 8 ~ ..., \ (iv) Octahedral (S) NaCI
Q.16 Which of the following is correct set?

(A) I, i, P (B) IV, ii, S (C) II, ii, R (D) III, iv, S
Q.17 Which of the following is incorrect set?

(A) I, iv, P (B) I, i, Q (C) III, iv, S (D) II, ii, R
Q.18 Which of the following is correct?

(A) II, ii, R (B) IV, ii, P (C) I, i, Q (D) All
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Unit Test-7
[Paper-2]
Time allowed: 1 hours Max. Marks : 61
SYLLABUS
CHEMISTRY Electro Chemistry, Chemical Kinetics
A. GENERAL:
B. MARKING SCHEME :
SECTION -I
SECTION -/I
SECTION - III
answers), Section -I! ( column matching type), Section-II! (include integer answer type)]

For example if only 'A' cho i ce is For examp le, if the correct answers to question For example if Correct matcb for (A) is P;
correct then , the correct method for numbers X, Y, Z and W (say) are 6, 0, 9 an d 2 , for (8) is R, S ; for (C) is Q; for (D) is P, Q,
filli n g the bubbles is respective ly, then the correct me thod fo r fi lli ng S the n the cor rect method for fi lling the
ABC D t he bubb les is bubb les is
• 0 0 0 X Y Z W
P Q R S T
For examp le ifonly 'A & C' choices @ CJ) @ @ A • 0 0 0 0
a re correct then, the correct method I cr leD BOO •• 0
[or filli ng the bubb les is
ABC
• 0 •
D
0
CD CD CD
<D <D <D <D
@) @) @) @
• CO
D ••
. 0
0
0
•
0
0
bubble are ~ (2) ~ 5

<0 ® ~ G 0 ®®®
T he a n swer of the questions in (]) (]) (j) (j)
treated as wrong.
®®®®
(§) (§) CI) (§)
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CHEMISTRY

Q.l The half period of 14C is 5760 year. A piece of wood when buried in the earth, had 1% 14C. Now as charcoal
it has only 0.25% 14C. How long has the piece of wood been buried?
(A) 11524 year (B) 11500 year (C) 12426 year (D) 11324 year
Q.2 Two radio isotopes P and Q of atomic mass 10 and 20 respectively are mixed in equal amount by mass. After
20 days, their weight ratio Wp is found to be I : 4. Isotope Q has a half-life of 10 days. The half-life of
WQ
isotope Pis:
(A) Zero (B) 5 days (C) 20 days (D) Infinite
Q.3 The activity of a sample of radioactive element is AI at time tJ and A2 at time t2(t2 > tJ). The mean life of
sample is T, then:
Q.4 In the reaction,

P+Q~R+S
the time taken for 75% reaction of P is twice the time taken for 50% reaction of P. The concentration of Q
varies with
time
Reaction time as shown in the figure. The overall order of the reaction is:
(A) 2 (B) 3 (C) 0 (D) 1
Q.S The overall cell reaction of Daniell cell is :

Zn(s) + Cu2+ ~ Zn 2+ + Cu(s); £0 = + l.10 volt
_ [Zn 2+]
Q - [Cu 2+]
When IOglOQ is plotted on X-axis and Ecell on Y-axis, then which ofthe following will correctly represent the
variation?
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(A)j£
-I 0 I
~ll.IOY
(B)~
-I 0 I
(C)
±
-I 0
.10Y
•
I
(D):i:
-I 0 I
Q.6 A layer of 0.25 rnm thick chromium metal is to be electroplated on the rims of auto vehicle with a total area
of 32 m2 from a solution of CrO~- . What amount of electric current is required for electroplating the rims in
60 sec? The density of chromium metal is 7.2 glee -
(A) 4.9 x 103 amp (B) 1.78 x 103 amp (C) 5.3 x 104 amp (D) 10.69 x 106 amp
Q.7 An alloy ofPb-Ag weighing 1.08 g was dissolved in dilute HN0 3 and the volume made to 100 mi. A silver
electrode was dipped in the solution and the emf of the cell set-up, Pt(s), H2(g) IW (1M)IIAg+ (aq)1 Ag(s) was
0.62 V. If E~II is 0.80 Y, what is the percentage of Ag in the alloy? (At 25°C, RTIF = 0.06)
[log-l (-1.3026) = 0.05]
(A) 25 (B) 2.50 (C) 50 (D) I

is( are) correct.
Partial Marks + I For darkening a bubble corresponding to each correct option, provided NO incorrect
option is darkened
Q.S Which of the following plot represents first order reaction :(r = rate at time 't' and ro is the initial rate)
k t
tl/2
Slope = 2.303
(B)
time -+ Concentration -+
- - - -log ro
rate
t ...t
OJ)
(C) (D) ..sa
Concentration -+ time-+
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Q.9 For a chemical reaction A -----t B ; the rate constant (K) is found to fit the following equation
. -I] -- 20 - 6600
Iog K [rrun --
T
Choose the correct statement for the reaction
(A) The reaction follow first order kinetics (B) Activation energy of reaction is 54.99 KJ
(C) Half-Life of reaction at 300 K is 69.30 min (D) Halflife is independent on concentration
Q.lO In a hypothetical reaction A~B, the activation energy for the forward and backward reaction are 15 & 9 kJ/mol
respectively. The potential energy of A is 10 kJ/mo!.
(A) Heat of reaction is 6 kJ/mol (B) The threshold energy of reaction is 25 kJ
(C) The potential energy ofB is 16 kJ (D) Heat of reaction is 9 kJ
Q.ll For a first order chemical reaction: A ~ P, then the correct statement(s) is/are -
(A) The extent of reaction completed at any time 't' is independent of initial concentration of the reactant
(B) The reaction must be an elementary reaction
(C) The time required for 99% completion of reaction is {(2tIl2)/log2}
(D) There are very less number of reactions with order one
Q.l2 For a first order reaction, which is/are correct here?

(A) The time taken for the completion of75% reaction is equal to the tll2 of the reaction
(B) The degree of dissociation is equal to 1 - e-kt
(C) A plot of reciprocal concentration of the reactant versus time gives a straight line
(D) The pre-exponential factor in the Arrhenius equation has the dimension of time, rl.
Q.l3 Which of the following statement is correct?

If E~u '+ICu = 0.34 V and E;n'+ISn = - 0.136 V,
E~+ IH, = + 0.0 V
(A) Cu+2 ions can be reduced by H2(g) (B) Cu can be oxidized by H+
(C) Sn2+ ions can be reduced by H2 (D) Sn can be oxidized by Cu 2+
Q.l4 The amount of ion discharged during electrolysis is directly proportional to-
(A) resistance (B) time (C) current (D) chemical equivalent of the ion

PARAGRAPHl
In the acidic medium the standard reduction potentials (in volts) of the following are as follows
MnO:; 0.56) MnO~- 2.26) Mn02 ~ Mn3+ 1.51) Mn2+ - 1.18) Mn
In the neutral or alkaline medium the standard reduction potentials (in volts) of the following are as follows
MnO:; 0.56) MnO~- 1.43) Mn02 -0.73) Mn3+ 1.51) Mn2+ - 1.18) Mn
Given: Ksp ofMn(OH)2 = 10- 13
Given: .!. O2 + 2H ++ 2e ~ H20 EO = 1.23 V
2
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Q.15 What is the reduction potential ofMnO:; to Mn02 in acidic medium?
(A) 1.33 volt (B) 1.69 volt (C) 2.82 volt (D) 1.78 volt
Q.16 What is the reduction potential of Mn2+ in saturated solution?

(A) -1.18 volt (B) - 1.13 volt (C) -1.56 volt (D) + 1.18 volt
PARAGRAPH 2
The instantaneous rate of an elementary chemical reaction: aA + bB ~ cC + dD can be given by:
rate = KtfAJ' [B]b - Kb[C]c [D]d
where, Kr and Kb are rate constants for forward and backward reactions respectively for the reversible
reaction. If the reaction is an irreversible one, the rate is expressed as: rate = K[ A J' [B]b where, K is rate
constant for the given irreversible reaction and (a + b) is order of reaction. It is also evident from the
stoichiometry of reaction that rate of disappearance of A is ~ times the rate of disappearance of B. The
b
variation of rate constant K with temperature is expressed in terms of Arrhenius equation: K= Ae- E, /RT
whereas, the ratio Kr is expressed in terms of van't Hoff isochore: .!S.. = Ae-dH /RT where, Ea and i1H are
Kb Kb
energy of activation and heat of reaction respectively.
Q.17 If the reaction: aA + bB ~ cC + dD is at equilibrium then which of the following statement is incorrect?
(A) Equilibrium constant Kc = Kr (B) i1G = 0
Kb
(C) Kc = ~b (D) i1H = Ti1S

r
Q.lS For a chemical reaction nlA -+ n2B
log [ - d~ ]] = IOg[ d~~]] + 0.3

the ratio of nl and n2 is approximately
(A) 3 (B) 0.3 (C) 2 (D) 0.5
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Unit Test-8
[Paper-I]
SYLLABUS
CHEMISTRY Hydrocarbon, Aromatic Chemistry, Halogen Derivative
A. GENERAL:
B. MARKING SCHEME:
SECTION -I
SECTION-II
SECTION - III

correct then , the correct met hod for numbers X. Y. Z and W (say) are 6 , 0 , 9 and 2, for (8) is R, S ; for (C) is Q ; for (0) is P, Q,
filli n g the bubbles is respect ive ly, then the correct me thod fo r fi lli ng S the n the correct method for fi ll ing the
• 0 0 0 x Y Z W P Q R S T
® CD ® ® A • 0 0 0 0
I (1 Q) Q) BOO •• 0
(b (b Q; 18 CO . 0 0 0
ABC 0
• 0 • 0 Q) <D Q) Q) o •• 0 • 0
bubble are CD W 5 5
o ® ~ C. CIt 6 6 6
t reated as wrong .
®®®®
<9: <9: 0) <9:
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CHEMISTRY

is( are) correct.
Q •1 (
COOH
+ 0:::0-...
~P
----,
1,I NaHCO , )Q OWIH,O) R W /6 )
S
Which of the following is/are correct -
(A)P=~ COOH
(B)R3
H
A-r-
Y\COOE>
OH
(C)Q-,0- (D)S-~ 0./ 11 0
o
CH2CH3 ale. KOH , Y
Q.2
© O
H1IEq)
NBS, (X)
I
1Eq lag. KOH , Z
P + Q
Iodide Alcohol
Correct statements for above reaction is/are -

OH
I
CH-CH]
CH] CH]
I I
(A)Y=© (B) W = Ph--CH -O-CH
I
Ph
(C) P contain one benzylic hydrogen (D) Q on dehydration produce Y
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Q .3 CH r CH r CH 2-CH-CH 3 ~ He [F] Br, / CCI,) C SHIOBr2 (G)
I - H,O
OH
Which of the following statements are correct for this process?
(A) F contains total 3 product including stereoisomer
(B) G product contain 3 enantiomeric pair
(C) Total no. of a-H in F Isomers are 11
(D) Total isomers ofG produce is 6 (including stereoisomer)
o 0 0 0
o I II II II
Q.4 A ~ H-C -CH2CHZ-C -C -CHrCHz-CH
(as one of the product) A can be-
i H
(A) 10 (B)<)--<)
h 3
(C)U (D)
CH 3
I
Q.5 Which of the following reactions are expected to give CH 3 - C - CH = CH 2 as the major product-
I
CH 3
CH 3 CH3
I I
(A) H3C- C- CH -CH3 (B) CH 3- C -CH 2- CH 2-OH POCh+ Base,
I I I
CH3 0H CH 3
CH 3 CH 3
I ale.KOH/A I Na/liq.NH 3
(C) CH3- C - CH - CH3- - - - (D) CH 3-C-C=CH ,
I I I
CH 3 Br CH3
H,IPdBaSO, OsO,/NaHSO,
'x
Q.6 CH3-C=C-CH3 ~ NalNH,
XandYare-
,y
KMnO, cold/Dilute
(A) H
"0=t=" "=t=0" OH HO H (B) HO"=t=oH H=t=oH H H OH
CH 3 CH 3 CH3 CH 3
(C) HO
H=t=oH H0=t=H CH 3 CH 3 H (D)HO
H=t=H H0=t=H OH H OH
H OH CH 3 CH 3
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Q.7 Which is not correct product (as major product)
(A) CHr C=C-CH3 Na /L iq .NH )

CH3'-....
/C=
H
c"
_ / , CH3
(cis) H
cis-But-2-ene (±) -2, 3-dibromobutane
H--+-Br
(D)
H - t - Br
CH 3
trans-But-2-ene
Meso -2, 3-dibromobutane

Q.8 In the Zerewitnoffs determination of active hydrogens in an alcohol (Z), 0.225 g of compound Z was treated
with CHNgBr when 224 mL of CH4 was evolved at STP. A rest determination showed that Z had molecular
weight of 180. How many acidic hydrogens are present per molecule of the compound Z?
Q.9 Find out number of alcohols that can give positive iodoform test.
OH
(a)~
OH
(b)~
OH
(c)
OH
o-~H-CH3 (d) 00
OH
HOO
(e) CHrCHrOH (f) o-CH:rOH (g)Q (h)
0
II (1) 'X' RMgX
Q.I0 CI-C-OC 2H s ) 3°Alcohol. Find out value of 'X'.
NH,CI
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Q.ll How many reaction involve SN I mechanism
CH 3 CH 3
I Hl I
(I) CH 3-y-0-H ----=--+ (II) CHr CH 2-Oi-CH 3 ~
CH 3 CH 3
(III)~~ (IV) @--o-CH 3 ~
CH 2 -OH
(V) @ c H2-O-CH-CH 3
9 H3
~ (VI)©
HI (less cone)
Polar solvent
CH
&
3 CI
Q.12
o NaNH,
liq. NH 3 '
In above reaction how many isomeric product will be formed? (Benzyne mechanism)
SECTION-3 (Maximum Marks: IS)

following table.

(i) hot & Conc. KMn04
(I) CH 3 -C ==C-CH2- CH3 (P) Two different type of carboxylic acid
(Q) Ketone as major product
(II) CH 3 -C ==C-H (ii) 0 3 1Zn I H 2O
(R) Aldehyde as major product
(III) Ph - C == C - H (iii) H 2S04 I HgS041 H 2O
e (S) Only one type of carboxylic acid
(IV) CH 3 - C == C -CH3 (iv) BH3 I THF I H20 21 0 H
Q.13 Which of the following is correct set:

(A) (I) (ii) (P) (B) (I) (i) (S) (C) (II) (iii) (Q) (D) (II) (iv) (Q)

(A) (III) (ii) (P) (B) (III) (iii) (R) (C) (III) (i) (Q) (D) (III) (iv) (R)
Q.lS Which of the following is incorrect set:

(A) (I) (iii) (Q) (B) (IV) (iii) (Q) (C) (IV) (i) (S) (D) (IV) (iv) (R)
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following table.

(I) CH 3 "
(i) Hg(O ACh I H20 I NaBH4 (P) Non classical carbocation
C=CH2
CH/
(II) Ph-CH=CH 2 (ii) H 3O'" (Q) Markownikov product (major)
(III) U (iii) HBr (R) Optically active compound
(IV) 0 e
(iv) BH3 I THF I H 20 2 I 0 H
(S) Optically inactive compound
\
Q.16 Which of the following is incorrect set:
(A) (I) (i) (R) (B) (II) (ii) (R) (C) (III) (ii) (Q) (D) (IV) (i) (P)

(A) (I) (ii) (P) (B) (II) (iii) (R) (C) (IV) (i) (R) (D) (I) (iv) (Q)
Q.18 Which of the following is incorrect set:

(A) (III) (ii) (R) (B) (III) (iii) (P) (C) (IV) (iv) (R) (D) All of these
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Paper -2
Medium
0
0
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® ® ® ® ®2> English 0
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2·0 ® © ® 2·0 ® © @ 2. @ ® © ®
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7·0 ® © ® 7. @ ® © ® 7. @ ® © ®
8. 9. 10. 11 . 12. 8. 9. 10. 11. 12. 8. 9. 10. 11. 12.
@ @ ® @ @ @ ® @ @ @ ® @ @ ® ®
(3) (3) CD CD (3) (3) CD CD (3)
(3) CD (3) (3) CD CD
® CD CD ®
<9 0 0 <9
<9 <9 0 0 0 0 0 <9 0 0 0
® ® ® ®
® ® ® ® ® ® ® ® ® ® ®
® ® ® ®
® ® ® ® ® ® ® ® ® ® ®
® ® ® ® ® ® ® ® ® ® ® ® ® ® ®
® ® ® ® ® ® ® ® ® ® ® ® ® ® ®

13·0 ® © ® 13.@ ® © @ 13·0 ® © @
14·0 ® © @ 14.@ ® © @ 14·0 ® © @
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16.@ ® © @ 16.@ ® © @ 16·0 ® © @
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Unit Test-8
[Paper-2]
SYLLABUS
CHEMISTRY Hydrocarbon, Aromatic Chemistry, Halogen Derivative,
A. GENERAL :
B. MARKING SCHEME :
SECTION -I
SECTION -"
SECTION - 11/
6. Passage based multiple choice questians with single correct option. 3 maries will be awarded for each correct answer and No negative

For example if only 'A' cho ice is Fo r examp le , i f t he correct answers to que stion For example if Correct matc h for (A) is P ;
correct t hen , the correct met hod for numbers X. Y , Z and W (say) are 6 , 0 , 9 and 2 , for (8) is R, S ; for (C) is Q ; fo r (0) is P , Q,
filli n g t he bubbles is respec ti ve ly, then the correct me thod fo r fi lli ng S the n the correct method for fi ll ing the
• 0 0 0 x Y Z W P Q R S T
® CD ® ® A • 0 0 0 0
I e! Q) Q) BOO •• 0
(b (b Q; Ie CO . 0 0 0
ABC 0
• 0 • 0 Q) <D Q) Q) o •• 0 • 0
th e w rong method for fi lli ng the @ @ @ @
bubble a re CD CD Sid)
o ® ~ G 0 6 6 6
treated as wrong .
®®®®
C2: C2: OJ 1C2:
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CHEMISTRY

Q.l Arrange these compounds in the order of increasing SN I reaction rate -
Ph+Brl
Br
+Br I CI
(I) (II) (III) (IV)
(A) IV < II < III < I (B) I < II < III < IV (C) IV < I < III < II (D) IV < I < II < III
Q.2 Consider the following reaction:
(CH 3hC - CH = CH 2 + HCI ~
The major product obtained in the reaction is-
(A) (CH 3)3 C - CH -CH3
I
CI
(C) (CH 3hC - CH(CH 3)2
I
CI
Q.3 Select the reagent that will yield the greater amount of substitution on reaction with CH 3- CH 2 - Br
(A) CH 3CH 20K in dimethyl sulphoxide (DMSO)
(B) (CH 3h COK in dimethyl sulphoxide (DMSO)
(C) Both (1) and (2) will give comparable amounts of substitution
(D) Neither (1) nor (2) will give any amount of substitution
Q.4 Benzene reacts with n-propyl chloride in the presence of anhydrous AICh to give predominantly-
(A) n-Propyl benzene (B) iso-Propyl benzene
(C) 3-Propyl-I-chlorobenzene (D) No reaction
Q.5 The reaction of 0

l0J + CH2Ch anhydrous) gives: -
A/ClJ
(A) rQJ:> (8)
(D) All of these
Q.6 B
H20, H,SO.,JHgS04 0- C=CH
D20, HgSOJ H2S04 A, A, Band Care -
I
BHl fHF
H,Oz/Ofr
C
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(A) OnCHD2,OnCH), OCH2CHO (B) II, I and III
o 0
(I) (II) (III)
(C) II in all cases (D) III in all cases
Q.7
lH) ?CH)
(C) CH)i-CH-CH) (D) No reaction
CH)

is( are) correct.
Full Marks : +4 If only the bubble(s) corresponding to all the correct option(s) is(are) darkened.
option is darkened
Zero Marks o If none ofthe bubble is darkened.
Q.8 Which of the following reactions are correct?
(A) 0 " '=" P. (B) 0 CH ,CO,H)

H ~ /H , O
P .
",
Br Br OH OH
(C) 0
/
Har )
~
Me)('l
(D) Me ~_
H~/ H,O)HO ~
MeX'l
Me Me Me
Br
Q.9 Which of the following gives Red ppt with ammonical Cu2Ch
(A) CH=CH (B) CH:r-C=C-H (C) CH:r-C=C-CH 3 (D) CH2=CH2
Q.I0 R-X+Mg ether) R-MgX CH ,OH) n-butane.

What can be R in the above reaction sequence?
(A) n-propyl (B) n-butyl (C) sec-butyl (D) Isopropyl
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Q.ll The product in following reaction:
) (P)
6 '"
Q.12 Which of the following gives same product with SN, & SN 2 reaction (including stereo product)-
(A) 0' --""-.. (8)
CH 3
W', (c)@-OI'-c' '" '"', (0) oc, '" '"',
CH 3
I
Q.13 CHr CH 2-CH-CH 2-CH 3 CI,/ hv
What is correct -
(A) total four products are formed including stereoisomer
(B) total 8 product are formed including stereoisomer
(C) 4 Enantiomeric pair are formed
(D) major product is 2° halide
Q.14 Which of the following compounds would not liberate two moles of methane when treated with methyl
magnesium bromide?
(A) CH 3-CH-CHz--C=CH (B) CH3-C-CH 2-CH 20H
I II
OH o
(O)~
COOC2H S

PARAGRAPH 1
Vladimir Markovnikov rule:
Alkene undergo electrophilic addition reaction. It is triggered by the acid acting as a electrophile toward
n-electrons of the double bond.
Markovnikov's rule states that when an unsymmetrically substituted alkene reacts with a hydrogen halide, the
hydrogen atom adds to the carbon that has the greater number of hydrogen, e.g.
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~D<CH3
D- ~ CH3+H-CI
I-methyl cyclopentene
Cl
I-chloro-I-methyl-cyclopentane
Mechanism:
Step-I:
D-cQ2
Step-2 :
- CIS
(fast)
Q.15 Which of the following is most reactive toward Markovnikov addition.

o 0
(A)Q (B) 0 (C)a (D)CJ(
Q.16 In which offollowing reactions carbocation rearrangement is possible?
HBr
(A) (CH 3 hCH - CH=CH 2 He l (B) (CH 3 hC-CH=CH 2
eCl,
(C) Ph - CH2 - CH = CH 2 HBr) (D) All ofthese
eCl,
PARAGRAPH 2
Mixed chloro fluoro carbons, sometimes called CFC, such as CFCI3, CF2Ch, CF3Cl are known as "Freons". They
are unreactive and are widely used as refrigeration fluids. Freons are very much more effective "greenhouse gases
" in the atmosphere than C02; though the amount of freons present is extremely small. Much more seriously, the
freons have penetrated the upper atmosphere and causing damage to the ozone layer.
Q.17 In which of the following way freons damage the ozone layer?
(A) By producing CCh free radicals (B) By producing CFCI free radicals
(C) By producing fluorine free radicals (D) By producing chlorine free radicals
Q.18 Hydro fluoro carbons (HFCs) such as CH2 FCF3 and hydro chloro fluoro carbons (HCFCs) such as
CHChCF3 are used as substitutes ofCFCs because
(A) HFCs & HCFCs are not green house producing
(B) HFCs and HCFs are liquid not gases
(C) HFCs and HCFCs are also green house producing but they do not remain in the atmosphere for so long
(D) HFCs and HCFCs are lesser green house producing than CFCs
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4·0 ® © ® 4·0 ® © @ 4·0 ® © @
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11· 0 ® © @ 11·0 ® © @ 11·0 ® © @
12· 0 ® © @ 12·0 ® © @ 12·0 ® © @
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Unit Test-9
[Paper-I]
SYLLABUS
CHEMISTRY Alcohol,Phenol,Ether, Carbonyl Compound, Carboxylic Acid and Derivatives, Nitrogen containing Compound,
Carbohydrate and Protein (Biomolecule)
A. GENERAL:
B. MARKING SCHEME:
SECTION -I
SECTION -/I
SECTION - 11/
7. Fill your Name, Roll No., Batch, Course and Centre of Examination in the blocks of OMR sheet and darken cirde properly.
9. While filling the bubbles please be careful about SECTIONS [i.e. Section-I (indude single correct, reason type, multiple correct
answers). Section-II (column matching type), Section-III (indude integer answer type)]
Section -I Section-II Section-III

For example i f only 'A' cho ice is For examp le , if the correc t answers to question For example if Correct match for (A) is P ;
correct then, the correct me th od for numbers X, Y, Z and W (say) are 6,0,9 and 2 , for (B) IS R, S; for (e) IS Q; for (D) IS P, Q,
filli n g Ih e bubbles is respective ly, then the correct met hod fo r fi lli ng S then the correct method for filling the
ABC D th e bubb les is bubb les is
• 0 0 0 X Y Z- W
P Q R S T
For examp le ifonly 'A & C' choices
are correct then, the correct method
® CD ® ® A • 0 0 0 0
I Q. 1: I BOO •• 0
for filling the bubb les is
ABC
• 0 • 0
D
the w rong method for fi lli ng the

<D (6) <D
CD <D <D <D
@) @) @) @)
• CO
D ••
. 0
0
0
•
0
0
bubble are 5 ) 5 5
8 ® ~ (J (it ® ® ®
T he a n swer of the questions In C]) C]) C]) (j)
wrong or a ny other manner will be
treated as wrong.
®®®®
®®0 ®
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CHEMISTRY

is( are) correct.
Negative Marks : - 2 In all other cases.
Q.l Which ofthe following reaction represent major product
NH2
(C)©
KOBr
(D) CHr -CHr C-NH 2
II
o
Q.2 For the given sequence
@--eN H,O$ ) X NH)/d ) Y KOBr) Z CHCl)/KOH) W
Which of the following is/are correct:
(A) Wand Ph-CN are Functional group isomer (B) Z is more basic than pyridine
(C) Compound X gives effervescence with NaHC0:J (D) On hydrolysis ofW compound Z is formed
Q.3 Which of the following give nitrosoamine on treatement with HN0 2 ?

(A) CN-H (B) H3C-fH-NH2 (C) ©--~-CH3 (D) Ph-CH r NH 2
CH 3 H
Q.4 Compound X react with NaN0 2 & H2S0 4 & Then react with ortho cresol to form sharp colour compound
then compound X may be-
o
II
C-NH2
(A)~
~OH
(C)©
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Q.S Which of the following can distinguish?
CH 3 H
I I
CHrCH - NH2 and CHrCH r N -CH3
(A) CHCh / base (B) NaN0 2 + HCI (C) CS 2, HgCh (D) Ag20/~
Q.6
Q N2
hv
o -.....:;:.:-.... H 20
, p- ----=---+, Q
LiAlH4 R H+/t,.
---,,---+, ---__+. S
Identity correct option (s) -
(A) P => D=c=o (B) Q => OCOOH
(C) R => O C H20H (D)S=>Q
Q.7 Choose the correct statement for the following compound
~o~~'O~o~:'O~o,
H OH H OH H OH
(A) this carbohydrate is a polymer ofD glucose (B) it has a(1, 4) glycosidic linkage
(C) it is a non reducing carbohydrate (D) it does not give fehling test

Q.8 How many products are possible between given inter conversion:
o
II
@- NH
2
CH,-C-CI
(I)
[X] HNO,+H,SO~ [Y]~[Z]
"
(2)
(3)
ICI
CH,COOH
(4)
[W]
~N02 (I) NaNO, + HCI

(2) H, PO,
(5)
I
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(2) X ~ @-NH-C-CH3
II
o
o
II
NH- C-CH3
(3) Y => 02N--@-NH-C-CH3

II
(4)Y~ ~ l S lN0 2
o
NH2 NH2
(5)Z->@ (6)z->$ 0.,.

N0 2
l~l
NH2
(7)W~ ~
(8)W~ 0-
N0 2
IYI N02
Q.9 How many primary amines are possible for the formula C4HIIN.
(2) H
t
Q.IO
(3) .... ©(N?(l) I
(!)
NO, (mononilration))
(4))" N 0
I
H
the nitration will mainly take place at position.
Q.ll How many products will be obtained when propane is subjected to vapour phase nitration.
Q.12 How many molecules of methyl bromide should react with ethylamine successively to convert the latter into
a quaternary ammonium salt.

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following table.
(I) Teflon COOH NH2
(i) (tH I
2)4 + (CH 2)6 (P) in fabrics
I I
COOH NH2 / '....
(II) Nylon - 6, 6 Cl
I (Q) as rubber
~ . . ,,>
(ii) CH 2=C-CH=CH 2
(III) Bakelite (iii) F2C = CF2 (R) in electrical switches
(IV) Neoprene (iv) H-C-H+@-OH
II (S) non stick cookware
0
Q.13 Which of the following is correct combinations -

(A) II, i, R (B) IV, iii,. S (C) I, iii, S (D) I, ii, Q
Q.14 Which of the following is correct statements-

(A) II, i, Q is correct set (B) III, iv, R is correct set
(C) IV, ii, Q is correct set (D) (B) and (C) both are correct
Q.lS Incorrect set is -

(A) I, iii, S (B) III, iv, R (C) II, i, Q (D) IV, iii, Q
following table.
(Conversions) (Name reactions) (Reagent)
(I) R-C-NH2~R-CH2-NH2 (i) Schmidt reaction (P) Br2 I KOH
I
°0II (ii) Reaction with P20 S (Q)4H
(II) R- C -NH2 ~ R-NH2
0 (iii) Hofmann Bromamide reaction (R) PC Is I SOCb
II
(III) R- C -NH2 ~ R-CN .~\
0 (iv) Reaction with LiAIH4 (S) NaN 3 1 H 20
(IV) R-~ -Cl (i) NaN 3
(ii) H 20 , d
) RNH2
Q.16 Which of the following is incorrect set as above data-

(A) I, iv, Q (B) II, iii, P (C) III, iii, R (D) I, ii, Q
Q.17 Which of the following is correct set as above data -

(A) I, iii, Q (B) II, iv, R (C) III, iii, S (D) IV, i, S
Q.18 Which of the following is correct set as above data-

(A) II, i, S (B) IV, ii, P (C) II, ii, R (D) III, iv, Q
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•
marks In the form
I
@) @) @) @) @)
G) G) G) G) G)s
® ® ® ® ®:§>
'J) 'J) 7 'J) 'J)'J)
Paper -I
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5·0 ® © ® 5. @ ® © @ 5. @ ® © ®
6·0 ® © ® 6. @ ® © @ 6. @ ® © ®
7·0 ® © ® 7. @ ® © ® 7. @ ® © ®
8. 9. 10. 11 . 12. 8. 9. 10. 11. 12. 8. 9. 10. 11. 12.
@ @ ® @ @ @ ® @ @ @ ® @ @ ® ®
(3) (3) CD CD (3) (3) CD CD (3)
(3) CD (3) (3) CD CD
® CD CD ®
<9 0 0 <9
<9 <9 0 0 0 0 0 <9 0 0 0
® ® ® ®
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® ® ® ®
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® ® ® ® ® ® ® ® ® ® ® ® ® ® ®
® ® ® ® ® ® ® ® ® ® ® ® ® ® ®

13·0 ® © ® 13.@ ® © @ 13·0 ® © @
14·0 ® © @ 14.@ ® © @ 14·0 ® © @
15·0 ® © @ 15.@ ® © @ 15·0 ® © @
16.@ ® © @ 16.@ ® © @ 16·0 ® © @
17.@ ® © @ 17.@ ® © @ 17.@ ® © @
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Unit Test-9
[Paper-2]
Time allowed: 1 hours Max. Marks : 61
SYLLABUS
CHEMISTRY Alcohol,Phenol,Ether, Carbonyl Compound, Carboxylic Acid and Derivatives, Nitrogen containing Compound,
Carbohydrate and Protein (Biomolecule)
A. GENERAL:
B. MARKING SCHEME :
SECTION -I
SECTION -/I
SECTION - 11/
6. Passage based multiple choice questians with single correct option. 3 marks will be awarded for each correct answer and No negative
S('ction -I S('ction-II Section-III

For example i f only 'A' cho ice is Fo r examp le, i f t he correc t answers to que stion For example i f Correct match for (A) is P ;
correct t hen , the correct met hod for numbers X , Y , Z and W (say) are 6 , 0 , 9 and 2 , for (8) is R, S ; for (e) is Q ; for (D) is P , Q,
filli n g t he bubbles is respective ly, then the correct me thod fo r filli ng S the n the correct method fo r fi lling the
A 8 e D the bubb les is bubb les is
• 0 0 0 x Y Z W s
~
R T
® CD ® ® A 2 o o o
A 8 e D
1 ([ IQ)
Q: Q: 0 18
8
eo .
0 0 • •o
o
o
o
• 0 • 0
t he wrong method for fi lli ng the
Q) <D Q) Q)
@ @ @ @
D •• o • o
bubble are G) cr> G) G)
o ® ~ G 0 6 6 6
T h e a nswer of the questions in CD CD CD CD
treated as wrong .
®®®®
l2: C2: CIJ 1l2:
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CHEMISTRY

Q.l Which of the following represent glyptal -
(A) +O--CHrCHrO--C~C* °11-0-°1

(C) +--I~
o
<Q)
0
0
./"-V 0T. n
Q.2 On hydrolysis of milk sugar, we get-

(A) aD glucose & 13D fructose (B) 13D glucose & aD glucose
(C) 2 x aD glucose (D) 13D galactose & 13D glucose
Q.3 In nucleic acid, corresponding nucleotides are linked together by -
(A) C 1' - Cs' glycosidic bond (B) C2' - Cs' phosphodiester bond
(C) C3' - Cs' phosphodiester bond (D) C4' - Cs' peptide linkage
Q.4 Identify structure of Guanine deoxyribo-nucleotide :
a°
NH2 NH2
(N~N
NJl~J
H0l'0'-j N H0l'0~
(A) 'r--' (B) 'r--'
OH OH
°
~
(D) HO-f-0l'0~
fex N NH2
OH 'r--'
OR
Q.S (P) ( (i) NH)/ II
@-C-OH NH)/ II ) (Q)~(R)
(ii)KOD / Br, II p,o,
° (i) CH)MgBr)
(ii)H,o$
(S) (i)H, NOH)
(ii)W I II
T+U
Which offollowing are correct
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(I) P=@-NH 2 (II)Q=@-rr-NH2 (III)R=@-C=N (IV) S = @-C-C H3
II
o o
(V) T = Phi-NH-CH3(Vl) 0 = CHr rr- NH- Ph
o 0
(A) I, II, III, IV only (B) II, III, IV, V, VI (C) I, III, IV, V (D) All are correct
Q.6 Which of the following diazonium salt is relatively stable at O-soC-

(A) CH 3-N=N} alcC (B) CH 3-C(CH 3}-N=N} alCl-
(C) C6HS-N=N} alCl- (D) (CH3hC-N=N} alCl-
H2
Q.7 8 OH
0
HNO,
"
l (A); Product (A) is -
0 0
(A) 6 (B)0 (C)O

is( are) correct.
option is darkened
Ph Me Ph Et
I I I I H 2SO4
Q.8 Ph-C- C-Me + Ph-C- C-Et )
I I I I
OH OH OH OH
(P) (Q)
When (P) and (Q) react with H2 S04, product obtained are-
Ph 0 Ph 0 Ph 0 Ph 0
I II I II I II I II
(A)Ph-?-C-Me (B)Ph-?-C-Et (C) Ph-?-C-Me (D)Ph-?-C- Et
Me Et Et CH3
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Q.9 8CH~c5
This transformation can be carried out by-
(A) H+/~, Zn(Hg), HCI (B) KMnOJ OH-, Sodalime/~, H-O-H
(C) HI04, LiAlH4 (D) Pb(OACh, NaBH4
Q.I0 @je CHClBri

aq . NaOH
'H
The product(s) formed are-
(A) cQo
0 I
Me
(B)
oo
0
Me- Cl
"" (C) ~Me (D) cQr:f~~O
N
'H
CHO
N
...-:.
~N0cl ' H
Q.ll 'X' ~ (I) AgNO , ) II HNO, ) III NaOH) IV
Choose the correct combination of ,X' and 'W'

'X' 'W'(colour of final product)
(A) CHrCH=CH-OH Red (B) Ph-CH-OH Blue
I
CH)
(C) Ph- CH-CH-CH) White (D) CH)-CH-CH=CH 2 Red
I I I
CH)OH OH
Q.12 How many offollowing are correctly matched
(A) QH
OH
~ Racemic mixture
(B) CD
OH
CH)
W
~ Major product
consist of even no.
(C)(Q
of a-hydrogen
w will not undergo w Product is a ketone
~ dehydration (D)++ ~
OHOH
OH
Q.13 Choose the correct statement (s) -

(A) The formation of a-hydroxynitrile from aldehyde and ketone is usually a reversible process.
(B) The formation of a-hydroxynitrile is catalysed by OH-. The use of H+ decreases the nucleophilicity
(HCN ~ H+ + CNl
(C) Acrolein (CH2=CH-CH=0) on treatment with HCN/OW do not give a-hydroxy nitrile (cyanohydrin)
(D) Benzaldehyde on treatment with HCN / OW give optically active cyanohydrin molecule.
Q.14 In the reaction sequence :

CH 3'-.
/ NHIt.
CH 3 Ell
C6HsCHO+ CH 3-C0-CH r COOC 2Hs • [Xl HOHIH. [Yl ~[Zl
[X], [Y] and [Z] will respectively be-
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/COCH 3
(B) C6Hs - CH = C ......... C C ' C6HS- CH = CH - COCH3
00 2HS
C6Hs - CH = CH - COOH
/COCH 3 /COCH 3
(C) C~s - CH = C ......... COOC H ' C6HS- CH = C ......... COOH
2 s
C6HS - CH = CH - COOH
OH
/COCH 3 I /COCH 3
(D) C6Hs - CH - CH ......... COOC2Hs ,C6HS- CH - CH .........
COOH
C H _CH=C/COCH 3
6 5 ......... COOH

PARAGRAPHl
The aldol condensation also offer a convenient way to synthesize molecules with five and six membered
ring. This can be done by an intramolecular aldol condensation using a dialdehyde, a keto aldehyde or a
diketone as the substrate. The major product is formed by the attack of the enolate from the ketone side of the
molecule that adds to the aldehyde group. The reason the aldehyde group undergoes addition preferentially
may arise from the greater reactivity of aldehyde towards nucleophilic addition generally. In reaction of this
type five membered rings form far more readily than seven membered rings and six membered rings are
more favourable than four or eight membered rings when possible.
Q.lS l-Ethylcyclopent-l-ene on reductive ozonolysis followed by aq. NaOH/~ gives-
(A)
et CH3
o
(B)Q
o
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Q.16 CHrC-H + H-C-H
l l
Excess
(B) 9r~H
HO OH
(C)+ (D) LfJ
HO
OH
PARAGRAPH 2
Starch is Homo polymer of (l-D Glucose. Starch molecule has 2 parts amylose & amylopectin amylose is
20% part and amylopectin is 80% part. Branches are present in Amylopectin
Q.17 Molecular formula of Amylopectin is -

(A) (CJfIOOS)n (B) (C SH 120 6)n
Q.lS More than one type of Glycosidic Bond is present in-

(A) Amylose (B) Amylopectin (C) Glycogen (D) Animal starch
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•
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(!J (!J (!J (!J (!J
Paper -I
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Unit Test -10
[Paper-I]
SYLLABUS
CHEMISTRY Co-ordination Compound, d and f-Block Elements, p-Block, Metaliurgy,Salt Analysis
A. GENERAL:
B. MARKING SCHEME :
SECTION -I
SECTION -/I
SECTION - III
answers), Section-II ( column matching type), Section-III (include integer answer type)]

For example if only 'A' cho i ce is For examp le, if the correc t answers to question For example if Correct matc h for (A) is P ;
filli n g the bubbles is respectively, then the correct method for fi ll ing S the n the correct method for fi lling the
• 0 0 0 X Y Z W
P Q R S T
For examp le i ronly 'A & C ' choices
II) ® A • 0 0 0 0
:( BOO •• 0
ABC 0 CO . 0 0 0
• 0 • 0 o •• 0 • 0
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treated as wrong .
"'"
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• This section contains SEVEN questions .
is( are) correct.
Q.l Which of the following statements is not true about the complex ion [CrCI(N0 2) (en)2t?
(A) It has two geometrical isomers cis and trans
(B) cis and trans forms are not diastereomers to each other
(C) Only the cis isomer displays optical activity
e
(D) It has three optically active isomers : d, and trans forms
Q.2 Select the correct statement:

(A) Chelation effect is maximum for five and six membered rings
(B) Greater the charge on the centralmetal cation, greater the value of ~ (CFSE)
(C) In complex ion [CoF6]3-, F is a weak field ligand, so that ~ < P (Pairing energy) and it is low spin complex
(D) [CoCh(NH 3)z(en)]EI> complex ion will have four different isomers
Q.3 In test of NO) ion, the dark brown ring complex is formed, which is true of this complex ?
(A) The colour is due to charge transfer spectra
(B) Iron and NO both have + 1 charge
(C) The complex species can be represented as [Fe i (H 20)sNO]2+
(D) Iron has +2 oxidation state and NO is neutral
Q.4 Which is correct statement(s) ?
(A) [Ag(NH3)2t is linear with sp hybridized Ag+ ions
(B) NiCI~- , crO~- and MnO:; have tetrahedral geometry
(C) [Cu(NH 3)4]2+, [Pt(NH 3)4]2+ and [Ni(CN)4tbave dsp2 hybridisation of the metal ion
(D) Fe(CO)s has trigonal bipyramidal structure with d z 2 Sp3 hybridized ion
Q.S Which of the following statement(s) is/are true?

(A) In metal carbonyl complexes dc-o increases compared to that in CO molecule
(B) The pair of compounds [Cr(H20)6]Cb and [CrCh(H20)3].3H20 show hydrate isomerism
(C) d z2 orbital of central metal atom/ion is used in dsp2 hybridisation
(D) Facid and Meridional isomers associated with [Ma3b3 J"" type complex compound, both are optically inactive
Q.6 The metallurgy of iron involves reactions in the blast furnace , which of the following statements(s) is (are)
correct?
(A) FeO is reduced to Fe below 1070K (B) Fe203 is reduced to Fe below 1070K
(C) FeO is reduced to Fe above I070K (D) CaSi0 3 is formed above I070K
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Q.7 Which of the following statements is incorrect regarding the slag obtained during the extraction of a metal
like copper or iron?
(A) The slag is lighter and has higher melting point than the metal
(B) The slag is lighter and has lower melting point than the metal
(C) The slag is heavier and has higher melting point than the metal
(D) The slag is heavier and has lower melting point than the metal

Q.8 A (Light pink colour complex) Pb,O,/dil.HNO, ) HMn0 4 H ,SI W ) A (Ligh pink colour complex).
t.
Calculate CFSE value in light pink colour complex.
Q.9 Calculate value of "x + y" if x is the total number of cr bonds and y is total number of 1t bonds in ligand
EDTA and phenantharolene.
{EDTA = Ethylene diarnine tetraacetate, phen = 1, 10 - N, N-Phenanthrolene}
Q.IO Consider the following complexes.

(i) [FeIF(CN) (H 20) (en)]
(ii) [Mo Cl 2 F2(gly)]2-
Then, calculate value of Ix - yl (where x and yare total number of possible optically active isomers in
(i) and (ii) complex respectively).
Q.ll M(CO)x (NO)y +NO) M(NO)z

-co
Where EAN of metal (M) in both product and reactant is same and it is 54. Then calculate value of
(x + Y - z). (where x, y and z are natural numbers and M belong to 6th group according to long form of
periodic table)
Q.12 Consider the following complex compounds.

(i) [Pt(NH 3MSCN)2] (ii) [Co(NH 3h(N0 2)3] (iii) [Pt(en)Ch]
(iv) [Cr(en)2Br2t (v) [Rh(enh]3+ (vi) [CoCh Br2]2-
Then calculate sum of total number of geometrical isomers in all above complex compounds.

• This section contains TWO tables (each having 3 coluruns and 4 rows)
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following table.

(I) P 4 (i) 70 bond (P) pn - pn bonding
(II) SO:;2 (ii) Central atom is Sp3 hybridised (Q) pn - dn bonding
(Ill) C 2H 6 (iii) No P-P bond (R) Totall.p = 4 r ...
(IV) P 4O lO (iv) No 0-0 bond (S) 0 n e- ~-~ -
.......
(v) No lone pair present at central atom A'- ,-j
l " ..... .,
Q.13 Which of the following is only correct option?
(A) (I) (iv) (P) (B) (II) (iii) (iv) (S) (C) (III) (iii) (iv) (v) (D) (IV) (ii) (iii) (Q)
Q.14 Which of the following is only incorrect?

(A) (III) (i) (ii) (v) (B) (II) (iii) (iv) (v) (C) (I) (iv) (v) (P) (D) (IV) (iii) (iv) (v)
Q.lS Which of the following is only correct option?

(A) (III) (i) (iv) (R) (B) (I) (iv) (R) (v) (C) (IV) (ii) (iii) (iv) (D) (III) (iv) (P) (Q)
following table.
Column-l (Metals) Column-2 (Ore) Column-3 (Process used in refining)

(1) Zn (i) Azurite (P) Distillation
(II) Sn (ii) Carenalite /(J (Q) Poling
(III) Cu
(rV) Hg
(iii) Calomine
(iv) Cassiterite
', "
....
h~'v
......
(R) Bessmerisation
(S) Electrolytic Refining
Q.16 Which of the following is correct match

(A) I (iii) P (B) I (ii) Q (C)I(i)S (D) 1 (iv) R
Q.17 Which is correctly match for Sn

(A) II (iv) S (B) II (ii) Q (C) II (i) S (D) II (iv) Q
Q.18 Which of the following is matched incorrectly
(A) IV (ii) S (B) II (iv) Q (C) I (iii) P (D) IV (iv) S
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I SIGNATUREOFCANDIDATE ISIGNATURE OF INVIGILATOR I
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Unit Test -10
[Paper-2]
SYLLABUS
CHEMISTRY Co-ordination Compound, d and f-Block Elements, p-Block, Metaliurgy,Salt Analysis
A. GENERAL:
B. MARKING SCHEME :
SECTION -I
SECTION -"
SECTION - 11/
6. Passage based multiple choice questians with single correct option. 3 maries will be awarded for each correct answer and No negative

For example if only 'A' cho ice is Fo r examp le , i f t he correct answers to que stion For example if Correct matc h for (A) is P ;
correct t hen , the correct met hod for numbers X, Y , Z and W (say) are 6 , 0 , 9 and 2 , for (8) is R, S ; for (C) is Q ; fo r (0) is P , Q,
filli n g t he bubbles is respec ti ve ly, then the correct me thod fo r fi lli ng S the n the correct method for fi ll ing the
• 0 0 0 x Y Z W P Q R S T
® CD ® ® A • 0 0 0 0
I e! Q) Q) BOO •• 0
(b (b Q; Ie CO . 0 0 0
ABC 0
• 0 • 0 Q) <D Q) Q) o •• 0 • 0
th e w rong method for fi lli ng the @ @ @ @
bubble a re CD CD Sid)
o ® ~ G 0 6 6 6
treated as wrong .
®®®®
C2: C2: OJ 1C2:
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CHEMISTRY

Q.l Amphibole silicate structure has 'x' number of comer shared per tetrahedron. The value of 'x' is:
(A) 2 (B) 2~ (C) 3 (D) 4

2
Q.2 Among the following compounds, which on heating do not produce N2 ?

(A) (NH 4hCr207 (B) NH4CI + NaN0 2 (C) NH4CI + CaO
Q.3 CrO~- (yellow) changes to Cr20~- (orange) in pH = x and vice-versa in pH = y. Hence, x and yare:
(A) 6,8 (B) 6, 5 (C) 8, 6 (D) 7, 7
Q.4 Hydrated aluminium chloride is ionic compound and soluble in water giving:
(A) Ae+ and CI- ions (B) [AI(H 20)6l 3+ and CI- ions
(C) [AICh(H 20)4t and [AIC4(H 20hr ions (D) None of these
Q.5 The sodium salt on treatment with MgCh give white precipitate only on heating. The anion of the sodium
salt is -
(C) HCO)" (D) NO)"
Q.6 Sulphur dioxide may be recognised by its

(A) Ability to decolourize dichromate paper (B) Ability to tum acidified KMn04 solution green
(C) Both of the above (D) Ability to tum Ca(OHh into milky
HN03
Q.7 (X) • Brown residue + colorless solution
t
Scarlet
red H2sf ~2Cr04
&;1
WithHN0 3
& Mn(N0 3)2 Black ppt yellow ppt
Soluble in
Purple solution dilHN0 3
Therefore (X) is -
(A) Hgh (B) HgO (C) Pb0 2 (D) Pb30 4
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is( are) correct.
option is darkened
•
Zero Marks
Negative Marks
o If none of the bubble is darkened.
-2 In all other cases. •
For example, if (A), (C) and (D) are all the correct options for a question, darkening all these three will get +4
Q.8 Which of the following is/are correct regarding the active nitrogen?
(A) It is produced by the passage of electric discharge through the molecular nitrogen
(B) It reacts with hydrocarbon to produce HCN
(C) It reacts with H2S to give blue solid
(D) When electric discharge is stopped it produces a yellow afterglow due to recombination of atomic
nitrogen
Q.9 Which of the following compounds can not be prepared by direct reaction between the constituent elements?
(A) XeF 2 (B) XeF4 (C) XeOF4 (D) Xe03
Q.I0 Aluminium becomes passive in -

(A) Conc. HN0 3 (B) H2Cr04 (C) Conc. HCI0 4 (D) Conc. HCI
Q.ll Which of the following substances are soluble in NaOH solution?

(A) Sn(OHh (B) AI(OH)3 (C) Bi(OHh (D) Pb(OH)2
Q.12 Which of the following statement is/are correct?

(A) [Ni(CO)4] is tetrahedral, paramagnetic, Sp3 hybridised
(B) [Ni(CN)4]2- is square planar, diamagnetic, dsp2 hybridised
(C) [Ni(CO)4] is tetrahedral, diamagnetic, Sp3 hybridised
(D) [NiCI4]2- is tetrahedral, paramagnetic, Sp3 hybridised
Q.13 Which of the following are paramagnetic?

(A) [Ni(H 20)6]2+ (B) [MnC4]2-
Q.14 Which of the following are 1t-bonded organometallic compounds ?

(A) Ferrocene (B) Diethyl zinc
(C) Ethylmagnesium iodide (D) Dibenzene chromium
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PARAGRAPH 1
r-FeC~13:...:s.;;..01",n~. (E)
o
Dil.HCI
Violet colour
compound
(A) NaOH soln. , (8) + (C) Dil. HCI , (D)

Yellow Colourless Colourless Gas having
solid compound Compound rotten egg smell
I I
1CaCI soln.
2
No ppt.
Q.lS Which of the following statements is/are correct for the gas D ?
(I) It has the state of hybridisation Sp3
(II) Gas can be identified by CaCh solution
(III) Gas can be identified by Pb(OAc)z solution
(IV) Gas can be identified by passing through sodium nitroprusside solution
(A) I, IV (B) I, III (C) III only (D) I, II, IV
Q.16 Compound (B) on reactin with [Ni(en)3] (N0 3)z gives a coloured complex exhibiting-
(A) Optical isomerism (B) Geometrical isomerism
(C) Linkage isomerism
• (D) No isomerism
PARAGRAPH 2
A salt (A) when heated with K2 Cr207 and conc.H 2S04 liberates a gas which is absorbed in NaOH solution
turns yellow. When this solution is acidified with acetic acid and lead acetate solution is added, a yellow
precipitate (B) is formed.
(A) is mixed with Mn02 and heated with conc. H 2S0 4 when a gas (C) is evolved which turns starch iodide
paper blue.
Q.17 The acidic radical present in the salt (A) is :

(A) NO.3 (B) cr (D) r
Q.18 What is the colour of gas which is evolved when salt (A) is heated with Mn02 and H 2S04 ?
(A) Violet (B) Brown (C) Greenish yellow (D) Colourless
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Revision Test -2
[Paper-I]
SYLLABUS
CHEMISTRY Units 6to 10
A. GENERAL:
B. MARKING SCHEME :
SECTION -I
SECTION -/I
SECTION - III
answers). Section-II (column matching type), Section-III (include integer answer type)]

For example i f only 'A' cho ice is Fo r exam pl e , if the correc t answers to question For exam ple if Correct matc h for (A) is P;
correct then, the correct me thod for numbers X, Y , Z and W (say) arc 6,0,9 and 2, for (B) is R, S; for (C) is Q ; for (D) is P , Q,
filli n g t he bubbles is respect ively, then the correct method fo r fi lli ng S then the correct method ror rilling the
A B C D the bubb les is bubb les is
• 0 0 0 x Y Z IV P Q R S T
are correct then , the correc t me thod
for filli ng th e b ubb les is
ABC
• 0 • 0
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th e wrong method for filli ng the

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is( are) correct.
Q.l The species not observed in the following sequence of reaction -
aCt
o
IRO-
! 1
RC(-
~. •
•
CI
(I) IRO- (VI)

! 1 !
0*
ORR~oO
'C) (ll)
* *
(IV)
* RCJ
(VII)
tfocf
+ +
(UI) (V)
(A) I, II, III (B) II, III, VII (C) VI, VII (D) I, IV, V
Q.2 An autocatalytic reaction is represented as A + B ~ D where initial concentrations of A and B each equal
to ao. initial concentration of D is zero-
(A) An autocatalytic reaction is the such reaction in which product itself increases the speed ofreaction
(B) In an autocatalytic reaction product form a complex oflower activation energies.
(C) The maximum rate for the above autocatalytic reaction is obtained when [D] = aJ3
(D) The overall order of the above reaction is three
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Q.3 Standard electrode potential of two metals A and Bare E? and E~ respectively. When half cells A 2+/A and
B2+/B are connected electrons flow from A to B but when A is connected with standard hydrogen electrode
electrons flow from A to standard hydrogen electrode. If magnitude of E? and E~ are 0.25 and 0.34 volt
respectively the among the following the correct statement(s) is/are-
(A) E? for A2+ + 2e ~ A is -0.25 V
(B) E~ for B2+ + 2e ~ B is -0.34 V
(C) E~ell of the cell connecting these electrodes is 0.59 V
(D) E~ for B2+ + 2e ~ B is 0.34 V
2
Q.4 A sample of water has a hardness expressed as 77.5 ppm Ca +. This sample is passed through an ion
2
exchange column and the Ca + is replaced by H+. Select correct statement(s) -
(A) pH ofthe water after it has been so treated is 2.4
(B) Every Ca 2+ ion is replaced by one H+ ion
(C) Every Ca2+ ion is replaced by two H+ ions
(D) pH of the solution remains unchanged
Q.S Which of the following are possible products from aldol condensation of 6-oxoheptanal ?
O~ /CH3 O~ /H
C C
(A) [ ] (B) CHcO (C)O o

(D)
CH~
3 V
o
1mole Me 2 CuLi ) [Y] [P]

Q.6 CHz-CH - (CH 2h - CHO [X] PCC ) ) [Z] NaCN ) ) [Q]
H,O
\/ CH,CI,
The correct option (s) is/are (Assuming major product is formed in each reaction) -
(A)[P] ~ &Ol'N (B)[Q] ~ H'N~OH

Meyyo
(C) [Z] = V (D) [Y] = MeCH 2CO(CH 2hCHO
Q.7 When 100 ml of 0.1 M KN0 3, 400 m1 ofO.2M HCI and 500 m1 of 0.3 M H2 S04 are mixed.
Then in the resulting solution
(A) The molarity ofK+ = 0.01 M
(B) The molarity of SO~- = 0.15 M
(C) The molarity of ofH+ = 0.38 M
(D) The molarity of NO) = 0.08 M and cr = 0.01 M

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Q.8 In molecule of nitro glycerin the number ofN atoms present are ..... . .. . .. .
Q.9 The total number of geometrical isomers exist for the complex M (AA) B 2C 2 is . ........ . . .
Q.IO A drug becomes ineffective after 50% decomposition. The original concentration of a drug in a sample was
10 mg/ml which becomes 4 mg/ml during 10 months. Assuming the decomposition of drug of first order,
what is the expiry time of the drug in months? Give the answer in nearest possible integer in month.
Q.ll One mole ofa substance is cooled at the rate of 0.04 KJ/rnin as shown in the graph
800 - A
I
t I
temp in K 400
100 D
5 10 40 50
time in minutes -
As represent cooling of liquid, BC represent conversion of liquid to solid, CD represent cooling of solid. The
entro py of fusion is ... . ...... J/mollK
Q.12 How many structure from the following are correctly matched with their IUPAC name
Structure IUPAC name
OHC CH 3
I. \==! .=<CH 3 3, 7 dimethyl oct- 2, 6, dienal
"--.J "CH 3
II. [::::)0 Spiro(3, 6) decane
III. 90
EI
3-ethyl-7-iodobicyclo (2.2.1) heptane
N-ethyl-N methyl etnanarnine

IV~N~
. I

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following table.
(I) -N0 2 (i) -M effect (P) 0 , P directing
(II) - 0 '" (ii) + M effect (Q) activating
(Ill) - 0 - CH 3 (iii) + I effect (R) deactivating
(IV) -F (iv) - I effect (S) meta directing
Q.13 Correct combination is : 0--)

(A) II (ii) R (B) II (i) P (C) II (iii) S (D) III (ii) Q
Q.14 Incorrect combination is :

(A) I (i) S (B) II (iii) Q (C) III (ii) P (D) None
Q.lS Correct combination is :

(A) II (iii) P (B) IV (iv) P (C) IV (ii) R (D) All
following table.
I
Column-l Column-2 '.J j Column-3

(No. of Isomer)
(I) Benzenoid isomer of C 7 H gO (i) 5 (P) Three Isomer are soluble in NaOH
(II) C6H 3ClBr I Benzenoid Isomer (ii) 10 /~ (Q) Isomers are positional isomer (Only)
(III) C4H IOO (Structural Isomer) (iii) 7 /(J (R) Five Isomers is cyclic other are open chain
(IV) C 5HIO (Structural Isomer) (iv) 3 "'- (S) It Include Alcohol & ether
'-
Q.16 Which of the following is correct combination
(A) I (iii) S (B) I (ii) Q (C) II (ii) Q (D) II (ii) P
Q.17 Which of the following is correct combination

(A) III (iii) P (B) III (iii)S (C) III (i) P (D) IV (iv) P
Q.18 Correct combination

(A) I (i) P (B)I(i)S (C) IV (ii) S (D) All
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Revision Test -2
[Paper-2]
SYLLABUS
CHEMISTRY Units 6 to 10
A. GENERAL:
B. MARKING SCHEME :
SECTION -I
SECTION -/I
SECTION - III
Section -, Section-II Section-II'

For example if only 'A' cho ice is For examp le, if the correc t answers to question For example if Correct match for (A) is P ;
correct then , the correct method for numbers X , Y, Z and W (say) are 6 , 0 , 9 a nd 2 , for (8) is R, S; for (C) is Q ; for (D) is P , Q,
filling th e bubbles IS respect ive ly, then the correct me thod fo r fill ing S the n the correct method for fil ling the
• 0 0 0 X Y Z W P Q R S T
® CD ® ® A • 0 0 0 0
I cr :r I BOO •• 0
ABC D
Q; <r CD IU CO . 0 0 0
• 0 • 0 Q) (D Q) Q) D •• 0 • 0
th e wrong method for fill ing the @) @) @) @)
bubble are 5 ) (5) 5
(2) ® ~ (J 0 ® 6 ®
T h e answer of the questions in (j) (j) (j) (j)
wrong or an y other manner will be
treated as wrong .
®®®®
® ® 0) ®
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CHEMISTRY

Q.l A ( PhCH, - I Ph-CH,-I ) B

CF,CH,OH DMSO
'A' and 'B' respectively are -
~
Ph-CH-C-H
I HO-
Q.2 -----:-:-,:---t) Q. P and Q are isomers Identify Q -
OH H,O
(P)
~ ~ ~
(A) Ph-CHz-C-OH (B) Ph-C-OCH3 (D) H-C-CHz-O--Ph
Q. 3 What is compound Z ?
$
CH r CH 2--CH r Br NaCN. X HlO. Y

H",!CH 3--C H2-0H
Z
o
II
(A) CH 3-CH=CHCOH (B) CH r CHz-CH 2CH=NOCH 2CH 3
~
(C) CH 3-CHz-CH 2CH(OCH 2CH 3h (D) CH 3-CHz-CH 2--c-OCH 2CH 3
Q.4 irritating smell
[Yl + K 2Cr207 + H 2S04 ----t green solution
[Xl and [Yl are, respectively -
(A) soj- ,S02 (B) cr, HCl
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Q.S P- tolyl chloride and sodium-p- toluate react to produce-
(A) P-toluic Anhydride (B) Toluic Acid (C) Benzoic Acid (D) p- toludene
Q.6 Which method of purification is represented by the following equations?

Ti + 2h 773K) Ti4 1675K) Ti + 2 12
(A) Cupellation (B) Poling (C) Van Arkel (D) Zone refining
Q.7 In a Cu-voltameter, mass deposited in 30s is m gm. If the time-current graph is shown in the following figure
200 rnA - - - - - - - - - - - - -
t I
current :
I
100 rnA
20 s 30 s
time_
What is the electrochemical equivalent of Cu ?
(A) ml2 (B) ml3 (C)ml4 (D) 6~5

is( are) correct.
option is darkened
Q.8 12 g of impure of cyanogen undergo hydrolysis by two different pathways -

(i) (CNh + 4H 20 -+ (NH4)2 C20 4
(ii) (CNh + 2H 20 -+ NH 2CONH2
The exact amount of urea was obtained when 11.52 g of pure ammonium carbonate was heated. If 20 ml of
1.6 M acidic KMn04 solution was required to completely oxidise (NH 4hC 20 4 then which statement is
correct -
(A) % purity of cyanogen is 86.67% (B) % purity of cyanogen is 60.67%
(C) % progress in case (i) is 40% (D) % progress in case (ii) is 60%
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Q.9 Select the correct order among the following :
(A) "'d~ ofh'" ofh,d",.="oo 666 < <
(B) Order of heat of combustion 0QD > >
(C) 0""""""0,","'''''',,, 66 6 < <
(D) Order of basic strength V

HNJlNH
> U
)lNH
>
6 NH
Q.I0 Select the correct statement:

\) fJ
N
(A) H/ I"-Et is optically inactive while )J)N is optically active
CH]
a ~ a ~
(B) CH] -CH 2 -CH 2 -CH] CH 3 -CH2-CH] About C(a) - C(P) bonds; (I) has more energy barrier for
(I) (II)
rotation as compared to (II)

(C) The boat form of cyclohexane is less stable than chair form due to torsional strain as well as flag pole
interaction
(D) In t-butyl substituted cyclohexane, most stable chair conformer has -CMe] group at equitorial position
Q.ll Which order is correct:
(A) Acidic strength in ethanol @< 0

OH@OH
N0 2
02N
0
N02
(B) B..ioity ,lreogth io ",0 q>!

(C) Leaving group tendency in DMSO r < cr < Br- < r
>~ > 'f
(D) Nucleophilticy in DMSO Br- < r < OW
Q.12 Select the incorrect statement(s) from the following :

(A) Rate of suiphonation ofCJf6 & C~6 will be equal
L S O]H
(B) On treatment Ofl2J with Bry'water (in excess) it results in a dibromo product
(C) When HCOOEt is treated with MeMgBr in excess followed by hydrolysis it will results in the formation of
tertiary alcohol.
Me CI
I I
(D) MeCH2 - CH - CH - Me aq.KOH) Product.
Optically pure SN2
Product is enantiomer of the reactant.
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Q.l3 A layered sequence for a~~
FCC = ~CP ~metal;
S shown b~~OW :
CD 9 7
4 3 8
Z=O Z=aJ2 Z=a.
A face diagonal passes through the centre of atom 4 and the centre (s) of which other atom (s)?
(A) 1 (B) 2, 5 (C) 8, 12 (D) 9, 10
Q.l4 A salt MX crystallising in KCI type of structure in which K+ is forming fcc.

(A) The nearest neighbour of cr ion is 6 K+ ion
. . . b l.732n
(B) The packi ng fr actIOn IS given y - - •
8
(C) The nearest neighbour ofK+ ion is 6 Cr- ion
(D) The second nearest neighbour ofK+ ion is 12 K+ ion.
&J
..,."...

PARAGRAPHl
Machanism for the monochlorination of alkane:
Light supplies the energy to break down the chlorine-chlorine bond homolytically. Reaction, radical
substitution starts with homolytic bond cleavage.
Step I CIlLCI ~ 2CI. Initiation step
CH2CH) CH 2CH)
Step II Hiliftl I -"H ,t'lCI
~H~+ ' - H C ~
~\.
H)C ) ~H
Trigonal planar
(Facilitates attack from both
sides equally well)
Alternative way to attack Racemic mixture
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Step IV
(a) Cl·+Cl· ---+ Clz
In step II Cl' can abstract 1° as well as 2° radical Actually Cl' is less selective towards 1° and 2° .
Quantitatively it is observed that Cl' is 3.8 times more reactive towards 2° (Hs) in comparison to 10(Hs) and
that is 5 times more reactive towards 3° (Hs).
C12 ,hv ) products
l-chloro-2-methyl butane is one of the possible product. Choose the incorrect statement regarding the
formation of l-chloro-2-methyl butane from 2-methyl butane-
(A) The formation involves 1° radical in step II
(B) The formation does not involve any kind of racernisation
(C) The percent yield of I-chloro-2-methyl butane is equal to _6_ x 100

21.6
(D) l-chloro-2-methyl butane and l-chloro-3-methyl butane both are possible products and both are
structural isomers
CH) CH)
. I C12'~ I
Q.16 ReactIOn I: CH)-CH-CD)-CH) ---=:.:..r...:.:.:~) CH)-CH- CD-CH)
rate =r\ I
CI
C'2 ,hv
rate= rIl
Compare the rate of reaction

(A) r, = rll (B) r , > rll (C) r, < rll (D) None of these
PARAGRAPH 2
Mixed chioro fluoro carbons, sometimes called CFC, such as CFCh, CF2Ch, CF3CI are known as "Freons". They
are unreactive and are widely used as refrigeration fluids. Freons are very much more effective "greenhouse gases
" in the atmosphere than CO 2 ; though the amount offreons present is extremely small. Much more seriously, the
freons have penetrated the upper atmosphere and causing damage to the ozone layer.
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Q.17 In which of the following way freons damage the ozone layer?
(A) By producing CCl 2 free radicals (B) By producing CFCI free radicals
(C) By producing fluorine free radicals (D) By producing chlorine free radicals
Q.18 Hydro fluoro carbons (HFCs) such as CH 2 FCF 3 and hydro chloro fluoro carbons
(HCFCs) such as CHCI 2CF 3 are used as substitutes ofCFCs because
(A) HFCs & HCFCs are not green house producing
(B) HFCs and HCFs are liquid not gases
(C) HFCs and HCFCs are also green house producing but they do not remain in the atmosphere for so long
(D) HFCs and HCFCs are lesser green house producing than CFCs
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Major Test
[Paper-I]
SYLLABUS
CHEMISTRY Full Syllabus
A. GENERAL:
B. MARKING SCHEME:
Each subject in this paper consists of following types of questions :-
SECTION -I
SECTION -/I
SECTION - III

correct then , the correct met hod for numbers X. Y. Z and W (say) are 6, 0, 9 and 2, for (8) is R, S; for (C) is Q ; for (0) is P, Q,
filli ng the bubbles is respect ive ly, then the correct me thod fo r fi lli ng S the n the correct method for fi ll ing the
• 0 0 0 x Y Z W P Q R S T
® CD ® ® A • 0 0 0 0
I (1 Q) Q) BOO •• 0
(b (b Q; 18 CO . 0 0 0
ABC 0
• 0 • 0 Q) <D Q) Q) o •• 0 • 0
bubble are CD W 5 5
o ® ~ C. CIt 6 6 6
t reated as wrong .
®®®®
<9: <9: 0) <9:
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CHEMISTRY

is( are) correct.
Q.l For a reaction: 2A + 2B --t Products, the rate expression is r = K[A]2[B] ; which of the following is/are
correct?
(A) the reaction is first order with respect to B (B) the reaction is of second order with respect to A
(C) overall the reaction is of third order (D) slowest step of the reaction is given as A + B --t AB
Q.2 Consider the following reaction.

P --t nQ
Let initial concentration ofP is Po and variation of concentration ofP and Q is shown by graphs given below.
Po
Conc.
t= t
Time
Select the correct statements about the reaction discussed above:
(A) at point A, [P] = [Q] (B) at point A, [Q] > [P]
. nPo . 1+ n
(C) at pomt A, [P] = - (D) at pomt A, [P] = -
1+ n nPo
Q.3 The specific rate constant for a first order reaction is independent of the:
(A) concentration of the reactants (B) time
(C) temperature (D) Catalyst
Q.4 Which one of the following square planar complexes will be able to show geometrical isomerism?
(A) MX4 (B) Ma3b (C) M(aa'h (D) M(aa)2
Q.S Three test tubes contain aqueous solutions as under

I. KCN
II. Fe(CNh
III: Mixture ofKCN, Fe(CN)2 in molar ratio 4: 1
pick up the correct statement
(A) Both I and III will give test for C~
(B) Both II and III will give test for Fe+2
(C) Solution III will neither give test for C~ nor Fe+2 ions
(D) Electrical conductivity of all solution will be same
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Q.6 Dimethyl glyoxime is used for estimation of
(A) Nickel (B) Cobalt (C) Zinc (D) Manganese
Q.7 The main function of roasting is -
(A) To remove the volatile matter (B) Oxidation
(C) Reduction (D) To make slag

Q.8 The conductance of a salt solution (AB) measured by two parallel electrode of area 100 cm2 separated by 10
cm was found to be 0.0001 0 - 1 If volume enclosed between two electrode contain 1.0 mole of salt, what is
molar conductivity (S cm2 mor 1) of salt at same concentration. Express your answer by multiplying by 10.
Q.9 A 4.0 molar aqueous solution ofNaCI is prepared and SOO mL of this solution is electrolysed. This leads to
the evolution of chlorine gas at one of the electrodes. The total number of moles of chlorine gas evolved is.
Q.I0 An alloy of Pb-Ag weighing 1.08 g was dissolved in dilute HN0 3 and the volume made to 100 ml. A silver
electrode was dipped in the solution and the EMF of the cell set up
Pt(s), H2Cg) IH+ (1M) II Ag+ (aq) I Ag(s)
was 0.62 V. IfEo",u = 0.80 V. What is the percentage of Ag in the alloy? [At 2SoC, RTIF = 0.06]
[At. wt. Ag= 108]
Q.ll The following sequence of reactions may be used to extract zinc from its sulphide ore
2ZnS + 302 ~ 2ZnO + 2S0 2
ZnO +C ~Zn+CO
How many tans of Zn can be obtained from 10 tons of ZnS, assuming that the yield is 7S%?
(Zn = 6S.3 & S = 32)
Q.12 How many reaction finally produce AlCOHOL.

(i) CaC 2 ~ A H,O ) B NaBH, ) C
HgSO,+DiIH,SO,
(ii) CHr-CHrCHrCHrO-CH3 ~ Product
(iii) CHr CHrO-CHrC H3 excess HI )
(iv) R-C--Cl ~
II LiAIH,
o
(v) R-C--NH2 ~
II LiAIH,
o
NaBH4
(vi) R-C--O-C H
~
Low temp.
2 5
(vii) R--C--O--C2HS LiAIH,

II
o
(viii) R-C=CH HBO )
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Ne ative Marks : -1 In all other cases.
following table.
Cons H 2SO4 , (i) Rearrangement involve transfer of (P) One Product
R-C=N-OH
(1) I Alkyl group at e- deficient soluble in NaOH
R' heteroatom
R C N H2 ' (ii) Better migratory group transfer (Q) a 0 amide is product
(II) II Br2IKOH
0
0 (iii) CROSS Product are not formed (R) Product gives
(III)
6 6~H H30
PhC03H ,
Ell
(iv) Configuration of migratory group
do not change
Isocyanides test
(S) product gives

neutral FeCl) Test
, A + B
(violet colour)
(IV) " ',~ / , ...
Q.8 Which. of the following is correct. .
(A) I (\) R (B) II (11) R ~ (C) III (\) P
. ..
(D) III (m) R
Q.9 Which of the following is incorrect
(A) I (i) Q (B) II (i) R (C) I (iii) R (D) III (ii) R
Q.I0 Which of the following is correct
(A) IV (ii) Q (B) IV (iv) R (C) II (i) S (D) IV (i) S
following table.
Column-l ......., \ Column-2 Column-3
(I) XeF4 ~ (i) spj d, see saw (P) Pre - Pre bonding
~.
(If) SF4 <., \ (ii) spjd", square planar (Q) No. ofL.P = 1
(III) SF6 -( ....... , \ .....' (iii) spJ d , distorted octahedral
2
(R) No. ofL.P = 2
spJ d 2 , octahedral
(IV) XeF6 .\~ (iv)
(S) No. ofB.P = 6
(v) 90°
Q.16 Which of the only correct option?
(A) (I) (S) (B) (II) (R) (C) (III) (Q) (D) (IV) (S)
Q.17 Which of the following is only correct?
(A) (I) (iii) (v) (B) (II) (ii) (v) (C) (III) (iv) (v) (D) (I) (v) (ii)
Q.18 Which is only incorrect option?
(A) (I) (ii) (R) (B) (III) (iv) (S) (C) (II) (ii) (P) (D) (IV) (iii) (Q)
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Major Test
[Paper-2]
SYLLABUS
CHEMISTRY Full Syllabus
A. GENERAL:
B. MARKING SCHEME:
SECTION -I
SECTION -/I
SECTION - 11/
S('ction -I Section-II Section-III

For example if only 'A' cho ice is Fo r examp le , i f the correct answers to que stion For example i f Correct match [or (A) is P ;
correct then , the correct method for numbers X. Y. Z and W (say) are 6 , 0 , 9 and 2, for (8) is R, S ; for (C) is Q ; for (0) is P, Q,
filli n g the bubbles is respect ive ly, then the correct method fo r filling S the n the correct method for filling the
• 0 0 0 x Y Z W P Q R S T
® CD ® ® A • 0 0 0 0
I (1 Q) Q) BOO •• 0
(b (b Q; 18 CO . 0 0 0
ABC 0
• 0 • 0 Q) <D Q) Q) o •• 0 • 0
th e w rong method for filling the @) @) @) @)
bubble are CD W 5 5
o ® ~ C. CIt 6 6 6
The an swer of the questions in (j) (j) (j) (j)
treated as wrong .
®®®®
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CHEMISTRY

Q.l to mL of 0.2 N HCI is added to 10 mL of 0.1 M H 2S0 4 and 10 mL of 0.4 N Ba(OH)2 solution. If Ba(OH)2 is
completely ionized, the resulting solution will be-
(A) neutral (B) strongly acidic (C) alkaline (D) slightly acidic
Q.2 The number of moles of KMn04 required to react completely with two moles of ferrous oxalate in acidic
medium is-
(A) 0.6 mol (B) 1.2 mol (C) 1.67 mol (D) 0.8 mol
Q.3 An aqueous solution of 6.3 g of oxalic acid dehydrate is made upto 250 mL. The volume of
0.1 N NaOH required to completely neutralize to mL of this solution is-
(A) 40 mL (B) 20 mL (C) to mL (D) 4 mL
Q.4 0.6 g ofa metal on oxidation gave 0.84 g of its oxide. The equivalent mass of the metal is-
(A) 10 (B) 15 (C) 20 (D) 30
Q.5 The density of gas A is twice that to B at the same temperature, the molecular weight of gas B is twice that
of A. The ratio of pressure of gas A and B will be -
(A) I: 6 (B) I : I (C) 4 : I (D) I : 4
Q.6 Calculate the number of moles of gas present in the container of volume to L at 300 K. If the manometer
containing glycerin shows 5m difference in level as shown diagram.
(Given: dglycin= 2.72g ImL ; dmercury = 13.6 g/mL)
P"m = [atm
(A) 0.94 mole (B) 0.49 mole (C) 0.64 mole (D) none of these
Q.7 Equation for Boyle's law is -

2 2
dP dY dP dY (D) d P = + d y
(A)-=-- (B)-=+-
P Y P Y P dT
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is( are) correct.
option is darkened
Q.S Which of the following combination are correct-
~
COOH COOH
(A) ©r OH
< ~
A,;di, ,treogili oc,,", (8) Boiling point order
OH N02
Cl Cl ~C/COOH
(C) ~ < ©rei M"ti., po;nl ocd~ (D) II <
H/C~OOH HOO~C"H
H"C/COOH
II Acidic strength
Cl
Q.9
0;/
_, I Na/liq.NH, ) (A)
Identify the correct statement (s) -

NBS) (B) (CH,h CuLi ) (C)
(A) On treating with hot alkaline kMn04 (A) gives propan-I,3-dioic acid
(B) On treating with aqueous KOH (B) gives cyclohexanol
(C) The product (C) is 3,6-dimethylcyclohex-I,4-diene
(D) On ozonolysis one mole of(C) gives one mole each of propan -1,3-dia I and 2-methylpropan-I,3-dial
(D)H
Q.ll Alkene are not significant products because BrEl is a poor base.
The work involved in a reversible adiabatic process of expansion of an ideal gas from P, and V, to P2 and V2
r
is given by-
w=-ncvT{I-(~~
CP
(A) W = P2 V2 -P,V,
y-l
(B) ]
(C) W = nCv (T2 - T,) (D) W = [efficiency of camot cycle x aabsorbed]
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Q.12 For resonating structures
0- 0
0
(I)~ (II)~ (III)~ C

C=N CN
lie
N
The correct order of stability is -
(A) I > II (B) I > III (C) II > III (D) III > II
aCOo~a<ll
Q.13 Electrolys is ) Major product
9 Ell
C00 Na
(A) 0 (B) ():=I:) (C)O (D)

CC OH
OH
Q.14 Which of the following compounds is most reactive for Wurtz reaction?
(C)o*
Br Br
(B) ~

PARAGRAPH 1
0.5 gm bleaching powder was suspended in water & excess 1<1 is added. On acidifying with di!. H 2S04, Iz was
liberated which required 50 ml of Ni l 0 Hypo (Na2S203.5H 20) in presence of starch. Reaction involved are
I. CaOCIz + H 2S04-----+ CaS04 + H 20 + Clz
II. 21<1 + Clz -----+ 2KCl + 12
III. 2Na2S203 + h -----+ Na2S406 + 2Nal
Q.15 In reaction (II) Clz acts as

(A) Reducing agent (B) Oxidising agent (C) Indicator (D) None of these
Q.16 Eq. wt. ofNa2S203 in reaction (III) is

(A) M (B) M (C) ~ (D) M
I 2 0.5 3
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PARAGRAPH 2
In real gases due to force of attraction between the molecules & finite size of the molecules. There is deviation in
the behaviour of the real gases from the ideal gas behaviour. Experimentally curves for PVm (Z, compressibility
RT
factor) were determined
Real gas Temp. T
p
The plot of Z vs P depends on the temperature.
Q.17 Which of the following can be true
~/J'~~:al
P
(A) P (B) P (C) ~:::l (D)
Real
gas
~ Ideal \'(
gas
gas
v v v v
Q.18 Given Z Vs P graphs for a real gas at different temperature
Real gas P
P
Identify the incorrect statement [TB = boyle temp. Tc= critical temp.]
(A)T, ""Tc (B)T4 > Tc (C)T B < T2 < Tc
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Answer Key
• UNIT TEST -1
Paper-l
•
1. (8,C,D) 2. (A,8) 3. (A,8) 4. (C,D) S. (A,C) 6. (A,8,CD) 7. (8,C)

8.5 9. 1 10.6 11.5 12. 7 13. (8) 14.(C)
15. (A) 16. (D) 17. (D) 18. (D)
Paper-2
1. (8) 2. (D) 3.(C) 4.(C) S. (D) 6.(C) 7.(C)
8. (8,D) 9.(8,C) 10. (C,D) 11. (A,8,C) 12. (A,D) 13. (A,8,D) 14. (A,8,C)
15. (A) 16. (8) 17. (8) 18. (A)
• UNITTEST-2 •
Paper-l
1. (A,8,C) 2. (8,C,D) 3. (8,C) 4. (A,8,C) S. (A,D) 6. (A,8 ,C,D) 7. (A,8 ,C)
8.4 9.5 10.2 11. 3 12.8 13. (8) 14. (A)
15. (8) 16.(C) 17. (8) 18. (C)
Paper-2
1. (C) 2. (D) 3. (D) 4.(C) S.(C) 6.(C) 7.(C)
8. (A,8,D) 9.(A,C) 10. (8,C) 11. (A,C) 12. (A,C) 13. (C,D) 14. (A,8,C)
15. (A) 16. (A) 17. (8) 18. (8)
• UNITTEST-3 •
Paper-l
1. (D) 2. (A,C) 3. (A,C,D) 4. (A,8 ,C) S. (A,8) 6.(C) 7. (A,8 ,C,D)
8.7 9.9 10.5 11.2 12.2 13. (D) 14. (D)
15. (D) 16. (D) 17. (C) 18. (D)
Paper-2
1. (D) 2. (A) 3.(C) 4.(C) S. (A) 6. (D) 7. (8)
8. (A,8,C,D) 9.(A,8,C,D) 10. (8,D) 11. (A,8) 12. (A,8) 13. (C,D) 14. (A,C,D)
IS.(C) 16. (8) 17. (C) 18. (A)
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• UNIT TEST -4
Paper-l
•
1. (A,C,D) 2. (A,B,C) 3. (A,B,C,D) 4. (A,B,C,D) S. (A,B,D) 6. (A,B,D) 7. (A,B,C,D)

8.2 9.5 10.5 11. 9 12.9 13. (D) 14.(C)
15. (D) 16. (D) 17. (D) 18. (D)
Paper-2
1. (C) 2. (B) 3. (B) 4. (A) S. (B) 6.(C) 7. (B)
8. (A,B,C) 9. (A,C,D) 10. (A,B,C) 11. (A,B) 12. (A,C) 13. (C,D) 14. (A,B,C)
15. (A) 16. (B) 17. (A) 18. (D)
• UNITTEST-S •
Paper-l
1. (C,D) 2. (A,B) 3. (B,C,D) 4. (A,B,C) S. (A,C,D) 6. (B,C,D) 7.(C)
8.3 9.3 10.3 11. 2 12.2 13. (D) 14. (A)
15. (D) 16.(C) 17. (B) 18. (D)
Paper-2
1. (D) 2. (C) 3. (B) 4.(C) S. (D) 6. (D) 7. (B)
8. (B,C,D) 9. (A,B,C,D) 10. (A,C,D) 11. (A) 12. (D) 13. (B,C) 14. (A,B,C)
IS.(C) 16. (C) 17. (A) 18. (B)
• REVISION TEST -1.

Paper-l
1. (B,C,D) 2. (A,B) 3. (A,B) 4. (B,C,D) S. (A,C) 6. (B,D) 7. (B,C)
8.7 9. 9 10.5 11. 7 12.6 13. (D) 14.(C)
15. (D) 16. (D) 17. (B) 18. (D)
Paper-2
1. (B) 2. (B) 3. (B) 4. (D) S. (D) 6. (A) 7. (D)
8. (C,D) 9. (A,C) 10. (B,C,D) 11. (A,C,D) 12. (A,B,D) 13. (A,C) 14. (B,C)
IS.(C) 16. (B) 17. (A) 18. (D)
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• UNIT TEST -6 •
Paper-l
1. (A,B,C) 2. (A,B,C,D) 3. (A,C,D) 4. (B,C,D) S. (C,D) 6. (A,B,C) 7. (A,B,C)
8.5 9.3 10.2 11.5 12. 1 13. (B) 14. (A)
IS.(C) 16. (A) 17. (D) 18. (D)
Paper-2
1. (A) 2. (B) 3. (B) 4. (B) S. (B) 6. (B) 7.(C)
8. (A,B,D) 9. (A,B,C) 10. (B,C) 11. (A,B,C) 12. (A,C) 13. (A,B,D) 14. (B,C,D)
15. (B) 16. (A) 17. (D) 18. (D)
• UNIT TEST -7 •
Paper-l
1. (D) 2. (A,D) 3. (A,C) 4. (A,C,D) S. (B,D) 6. (A,C,D) 7. (B,C)
8.3 9.3 10.1 11.8 12.2 13. (A) 14. (B)
15. (A) 16. (D) 17. (A) 18. (D)
Paper-2
1. (A) 2. (B) 3.(C) 4. (D) S. (B) 6. (D) 7.(C)
8. (A,B,D) 9. (A,C,D) 10. (A,B,D) 11. (A,C) 12. (B,C,D) 13. (A,D) 14. (B,C,D)
15. (B) 16. (C) 17. (C) 18. (C)
• UNIT TEST -8
Paper-l
•
1. (A,B,C) 2. (B,C,D) 3. (A,B,D) 4. (A,C) S. (B,C,D) 6.(C) 7. (A)
8.8 9.4 10.3 11. 4 12.2 13.(C) 14. (D)
15. (D) 16. (A) 17. (B) 18. (D)
Paper-2
1. (A) 2.(C) 3. (A) 4. (B) S. (D) 6. (A) 7.(C)
8. (A,B,C) 9. (A,B) 10. (B,C) 11. (B,C) 12. (C,D) 13. (B,D) 14. (B,C,D)
15. (B) 16. (D) 17. (D) 18. (C)
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• UNITTEST-9 •
Paper-l
1. (A,B,D) 2. (A,C,D) 3. (A,C) 4. (B,D) S. (A,B,C) 6. (A,D) 7. (A,C,D)
8.4 9.4 10.4 11. 4 12.3 13.(C) 14. (D)
IS.(C) 16. (D) 17. (D) 18. (C)
Paper-2
1. (C) 2. (D) 3.(C) 4. (D) S. (B) 6.(C) 7. (A)
8. (A,B) 9. (B,C,D) 10. (A, B) 11. (B,C,D) 12. (A,B,C,D) 13. (A,B,D) 14. (A)
15. (A) 16. (B) 17. (A) 18. (B)
• UNIT TEST -10.

Paper-l
1. (B,D) 2. (A,B,D) 3. (A,B,C) 4. (A,B,C,D) S. (A,D) 6. (A,D) 7. (A,C,D)
8.0 9.5 10.8 11. 1 12.5 13.(C) 14.(C)
IS.(C) 16. (A) 17. (D) 18. (D)
Paper-2
1. (B) 2. (C) 3. (A) 4.(C) S.(C) 6. (D) 7. (D)
8. (A,B,C,D) 9. (C,D) 10. (A,B,C) 11. (A,B,D) 12. (B,C,D) 13. (A,D) 14. (A,D)
IS.(C) 16. (A) 17. (B) 18. (C)
• REVISION TEST -2.

Paper-l
1. (B,C) 2. (A,C,D) 3. (A,C,D) 4. (A,C) S. (A,C) 6. (B,D) 7. (A,B,C,D)
8.3 9.3 10.8 11. 3 12.3 13. (D) 14. (A)
15. (D) 16.(C) 17. (B) 18. (D)
Paper-2
1. (B) 2.(C) 3. (D) 4. (A) S. (A) 6.(C) 7. (B)
8. (A,C,D) 9. (B,C,D) 10. (A,B,C,D) 11. (A,B,C,D) 12. (A,B,C,D) 13. (B,C,D) 14. (A,C,D)
15. (B) 16. (C) 17. (D) 18. (C)
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• MAJOR TEST
Paper-l
•
1. (A,B,C) 2. (A,C) 3. (A,B) 4.(C) 5.(C) 6. (A) 7. (B)
8. 1 9. 1 10.1 11.5 12.4 13.(C) 14. (D)
15. (D) 16. (D) 17. (D) 18. (C)
Paper-2
1. (A) 2. (B) 3. (A) 4.(C) 5.(C) 6. (A) 7. (A)
8. (A,B,D) 9. (B,D) 10. (A,C,D) 11. (C) 12. (A,B,C) 13. (A) 14. (B)
15. (B) 16. (A) 17. (D) 18. (C)
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Unit Test-l
Hints &Solutions~
• Solution Paper-1
1. [B,C,D] Z2 42
I $I excitation energy 3 - = 13.6 x 2 = 13.6 x 2 eV
3 3
24 = 13.6 (~ __
1) Z2
= 24.178 eV
e 22
4. [C,D]
~ Z2 = 2.3529 and z = 1.5339 o 0-
I.E. = 13.6 x Z2 = 32 eV H----C"'" - - H-c( B.O. = 2 + 1 = 1.5
"0- "'0 2
~~J- b!J- [)~'

Z2
B.E. =-E4= 13.6 x - eV = 2eV
16
nd
2 excitation energy
= 13.6 Z2 C~ -
312 ) B.O. = 2+1+1 =~=1.33
3 3
8 32x8 C-O bond length in HCOO- is less than C-O
=32x-eV=--eV
9 9 bond length in CO~-
Excitation energy = Excitation potential
5. [A,C]
= 32x8 Volt
2.
9
[A,B]
I~ J}"dT No. of (j bonds in [BF4r = 4
Atom may be He+ or Li2+.

~ B.O. ofNO+ = 3.0, i.e., one sigma bond and two
If no of photons absorbed = no. of photons
rr bonds
emitted then excited state of ions is I $I excited
No. ofrr bodns = 2
state.
So energy absorbed by He+ = 13.6 x 22 No. of (j bonds = 5
~ B.O. ofNO+ = 3.0
=(~ __I )
12 22
= 40.80 V and B.O. of NO = 2.5
~
energy absorbed by Li + = 13.6x 3 C~
2 2
-;2) =
NO+
diama gneti c
is diamagnetic and BF; is also
~ B-F bonds are longer in BF4- than in BF3 due to

91.8eV
absence of prr-prr back bonding in [BF41
3. [A,B]
Z2 6. [A,B,C,D]
B.E. = 13.6 x -2
4 ......CHJ
'0.
~Z2= ~ xB.E= ~ x 13.6~z=4 //¢j:
.S,- ••
13.6 13.6
I "C;1:
I.E. from 2nd excited state :~
CH 3
.
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7. [B,C) Mg(s) + (1 /8) S8(S) ~ MgS(s) t.H = -82.2
Due to incomplete octet.
8. [5]
Z2
36'1
Mg(g)
1
S(g)
1332
LE
IE = 13.6 x -2 eV
n
Z = 4 , so th IS·IS B e 3+
· 520.~
Atomic mass of Be is 5. Mg2+(g)
9. [I]
rcovalent = rA + rB - 7 (t.X)2
= 100 + 50 -7 x (1.9)2pm
= 1.25 A
10. [6] 36.5 + 133.2 + 520.6 -72.4 + LE = - 82.2
Energy of e- ej ected from He + ion or LE = - 82.2 + 72.4 - 36.5 - 133.2 - 520.6
= Ep - I.E. He+ or LE = - 700.1 kcallmol.
= (67.15 - 54.4) eV = 12.75 eV :. energy released due to formation of lattice
Let e- of H-atom goes to nth orbit after being :: 700 kcallmol
stroken by e- ofHe+ ion then
13. [B]
12.75=En- E ,
2s orbital
= -13.6 x n12 + 13.6 = 13.6 ( 1- n12 ) No. of radial node = n - e- I = 2 - 0- I = I
=> 1 __1 = 12.75 14. [C)

n 2 13.60 For He+ ion
He+ = Is' it has non directional characteristics
=> _1 = I _ 1275 =~
n2 1360 1360 15. [A]
=> n2 = 1360 = 16=>n=4 For Is orbital
85 There is no radial node
So no. of diff. spectral line obtained by H-atom 3/ 2 Zr
n(n - 1) = 4 x 3 = 6 So 'I' function will be 'I' n I

, ,moc ( !:..
a ) e-;;:-
2 2 o
E2 4 27
11. [5] Energy -....:::!.- =-
E 2-+ 6 32
v = 2.18 x 106 x Z mlsec 16. [0]
4
Theory based
=> 2.725 x 106 = 2.18 x 106 x Z
4
17. [0]
=>Z=5
Theory based
12. [7]
18. [0]
Theory based
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1. [B)
It is not true direction of overlapping because 6. [C)
overlapping occur's in only e-. IP, => Li Be B C
,j, ,j, ,j,
,j,
2. [D) IP2 => He Li Be >B
l
H 2S is more acidic than H 20. It is due to the fact I IPt I
than H-S bond is weaker than H-O bond. : . so Li > B > C > Be
7. [C)
3. [C)
Suppose the no. of electrons in ion = x Force = kq,Q2 => F oc ~
r2 r2
. . 30.4
no. 0 f neutrons Ion = x + - - x x
III and .: roc n2
100
I
= x + 0.304x : . F oc 4
n
= 1.304x
Number of electrons in neutral atom = x + 3 8. [B,D)
..
Number of protons in neutral atom = x + 3 SnCh ~ Sp2 hybridisation /Sn"
Mass number = P + x Cl CI
Bent
56 = x + 3 + 1.304 x (0)
53 = 2.304 x N
·N02~ / ~
53 o 0 Bent
x= - - =23 Rest are linear.
2.304
no. of protons = 23 + 3 = 26 => ~~Fe+3 9. [B,C)
(SiH 3)3 N lone paire electron participate in back

4. [C) donation.
Atomic number of fluorine = 9. 10. [e,D)
M+2 = Is2 2S2 2p6 3s2 3p6 3d3
5. [D) :. M = Is2 2S2 2p6 3s2 3p6 3d3 4s 2
A=~I~O
For d-blockgroup no. = no. ofe-in 3d + no. ofe- 4s
=3+2=5
or A.JV = constant
11. [A,B,C)
5
.JVdA+ ~dV=O 24Cr = [Ar]'8 3d 4s' (exceptional configuration)
2"V 'm' can have values from - € to +€
dA 1 dV 'Ag' ~ [Kr]36 4d'o 5s'
--=--
A 2 V
,j, ,j,
I dV
18 ~ +112 S = +112
100 2 V
18 ~ -112 S = - 112
dV 2
V 100
or % increase in V = 2%
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12. [A, D)
E3 = EI + E2 => hV3 = hVI + hV2
he he he AIA 2
- = -+ - =>A3=---'--=-
A3 AI A2 AI +A 2
13. [A,B,D)
fact
14. [A,B,C)
nh
mvr= -
21t
D is not correct
15. [A)
tlE 3.... 2 = E3 -E2 3.4-1.5 1.9
tlE 3.... 1 E3 - EI 13.6 -1.5 12.1
16. [B)
I he he
he - = - + -
A AI A2
17. [B)
I -; Size of'P' < Size of 'AI'
II -; Size of 'As' < Size of 'Ga'
m -; Size of'P' < Size of 'As'
IV -; Size of 'AI' ~ Size of 'Ga'
18. [A)
Order ofIE I -; P > As > Ga > Al
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Unit Test-2
Hints &Solutions~
1. [A,B,C) S. [A, D]
V strength = 56; Mass of I mole CO 2 = 44 gm
28 I
:. M= - =2.5 1 gm = u
11.2 1.67 x 10-24
:. 1 contain 2.5 moles ofH 20 2
or 2.5 x 34 = 85 g H 20 2 = 100 x 10 24x44 u
167
wt. of I litre solutin = 265 g (.: d = 265 giL)
:. wH,o = 180g or moles of H 20 = 10 = 4400 x 10 24 u
167
x = 2.5 = 0.2 = 2.65 x 1025 u
HP, 2.5+ 10
% w = 2.5 x 34 x 100 = 8.5 6. [A,B,C,D]
v 1000
m = 2.4 x 1000 = 13.88
+IC_H
~ -~
H-C-DH ~
+3C-D-
180
(A) +36-DH ~ +36_0 + I
+3C-D-
2. [B,C,D] II II
o II
3Sn2++ 14W + crO~- --+ 3Sn3+ + 2c?+ + 7H20 0 o
2 -3 -1 / 2
(B) P2 H 4 ~ PH 3 + P4H 2
3. [B,C)
16 o +1-3
no = - =0.5N A no. of molecules (C) P4 + NaOH ~ NaH 2P0 2 + PH 3
, 32
o -I +5
(D) CaOCI 2 ~ CaCI 2 + Ca(Ce0 3)2
16
n = -=0.33 atoms = 0.5 x 2NA
0, 48
no. of molecules of
0 3 = 0.33 NA = 0.99 NAatom
4. [A,B,C)
CS 2 + 3Ch --+ CCI 4 + S2Ci 2
1 2
74 71 x3
1 2 :. H 2S04 can be between 1.44 mole to 5.76 mole
74 213
before = 0.0135 0.0093 8. [4]
reaction (Limiting reagent) Initial moles ofNH3 = 0.38 moles
0.0135 - .0093 0.0093 x 154
Moles ofNH3 remaining after completation
0.0042 x 74 = 1.45 gm CCI 4
= (0.38 - 0.025x)
formed
Moles of NH 3 in water = 24
MoiesofNH3 inCHCI 3
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. . Moles ofNH3 in CHCI 3 N 2H4 -+ Y + lOe-
2X +4=0
= MoiesofNH3 in water = 0.0112
X=-2
24
.: two nitrogen atoms losses = 10 e-
.. 0.38 - 0.025 x = 0.0112 x 24 + 0.0112
: . I nitrogen atoms losses = 5e-
= 0.0112 x 25 N"2 -+ N+3
.. 0.025 x = 0.38 - 0.0112 x 25
= 0.38 - 0.28 = 0.1 12. [8]
0.1 12
orx=--=4 27= - x l8
0.D25 x
x= 12 x 18=8
9. [5]
0.,.
27
No. ofm equ. OfNa2C03 in 80 ml of resulting
. 42.4 13. [B]
so IutlOn = - x 30 - 0.4 x 50
53 Theory based
=4
No. ofm equ ofNa2C0 3 in 10 ml of above 14. [A]
Theory based
solution = 0.5
No. ofm equ in 50 ml of diluted solution 15. [B]
=0.05
So 0.05 = Normality of 40 times diluted A x V Theory based
~ 0.05 = 0.4 x V ~ V = 5 rnL 16. [C]

40
Theory based
10. [2]
17. [B]
0.7 I I
2x =5 x I9.8 x - x - -
106 + 18x 10 1000 Theory based
On solving, we get
18. [C]
x=2
Theory based
11. [3]
1. [C]
Structure of H2S 20 g is 2. [D]
~ ~
+ 2+
MnO:; + 8H + 5e- -+ Mn + 4 H20] x 2
H-O-S-O-O-S-O-H
C20~- -+ 2C0 2 + 2e-] x 5
~ ~
It contains peroxide linkage for which oxidation
number of these two O-atoms will be -I each 2+
2 Mn + 10 CO 2 + 8 H20
:. 2 x (+I)+2x+6 x (-2)+2 x (-1)=0
Thus, the coefficient of oxalate ion C20~- is 5.
or 2 + 2x - 12 - 2 = 0 or x = + 6
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3. [DJ 10. [B, C)
Only in reaction (d), the O.N. of the elements CH,COOH + C2HsOH -+ CH3COOC2H5+ H20
undergo a change 72 grn 2.77 x 1025 x 1.67 x I 0-24
+1- 2 +2 0 0 +4
Cu 2S+ 2FeO --+ 2Cu+ 2 Fe+S02 72 = 2.77 x 1.67 x 10
60
i.e. O.N. of Cu decreases from + 1 to 0 and that of
Fe decreases from +2 to 0 while that of S increases 1.2 2.77 x 16.7 = 1.005
46
from -2 to +4. Therefore, it is a redox reaction.
alcohol is limiting reagent
4. [C) acetic acid is excess reagent
Blackness appears in lead paintings due to its slow
and gradual conversion to PbS. H 20 2 oxidises 11. [A, C)
black lead sulphate to white lead sulphate. CaC03 --+ CaO + CO 2
100 gm
5. [C)
:. 100 gm --+ = 56 gm
Sodium hexameta phosphate
56
:.90 gm-+ = -x90
6. [C) 100
Ca(OHh removes soluble bicarbonates in the form = 50.40 gm
of insoluble CaC0 3. or 0.9 gm molecule
7. [C) 12. [A,C)

Factual. Xe 67.2 67.2 = 0.512
131
8. [A,B,DJ o 32.8 32.8 = 2.05 4
M1V 1 +MN2=MV 16
Xe04 or Xe20 g
I x 100+ IOx98xO.1 x 100=M x 200
98 13. [C, DJ
M= 1 Since the molecular mass of N2 & CO is 28 and
M = I x 98 x 200 = W N 20 & C02 is 44 so both have no. of molecules in
1000 44 28
one gram = - &-
W = 19.6 NA NA
9. [A,C) 14. [A,B,C)

M= 10xwt%xd
NaCI) mol.wt.
c£. ~l
+ 4.44 grn
CaCI2
CaCI 2 ~ CaC0 3 -+ CaO
M~
Illgm 56gm
Only ppm can not be calculate
.. 56 gm CaO req. = III gm CaCI 2
III
.. 1.12 grn ofCaO req. = - x 1.12 = 2.22 grn 15. [AJ
56
Meq. OfKl03= Meq. ofKl 215++ lOe -+ I~
2.22
% CaCI 2 = - - x 100 = 2.22 gm
4.44 M x 5 x 50 = lO x 0.1 x I 2r --+ I~ + 2e
=50% :. M=4 x 10-3
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16. [A)
Meq. of ascorbic acid in 50 mL solution mixture
withHCI
= Meq. ofKI0 3 (Is+ + 6e ~ 1)
3
= 4 x 10- x 6 x I = 0.024
Meq. of ascorbic acid in 500 mL
= 0.24 meq. in 250 ml
mixture of original solution
:. N x 1000 = 0.96
or N = 9.6 x 10-4
.. M= 9.6xl0-4 4.8 x 10-4

2
Strength = 4.8 x 10-4 x 176 = 0.0845 gliitre
17. [B)
Meq. ofCuS04 in 100 mL = 100 x 0.02 = 2
2x249.6 = 0.499
.. Wcuso, = 1000 g
.. WCu = 0.499x63.6 =0.127g

249.6
0.127
:. % ofCu= - - x 100 = 5.08
2.5
18. [B)
10 x O.02 -4
Eq. 12 = Eq. ofCuS04 = = 2 x 10
1000
.. ~=2xlO-4
254 / 2
:. WI, = 0.0254 g
Chemistry
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Unit Test-3
Hints &Solutions
1. [D] For the acids and it's conjugate base
KaKb = 10- 14
Kc= [H 2 ][I 2 ] = 4x4 =4 I Ox 10- 14
[HI]2 22 Hence Ka for HCN = ' 5 = 5 x 10- 10
2x10-
2HI ~ H2 + 12
2+2x (4+a-x) 4-x (H30+] = (CN"] = ~KaC = ~5xI0-1O x 0.1
(4-x)=2+2x = 7 x 10-6
x = 2/3
2. [A,C] 9. [9]
H 20( e) ~ H 20(g) Ksp Mg(OHh = [Mg+2] [OHl 2
If pressure is increased 10- 11 = [.I] [OIrf
equilibrium shift in backward [OIr]2 = 10- 10
so more H 20(e) formed and b.p. increased pOH=5
pH+pOH=14
3. [A,C, D]
On conversion of ice into water pH= 14-5=9
Solid ~ liquid
Entropy increases. 10. [5]
free energy decrease due to which process is We have
spontaneous. [Salt]
pH=-logK + log - -
4. [A,H,C] a [Acid]
Because size of cation increases. 0.2 x 1000
5. [A,B] 5 100
=-log2x 10- + log O.lxIOOO
When hydration energy of compound is more
than its lattice energy then only it is soluble 100
=4.7 + 0.3 = 5
6. [C]
F 11. [2]
BF
I
B >
fJ_ F > (b CI-F
/p,
I
(OJ
NH 40H
I
~
0
3/",
F F
F 'F \YIF c(1-a) ca ca
Given pH = 11
7. [A,B,C,D] :. [H+] = 10- 11
factual [~Irl = 10-3 = ca
Since, c = 0.05
8. [7]
10-3 10-3 -2
NaCN + HCI------t HCN + NaCI :. a=-=-=2xI0 or 2%
c 0.05
[HCN] = 0.2x50 = 0.1 M
100
HCN + H 20 ~H30+ + CN-
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12. [2J 13. [OJ
CH, COOH + C,H,OH ~ CH, coo C,H, + H,O By Theory
Initially: O. I mol 0.1 mol o o 14. [OJ
At equilibrium : (0.1 - xl mol (0.1 - xl mol x x
By Theory
In 10 mI solution at equilibrium moles of 15. [OJ
CH3COOH present=O.1 (0.1- x)=O.1 (O.l-x) By Theory
moles ofNaOH
:. 0.1 (O.l-x) = 80 x 10-4 = 8 x 10- 3 16. [OJ
or 0.01-0.lx=0.008 By Theory
or x = 0.02
17. [C)
x2 (0.02)2
Kc = -----,;-
(0.I-x)2
1
= 32 Kc = 32 x - = 2
16
(0.08)2 = 42 =16
By Theory
18. [OJ
By Theory
0.,.
1. [OJ : . order of solubility
(Na + Hg) => Sodium amalgam. S2 > Sl > S3
due to amalgam decrease the rate of reaction. AX > A2X > AX3
2. [AJ 7. [BJ
T LiOH < NaOH < KOH < RbOH < CsOH ) B CO + H20 ~C02 + H2
so lub ilityt Initial conc. 3 3 x 0
3. [C) At eqn. 2 2 (x + 1) 1
(i) Mg3N2+ 6H 20 ~ 3Mg(OH)2 + 2NH3(A) ( X +1)
5 = - - = 20 = x + 1
(ii) AIN + 3H20 ~ AI(OHh+ NH3(B) 4
(iii) Na202 + 2H 20 ~ 2NaOH + H20 2(C) => x = 19
4. [C) 8. [A, B, C, OJ
Correct order of stability is Due to smaller size BeH2 & MgH2 are covalent.
BeS04 > MgS04 > CaS04> SrS04 For stability BeH2 containts 3 centre 2e bond.
Down the group solubility of sulphates of
alkaline earth metal decreases. 9. [A,B,C,DJ
5. [AJ K hydr = Kw or log K hydr = log Kw + pKb
M + (x + y) NH3 ~ M+ (NH 3)x + e- (NH3)Y Kb
Ammoniated Ammoniated or pK hydr = pKw - pKb
cation electron or pKhydr = 14 - pKb
Blue colour due to ammoniated electron.
Smaller Kb for the base, greater is pKb value
6. [OJ hence smaller will be the pKhydr and hence extent
A2X ~ 2A+ + X- of hydrolysis increases.
2s l Sl Hydrolysis of Fe3+ is more acidic, hence pKb is
AX~A++X- Ksp -- S22 higher, therefore, for Fe 3+ pK hydr is greater than
S2 S2
AX3 ~A+3 + 3:A that ofFe2+.
S3 3S3 Hydrolysis of Ba2+is more basic, therefore pKb is
smaller, hence pK hydr is higher.
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10. [B,D) 14. [A,C,D)
2 K 10- 14
HA~H+ +A- Ca
Ka=-- ForNaA Kh = ~= _ _ =10-6
, K. 10-8
(I-a)
CCI-a) Ca Ca K 10- 14
ForNaB K h = ~= _ _ =10-8
.
Smcea«I,hencea= ~Ka
C = JKa
JC
, K. 10-6
Kw 10- 14 10 ~
ForNaC,Kh= - 2 8
A-+H20~ HA+Olf" K. 2x10-
Excess ofHA present in the system reduces the K 10- 14
ForNaD K h = ~= _ _ =10-4
hydrolysis ofHA. , K. 1010-
For isohydric solution of two weak acid initial
K 10- 14
concentration of H+ must be equal. ForNaE K h = ~= _ _ =1O-7
, K. 10-7
11. [A,B) Since Kh ofNaD is the highest, therefore, NaD is
Ksp(MnS) = 5.6 x 10- 16 = [Mn2+] [S-2] most extensively hydrolysed
I
~ [S-2] = 5.6 x 10- 14 (For precipitation ofMnS) ForNaBpH= -(pKw+pK.+logC)
Now [H+]2 [S-2] = 1.0 x 10-22 2
I I
+ 10-22 or pH = - (14 + 6 + log - )
~[H]- .J--~ 2 10
14
5.6x 10- I I
="2 (20-1)= "2x19
=4.2 x IO-S M
~ pH = 5 - log 4.2 = 5 - 0.6232 = 4.38 orpH =9.5
For isohydric solution, Kal C I = Ka2C 2
10-22 .: 10-7 x 0.1 = 10-6 x 0.0 I = 10-8
At this pH, [Zn 2+] =
9
14 = 1.8 x 10- M
5.6 x 10- Hence, O.I(M) HE is isohydric to O.OI(M) HB
Now Ksp(CdS) < Ksp(ZnS) < Ksp(MnS) So ease solution
of precipitation of ions is in order of
15. [C)
Cd 2+ > Zn 2+ > Mn2+ .
For A-: log Keq = 21.2 - 14.7 = 7
Again higher [Hj i.e. lower [S-2] ion concentration
ForB-:logK eq =9.2-15.2=- 6
Cd2+ is most easily precipitated so it needs least
[S-2] conc. hence maximum [Hj so order of For C- : log Keq = 1.2 - 3.2 = - 2
required [Hj conc. is Mn2+< Zn2+< Cd2+ 16. [Bt
[H ] = [OIr] = 10-7 only at T = 298 K on
changing temperature Kw changes so conc of H+
12. [A,B)
& OIr also changes.
HIn ---..:::::.. In- + H+
~ 17. [C)
Red blue
a2
H = pK + log [In-] K = Increase 10 pressure will
P c V(I- a)
In [HIn]
decrease volume. To have Kc constant a i.e.
(A) pH = (5-log 3) + log (~~) degree of dissociation of PC Is should decrease.
18. [A)
=4.05 An increase in temperature will favour backward
reaction (endothermic). Also
(B) pH = pKln + log G~) Kc for 2S0 2 + O 2 ~ S03 will
= 5 - log 3 + log 3 = 5 2.303 log K c, = t.H [T2 - TI]
KCI R TIT2
13. [C, D) t.H = -ve
On decreasing the conc. of H2 Qc < Kc so eqm
shifting forward and on adding CO in eqm it
shifts in forward direction.
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Unit Test-4
Hints &Solutions~
1. [A,C,D) (B) From expression of Maxwell distribution
fraction of molecules between V mps ---+ V mps + f
~G=RT In P2
PI V mps is independent of value of V mps and is
dependent only on!
2
= 8.314 x 298 x 2.303 log - (C) T2 is higher temperature
1 (D) As seen from graph, :. A, B, D
P2
~S=-Rln- <0
PI 6. [A,B,D)
PT = (1 + 3 x) = 1 + 3 x 0.1 = 1.3 atm
2. [A,B,C) ~P = 0.2 atm or 76 x 0.3 cm ofHg
U rms= or 760 x 0.3 mm ofHg.
.---~----~--~~----~----~
lOx (40)2 +8x(45)2 +15x(50j2 +10x(55j2 +12x(60j2 7. [A,B,C,D)

55 Work done in piston (I) = PI VI
16000+ 16,200 + 37,500+ 30,250 + 43,200 Work done in piston (II) = - P2V2
Vrms=
55 ~W= PSI -P2V2
Vrms= 51.01 kms/hr. Since system is completely thermally insulated,
V.vg hence ~q = 0
IOx40 +8x45 + 15 x50+ lOx 55+ 12x 60
:. ~E=~W=PIVI -P 2 V2 *,0
55
or E2 - EI = PI VI- P2 V2
V.vg = 50.54 lans/hr.
:. V.vg
Vrms
*' rs
~J;
or E2 + P2V2 = EI + PI VI or H2 = HI
Thus entire process is isoenthalpic process
8 (2)
3. [A,B,C,D)
Number of moles ofN 2 in vessel
PV= ~RT
M (A) at TI = 2.8 = 0.1
2.8
Number of moles oflzin
4. [A,B,C,D)
At the point of maximum value ofRDF Vessel (A) at TI = 12.7 = 0.05
254
dP =0
dr
2zr2) a
( 2r-~ =0; r= ~
where Z = 3 for Li2+ and Z = 2 for the He + ; A B
Z = 1 for hydrogen Vessel (A) is heated to T2 the evacuated vessel
(B) is heated to T2/3. On opening stop-cock lz
S. [A,B,D) sublimes in (A) and its vapours condense to solid
(A) .: area under the curve gives fraction of lz in (B). Let the number of moles ofN2 moved
molecules and total area is constant from (A) to (B) at equilibrium be x.
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Pressure ofN 2 in (A) = Pressure ofN 2 in (B) 1 mole 12 mole t.H =-3690 J/mole By 12 moles
(0.1 - x)RT2 xRT2 of O 2, heat liberated = -3690 J
V 3V => By 29.27 moles of O 2, heat liberated
One solving, x = 0.075 = 29.27 x (-3690) J
: . Mass ofN 2 is vessel (A) = 0.7g 12
Mass ofN 2 in vessel (B) = 2.lg 12 (9)
0.1 I mol
At 2 atm pressure, ro = - x - - .
9 (5) , 32 50 mm
No. of moles of gas molecules present
In lInd case, Po, = 6 atm and Px = 4 atm
10 23 I
,0.1 I 3 mol
6 x lO 23 -"6 At 6 atm pressure, r 0 = - x _ x - .
23 , 32 50 mm
Mol wt. of gas = 6 x 10 x 10- 22 = 60
~3~T ..2..- = ~Mo, x ~

or Urms = r o, Mx Po,
u~
3RT
or
rx [32 4 4 2
M ~ xJ... x3 = V162 x "6 =9" x "3
Mu~s 32 50
or RT 4 2 0.1 I mol
3 or rx = - x - x - x - x3 - .
Mu~ 9 3 32 50 mm
Per mol KE = ~2 RT = 3 x
I
, 2 3 2 = ~ x ~ x ~ x J... x 3 x 162 gm
Mu~ 9 3 32 50 min
I I 2 I 8 0.1 I
:. for - mol, total KE = - x M x U nns x - or rx = - x - x - x 3 x 162
6 2 6 27 32 50
I 10 I 3
= - x 60 x 10 x - Arg = 5 x 10 J = 5 kJ = 0.3 x 3 gm
2 6 100 min
10 (5) :. in 100 mins, wt ofx gas effused out
t.WA-+B=-10J = 0.9 gm = 900 mg
t.WAB = Pt.V; t.W BC = 0 = 9000J = 9 KJ
t.q = t.E - t.W 2
= 8.314 x 298 x 2.303 log -
t.E=O I
t.q=5=0-t.W
t.W = - 5J = t.W A-+ B+ t. W B-+ C + t.W C-+ A
or - 5 J = - 10+ 0 + t.W C-+ A
13. [D)
t.WC-> A= 5 J
By theory
11 (9) 14. [C)

Amount of O 2 taken per day By theory
15. [D)
= 500 x ~ x 20 x 60 x 24 ml
By theory
100
= 720 litre 16. [D)
PV By theory
No. of moles of O 2 taken/day = -
RT 17. [D)
I x 720 = 29.27 By theory
0.082 x 300 18. [D)
CI2H22011 (s) + 12 O2 (g) --+ 12 CO2(g) + l1H20( e) By theory
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1. [C]
W =-PliV
=-rrr2
r = _P2_-_P_1 = _V,,---2-_V--,-I
2 2 7. [B)
PV PV PV
2. [B) 111 = RT 112= 2RT 113 4RT
v
liS = nR In _2 = 2.303 nR log-2
V
( nl+n2+n3····)RT
VI VI A Iso fiIIId pressure = -'--'---=------"---'---
V
= 2.303 x 5 mol x (8.314 JK- I mol-I) log 100L
10L =P (1+~+~+i+ ... .)
= 95.7 JK- I
3. [B)
=P (1+.!.+~+~+
2 2 2
....)
liS A-> c = Sc - SA = 50 e.u. . .. (i)
liSC->D = SD- Sc = 30 e.u. . .. (ii)
liS B-> D = SD - SB = 20 e.u. . .. (iii) =P [_II]=2P
liS A-> B= SB- SA 1- -
2
eq (i) + eq (ii) - eq. (iii)
= 50 + 30-20
=60 eu 8. [A,B,C]
liu = Q + w ~ nCv liT = 0 + W (In adiabatic
4. [A) process Q = 0)
Plot given in Figure 'a' gives variation of z vs. P. ... ..(i)
{Since C v = ~}
5. [B) y-l
..... (ii)
P = Poe
-kt 228
P = - + 76 = 152cmHg Againw=-nCv (TI-T2)=-nCV [1- ~~ ]TI
. o 3
. ll4 p j(Y-ll/Y]
Att= 14 mill; P = -+76 =1l4cmHg ~w=-nCvTI 1- ( p~
r
3 [
~ 152e-kt = ll4
[1-(~~
Cp
1 152 1
~ k= -€n-=-xO.28 =-nCvTI ] .... (iii)
t ll4 14
= 0.02 x 60hr- 1 = l.2 hr-I
9. [A,C,D)
6. [C] Qp = Qv + PliV = Qv+ P(Vv- VI)
= Qv + nRT (": V v< < VI)
Compressibility factor Z = PV
RT Qp = 2260 x 18 x 10 = 406.8 kJ
Qv =Qp-nRT=406.8-lO x 8.314x W- 3 x373
From the given equation (p + ~2 ) V = RT = 375.8 kJ
~ =RTorPV= (RT- ~)
liS = 406800 = 1091 Jik
orPV+ 373
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10. [A,B,C] 18. [D)
by theory Along path BA,
~E = -52 k.J and ~W=21 k.J
11. [A,B)
: . ~q=~ E -~W=-52-21=-73k.J
~G ;98 =-92+298 x 198 x 1O- 3 = - 33KJ
~Go = -2.303 x 8.314 x 298 x 10-3 log Kp
- 33
~ 10gKp= = 5.78
- 2.303 x 8.314 x 298 x 10- 3
~ Kp = 6.03 x 105
optimum condition for high yield is high pressure
and low temperature (- 700K)
12. [A,C]
K > 103 ~Ptotal=Po , =10
P J
& ~ = 10 ~ Po = 10- 3 atm
Po'J J
13. [C,D)
AtV A = IxR x 100 = 100R
1
VB = I x R x 600 = 200 R
3
-: VB > V A so expansion of gas takes place
VB = 200 x 0.0821 = 16.42 L.
14. [A,B,C]
~H = ~U + P.~V + v.~P + ~P . ~V
is correct relation.
15. [A)
V/3
Pe = nCt
1 x eO= 3x C x 300
C = -1= l . l x IO- 3 •
900
16. [B)
3
Slop = ~= nC = 3x 1.l x lO-
T e V /3 e2/ 3
3.3x 10- 3
e I
3.3
IOOOe
17. [A)
Along path ACB,
~q = 84 k.J and ~ W = -32 k.J
~E = ~q + ~ W = 84 - 32 = 52 k.J
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Unit Test-S
Hints &Solutions
1. [C,D) 6. [B,C,D)
[C] Both have same IUPAC name Me,,-~
....-'C = C
=o<Me ~ pos present
3-ethyl-2,5,6-trimethyl-4-[ methyl propyl] Ph...- Ph
heptane ~ Optically inactive & not resolvable
[D] Both have same IUPAC name B,C,D in all there is no syrnrn. Element and
4-arnino-2-chloro methl-3-fluoromethyl bulan-I-ol resolvable & optically active
2. [A,B) 7.
A & B both have same IUPAC name as given in
question.
3. [B,C,D)
CH3 Cl
Cl~CH3& ):d
~ Both are positional isomer of each other
~H
4. [A,B,C)
HO CliO H
I I I I
H3C-C-C-OH H3C-C-C-CH 2-CH 3 H3C-C-CH:rCH3
I I I I N0 2
OH J-[H Cl
(A) (B) (C)
L Meso nL possible ....

, _--,-_-,I 8. (3)
C are incorrect
!
For meso chiral centre &
Example where SIR is possible
syrnm. both are essential Me'N/Me COOH COOH
[D] sym. & chiral centre both present ~ so meso Me~Me ~CH3 ~Cl
5.
form possible
[A,C,D)
LQJ 'LQJ 'LQJ
Me Me 9. (3)
H~$~H E~:::e) H~$~H

n ~ complete imaginary number
Total no. of electron participating III outer
HO H HO H periphery is = 14 e-
HO Me H OH so if value ofn = 3
then (4 x 3)+2= I4e-
H Me
~ sym. present [POS] ~ optically inactive 10. (3)
Remaining all does not have any syrnrn. Element 6) 6)
& optically active (I)CH 3-C=0<CH3 -C",O (correct)
$ 0 0 0
(II) CH 2 = N = N > CH 2 - N '" N (correct)
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W=>7[6
=2-3-4+7=>2
13. [D]
Theory Based
14. [A]
Theory Based
11. [2] 15. [D]
S03H Theory Based
HO-o--t-COOH -+ only-S03H and 16. [C]
Theory Based
C",CH 17. [B]
-COOH group react with NaHC0 3 so only 2 Theory Based
equivalent of NaHC0 3 is used or (2) acidic
hydrogen is removed 18. [D]
Theory Based
12. [2]
X=>2
V=> 3
r~-co'"
l~ 00
"'-CO:?'I~::,..::,..~
b'lCXO
1. [D]
(4-ethyl pent-4-en-2-amine) •
(3-methylbutan2-01)
5. [D]
4. [C]
Due to opposite configuration I and II
compounds are enantiomer but. Due to different
structures I and II are structural isomers.
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6. [OJ
When benzene react with Ch in presence of
sunlight, gives benzene-hexachloride by free
radical addition reaction, not benzyl chl oride.
O
~
..v
+ 3CI, h' , CI A
C1 V CI
CI
CI 11. [A]
CH r CHrCH 3 } No lone pair least basic
CHrCHrSH} sizet B.S. ,J..
CH 3- CH 2- OH} E.N. t B.S . .J,.
'
(C 6II 6CI 6)
CH r CH 2- NH 2 Size same
7. [BI
2' 3' 4'
(I H,-CH,-C- CH3
- - II
o
2-(3' oxobutyl) cyclohexan -I-one
12. [0]
+ I,J.. ofCH 3
E9 +
(CH 3h-C > (CH 3)2 CH > CHr CH 2 > CH3
+ +
Stability ,J..
8. [B,C,DJ 13. [B,C]
For
CH 3 ....... EB /CH 3
(A) C I Jl = 0 so cis is more soluble in water
6H II Jl '" 0 so more polar in nature
is more stable due to the more stabilizing
14. [A,B,C]
resonance structure
3 2 '
(B) 2nd is more acidic due to vacant d-orbital CH 3- CH 2-CH 2-pH
resonance. A & B is W.r.t. to C, - C 2
(C) Cl .......C ({CI C is W.r.t. to C 2 - C3
I D is not possible because it takes carbon.
CI
is more stable due to involvement of vacant d 15. [C]
(D) In 0
orbital of chlorine with carbon anion
pyrole lone pair is part of aromatic
St. order => chair form > twist boat > Boat > Half chair
energy order => Half chair(B) > Boat (D) > twist
Boat(C) > Chair (A)
~ 16. [C]
H Twist boat form is optically active
sextet. So it is least basic
17. [A]
~ _~1~3
9. [A,B,C,D]
..j_.i·_/"-5
_ -_ -_ - OH => Bicyclo [3.1.1] heptan-2-ol
I 2
18. [B]
10. [A,C,D]
UCH'< QM' Me
2
5-[2,'4'-dihydroxy cyclobutyl] Bicyclo [4.3 .0]
non-7-ene
Chemistry
Revision Test-l
Hints &Solutions~
1. [B,C,D] 4. [B,C,D]
st
1 excitation energy 3 -
[Constant temperature,
24 = 13.6 (~ __
I ) Z2 -+ For a perfect gas U is independent of volume.
12 22
-+ In case of attraction (real gases) U increases
=> Z2 = 2.3529 and z = 1.5339
with volume as molecules on an average go apart
I.E. = 13.6 x Z2 = 32 eV
z2 -+ If repulsions are dominant the internal energy
B.E.=-E4=13.6 x - eV=2eV decreases with isothermal expansion of the gas.
16
nd
2 excitation energy 5. [A,C]
= 13.6 z2 C~ -312 )
K>10 3 =>Ptotal=Po 2 =10
Po'
& - ' = 10 => Po = 10-3 atrn
8 32x8 Po', '
=32 x - eV= - - e V
9 9
Excitation energy = Excitation potential 6. [B,D]
..
= 32x8 Volt SnCI2 -+ Sp2 hybridisation /Sn"
9 CI CI
2. [A,B] Bent
o
Atom may be He+ or LiH N
·N0 2 -+ ,/ ~
If no of photons absorbed = no. of photons emitted o 0 Bent
then excited state of ions is 1st excited state. Rest are linear.
So energy absorbed by 7. [B,C]
He+ = 13 6 x. i = (~- _I
e22 ) = 40 .80 V (SiH 3)3 N lone paire electron participate in back
donation.
energy absorbed by
8. [7]
Li 2+= 13 6x 3 2 (~ __I )= 918 eV NaCN + HCI ~ HCN + NaCl
. 12 22 .
[HCN] = 0.2x50 = 0.1 M
3. [A,B] 100
Z2 HCN + H 20 ~ H30+ + CN-
B.E. = 13.6 x 2""
4
For the acids and it's conjugate base
=> Z2 = ~ x B.E = ~ x 13.6 => z = 4 KaKb = 10- 14
13.6 13.6 14
HenceKa forHCN= 1.0x10- =5x 10- 10
I.E. from 2 nd excited state 2x10- 5
z2 42 (H30+j = (CNl = ~KaC = ~r-5x-I-0--IO-x-0-.1

= 13.6 x 2"" = 13.6 x -2 eV
3 3 = 7 x 10-6
=24.178eV
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9. [91 12. [61
Ksp Mg(OH)z = [Mg+2] [OHl 2
10- 11 = [.1] [OIr]2 dx =2d mx=m P1 = ~xRT
ml
[OIr]2 = 10- 10
pOH=5 my= 3 m P2 =~RT
pH+pOH=14 m2
pH= 14-5=9 .!L = ~ x m 2 = 2d x 3m = 6
P2 ml d2 m d
10. [51
We have
13. [DI
[Salt] J\s per theory
pH=-logK + log - -
a [J\cid]
14. [C)
0.,.
0.2 x 1000
J\s per theory
= - log 2 x 10- 5 + log 0.1 ~010000 15. [DI
100 J\s per theory
=4.7+0.3=5
16. [DI
11. [71 J\s per theory
2S0 2 + O2 -+ 2S0 3 17. [BI
total 4 4 0 J\s per theory
at eqrn 4-2 4-4 xO.2 2
18. [DI
=2 =3 2
J\s per theory
Total moles 2 + 3 + 2 = 7
6. [AI
1. [BI EA, in general increases along the period from
180 left to right but Ar being a noble gas has stable
w = mgh' 58.8 x - -
, 2870 configuration and bence possess zero electron affinity.
2. [BI 7. 101
2 1
-400x-+400x-
N= 200 50
400 + 400 + 200
= [OH-] =4 x 10- 3 pH = 3 - 0.6 = 2.4
3. [BI
!1W =- 105 x (0.15 - 0.3) kJ = + 15.75 kJ
!1q =-37.6kJ 8. [C,DI
o 0-
:. !1E=!1W+!1q=-37.6+ 15.75=-21.85kJ H----e7 +-+ H- c.' B 0 = 2+1= 15
4. [DI
'0- """0" 2 .
~lJ- bJJ- bJ~' ,

Na < K < Rb : is the correct order of reducing
character.
5. [DI
The IE does not increase regularly. The elements 8.0. = 2+1+1 ~ = 1.33
Be, N have exceptionally high IOmzation 3 3
energies due to their stable electronic C-O bond length in HCOO- is less than c-o
configurations. bond length in cOj-
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9. [A,C)
~~ J No. of cr bond, in [BF.r =4
B.O. ofNO+ = 3.0, i.e., one sigma bond and

14. [B,C)
The process is
C6H6(1, 80°C, I atm) ~ C~6 (g, 80°, I atm)
~ C6H6 (g, 80°C, 0.5 atm)
two 1t bonds P
~G, = 0, ~GII = nRT In ~
No. of 1t bodns = 2 Pj
No. of cr bonds = 5
= 3 x 2 x 353 x 2.303 log 0.5
=> B.O. ofNO+ = 3.0 1
and B.O. of NO = 2.5 =- 0.49 kcal
=> NO+ is diamagnetic and SF" is also
diamagnetic
=> B-F bonds are longer in SF4- than in BF)
due to absence of p1t-p1t back bonding in
[BF4J
10. [B,C,D) 16. [B)
11. [A,C,D) C6H,-CH=CH-CH=CH-CH=CH-C00H
For aromatic (4n + 2) 1t e- should be present n=3
For antiaromatic 4 n1t e- should be present R, ",R2
For nonaromatic compounds should be non No. ofGI = 2) = 8
planar
17. [A)
12. [A,B,D) K, Rb, Cs forms stable superoxides.
Only CH 2=CH-OCH) show resonance
o $ ..
18. [D)
CH 2-CH=q-CH) B CH 2=CH- q-CH)
All ions get hydrolysed easily
13. [A,C)
.. $ $
CH)- ~-CH 2 BCHr S =CH 2
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Unit Test-6
Hints &Solutions~
1. [A,B,C) 4. [B, C, D]
(A)Na+ present in octahedral void have six cr (A) For different solution Krrnay be different.
around
(B) cr have 6Na+ at it edge 5. [C,D]
(C) second nearest nighbour ofNa+ ion are twelve (C) O.P. of more concentrated solution is move.
Na+ ion at distance Jz (4 body center, 8 edge

(D) Water flow from low conc to higher conc
solution.
centre) 6. [A,B,C)
(A) H20 & C2HsOH shows +ve deviation
2. (B) C6H6 & C6HsCH3 almost behaves ideally.
(C) CH 3COCH 3 & CHCh shows -ve deviation.
7. [A,B,C)
For ideal solution ~ V = 0, m = 0, ~S = +ve
If solution is less volatile, i.e. case of -ve deviation
8. [5]
The no. of fatty acid molecule required
(B) Fe present in tetrahedral void distance from 10 =5 x 1019
a,fj 0.2xlO- 18
corner = --
:. The no. of moles offatty acid "X" required
4
= ~ x 10-4
(C) Na+ present in tetrahedral void from comer = a,fj 6
4
(D) The nearest distance between two nearest Wt 0f Co
latty aCl'd reqUire
. d = -5 x 10-4 x 252
6
particles from comer to body centre = a,fj = 2.1 x 10-2 gm.
2 : . vol. of fatty acid solution in benzene required
2.1 x lO-2 3
3. [A,C,D] ---'-------'--- litre = 5 x 10- litre = 5 ml
M = 28/1 1.2 = 2.5 4.2
=> IL => 2.5 mole H 20 2 = 85g H 20 2 & wt of 9. [3]
I L solution = 265 g x 1
265-85 log - = log K + - log p
.. mole of H 20 = 10 m n
18 I
- = tan 45° = => x = 1
..
X
H 20 2
=~=0.2
25+10
x
log k = 0.310
k=2
% w 2.5x34 xI00=8.5
V 1000 ' X
- = 2x(0.3)
I
m
m= ~x 1000 = 13.88 => x = 0.6
180
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w"
10. [2)
Kb X(WB XI000)
(Ll.T)P = m B xw A p
(Ll.T)Q Kb X(WB XI000) C

mBxw A Q
CD = 10 sin 60° = lO x ..f3
0.1 X1000) 2
(
0.2 _ 100xl00 p Total length covered by spheres = 5 + 4 CD
0.4 - (0.IXI000) = 5 + 4 x 10 x ..f3 = 5 + 20 ..f3 ~ 39.64

2 -
100xm B Q
Total no. of spheres in the above rectangle
.!.. = (mB)Q 1
= 14 + 8 x - = 18
2 100 2
mB=50 .. 18
: . (mB)P : (mB)Q = 100 : 50
. . No. 0 f spheres III umt area = 16
= 2: 1 2
= 1.125 no/cm
11. [5) 13. [B)
P P P
X A = - A or X B= - B (1 - X A) = - B Theory based
PT PT PT
14. [A)
PA = XA Theory based
PB (I-XA)
15. [C]
For liquid phase P A= P~XA Theory based
P B = P~XB= P~(l-XA) 16. [A)
PA = 60-0.2 Theory based
PB 15 - (1- 0.2) 17. [D)
Theory based
~= 0.5 compare with 0.2
l-XA 18. [D)
X=5 Theory based
12. [1)
The arrangement of maximum number of spheres
of 10 mm diameter is shown above.
1. [A)
Mass of unit cell = d x V No. of molecules present in given unit cell
= (5 x 10-8)3 x 3.84 x 6 x 1023 = 519.6=2
=288 a.mu. 259.8
Mass offormula unit ofFeO = 56 + 16 = 72 a.mu.
. 288 3. [B)
:. no.o ftiormuaumt=-=4
I
72 Vol. of all atoms in 1.68 g of A
2. [D) = 1.68 x 6 x 10 23 x ~ x 22 x (1.50 3 x 10- 8 )
2
Vol. of unit cell = a sin 60° x b 40 3 7
24 3
= 173.2 x 10- cm = 0.3564
a=5A Vol. of solid A = 1 cm3
Mass of unit cell = 173.2 x 10-24 x 5 x 6 x 1023 % of empty space = (1- 0.3564) x 100
= 519.6 g = 64.36
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4. [B] 11. [A,B,C!
Protecting strength oc gold no. (A) Na+ present in octahedral void have six cr
around
5. [B] (B) Cl- have 6Na+ at it edge
As2 S3 is negative colloidal solution.
(C) second nearest nighbour of Na+ ion are
6. [B] a
I
twelve Na+ ion at distance fi (4 body
log (x/m) = - log P + log K
n center, 8 edge centre)
0
1
tan 45 = - 12. [A,C]
n The vectors given in choices (A) and (C) are
~n= 1 .... .... ....
log K= log 2 meaningful since u x (v x w) = vector product
K=2 of two vectors.
~ --+ --+ --+
( : ) = 2 (p)1 = 2(2) = 4. ( u . v ) w = scalar multiple of w with a scalar
7. [C] 13. [A, B, D]

Theoretical
14. [B,C,D]
Theoretical
15. [B]
X A= 0.3 (given) then l-XA = 0.7
P = poAXA+ pCB (l-XA) = 110 x 0.3 + 125 x 0.7
= 120.5
2=0.27
BE
-=cos30°=- J3 120.5
BC 2 - pOBX B -
- -
87.5 -073
Distance between the centres of two B atoms andY B- -- .
P 120.5
=2 x BE= J3A [A]
8. [A,B,D] PAo= 110PBo= 125
BaCh + K 2S04 ~ BaS04 + 2KCI P = PA° X A+ P B° X B= 120.5
meq 22 12 xO.6 0 0 pAo < P < P Bo
= 7.2 17. [D]
14.8 0 7.2..1- 14.4 1 +2
Total meq = 14.8 + 17.7 = 29.2 No.ofCa =8x - = 1
8
No. of particles are more than initial. No. ofTi+4 = 1
9. [A,B,C]
NO. of 0 - 2 = 6 x .!.= 3
factual 2
10. [B,C] Total no. of atoms = 5
3
Z= a x d x N 18. [D]
M MgAh04 does not have formula like ABX 3
10 23
= (654 x 10- )3 x 2.75 x 6.023 x 10 '" 4
119
Chemistry
Unit Test-7
Hints &Solutions~
1. [D] E~II = 0.34 + 0.25 = 0.59 V
k2=A e- E" /RT ; k, =A e-E., /RT
Ink2= In AEa2
- - & Ink,= lnEAa-,-
RT RT s. [B, D]
A The given cell is concentration cell :
or Ea2= RTln Alk2 & Ea = RT In -
, k, Ag ~ (Ag+) LHE + e
(Ag) RHE + e~ Ag
.. 2RT In ~ = RTln~ + +
k, k2 Net reaction: (Ag )RHE ~ (Ag kHE
.. In (~)2
k,
= In ~
k2
Ecell = 0 - 0.0592 log [Ag:1 LHE
[Ag lRHE
. (~)2 ~
= 0.0592 log [Ag+1RHE
[Ag+1LHE
Ecell = 0.0592 log [Ag+1Ag 2C 20 4
2. [A,D] [Ag+1AgI
.
In AgI solutIOn,
+
[Ag 1= Ksp (AgI)
,n
Amount. J-!u..4 ~ ~ ~ ~
Remammg 2 4 8 16 In Ag2C204 solution [Ag+]
Amount o~.!.~l~7..~.!2
consume 2 4 8 16
tl/2 2tl/2 3tl/2 4tl/2
3. [A,C]
If E~ell = -ve then reaction will be non spontaneous
For option A & C, EO = -ve 6. [A,C,D]
The A is more oxidising than B and A is more
4. [A,C,D] oxidising than H2
The A is more oxidising than B and A is more
:. A~A2++2e E? =0.25V
oxidising than H2
: . A~A2++2e E? =0.25V A2++2e~A E? =-0.25V
A~A2++2e
A2++2e~A E? =-0.25V B2++2e~B
A~A2++2e A+B2+ ~ A2+ +B
B2++2e~B E~II = 0.34 + 0.25 = 0.59 V
A + B2+~ A2+ + B
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7. [D,C)
Let expiry time of the drug, te = .!. In 2
k
_9_=~ x O.5
18 / 2 96500 In 2
or t = 1 0 - -
Q = 96500 x 2 e 1n5 / 2
V IO x O.693 IO x O.693
0, =96500 or t =
22.4 / 4 e (In5-ln2) (lnlO-2In2)
:. Vo , =5.6L (:.11 = 0.5) or t = IO x O.693 IOxO.693

e (2.303 - 21n 2) (2.303 - 2 x 0.693)
8. [3] or t = lO x 0.693 6.93 = 7.56

ItE e (2.303 - 1.386) 0.917
w=--
96500 or te '" 8 months
E= w x 96500
12. [2]
It
. I
22.2 x 96500 = 59.5 Smce, t I 12 OC ----n=t'
2 x 5 x 3600
a
. Atomic mass
eqUIvalent mass = ---~~
So ..!.L = [~]n-I = [12.]n-1
oxidation state t2 al PI
Here PI = 500 mm, P2 = 250 mm,
59.5 = 177
n tl = 100 sec, t2 = 200 sec. Thus
"",3 100 = [250]n- 1
200 500
9. [3]
or n=2
The cell reaction is
H 2(g) + h(s) ~ 2H+(aq) + 21(aq) i.e. Order of reaction = 2nd
0.7714 = 0.535 _ 0.0591 log [Wf[r-]2 [A]

2 PH , By theory
[D]
By theory
H+ = 10-3
15. [A]
pH=3
By theory
10. [I]
16. [D]
fc 10 -5
By theory
K= - = - x 0.0001 = 10
a 100
5 17. [A]
Am= K x lOOO 10- xlOOO =0.1
By theory
m 0.1
Multiplication by 10 = 0.1 x 10 = 1 18. [D]
By theory
11. [8]
k= ~ In ~ = ~ In 5/2
t ao-x 10
Chemistry
1. [A]
Given ' 1No = 1%; N'4 c = 0.25% 4. [D]
4c
P+Q--+R+S
and tl/2 = 5760 year
Given: T75% = 2 x T50'10 (for P)
t = 2.303 log No Since tl/2 is independent of concentration and
.. A N
thus it is first order for P.
2.303 x 5760 I I From graph it is clear that reaction is of zero
0.693 og 0.25 order with respect to Q
= 11524 year [Q]t = [Q]o - Kt
So overall order will be = 1 + 0 = 1
2. [B]
Let wg of each be taken, then 5. [B]
log Q = 0 E = EO = 1.1 V
Initial mole ofP = ~ ; mole ofQ = ~
The value of Ecell will decreases with increase in
value oflog Q
Final moleofP= 5:{0;
- - I og Q
E -- EO -0.059
. 4w, n
Fmal mole ofQ = - -
20x5
6. [D]
ForP Nop = e Ap xt Volume of coating = Area x thickness
Np 4
= 32 x 10 x 0.025
N = 8000 cm3
ForQ ~=eAQxt
NQ mass = value x density
= 8000 x 7.2
:. ForP wx5xl0 = eAp x20 = 57600 gm
10xw,
ItE
... (i) w=--
96500
w x 20 x 5 _ AQx20
For Q - e ... (ii) Ix60x(52 / 6)
20xw, x4 57600 = 96500
By Eqs. (i) and (ii) 4 = e(Ap-AQ)x20 1= 10.69 x 106Amp
.. 20(Ap - AQ) = log. 4
7. [C]
or 21 0.693 _ 0.693J = log. 4 Cell reaction is
vl t' /2 10 H 2(g) + 2Ag+ ~ 2Ag(g) + 2H+(aq)
E=Eo 0.06 x 2.303 Iog _-,[~H-:+f-f_

3. [C]
2 [Ag+f.P H2
2xO.06x2.3031 [A +]
0.62 = 08
. + 2 og g
10g[Ag+] = -1.3026
[Ag+] = 0.05 M
no. of moles in 100 rnl = 0.005
mass of silver = 0.005 x 108 gm
or A2 = e(t, -t,).A = e(t, - t,)/T
A, 0.005x108x100 0
%inl.08gmofalloy= 1.08 =50Yo
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8. [A, B, D) 16. [C)
Theory Mn2++ 2e~Mn EO=-1.l8volt
0.0591
E Mn2+lMn = Eo Mn2+lMn - - E
9. [A,C,D) - og or
2 [Mn2+]
-Ea
=-6600 0.059
2.303R Mn2+/Mn = E oMn2+lMn+ - - Iog [M n2..,J
2
so, Ea = 54.99 kJ 0.059
or E Mn2+/Mn = -1.18 + --log Ksp
10. [A,B,D) 2
0.0591
- og 10-
13
t 25 or E Mn2+lMn = -I. 18 + -
2
kJ
9 0.059
or E Mn2+lMn = -1. 18 - - - x 13
2
= - 1.5635 volt
01------
11. [A,C) 17. [C)

Theory t eq. 8G = 0 :.8H=T8S
and .!S.. = K [CnD]d

12. [B,C,D) Kb C [A]a[B]b
Theory
13. [A,D) 18. [C)

SRP of Cu+2/Cu is less than H+/H2 So it will be d[A]
----=---
I d[B]
reduced by H2 n, dt n 2 dt
SRP of Cu+2/Cu is more so it will oxidise Sn to d[A] n, d[B]
- -- = - - -
Sn+2. dt n 2 dt
14. [B,C,D) 10g[- d[ A]] = log E.L + log d[B]
W=Zi t dt n2 dt
15. [B) log E.L =.3

n2
MnO:; + e ~ MnO~- 8G; = -1 x F x 0.56
MnO~- +2e ~ Mn0 2 8G; =-2xFx2.26 E.L=2
n2
Mn04+3e~Mn02 8G ne• =-5.08xF
:. Ene. = 5.08 = 1.693 "" 1.69 volt

3
Chemistry
Unit Test-8
Hints &Solutions~
1. [A,B,C] 4. [A,C]
Alkyne gives 1,2-dicarbonyl on the other hand
A,B,C are correct and D is wrong.
alkene gives carbonyl compounds by breaking
e +0-COOH:::-'"
~~ P
v--z:.COOH
I
5.
double bond in Reductive ozonolysis.
[B,C,D]
In case of (A) product obtained is-
! l,lNaHCO,
CH3 CH3
&fr-
'_8__
o
C
II
I ~ y~000
y;?'~
rr
A-r HO
OH R
CH3 -
I
T- CvH
CH3
- CH3 + H+=H;O CH3 - T:Jt£H - CH3
I
CH3
o 0
:OH
O~OOH
2. [B,C,D]
CHz-CH3 6. [C]
© 7.
X is erythro; Y is Threo.
[A]
'A' is Birch reduction and in this trans alkene is formed .
8. [8]
Let the compound Z be ROH
Hg(OAc),
NaBH4 ROH + CH~gBr~ CH4 + Mg(OH)Br
No. of mole ofZ= 0.00125
No. of mole of CH4 = 0.01
': 0.00125 mol of alcohol gives O.oI molofCH4
:. 1 mol of alcohol gives 8 mol ofCH4
9. [4]
3. [A,B,D] Following four compound give +ve iodoform test
(D) '-..../"'--..../ W l t.)"' ./'... /. + OH
~ T - Hel ""v' ~ (b)/"'V
OH 1 Pentene (c) @-TH-CH3
~+~ OH
Trans 2pentene cis 2-pentene HO~
(e) CHrCHrOH (h) U
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10. [3J 13. [C)
_~_~-"g_X-+)~I_,-+1b- ~
CH - C == C - H H,sO,IHaSO,IHO)
3 Acidic hydration of Alkyne
Cl- C -
II
(0
0 - Et
(1st mole)
\.00
OEt
-Cl
R - CCYOEt
II
(0
CH3- fi -CH3
o
l
~~gX 14. [DJ
(2nd mole) e
Ph - C == C - H BH 1 [THFlH,o,IO H )
Ph-CH 2 - fi -H
R
I 0$ X
RM
~ R
I ~ 15. [DJ
o
R-C-R ( g R-C-R +-R-C-OEt e
I (3rd mole) II o'it c. 1 CH 3- C == C - CH 3 BH1ITHFIHPliO H )
00 0) 00
CH 3 -fi - CH 2- CH 3
l
R
NH4Cl 0
Ketone (not aldehyde)
I 16. [AJ
R-C-R By Theory
I
OH 17. [BJ
By Theory
11. [4J .
I, II , V, VI involve fonnation of stable carbocatlOn. 18. [DJ
By Theory
1. [AI CH 3
SN reaction proceeds with carbocation so I +
CH3
2.
reactivity order is I> III > II> IV.
Ic)
CHCb;r -
CH3 1 : 2 ~H3 shift
CH rr I
-CH=CH 2 ~
w 1
CH r C-CH-CH3
CH 3
(j) lcr
CH 3 CH3
I I
CH r C-CH-CH3
I
Cl
Chemistry
3. [A) 9. [A,B)
CH 3-CH 2-Br 10AIkyi halide mainly give SN 2 Terminal Alkyne give ppt.
2
mechanism strong neucleophile favours SN
2
mechanism inert solvents are used in SN 10. [B, C)
mechanism Mg I Ether
CH 3 -CH 2 -CH 2 -CH 2 -X
4. [B) n-butyl halide
n-Propyl carbocation formed as intermediate,
rearranges through 1, 2-hydride shift to form
more stable iso-propyl carbocation.
©
5. [D) CH 3 - CH2 -CH2 -CH3
n- butane
+ CH2Cl2 Aiel, ) many products are
11. [B,C)
there CHr CH(Br) CH 3 EtOH »
(a)O+CH2~O>CH2
Williamson's syn .(NSR)
CH r CH-CH 3
I
OEt
EtONa » CH r CH=CH 2
EtOH
(Elimination)
12. [C,D)
Because @-CH 2--C1 and O C I not

have any chiral -C so that they gives same
product by SN I, SN 2
6. [A) 13. [B, D)

n
Add of H 20ID 20 by M-Rule in A & B 1°
(Kuchrov's reaction) CH 3
n
Add of H 20 by A.M. Rule in C [HBO] 1° 2° I 2° 1°
CHr CH-CH-CHz-CH3 ~
3° hv
7. [C)
yH 3
CHrCH2-CH-CH2-CHz-CI
TH 3 *
2"=21=2
CH 3-C-CH=CH 2 +
6H 3
CH 3
I *
CH r CH2-CH-CHz-CH-CI
(Alkoxy mercuration-Demercuration) 2n=;2 = 4 tl
8. [A, B, C)
yH 3
CH 3-CH,---C-CH 2--CH 3
A Br, » Anti addtion
CCI,
- I
Cl
B CH ,COOH» Anti addtion +
H + I H 20 yH 2-CI
C H- Br» by M.K. Rule CHrCHz-CH-CHz-CH3
Total (8) Product
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14. [B,C,D) Chlorine free radicals reacts with ozone and
CH3MgBr+ produce CIO -
CH3iH-CH:rC=CH- 2moles of CH 4 The CIO - formed decompose slowly, reforming
OH CI- The CI- react further 03 molecules.
L blc it contain 2moles of acidic rapid

CI- + 03 -----o~--- Cb + CIO-
hydrogen
(-OH group and =C-H gr.) CIO ___s-313~w_ _ Cl- + 0-
B,C,D compound contains only I moles of acidic
hydrogen in it . CIO- + 0- ----:)~ Cl- + 02
15. [B]
From - stability of carbocation
further react with 03
16. [D)
From - stability of carbocation 18. [C)
The hydrogen atoms in HFCs and HCFs are
attacked by hydroxyl radicals in upper
17. [D)
atmosphere, producing trifluoro acetic acid. The
In the upper atmosphere freons undergo
CF3COOH is not so toxic, removed from the
photolytic reaction and yield chlorine free
radicals. atmosphere during raining and in soil CF3COOH
is destroyed by the bacteria.
photolysis
Freons ) Cl-
Chemistry
Unit Test-9
Hints &Solutions~
1. [A,B,D] 6. [A,D]
(A) Backmann rearrangement
(B) Anti to Br group
(C) Isocynide product
(D) Hoffinann degradation
2. [A,C,D]
H,O$ ) Ph-COOH NH,/~) Ph-C-NH2

Give effervescence II
o [Yl
with NaHCO] 7. [A, C, D]
[Xl
KOBr
(Hoffinan
degradation)
CHCI, / KOH
Ph-NC ( Ph-NH 2
W Z
3. [A,C]
a,13 (1, 4) glucosidic linkage
* it is a polymer of D-glucose
CNH HNO,) CN-N=O * it has no free aldehyde group so a non-reducing
(2° amine) sugar (does not give a test with fehling solution).
8. [4]
4. [B,D] o o
II II
Compound should be aromatic amine & also have H
$~-'"":f, ~
o@NH-C-C 3
II NM/~
-NH2 gr [10 amine] to show diazotisation reaction ~
@- NH CH,-C-CI
, (I)
0 ( )
followed by coupling reaction of BDC to give [X]

NO, NO,
sharp colour.
I
[~}
2 [Y] [Z]
NH
S. [A,B,C] 0 ~
*
NaNO,+HCl I
CHlCOOH
(A) CHChlBase ----t Carbyl amine test
NO, NO,
(B) NaN0 2IHCI----t Diazotisation tests
[w]
(C) CS 2, HgCl 2 ----t Hinsberg test
(D) Ag20/t':!.----t Tollen's test not used to I~I
Distinguish between 1 amine & 2 amine
0 0
NO,
[Product]
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9. [4J 12. [3J
11 0
amine I ·0Hlr
CHr CH 2-NH 2
I" ' CH 3-CHz-j'!H-CH 3
(l) CH3-CH2-CH2-CHrNH2 8>,'=m, t

II"
j CH~r
(2) CH 3-CH2-CH-CH 3
1
NH2
[ EIlI
CH, 1
eB~'
CH 3-CH r N-CH3 Br'
1
$,
III'
-CH r N--CH3
3 CH 3
1
(3) CH 3-CH--CH2-NH2 CH 3 CH 3
1
CH 3 Quaternary Ammonium Bromide
NH2 13. [C)

1 By Theory
(4) CH 3-C-CH 3
14. [OJ
1
By Theory
CH 3
10. [4J 15. [C)
2 H By Theory
! 1
!:@XN~-I
16. [OJ
By Theory
N 0 17. [OJ
1 By Theory
H
At position 4th e- density is maximum that why at 18. [C)
4th position nitration takes place By Theory
11. [4J
CHr CH z-CH 3 Vapour phase

Propane Nitration
(2) CHr CH-CH 3
I
NO z
(3) CH 3-CHr NOz
(4)CH r NO z
Chemistry
1. [C) 8. [A,B)
Glyptal is polymer of ethylene glycol & pthallic
acid Ph Me Ph Me Ph
I I I I I
Ph-C-C-Me H, 4. Ph-C-C-Me~ Ph-C-C-Me
(A) -t Terylene (B) -t Nylon-6,6 S0
(C) -t Glyptal (D) -t Nylon-6 I I + I I II
OHOH OH Me 0
2. [D)
Milk sugar => Lactose
Ph Et Ph Et Ph
Lactose => [/3 .D-G lucose + /3 .D-Galactose1
I I I I I
H, 4. Ph-C-C-Et
S0
Ph-C-C-Et ~ Ph-C-C-Et
3. [C) I I $ I I II
OHOH OH Et 0
Phosphate linked to Cs' in a nucleotide is
9. [B,C,D)
o
attached to C3' of the next nucleotide.
4. [D) HO CH -DH 0 LAH OH
o
HIOJ~. 6~6
o f
11
N
(:
~
NH
2
o
I
HO-f-O---r- o 1 N NH2
HO
A& N
C-OH
aoH+cao.6
OH
OH 'r-' U -co,t
OH
5. [B) -H-Co-H
Pb(OAC).
SBH) OOH
Ph- II
NDz( (i)NH ,/ ~ @-C-OH NH,/~ )
(ii)KOD/Br, ~
10. [A,B)
@-Ti-NH,
o
(i)CH , MgBr
(ii)H,om
Beckmann)
Ph-C-NH-CH3
Rearrangemen t
&
+ CH 3-C- NH-Ph
& 11. [B,C,D)
6. [C) Victor mayer test
Due to aromatic ring benezenediazonium salt is
stable. I ° Alcohol ~ Red colour
2° Alcohol ~ Blue colour
7. [A)
3° Alcohol ~ Colourless
Carbocation and Ring expansion.
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12. [A,B,C,D) (D)
~N
(A)
C-H @-CH-CN
o~o~~~c5
l
@- I
I OH
o OH
Optically active
OH +OH 2 Racemic mix 14. [A)
(B)
c$~cP-CP("H~4)
CH3 CH3 CH 3
(C) o 0 o
II ~ ~
./Y ~l No reaction because ofBredt's rule c "' a H,o" II ,C-C,,- -H,o
H'C~~_Ph
~
HO
[No carbocation] ij> ~
C=CH- Ph -
[Y]
Et
1CC~CH_Pb
~
a
Et-O-c"
~
o
OH
(D) -co, t \ 6 II II [X]

Me
Pinnacole-Pinnacolone
MerC-Me C HJ-C-C H~ H-Ph
HO OH Reaction Me II ~
o
o [Z]
13. [A,B,D)
The use of II' decreases nucleophilicity but
15. [A]
mcreases electrophilicity. HCN/OIr gives 1,2-
adition.
IX ~HrCHl (1)0,
(A) ~ (2) H,O/Zn Hi+CH2""fi-CHrCHl
)C=O H': l )C(OH Reversible process o 0
1Na~HI~
OH CN
a-Hydroxy nitrile
(B)
e
HCN + OH
(Basic medium) e
(nu)
fe
weak nu ~Strong~u
16. [B)
CH3-C-H + H-C-H
__ -=~~H:""-_ _ l H? i OH
II II Aldol followed by HO~OH

cannizzaro
o 0
(Excess)
17. [A)
Fact based
18. [B)
CHrCHrC-H
1, 4 - GB & 1, 6 - GB
I II
CN 0
Chemistry
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Unit Test-lO
Hints &Solutions~
1. [B,D] compound. Brown colour is just due to charge
-L
+ transfer spectra.
r----..... T/
Cl
N0 4. [A,B,C,D]
eDlGn
I
e~cD
3+
2
5. [A,D]
N0 2 M ~ L, In metal carbonyl complexes, C-O
Trans-form cis-form bond length increases compared to that in CO
(optically inactive) (optically active) molecule as filled 'd' orbital of metal atom overlaps
cis and trans are diastereomers to each other. with 1t-antibonding M.O. of CO [CrCh(H 20)3].
3H20 is not hydrate isomer of [Cr(H 20)6]Ch.
2. [A,B,D] Facial and Meridional isomers of [Ma 3b3 r+
[CoF 6]3-: ~o < P and High spm complex complex are optically inactive as each one contains
+ plane of symmetry.
Cl
~llIyNH3 [A,D]
e~co", FeO + CO ISOO- I600'C) Fe + C02
I NH3 Si02 + CaO 800-JOOO'C) CaSi0 3
NH3
cis-form 7. [A,C,D]
=> Asymmetric configuration hence exist in d and As per theory
eforms 8.
+
CI
~lllVNH3
e~co", => Optically inactive
I
Cl
NH3
]~
trans-form
11 11 11 It2g
+ d xy dyz dzx
NH3
CFSE of pink colour complex
~luVCl
e~lo~1 => Optically inactive
NH3
trans-form
Total isomers ~ 4 9. [5]
EDTA Phen
3. [A,B,C] cr bond 31 + 24 55
Nitrate ion gives a brown ring when reacts with 1t bond 4 + 7 11
conc. H 2S0 4 in presence of FeS04 due to 55
formation of [Fe(H 20)sNO]S04 complex x+y=-=5
II
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10. [8) 13. [C]
(i) [Fe IF(CN) (H 20) (en)] As per theory
x = 12 (active isomer)
14. [C]
(ii) [MoCh F2(gly)r
As per theory
y = 4 (active isomer)
x-y= 12-4 => 8 15. [C]
As per theory
11. [1)
16. [A)
Metal (M) => Mo (z = 42) As per theory
Mo(COh(NO)y +NO l Mo(NO)z
-co 17. [D)
Ify = 2, then x = 3 and z = 4, As per theory
hence x = y - z = 3 + 2 - 4 = 1
18. [D)
As per theory
12. [5)
Complexes No. of geometrical isomers
(i) [Pt(NH 3h(SCN)z] 2
(ii) [Co(N02)J(NH 3h] 2
(iii) [Pt( en)Ch] o
(iv) [Cr(en)2Br2t 2
(v) [Rh(en)3]3+ o
(vi) [CoChBr2]2- o
Hence, sum of total number of geometrical isomers =6
1. [B)
2. [C]
NH4Ci + NaN0 2 -----+ NH4N0 2 + NaCI
N~N02 ~ N2 t 2H 20
Ba(N3)z -----+ Ba + 3N2.J,
2NH4Cl + CaO -----+ CaCl 2 + 2NH3 t + H 20
3. [A)
2CrO~- + 2H+ ~ Cr20~- + H 20
Cr20~- + 20Ir ~ 2CrO~- + H 20

One tetrahedral shares three comers while other
adjacent one shares only two comers hence 4.
3+2 1 dissociati on
l [AICI 2(H 20)4t
average shared comers = - - = 2-
2 2 + [AICI4(H 20)2r
Chemistry
5. [C) 10. [ABC)
MgCh + NaHC03 ~ Mg(HC03h + NaCI Al forms layer of Al 20 3 over surface
Soluble 11. [A, B, D)
1~ NaOH + Sn(OH)2 ~ Na2Sn02 + H 20

Al(OH)3 + NaOH ~ NaAl0 2 + H 20
H20 + CO2 t + MgC0 3 -l.
Insoluble Pb(OH)2 + NaOH ~ Na2P02 + H 20
6. [D)
12. [B,C,D,)
S02 + K2Cr207 + dil. H2S0 4 ~ Cr2(S04h
(C) is correct because in Ni(CO)4 The ground
Orange Green
state electronic configuration
S02 + KMn04 + dil. H 2S0 4 ~ MnS04
Ni(28) 4s2 3ds Nio 4so 3d 10
(Pink) (Colourless)
S02 + Ca(OH)2 ~ CaS03 CO is a strong field ligand
(Milky) 3d 4s 4p
~---------------,
7. [D) ....-;-ltl....-;-lt
It tl-;-;-rt t ~ t t I:[ll]
M-:--:T 77"1
3
Ittl t Mttl:
I_ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ J
Pb30 4 + HN03~ Pb02 Tetrahedral, sp ,
(black residue) + Pb(N03h diamagnetic
Pb(N03h + K2Cr04~ PbCr04 (B) is correct [Ni(CN)4]2-
(yellow ppt)
Pb(N03h + H 2S ~ PbS
(black ppt)
2
Pb02+ Mn ++ HN03~ HMn04 (D) is correct because Cl- is weak field ligand,
(purple solution) does not cause pairing of electron.
8. [A,B,C,D)
[NiC4]2-
The active nitrogen is more reactive than ---------------
molecular nitrogen because it contain atomic
....-;-ltl....-;-lt
It tl-:--:T t I t I j [ll] Itt Itt Ittl
t M--:-T ""7O
nitrogen. Active nitrogen when reacts with H2S ---------------
blue solid is obtained because of the formation of paramagnetics Sp3, tetrahedral
sulphur nitride ofm.f. (NS).
The nitrogen atoms have three unpaired 13. [A,B)
electrons. When two such atoms combine, an H20 & Cl- are weak ligand
excited nitrogen molecule .. molecule

:N - N: Ni(28)-11~11~11~11111 [1]
with four unpaired electrons, which then
rearrange to give diamagnetic :N == N.: . In this Nt
2
_ 11~11~11~11 11 1 D
combination process the energy liberated Pairing of e- can not provide coordination NO.6
produces yellow afterglow. => [MnC14 2 r
9. [C,D)
[1]
Mn(2S) = ""---11,......,.11-.---:11-.--:11~1...,......,11
XeF 6 + H 20
XeF 6 + 3H20
~
~
XeOF4 + 2HF
Xe03 + 6HF
Mn+2 = 111111 11 11 1 D
cr is weak ligand, can not paired up the
electrons.
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14. [A,D)
S;- (Chain Structure) SO~- (Tetrahedral)
H 2S reacts with sodium nitroprusside only In
alkali medium
Na2[Fe(CN)s(NO)] + 2NaOH + H2S t
-t N14[Fe(CN)s(NOS)] + 2H 20 + 2H 20
Purple
Ferrocene Dibenzene Na2S203 + [Ni(en)3](N0 3)2-t
chromium [Ni(en)3]S203,} + 2Na+ + 2N03
15. [C) & 16. [A) Violet

S8 + l2NaOH -t 2Na 2S203 + 4Na2S + 6H 20 (optically active)
(A) (B) (C) 17. [B)
It is chromyl chloride test
Na 2S203 + FeCh -t [Fe(S203)2r + 3Cr + 4Na+
(Violet sol. (E) 18. [C)
Na2S203 + 2HCl -t 2NaCI + S02 ,} + st + H20 Mn02 + H 2S04 + cr -t Cl 2 gas is evolved
(A)
Na2S203 + eaCh -t No ppt. as eaS203 is soluble
Chemistry
Revision Test-2
Hints &Solutions~
1. [B,C] 4. [A,C]
The path of the reaction is. Ca2+ + RH2 ~ CaR + 2H+
6- -6* '0 +0'.L

RO 0 OR 77.5 ppm = 77.5 g Ca 2+ per 106 mL
= 77.5 x 10-3 g L- 1 Ca2+
o CI
0
3
Jill:.. * _77__.5__x_lo__-_ I L- 1 C 2+ .
mo a IOn
40
3
2. [A,C,D] 77.5xI0- x2 mo IL-1H+'IOns
=
A + B ~ D 40
.. [H+] = 3.875 x 10-3
ao ao o
.. pH = - log (H+) = 2.4
(ao- x) (ao- x) x
5. [A,C]
dx
: . - =K(ao-x) x
2 o H
dt II I
CHrC-CH2--CH2-CH2-CHr:: =0
dx 2 2
or - =K(ao +x -2aox)x=r
dt
3 2
: . r = K( a6 x + x - 2ao x )
dr 2 2
or - = K ao + K3x -4aoxK
dx
: . at the maximum rate, ~ =0

dx
2
:. 3x - 4ao x + a6 = 0
2
or 3x - 3ao x - xao + a6 = 0
•
or 3x (x - ao) - ao (x - ao) = 0 (major)
or (3x - ao) (x - ao) = 0 6. [B,D]
:. x = ao or x = ao/3 CH 2--CH - (CH2)3 - CHO Me,CuLi)
3. [A,C,D] \/
The A is more oxidising than B and A is more MeCH2CH (CH 2)3CH = [X]
oxidising than H2 I II
OH 0
: . A~A2+ +2e E? =0.25V
A2+ + 2e~A E? =-0.25 V lpcc
A~A2++2e
B2++2e~B
A + B2+ ~ A2+ + B NC~O
U N CN
E •
Lo-E~H
U MeCH2tr(CH2)]CHO; [Y]
E~ell = 0.34 + 0.25 = 0.59 V
[P] [l] 0
1 LiAIH4
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crfir
7. [A, D, C, D]
When the three solutions are mixed then the
C~ B
molarity of each solution changes but number of Cis B &CisC
moles does not change. Hence it is similar to
dilution. 10. [8]
ForKN0 3 M,V ,= M 2V2 1 ao 1
k = - In - - = - In 512
100 x 0.1 = M2 x 1000 t ao-x 10
=> M2 = 0.01
=> resulting molarity ofKCI = O.oJ
Let expiry time of the drug, te = .!.. In 2
k
=> K+ = O.oJ M In 2
Cr=O.OI M or te= 1 0 - -
ln5 / 2
ForHCI M,V, =MN2
IO x O.693 IOxO.693
0.2 x 400 = M2 x 1000 or te=
(InS -In 2) (InI0-2In2)
=> M2 = 0.08
=> H+=0.08 M or t = lOx 0.693 IOxO.693
NO) =0.08M e (2.303-2In2) (2.303 - 2 x 0.693)
For H 2S04 M,V , =M 2V2 or t = lO x 0.693 6.93 = 7.56
0.3 x 500 = M2 x 1000 e (2.303 - 1.386) 0.917
=> M 2=0.15 or te "" 8 months
=> H+= 0.3 M
SO~-=0.15M 11. [3]
Fusion occur along BC.
cr = 0.01 M;
Hence in the solution K+ = 0.01 M;
For fusion , t.q = 0.04 x 30 x 103J
NO) =0.08M;H+=0.38M; sol- =0.15M For fusion T = 400 K
8. [3] t.S fu = t.q = 40 x 30 = 3 J/mol K
The structure of nitroglycerin is s T 400
IH IH IH 12. [3]
H-C C C-H In option [III] Ethyl is at 2 position
I I I
000 13. [D]
I I I Theory based
N N N
0/ '0 0/ '0 0/ '0 14. [A]
Theory based
15. [D]
9. [3] Theory based
16. [C]
Theory based
17. [D]
Theory based
18. [D]
Cis B & trans C Cis C & trans B Theory based
Chemistry
7. [B)
1. [B)
Total current passed in 30 sec.
In DMSO SN2 mechanism occurs in
CF 3CH 20H, it accept proton Ph -CH2 attacks at
= ..!. x 100 x 10 + 100 x 10 + 100 x 10 + ..!.
2 2
p-position x 100 x 10
=3xlOOxlOmA x s
2. [C) = 3000 x 10-3 amp s = 3 C
o
II ow @cP~ W = EQ or W = E = Z = m
F Q F 3
Ph-CH-C-H ) Ph-C-C-H----+
I I
OH OH 8. [A, C, D)
(N~hC03 ~ NH 2CONH 2 + H 20
0-
I moles of (NH 2) C0 3 = 11.52 = 0.12 = moles of
Ph-C~C-H ----+ 96
I urea.
OH
2 Mn04 + 5(NH 4 )zC 20 4 ~
2Mn+2 + 10 CO 2 + 10 NH/
----+ Ph-C-CH,OH
II Meq of (NH4)2 C 20 4 = Meq ofKMn04
o W
- - x 1000 = 20 x 1 6 x 5
3. [D) M/2 .
X = CHr CH 2-CHrC=N
moles of (NH4)2 C20 4 = W = 0.08
Y = CH3-CHrCH2-C02H M
Z = CH 3-CHrClz--c-OEt
9 (i) (CNh + 4H20 ~ (NH4)2 C 20 4
0.08 0.08
Y ----+ Z is esterificatin reaction (ii) (CN)2 + 2H 20 ~ NH2 CO NH2
0.12 0.12
4. [A)
total moles of(CN)2 = 0.08 + 0.12 = 0.2
Since S02 has a burning sulphur smell which is
0.2
imitating, hence, X is soi- , and Y is S02 which
0/'
/0 purity = - - = 86.67 %
12/52
turns acidified K2Cr207 solution green due to its
reduction to Cr3+ ions. . case (.)
Progress IS I -
0.08 x 100 = 40 %
0.2
s. [A) . case ( 11
Progress III .. ) -0.12 x 100 = 60 %
0.2
::;C'6<6<6
9.
HOHoc - - -
stability
locH 30cH 40cH
~~,md~6<6<6
6. [C)
Decomposition of iodide is followed for Zr
(b)O<O<D
HOC oc No. of cation
Ti, Hf, Si etc. '
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14. [A,C,D]
KCl crystallise in rock salt having six nearest
neighbor of K+ and cr
ion. Packing fraction is
nd
0.74. The number of 2 nearest neighbor of
Resonance energy ex; delocalisation/conjugation cation is 12.
simple < cross < exterded
<d) ,sH>(~y>c5
15. [B]
CH 2CH J CH2CH J CH 2CH J
CHJI~H Ch, hy
ClCH21~H CHJ I~H+
Basicity ex; e- density on N atom HJC CH J ClCH 2
R S
10. [A,B,C,D]
Racemic mixture of
(a) Amine inversion
l-chloro-2-methyl butane
(b) Steric hindrance
(c) In boat form eclipsed condition & flag-pole Racemisation due to reaction at enantiotropic face.
interaction is present
(d) Large arp is more stable at equatorial 16. [C]
Abstraction of hydrogen is reduction
11. [A,B,C,D] So primary isotopic effect is observed
(A) Ethanol can solvate anion of
@H
r) < rll
~~o, 17. [D]

In the upper atmosphere freons undergo
photolytic reaction and yield chlorine free
0 2N 0 N02 as compared to anion Ofl2J radicals.
QJ)\~/)l(j)W
photolysis
Freons ) Cl-
(B)
Chlorine free radicals reacts with ozone and
o 0 0 0is present in
No flipping 2° amine 3° aminel.p.
produce CIO -
The CIO - formed decompose slowly, reforming
more ENorbital Cl- The Cl- react further OJ molecules.
(C) L.G. tendency does not depend on solvent nature. rapid
(D) Polar Aprotic solvent does not solvate anion Cl- + 03 -~)--- Cl2 + ClO-
12. [A,B,C,D I CIO- sl~w CI-+O-

(A) Isotopic effect is observed in sulphonation.
(B) Salicylic acid gives 2,4,6-tri bromo phenol ClO- + 0- ---)~ CI- +02
(i.e. decarboxy bromination takes place)
(C) Product is sec. alcohol
(D) Products are distereomers further react with 0 3
13. [B,C,D]
18. [C]
The hydrogen atoms in HFCs and HCFs are
attacked by hydroxyl radicals in upper
atmosphere, producing trifluoro acetic acid. The
CFJCOOH is not so toxic, removed from the
atmosphere during raining and in soil CF JCOOH
is destroyed by the bacteria.
Chemistry
Major Test
Hints &Solutions~
1. [A,B,C] 10. [B,C]
~® ~
Theory based
2. [A,C]
Theory based
(Highly stable) ~H ~n
3. [A,B]
!Bre Ye
4.
Theory based
[C] !Br
5.
Theory based
[C]
MBr
(rnaj or product)
qBr
Test tube III contains ~[Fe(CN)6]. Which does 55%
not give test for Fe +2 and CN- ions.
11. [A,B,C]
6. [A] tm=Q+w=> nCv ~T= 0+ W
Dimethyl glyoxime is used to detect nickel.
(In adiabatic process Q = 0)
7. [B] => W = nC v (T2 - T)) .... (i)
Roasting involves heating of an ore in limiting
supply of air (oxidation) below it m.p., to remove = -
nR
(T2-T)) {Since C v = ~}
S, Se, As. and Sb y-I y-I
8. [I] _ nRT2 -nRT)

.... (ii)
No. of moles ofCr ion y-I
= MV = 4x500 2
1000 1000
2Cl- --+ Cb + 2e- (at anode)
2 mol Cl- = I mol CI 2
p )(1-))/1]
=>w=-nCvT) 1- ( P~
9. [A,D] [
=-nCvT) [I-(~~ rep] . . (iii)
12. [4]
i, ii, iv, vii finally produce alcohol
13.[C]
By theory
14.[D]
By theory
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15.[D] 17. [D]
By theory By theory
16. [D]
18. [C]
By theory
By theory
1. [A]
Milli-equivalents ofHCI = to x 0.2 = 2
Milli equivalents of H 2S0 4 = to x 0.1 x 2 = 2 6. [A]
( .: normality of H2S04 = 0.1 x 2) hgdg = h Hg d Hg ; 5 x 2.72 = 13.6 h Hg
Milli-equivalents ofBa(OH)2 = 10 x 0.4 = 4 hHg= 1 m
Thus, total milli-equivalents of acids (2 + 2) are Pgas =0.76dg+ Ig= 1760mmofHg
equal to those of alkali (4) therefore, the solution
1760 x to = n x R x 300
will be neutral. 760
2. [B] 7. [A]
(Equivalent)KMnO, = (Equivalent) Fec,o, By Boyle's law PV = constant
PdV + VdP= 0
x x 5=2 x 3
VdP=-PdV
x=6 / 5=1.2
dP dV
3. [A] P V
Normality of oxalic acid solution
8. [A,B,D]
= 6.3 x 1000 = O.4N
200 63 (A) .: area under the curve gives fraction of
N,V, =N 2V2 molecules and total area is constant.
i.e. to x 0.4 = V x 0.1 or V = 40 mL (B) From expression of Maxwell distribution
fraction of molecules between Umps ~
4. [C]
Umps + f Umps is independent of value of
Wt.ofmetal 8
Eq. mass = x Umps and is dependent only on f.
mass of oxygen combined
(C) T2 is higher temperature
= ~x8=20 (0) As seen from graph; :. A, B, 0
0.24
9. [B,D]
5. [C]
dA = 2dB ; 3M A = M B ; PM = dRT 10. [A,C,D]
_ P MA d RT (b), (c), (d), (e), (h) are correct
- - A x- = -Ax -
PB MB dB RT Acidic strength oc - I, - M.
= PA x ~ =2 11. [C]
PB 2
Theory based
www.jeebooks.in
Chemistry
IWWW.JEEBOOKS.INI
12. [A,B,C)
13. [AI
-2.- )OCOO·
COO·
-2CO, )
O:~O
14. [B]
(C) & (D) are 3°allyl halide mainly give alkene
structure (b) forms 2°benzylic free radical which
is highly stable.
15. [B]
Theory based
+2 2.5
16. [A] Na 2S20 3 ~ Na 2S40 6
17. [D]
Theory based
18. [C)
Theory based
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•
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JEE ADV Chemistry Unit Wise Tests & Sol

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JEE Advanced

CAREER POI tty

Copyright © 2017, by Career Point Ltd.

This edition can be exported from India only by the publisher.

Published by Career Point Ltd.

Book No. : CPP-365

c) Tests are as per the latest pattern of the examination

d) Detailed explanatory solution of each test paper s also given

Student is advised to attempt these Tests once they complete the

Test No, Chapters

Unit Test-1 Atomic Structure, Periodic Table, Chemical Bonding

Basic concept of chemistry ,Redox & Volumetric Analysis, Hydrogen

Unit Test-3 Chemical Equilibrium, Ionic Equilibrium , s-Block Element

Unit Test-4 Gaseous State, Chemical EnergetiC

Unit Test-5 IUPAC and Nomenclature, GOC , Isomerism

Revision Test -1 Units 1 to 5

Unit Test-7 Electro Chemistry, Chemical Kinetics

Unit Test-S Hydrocarbon, Aromatic Chemistry, Halogen Derivative,

Alcohol,Phenol ,Ether, Carbonyl Compound, Carboxylic Acid and

Co-ordination Compound, d and f-Block Elements, p-Block,

Revision Test -2 Units 6 to 10

Major Test Full Syllabus

• Paper-1 59 18. Solution Unit Test-4 208-211

• Paper-1 87 21. Solution Unit Test-6 218-220

• Paper-1 115 24. Solution Unit Test-9 229-232

• Paper-1 147 27. Solution Major Test 241-243

S('ction - I S('ction-II S('ction-III

Unitwise Practice Test for JEE Advanced

• This section contains SEVEN questions.

SECTION-l (Maximum Marks: 28)

Q.l I st excitation potential for the R-like (hypothetical) sample is 24 V. Then-

Q.S Select the correct statements about the compound NO[BF4J :

Q.7 Which of the following is/are electron deficient compounds ?

SECTION-2 (Maximum Marks: 15)

Unitwise Practice Test for JEE Advanced

Q.14 For He+ ion, the only INCORRECT combination is

Q.15 For hydrogen atom, the only CORRECT combination is

Column -1 Column - 2 Column - 3

Q.17 Which of the following is correct option?

Q.18 Which of the following option is only correct?

Unitwise Practice Test for JEE Advanced

Use only HB pencils Enrolment No. Test Date

Section III Section III Section III

I SIGNATURE OF CANDIDATE ISIGNATURE OF INVIGILATOR I

Unitwise Practice Test for JEE Advanced

Scction -I Scction-ll Scction-Ill

th e wrong m ethod for fi ll ing the

bubble are ~ (2) CD CD

Unitwise Practice Test for JEE Advanced

SECTION - 1 (Maximum Marks: 21)

Q.l Which type of overlapping is not possible -

Q.4 Which element is represented by the following electronic configuration -

Q.6 Correct order of second ionization potential of

Q.7 Choose the incorrect relations on the basis of Bohr's theory

Q.S CO 2 molecule is not isostructural with:

Q.9 Which is wrong statement about (SiH 3hN is -

Q.13 Choose the correct statement(s) -

Unitwise Practice Test for JEE Advanced

SECTION - 3 (Maximum Marks: 12)

Q.l8 Order of lEI values among the following is -