Chemistry FRM

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FINAL
REVISION
MODULE
JEE - MAIN
CHEMISTRY
394 - Rajeev Gandhi Nagar Kota,

Ph. No. 0744-2209671, 93141-87482, 93527-21564
IVRS No. 0744-2439051, 0744-2439052, 0744-2439053
www.motioniitjee.com, email-info@motioniitjee.com
CONTENTS
S.No. Topic Page No.

1. Physical 7 – 23
2. Organic 24 - 48
3. Inorganic 49 - 61
Answer Key & Solutions
4. Answer key 62 – 64
5. Physical 65 – 74
6. Organic 75 - 85
7. Inorganic 86 - 96
IIT - JEE SYLLABUS

CHEMISTRY
PHYSICAL CHEMISTRY
UNIT 1: SOME BASIC CONCEPTS IN CHEMISTRY
Matter and its nature, Dalton’s atomic theory; Concept of atom, molecule, element and compound; Physical quantities and their
measurements in Chemistry, precision and accuracy, significant figures, S.I. Units, dimensional analysis; Laws of chemical combination;
Atomic and molecular masses, mole concept, molar mass, percentage composition, empirical and molecular formulae; Chemical
equations and stoichiometry.
UNIT 2: STATES OF MATTER
Classification of matter into solid, liquid and gaseous states.
Gaseous State:
Measurable properties of gases; Gas laws - Boyle’s law, Charle’s law, Graham’s law of diffusion, Avogadro’s law, Dalton’s law of
partial pressure; Concept of Absolute scale of temperature; Ideal gas equation; Kinetic theory of gases (only postulates); Concept
of average, root mean square and most probable velocities; Real gases, deviation from Ideal behaviour, compressibility factor and
van der Waals equation.
Liquid State:
Properties of liquids - vapour pressure, viscosity and surface tension and effect of temperature on them (qualitative treatment only).
Solid State:
Classification of solids: molecular, ionic, covalent and metallic solids, amorphous and crystalline solids (elementary idea); Bragg’s
Law and its applications; Unit cell and lattices, packing in solids (fcc, bcc and hcp lattices), voids, calculations involving unit cell
parameters, imperfection in solids; Electrical, magnetic and dielectric properties.
UNIT 3: ATOMIC STRUCTURE
Thomson and Rutherford atomic models and their limitations; Nature of electromagnetic radiation, photoelectric effect; Spectrum of
hydrogen atom, Bohr model of hydrogen atom - its postulates, derivation of the relations for energy of the electron and radii of the
different orbits, limitations of Bohr’s model; Dual nature of matter, de-Broglie’s relationship, Heisenberg uncertainty principle. Elementary
ideas of quantum mechanics, quantum mechanical model of atom, its important features, ?? and ??2, concept of atomic orbitals as
one electron wave functions; Variation of ?? and ??2 with r for 1s and 2s orbitals; various quantum numbers (principal, angular
momentum and magnetic quantum numbers) and their significance; shapes of s, p and d - orbitals, electron spin and spin quantum
number; Rules for filling electrons in orbitals - aufbau principle, Pauli’s exclusion principle and Hund’s rule, electronic configuration
of elements, extra stability of half-filled and completely filled orbitals.
UNIT 4: CHEMICAL BONDING AND MOLECULAR STRUCURE
Kossel - Lewis approach to chemical bond formation, concept of ionic and covalent bonds. Ionic Bonding: Formation of ionic bonds,
factors affecting the formation of ionic bonds; calculation of lattice enthalpy. Covalent Bonding: Concept of electronegativity, Fajan’s
rule, dipole moment; Valence Shell Electron Pair Repulsion (VSEPR) theory and shapes of simple molecules.
Quantum mechanical approach to covalent bonding: Valence bond theory - Its important features, concept of hybridization involving
s, p and d orbitals; Resonance.
Molecular Orbital Theory - Its important features, LCAOs, types of molecular orbitals (bonding, antibonding), sigma and pi-bonds,
molecular orbital electronic configurations of homonuclear diatomic molecules, concept of bond order, bond length and bond energy.
Elementary idea of metallic bonding. Hydrogen bonding and its applications.
UNIT 5: CHEMICAL THERMODYNAMICS
Fundamentals of thermodynamics: System and surroundings, extensive and intensive properties, state functions, types of processes.
First law of thermodynamics - Concept of work, heat internal energy and enthalpy, heat capacity, molar heat capacity; Hess¡¦s law
of constant heat summation; Enthalpies of bond dissociation, combustion, formation, atomization, sublimation, phase transition,
hydration, ionization and solution. Second law of thermodynamics; Spontaneity of processes; DS of the universe and DG of the
system as criteria for spontaneity, Dgo (Standard Gibbs energy change) and equilibrium constant.
UNIT 6: SOLUTIONS
Different methods for expressing concentration of solution - molality, molarity, mole fraction, percentage (by volume and mass both),
vapour pressure of solutions and Raoult’s Law - Ideal and non-ideal solutions, vapour pressure - composition, plots for ideal and
non-ideal solutions; Colligative properties of dilute solutions - relative lowering of vapour pressure, depression of freezing point,
elevation of boiling point and osmotic pressure; Determination of molecular mass using colligative properties; Abnormal value of molar
mass, van’t Hoff factor and its significance.
UNIT 7: EQUILIBRIUM
Meaning of equilibrium, concept of dynamic equilibrium.
Equilibria involving physical processes: Solid -liquid, liquid - gas and solid - gas equilibria, Henry’s law, general characterics of
equilibrium involving physical processes.
Equilibria involving chemical processes: Law of chemical equilibrium, equilibrium constants (Kp and Kc) and their significance,
significance of DG and DGo in chemical equilibria, factors affecting equilibrium concentration, pressure, temperature, effect of
catalyst; Le Chatelier’s principle. Ionic equilibrium: Weak and strong electrolytes, ionization of electrolytes, various concepts of acids
and bases (Arrhenius, Br??nsted - Lowry and Lewis) and their ionization, acid - base equilibria (including multistage ionization) and
ionization constants, ionization of water, pH scale, common ion effect, hydrolysis of salts and pH of their solutions, solubility of
sparingly soluble salts and solubility products, buffer solutions.
UNIT 8: REDOX REACTIONS AND ELECTROCHEMISTRY
Electronic concepts of oxidation and reduction, redox reactions, oxidation number, rules for assigning oxidation number, balancing
of redox reactions. Eectrolytic and metallic conduction, conductance in electrolytic solutions, specific and molar conductivities and
their variation with concentration: Kohlrausch’s law and its applications.
Electrochemical cells - Electrolytic and Galvanic cells, different types of electrodes, electrode potentials including standard electrode
potential, half - cell and cell reactions, emf of a Galvanic cell and its measurement; Nernst equation and its applications; Relationship
between cell potential and Gibbs energy change; Dry cell and lead accumulator; Fuel cells.
UNIT 9 : CHEMICAL KINETICS
Rate of a chemical reaction, factors affecting the rate of reactions: concentration, temperature, pressure and catalyst; elementary
and complex reactions, order and molecularity of reactions, rate law, rate constant and its units, differential and integral forms of
zero and first order reactions, their characteristics and half - lives, effect of temperature on rate of reactions - Arrhenius theory,
activation energy and its calculation, collision theory of bimolecular gaseous reactions (no derivation).
UNIT-10 : SURFACE CHEMISTRY
Adsorption- Physisorption and chemisorption and their characteristics, factors affecting adsorption of gases on solids - Freundlich
and Langmuir adsorption isotherms, adsorption from solutions.
Colloidal state - distinction among true solutions, colloids and suspensions, classification of colloids - lyophilic, lyophobic; multi
molecular, macromolecular and associated colloids (micelles), preparation and properties of colloids - Tyndall effect, Brownian
movement, electrophoresis, dialysis, coagulation and flocculation; Emulsions and their characteristics.
INORGANIC CHEMISTRY
UNIT 11: CLASSIFICATON OF ELEMENTS AND PERIODICITY IN PROPERTIES
Modem periodic law and present form of the periodic table, s, p, d and f block elements, periodic trends in properties of elements
atomic and ionic radii, ionization enthalpy, electron gain enthalpy, valence, oxidation states and chemical reactivity.
UNIT 12: GENERAL PRINCIPLES AND PROCESSES OF ISOLATION OF METALS
Modes of occurrence of elements in nature, minerals, ores; Steps involved in the extraction of metals - concentration, reduction
(chemical and electrolytic methods) and refining with special reference to the extraction of Al, Cu, Zn and Fe; Thermodynamic and
electrochemical principles involved in the extraction of metals.
UNIT 13: HYDROGEN
Position of hydrogen in periodic table, isotopes, preparation, properties and uses of hydrogen; Physical and chemical properties of
water and heavy water; Structure, preparation, reactions and uses of hydrogen peroxide; Hydrogen as a fuel.
UNIT 14: S - BLOCK ELEMENTS (ALKALI AND ALKALINE EARTH METALS)
Group - 1 and 2 Elements General introduction, electronic configuration and general trends in physical and chemical properties of
elements, anomalous properties of the first element of each group, diagonal relationships. Preparation and properties of some
important compounds - sodium carbonate and sodium hydroxide; Industrial uses of lime, limestone, Plaster of Paris and cement;
Biological significance of Na, K, Mg and Ca.
UNIT 15: P - BLOCK ELEMENTS
Group - 13 to Group 18 Elements General Introduction: Electronic configuration and general trends in physical and chemical
properties of elements across the periods and down the groups; unique behaviour of the first element in each group. Groupwise
study of the p - block elements Group - 13
Preparation, properties and uses of boron and aluminium; properties of boric acid, diborane, boron trifluoride, aluminium chloride and
alums.
Group - 14
Allotropes of carbon, tendency for catenation; Structure & properties of silicates, and zeolites.
Group - 15
Properties and uses of nitrogen and phosphorus; Allotrophic forms of phosphorus; Preparation, properties, structure and uses of
ammonia, nitric acid, phosphine and phosphorus halides, (PCl3, PCl5); Structures of oxides and oxoacids of phosphorus.
Group - 16
Preparation, properties, structures and uses of ozone; Allotropic forms of sulphur; Preparation, properties, structures and uses of
sulphuric acid (including its industrial preparation); Structures of oxoacids of sulphur. Group - 17
Preparation, properties and uses of hydrochloric acid; Trends in the acidic nature of hydrogen halides; Structures of Interhalogen
compounds and oxides and oxoacids of halogens.
Group - 18 Occurrence and uses of noble gases; Structures of fluorides and oxides of xenon.
UNIT 16: d - and f - BLOCK ELEMENTS
Transition Elements
General introduction, electronic configuration, occurrence and characteristics, general trends in properties of the first row transition
elements - physical properties, ionization enthalpy, oxidation states, atomic radii, colour, catalytic behaviour, magnetic properties,
complex formation, interstitial compounds, alloy formation; Preparation, properties and uses of K2 Cr2 O7 and KMnO4.
Inner Transition Elements Lanthanoids -
Electronic configuration, oxidation states and lanthanoid contraction. Actinoids - Electronic configuration and oxidation states.
UNIT 17: CO-ORDINATION COMPOUNDS
Introduction to co-ordination compounds, Werner’s theory; ligands, co-ordination number, denticity, chelation; IUPAC nomenclature of
mononuclear co-ordination compounds, isomerism; Bonding-Valence bond approach and basic ideas of Crystal field theory, colour
and magnetic properties; Importance of co-ordination compounds (in qualitative analysis, extraction of metals and in biological
systems).
UNIT 18: ENVIRONMENTAL CHEMISTRY
Environmental pollution - Atmospheric, water and soil. Atmospheric pollution - Tropospheric and Stratospheric Tropospheric pollutants
- Gaseous pollutants: Oxides of carbon, nitrogen and sulphur, hydrocarbons; their sources, harmful effects and prevention; Green
house effect and Global warming; Acid rain; Particulate pollutants: Smoke, dust, smog, fumes, mist; their sources, harmful effects
and prevention. Stratospheric pollution- Formation and breakdown of ozone, depletion of ozone layer - its mechanism and effects.
Water Pollution - Major pollutants such as, pathogens, organic wastes and chemical pollutants; their harmful effects and prevention.
Soil pollution - Major pollutants such as: Pesticides (insecticides,. herbicides and fungicides), their harmful effects and prevention.
Strategies to control environmental pollution.
ORGANIC CHEMISTRY
UNIT 19: PURIFICATION AND CHARACTERISATION OF ORGANIC COMPOUNDS
Purification - Crystallization, sublimation, distillation, differential extraction and chromatography - principles and their
applications.
Qualitative analysis - Detection of nitrogen, sulphur, phosphorus and halogens.
Quantitative analysis (basic principles only) - Estimation of carbon, hydrogen, nitrogen, halogens, sulphur,
phosphorus.
Calculations of empirical formulae and molecular formulae; Numerical problems in organic quantitative analysis.
UNIT 20: SOME BASIC PRINCIPLES OF ORGANIC CHEMISTRY
Tetravalency of carbon; Shapes of simple molecules - hybridization (s and p); Classification of organic compounds
based on functional groups: - C = C - , - C h C - and those containing halogens, oxygen, nitrogen and sulphur;
Homologous series; Isomerism - structural and stereoisomerism.
Nomenclature (Trivial and IUPAC)
Covalent bond fission - Homolytic and heterolytic: free radicals, carbocations and carbanions; stability of carbocations and free
radicals, electrophiles and nucleophiles.
Electronic displacement in a covalent bond -
Inductive effect, electromeric effect, resonance and hyperconjugation.
UNIT 21: HYDROCARBONS
Classification, isomerism, IUPAC nomenclature, general methods of preparation, properties and reactions.
Alkanes - Conformations: Sawhorse and Newman projections (of ethane); Mechanism of halogenation of alkanes.
Alkenes - Geometrical isomerism; Mechanism of electrophilic addition: addition of hydrogen, halogens, water, hydrogen halides
(Markownikoff’s and peroxide effect); Ozonolysis and polymerization. Alkynes - Acidic character; Addition of hydrogen, halogens,
water and hydrogen halides; Polymerization. Aromatic hydrocarbons - Nomenclature, benzene - structure and aromaticity; Mechanism
of electrophilic substitution: halogenation, nitration, Friedel - Craft’s alkylation and acylation, directive influence of functional group in
mono-substituted benzene.
UNIT 22: ORGANIC COMPOUNDS CONTAINING HALOGENS
General methods of preparation, properties and reactions; Nature of C-X bond; Mechanisms of substitution reactions.
Uses; Environmental effects of chloroform & iodoform.
UNIT 23: ORGANIC COMPOUNDS CONTAINING OXYGEN
General methods of preparation, properties, reactions and uses.
ALCOHOLS, PHENOLS AND ETHERS
Alcohols: Identification of primary, secondary and tertiary alcohols; mechanism of dehydration.
Phenols: Acidic nature, electrophilic substitution reactions: halogenation, nitration and sulphonation, Reimer - Tiemann reaction.
Ethers: Structure. Aldehyde and Ketones: Nature of carbonyl group;Nucleophilic addition to >C=O group, relative reactivities of
aldehydes and ketones; Important reactions such as — Nucleophilic addition reactions (addition of HCN, NH3 and its derivatives),
Grignard reagent; oxidation; reduction (Wolff Kishner and Clemmensen); acidity of - hydrogen, aldol condensation, Cannizzaro
reaction, Haloform reaction; Chemical tests to distinguish between aldehydes and Ketones.
CARBOXYLIC ACIDS Acidic strength and factors affecting it.
UNIT 24: ORGANIC COMPOUNDS CONTAINING NITROGEN
General methods of preparation, properties, reactions and uses. Amines: Nomenclature, classification, structure, basic character
and identification of primary, secondary and tertiary amines and their basic character.
Diazonium Salts: Importance in synthetic organic chemistry.
UNIT 25: POLYMERS
General introduction and classification of polymers, general methods of polymerization-addition and condensation, copolymerization;
Natural and synthetic rubber and vulcanization; some important polymers with emphasis on their monomers and uses - polythene,
nylon, polyester and bakelite.
UNIT 26: BIOMOLECULES
General introduction and importance of biomolecules.
CARBOHYDRATES - Classification: aldoses and ketoses; monosaccharides (glucose and fructose) and constituent monosaccharides
of oligosacchorides (sucrose, lactose and maltose).
PROTEINS - Elementary Idea of - amino acids, peptide bond, polypeptides; Proteins: primary, secondary, tertiary and quaternary
structure (qualitative idea only), denaturation of proteins, enzymes.
VITAMINS - Classification and functions. NUCLEIC ACIDS - Chemical constitution of DNA and RNA. Biological functions of nucleic
acids.
UNIT 27: CHEMISTRY IN EVERYDAY LIFE
Chemicals in medicines - Analgesics, tranquilizers, antiseptics, disinfectants, antimicrobials, antifertility drugs, antibiotics, antacids,
antihistamins - their meaning and common examples.
Chemicals in food - Preservatives, artificial sweetening agents - common examples. Cleansing agents - Soaps and detergents,
cleansing action.
UNIT 28: PRINCIPLES RELATED TO PRACTICAL CHEMISTRY
• Detection of extra elements (N,S, halogens) in organic compounds; Detection of the following functional groups: hydroxyl (alcoholic
and phenolic), carbonyl (aldehyde and ketone), carboxyl and amino groups in organic compounds.
• Chemistry involved in the preparation of the following: Inorganic compounds: Mohr’s salt, potash alum. Organic compounds:
Acetanilide, pnitroacetanilide, aniline yellow, iodoform.
• Chemistry involved in the titrimetric excercises - Acids bases and the use of indicators, oxalic-acid vs KMnO4, Mohr’s salt vs
KMnO4.
• Chemical principles involved in the qulitative salt analysis.
Cations - Pb2 +, Cu2 + Al3 +, Zn2 +-, , Ni2 +, Ca2 +, Ba2 +, Mg2 +, NH4+.
Anions - CO3 2-, S2 -, SO4 2 - NO2 NO3 -, Cl -, Br, l.
(Insoluble salts excluded).
1. Enthalpy of solution of CuSO4
2. Enthalpy of neutralization of strong acid and strong base.
3. Preparation of lyophilic and lyophbic sols.
4. Kinetic study of reaction of iodide ion with hydrogen peroxide at room temperature.
1 Physical
EXERCISE
1. A sample of protein was analyed for metal content and analysed for metal content and
analysisi revealed that it contained magnesium and titanium in equal amounts, by mass. If
these are the only metallic species present in the protein and contains 0.016% metal, the
minimum possible molar mass of the portein is [Mg=24, Ti = 48]
(A) 600000 (B) 150000 (C) 300000 (D) 1200000
2. 1 mol of N2 and 4 mol of H2 are allowed to react in a vessel to form NH3 gas as only product
and after reaction, water is added. Aqueous solution required 1 mol of HCl for complete
reaction. Mol fraction of H2 in the gas mixture after reaction is
(A) 1/6 (B) 5/6 (C) 1/3 (D) 1.0
3. pH of 0.05 M H2SO4 solution will be
(A) 0.005 (B) 2 (C) 1 (D) 0.01
4. Which of the following does not make any change in pH when added to 10 mi dilute HCl
(A) 5 ml pure water (B) 20 ml pure water (C) 10 ml HCl (D) Same 20 ml dilute HCl
5. The pH of a soft drink is 3.82. Its hydrogen ion concentration will be
(A) 1.96×10–2 mol/l (B) 1.96×10–3 mol/l (C)1.5×10–4 mol/ l (D) 1.96×10–1 mol / l
6. A monoprotic acid in a 0.1 M solution ionizes to 0.0001%. Its ionization constant is
(A) 1.0×10–3 (B) 1.0×10–6 (C) 1.0×10–8 (D) 1.0×10–10
7. In the reaction A+2B 2C, if 2 moles of A.3.0 moles of B and 2.0 moles of C are placed in
a 2.0 lit. flask flask and the equilibrium concentration of C is 0.5 mole/ l. The equilibrium
constant (KC) for the reaction is
(A) 0.073 (B) 0.147 (C) 0.05 (D) 0.026
8. For which state of matter, the coefficient of cubic expansion is independent to chemical
composition ?
(A) solid (B) liquid (C) gas (D) all
k1
9. In a reversible 2NO2 N2O4, the rate of disappearance of NO2 is equal to
k2
k1 2
(A) k [NO2 ] (B) 2k1 [NO2]2– 2k2 [N2O4]
2
(C) 2k1 [NO2]2 – k2 [N2O4] (D) (2k1–k2) [NO2]

10. 4.5 moles each of hydrogen and iodine headed in a sealed ten litre vessel. At equilibrium, 3
moles of HI were found. The equilibrium constant for H2(g) + I 2(g) 2HI(g) is
(A) 1 (B) 10 (C) 5 (D) 0.33
11. Average velocity of molecules of an ideal gas in a container, moving only in one dimension, is
8RT 1 8RT
(A) (B) (C) zero (D) Infinite
M 3 M
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12. In a chemical equilibrium A+B C+D, when one mole each of the two reactants are mixed,
0.6 mole each of the products are formed. The equilibrium constant calculated is
(A) 1 (B) 0.36 (C) 2.25 (D) 4/9
13. The ratio PVm/RT fof a gas is known as the compressibility factor. What is the value of this
ratio ofr one mole of a vanderwaal's gas at its Boyle temperature ?
b2 b2 b b2
(A) 1  (B) 1  2 (C) 1  (D) 1 – 2
Vm(Vm  b) Vm Vm Vm
14. The following equilibrium exists in aqueous solution CH3COOH CH3COOH— + H+. If dilute
HCl is added without a change in temperature then the
(A) Concentration of CH3COO– will increase
(B) Concentration of CH3COO– will decrease
(C) Equilibrium constant will increase
(D) Equilibrium constant will decrease
15. Reaction in which yield of product will increases with increases in pressure is
(A) H2(g) + I2(g) 2HI(g (B) H2O(g) + CO(g) CO2(g)+H2(g)
(C) H2O(g) + C(s) CO(g) + H2(g) (D) CO(g)+ 3H2(g) CH4(g) + H2O(g)
16. The distance between tow nearest neighbors in body centered cubic lattice of axial length, l,
is
3 2
(A) l (B) l (C) l (D) none
2 2
17. Let the height of hop unit cell is 'h'. The height of tetrahedral voids from the bases i
h h 2h h 7h h 3h
(A) (B) , (C) , (D) ,
2 2 3 8 8 4 4
18. 3.0 molal NaOH solution has a density of 1.110 g/ml. The molarity of the solution is
(A) 3.0504 (B) 3.64 (C) 3.05 (D) 2.9732
19. Boiling point of chloroform was raised by 0.323 K, when 0.5143 g of anthracence was
dissolved in its its 35 g. Molecular mass of ant hracence is (Kb for CHCl3 = 3.9 k-kg-mol–1)
(A) 79.42 g/mol (B) 132.32 g/mol (C) 177.42 g/mol (D) 242.32 g/mol
20. A solution containing 30 gms of non-volatile solute in exactly 90 gm water has a vapour
pressure of 21.85 mm Hg at 25° C. Further 18 gms of water is then added to the solution. the
resulting solution has a vapour pressure of 22.15 mm Hg at 25°C, Calculate the molecular
weight of the solute
(A) 74.2 (B) 75.6 (C) 70.3 (D) 78.7
N
21. With 63 gm of oxalic acid how many litres of solution can be prepared
10
(A) 100 litre (B) 10 litre (C) 1 litre (D) 1000 litre
22. The heat evolved on combustion of 1 gm of starch, (C6H10O5), into CO2(g) and H2O(l) is 4.18
Kcal. What is the standard enthalpy of formation of 1 gm of starch ? Heat of formation of
CO2(g) and H2O(l) are –94.05 and –68.32 Kcal/mol.
(A) –2.82 Kcal (B) –0.71 Kcal (C) – 1.41 Kcal (D) – 8.46 Kcal
23. The bond enthalpies of C–C=C and bonds are are 348, 610 and 835 kJ/mol, respectively at
298K and 1 bar. The enthalpy of polymeristion permole mole of 2-Butyne at 298K and 1 bar, as
shown below, is
n CH3–C  C—CH3 (g)  –(CH2–CH=CH–CH2)n –(g)
(A) –123 kJ (B) –132 kJ (C) – 139 kJ (D) – 37 kJ
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24. Which of the following in not correct for dieal solution

(A) Smix=0 (B) Hmix=0
(C) It obeys Raoult's law (D) Vmix= 0
25. A 5% solution of canesugar (mol. wt. = 342) is isotonic with 1% solution of a substance X.
the molecular weight of X is
(A) 34.2 (B) 171.2 (C) 68.4 (D) 136.8
26. A certain aqueous solution of FeCl3 (formula mass =162) has a density fo 1.1 g/ml and
contains 20.0% FeCl3. Molar concentration of this solution is.
(A) 0.028 (B) 0.163 (C) 1.27 (D) 1.47
27. The exact mathermatical expression of Raoult's law is (n= moles of non-volatile solute, N =
moles of solvent, P = V.P. os solution & P°=V.P. of pure solvent)
P0 – P n P0 – P N P0 – P n P0 – P
(A)  (B)  (C)  (D)  nN
P0 N P0 n P N P0
28. Pressure over an ideal binary liquid solution contaaining 10 moles each of liquid A and B is
gradually decreased isothermally. At what pressure, half of the total amount of liquid will get
converted into vapour ? (P0A=200 torr, P0B = 100 torr)
(A) 150 torr (B) 166.5 torr (C) 133.3 torr (D) 141.4 torr
29. Which of the following sets is possible for quantum numbers

1
(A) n=4, l=3, m=–2, s=0 (B) n=4, l=4, m=+2, s=–
2
1 1
(C) n=4, l=4, m=–2, s=+ (D) n=4, l=3, m=–2, s=+
2 2
30. The value of Planck's constant is 6.63×10–34 Js. The velocity of light is 3.0×108 ms–1. Which
value is closest to the wavelenggh in nanometres of a quantum of light with frequency of
8×1015 S–1
(A) 3×107 (B) 2×10–25 (C) 5×10–18 (D) 4×101
31. Values of four quantum numbers for the last electron in the atom are n=4, l=1, m=+1 and s=–
1
. Atomic number of the atom will be
2
(A) 22 (B) 32 (C) 33 (D) 36
32. which one of the following explains light both as a stream of particles and as wave motion
h
(A) Diffraction (B)   (C) Interferecne (D) Photoelectric effect.
p
33. On adding AgNO3 solution into KI solution, a negatively charged colloidal sol is obtained when
they are in
(A) 100 ml of 0.1 M-AgNO3 +100 ml of 0.1 M-KI
(B) 100 ml of 0.1 M-AgNO3 +50 ml of 0.2 M-KI
(C) 100 ml of 0.1 M-AgNO3 +50 ml of 0.1 M-KI
(D) 100 ml of 0.1 M-AgNO3 +100 ml of 0.15 M-KI
34. Be's 4th electron will have four quantum numbers

n l m ms
(A) 1 0 0 +1/2
(B) 1 1 +1 +1/2
(C) 2 0 0 –1/2
(D) 2 1 0 +1/2

35. In a 3.0 litre vessel, the following equilibrium partial are measured : N2 = 100 mm, H2=400 mm
and NH3=100 mm. Nitrogen is removed from the vessel at constant temperature unit the
pressure of hydrogen at equilibrium is equal to 700 mm. The new equilibrium partial pressure
of N2 is
(A) 11.94 mm (B) 200 mm (C) 18.66 mm (D) 43.78 mm
36. Suppose the gas phase isomeriation reactions A B, A C and B C reach equilibrium at a
fixed temperature. Express the quilibrium mole fraction of A in terms of equilibrium constants,
which are K1, K2 and K3 respectively.
K1 1 1 1
(A) K  K  K (B) 1  K  K (C) K  K  K (D) K  K
1 2 3 1 2 1 2 3 1 2
37. The data for the rection A+B  C is

Exp. [A]0 [B]0 Inittila rate
1 0.012 0.035 0.10
2 0.024 0.070 0.80
3 0.024 0.035 0.10
4 0.012 0.070 0.80
The rate law corresponds to the above data is
(A) Rate = k[B]3 (B) Rate = k[B]4 (C) Rate = k[A] [B]3 (D) Rate = k[A]2 [B]2
38. The rate of a gaseous reaction is given by the expression K [A] [B]. If the volume of the
reaction vessel is suddenly reduced to 1/4th of the initial volume, the reaction rate relating to
original rate will be
(A) 1/10 (B) 1/8 (C) 8 (D) 16
39. The rate of of reaction is doubled for every 10° rise in temperature. The increases in reaction
rate as a result of temperature rise from 10° to 100° is
(A) 112 (B) 512 (C) 400 (D) 614
1
40. The decomposition of N2O5 is a first order reacton represented by N2O5  N2O4+ O . After
2 2
15 minutes the volume of O2 produced is 9 ml and at the end of the reaction 35 mL. The rate
constant it equal to
1 35 1 44 1 44 1 35
(A) In (B) In (C) In (D) In
15 44 15 26 15 35 15 36
1
41. C+ O  CO; H = –42 kJ
2 2
1
CO+ O  CO2; H = –24 kJ
2 2
The heat of formation of CO2 is
(A) –16 kJ (B) +66 kJ (C) +16 kJ (D) –66 kJ
42. The heat of combustion of CH4(g). C(graphite) and H2(g) are 20 kcal, –40 kcal and –10 kcal
respectively. The heat of formation of methane is
(A) –4.0 kcal (B) + 40 kcal (C) –80 kcal (D) + 80 kcal
43. The work done in ergs for the reversible expansion of one mole of an ideal gas from a volume
of 10 litres to 20 litres at 25° C is
(A) 2.303×298×0.082 log 2 (B) 298×107×8.31×2.303 log 2
(C) 2.303×298×0.082 log 0.5 (D) 8.31×107×298–2.303 log 0.5
44. When different types of salts have nearly solubility product constant Ksp but less than one,
the most soluble salt is that which
(A) produces maximum nuber of ions (B) produces minimum number of ions
(C) produces high charge on ion (D) produces low chages on ions
45. When 20 ml of a strong acid is added to 20 ml of an alkali, the temperature rises by 5°C. If
200 ml of each liquid are mixed, the temperature rise would be
(A) 5°C (B) 50°C (C) 20°C (D) 0.5°C
46. To perform an analysis of a mixture of metal ions by electrodeposition, the second metal to be
deposited must not being plating out until the concentration ratio of the second to the first is
about 106. What must be the minimum difference in standard potential of the two metals at
25°C, which form dipositive ions in order for such an analysis to be feasible ?
(A) 0.177 V (B) 0.354 V (C) 0.708 V (D) 0.005 V
47. The heat of neutralisation of a strong acid and a strong alkali is 57.0 kJ mol–1. The heat
released when 0.5 mole of HNO3 solution, is mixed with 0.2 mole of KOH is.
(A) 57.0 kJ (B) 11.4 kJ (C) 28.5 kJ (D) 34.9 kJ
48. In a discharge tube, there are only two hydrogen atoms. If the electrons in both atoms are
de-exciting from 4th orbit, the minimum and maximum number of spectral lines should respectively
be
(A) 1, 4 (B) 4, 1 (C) 3, 4 (D) 1, 6
49. If n and l are respectively the principal and azimuthal numbers, then the expression for
calculating the total number of electrons in any energy level is
l n l  n–1 l n 1 l n–1
(A)  2(2l  1)
l1
(B)  2(2l  1) (C) 
l0
2(2l  1) (D)  2(2l  1)
l 0
l 1
50. The mass defect of the nuclear reaction: 5B84Be8+e+ is

(A) m = At, mass of 5B8 – At. mass of 4Be8
(B) m = At, mass of 5B8 – At. mass of 4Be8+mass of one electron
(C) m = At, mass of 5B8 – At. mass of 4Be8–mass of one electron
(D) m = At, mass of 5B8 – At. mass of 4Be8+mass of two electron
51. An electron is allowed to move freely in a closeed cubic box of length of side 10 cm. The
maximum uncertainty in its velocity will be –
(A) 3.35 × 10–3 m/sec (B) 5.8 × 10–4 m/sec
(C) 4 × 10 m/sec
–5
(D) 4 × 10–6
52. A single e– in an ion has ionization energy equal to 217.6 ev. What is total no. of neutrons
present in one ion of it?
(A) 2 (B) 4 (C) 5 (D) 9
53. A small particle of mass m in such a way that P.E. = – 1/2 mKr2, where K is a constant and r
is distance of particle from origin. Assuming Bohr's model of quantization of angular momentum
and circular orbit, r is directly proportional to –
(A) n2 (B) n (C) n (D) None
54. If value of l = 0 to (n + 1) then calculate max. no. of elements in II period of pariodic table
(A) 2 (B) 8 (C) 18 (D) 32
55. When 2L mixture of CO & CO2 is passed over red hot charoal, its volume increased by 1.4
times. If all the volume measurement one made under similar conditions of P & P. Find out the
% composition of mixture –
(A) 40 %, 60% (B) 60 %, 40 % (C) 50 %, 50% (D) 70 %, 30 %
56. 0.8 mole of a mixture of CO & CO2 requires exactly 40 gm of NaOH is solution for conversion of
all the CO2 into Na2CO3. How many moles of NaOH would it requires for conversion nito Na2CO3
if the mixture (0.8 mle) is completely oxidised to CO2?
(A) 0.2 (B) 0.6 (C) 1 (D) 1.5
57. The total no. of neutrons present is 54 ml H2O () are –

(A) 3 NA (B) 30 NA (C) 24 NA (D) None of these

58. The sulphate of a metal contains 20% metal. This sulphate is isomorphous with zinc sulphate
hepta hydrate. The atomic mass of the metal is–
(A) 30 (B) 12 (C) 24 (D) 36
59. If w1 g of a metal X displaces w2 g of another metal Y from its salt solution and if the
equivalent weights are E1 and E2 respectively, the correct expression for the equivalent
weight of X is :
w1 w2  E2 w1  w2 w1
(A) E1 =  E2 (B) E1 = (C) E1 = (D) E1 =  E2
w2 w1 E2 w2
60. A metal oxide is reduced by heating it in a stream of hydrogen. It is found that after complete
reduction, 3.15 g of oxide yielded 1.05 g of metal. From the above data we can say that
(A) The atomic weight of metal is 8 (B) The atomic weight of metal is 4
(C) The equivalent weight of metal is 4 (D) The equivalent weight of metal is 8
61. 100 mL of 0.1 N hypo decolourised iodine by the addition of x gram of crystalline copper
sulphate to excess of KI. The value of 'x' is
(molecular wt. of CuSO4.5H2O is 250)
(A) 5.0 g (B) 1.25 g (C) 2.5 g (D) 4 g
62. Which of the following is not a redox reaction?

(A) 2Na + Cl2  2NaCl (B) C + O2  CO2
(C) AgNO3 + NaCl  AgCl + NaNO3 (D) Zn + H2SO4  ZnSO4 + H2
63. The value of n in

MnO4– + 8H+ + ne–  Mn2+ + 4H2O is
(A) 5 (B) 4 (C) 2 (D) 3
64. When KMnO4 acts as an oxidizing agent and ultimately forms MnO42–, MnO2, Mn2O3 and Mn2+
then number of electrons transferred in each case respectively are–
(A) 4, 3, 1, 5 (B) 1, 5, 3, 7 (C) 1, 3, 4, 5 (D) 3, 5, 7, 1
65. The ratio between the root mean square velocity of H2 at 50 K and that of O2 at 800 K is
(A) 1 (B) 4 (C) 2 (D) 1/4
66. 1.22 g of a gas measured over water at 15ºC and a pressure of 775 mm of mercury occupied
900 mL. Calculate the volume of dry gas at NTP (vapour pressure of water at 15ºC is 14 mm).
(A) 372.21 mL (B) 854.24 mL (C) 869.96 mL (D) 917. 76 mL
67. A bhalloon filled with methane gas is pricked with a sharp point and quickly plunged into a
tank of hydrogen at the same pressure. After sometime, the balloon will have
(A) Enlarged (B) Collapsed
(C) Remained unchanged in size (D) Unpredictable
68. Gas CO CH4 HCl SO2

Critical
temp.Tc(K) 134 190 324 430
In the context of given values of critical temperature, the greter ease of liquefication is of
(A) SO2 (B) HCl (C) CH4 (D) CO
69. In the heterogeneous equilibrium:

CaCO3(s) NH3(g) ; Kp = 4.0 ×104
what would be the effect of addition of CaCO3 on the equilibrium concentration of CO2?
(A) increases (B) Unpredictable (C) Decreases (D) Remains unaffected
70. What is Gº for the following reaction?

1/2 N2(g) + 3/2 H2(g) NH3(g) ; Kp = 4.0 ×104 at 25ºC
(A) –26.5 kJ mol –1
(B) –11.5 kJ mol–1 (C) – 2.2 kJ mol–1 (D) – 0.97 kJ mol–1
71. Reaction K
1/2N2(g) + O2(g) NO2(g) K1
1/2N2(g) + O2(g) NO2(g) K2
Using above equations, write down expression for K of the following reaction :
N2O2(g) N2(g) + 2O2(g)
K 22 1 1
(A) K1K2 (B) (C) K K (D)
K1 2 1 K12K 2
72. In Haber's process, the ammonia is manufactured according to the following reaction:
N2(g) + 3H2(g) 2NH3(g) ; Hº = – (22.4 kJ)
The pressure inside the chamber is maintained at 200 atm and temperature at 500ºC. Generally,
this reaction is carried out in presence of Fe catalyst.
The preparation of ammonia by Haber's process an exothermic reaction. If the preparation

follos the following temperature pressure relationship for its % yield. Then for temperature T1,
T2 and T3 the correct option is :
50
40 T3
% yield
30 T2
20 T1
10
1 2 3 4
Pressure (atm)
(A) T3 > T2 > T1 (B) T1 > T2 > T3
(C) T1 = T2 = T3 (D) Nothing could be predicted
N2(g) + 3H2(g) 2NH3(g) ; Hº = – (22.4 kJ)
If Kp for the reaction is 1.44 × 10–5 then the value of Kp for the decomposition of NH3,
2NH3(g) N2(g) + 3H2(g)
will be:
1
(A) 1.44  10  5 (B) (1.44×10–5)2 (C) (D) 2.88 × 10–5
1.44  10 5
N2(g) + 3H2(g) 2NH3(g) ; Hº = – (22.4 kJ)
For which of these processes is the value of S negative ?

a. Sugar is dissolved in water
b. Stream condenses on a surface
c. CaCO3 is decomposed into CaO and CO2
(A) a only (B) b only (C) a and c only (d) b and c only

75. Consider this equation and the associated value for Hº.
2H2(g) + 2Cl2(g) 4HCl(g) ; Hº = – 92.3 kJ
Which statement about this information is incorrect?
(A) If the equation is reversed, the Hº value equals + 92.3 kJ
(B) The four HCl bonds are stronger than four bonds in H2 and Cl2
(C) The Hº value will be –92.3 kJ if HCl is produced as a liquid
(D) 23.1 kJ of heat will be evolved when 1 mole of HCl (g) is produced
76. The heat of formation (Hºf) of H2O() is equal to:

(A) Zero (B) Molar heat of combustion of H2()
(C) Molar heat of combustion of H2(g) (D) Sum of heat of formation of H2O(g) and O2(g)
77. Which salt can furnish H+ in its aqueous solution:

(A) NaH2PO2 (B) Na2HPO3 (C) Na2HPO4 (D) All of these
78. Given that Kw for water is 10–13 M2 at 62ºC, compute the sum of pOH and pH for a neutral
aqueous solution at 62ºC.
(A) 7.0 (B) 13.30 (C) 14.0 (D) 13.0
79. 1 mL of 0.1 N HCl is added to 999 mL solution of NaCl. The pH of the resulting solution will be:
(A) 7 (B) 4 (C) 2 (D) 1
80. What is the molar solubility of Ag2CO3 (Ksp = 4 × 10–13) in 0.1 M Na2CO3 solution ?
(A) 10–6 (B) 10–7 (C) 2 × 10–6 (D) 2 × 10–7
81. Which of the following sets of quantum numbers is not possible ?
1 1
(A) n=2, =1, m = –1, s=– (B) n=2, =0, m = 0, s=+
2 2
1 1
(C) n=3, =2, m = –2, s=+ (D) n=3, =2, m = –3, s=+
2 2
82. The mass of the proton is 1840 times that of electron. If it accelerated by applying a
potential difference of 1 kV, the kinetic energy of proton is
1
(A) 1840 keV (B) keV (C) 1 keV (D) 920 keV
1840
83. The firest emission line in the atomic spectrum of hydrogen in the Balmer series appears at -
5R 3R 7R 9R
(A) cm–1 (B) cm–1 (C) cm–1 (D) cm–1
36 4 144 400
84. The four quantum numbers of valence electron of potassium are
1 1 1 1
(A) 4,0,1 (B) 4, 1, 0, (C) 4,0,0 (D) 4,1,1,
2 2 2 2
85. The energy of an electron in nth orbit of hydrogen atom is
13.6 13.6 13.6 13.6

(A) eV (B) eV (C) eV (D) eV
n4 n3 n2 n
86. If threshold wavelength (°) for ejection of electron from metal is 330 nm, then work function
for the photoelectric emission is -
(A) 6×10–10 J (B) 1.2×10–18 J (C) 3×10–19 J (D) 6×10–19 J
87. The uncertainty in the position of an electron moving with a velocity of 1.0×104 cm s–1
(accurate up to 0.011%) will be
(A) 1.92 cm (B) 7.68 cm (C) 0.528 cm (D) 3.8 cm
88. The ionization energy of hydrogen atom is 13.6 eV. The third ionization energy of lithium
would be -
(A) 13.6 eV (B) 27.2 eV (C) 40.8 eV (D) 122.eV
89. For a 'p'-electron the orbital angular momentum is
(A) 6 h (B) 2 h (C) h (D) 2 h
90. The mass of CO2 that shall be obtained by heating 10 kg of 80% pure limestone (CaCO3) is -
(A) 4.4 kg (B) 6.6 kg (C) 3.52 kg (D) 8.8
91. The number of atoms in 20 g of SO3 is approximately -

(A) 1×1023 (B) 1.5×1023 (C) 2×1023 (D) 6×1023
92. The number of moles of SO2 in 6.4 g is

(A) 0.1 (B) 0.2 (C) 0.3 (D) 0.4
93. The number of ions present in 2.0 L of a solution of 0.8 M K4[(FeCN)6] is

(A) 4.8×1022 (B) 4.8×1024 (C) 9.6×2424 (D) 9.6×1022
94. The number of moles of BaCO3 which contains 1.5 moles of oxygen atoms is -
(A) 0.5 (B) 1 (C) 3 (D) 6.02×1023
95. The specific heat of metal is 0.16. Its approximate atomic weight would be -
(A) 32 (B) 16 (C) 40 (D) 64
96. Caffeine has a molecular mass of 194. If it contains 29.9% by mass of nitrogen, number of
atoms of nitrogen in one molecule of caffeine is -
(A) 4 (B) 6 (C) 2 (D) 3
97. The simplest formula of a compound containing 50% of element X (atomic mass 10) and 50%
of element Y (atomic mass 20) is
(A) XY (B) X2Y (C) XY3 (D) X2Y2
98. No. of moles in 11.2 L of CO2 at NTP is -

(A) 0.5 (B) 0.3 (C) 0.2 (D) 0.1
99. The oxidation number of I in HIO4 is -

(A) 7 (B) 6 (C) 9 (D) 4
100. In which of the following reaction, oxidation number of N does not change -
(A) 2NO2+H2OHNO3+HNO2 (B) N2+O22NO
(C) 2NO2N2O4 (D) NH4NO2N2+2H2O
101. In the following equation :

Cl3—+6H++. XCl—+3H2O, then X is
(A) O (B) 6e— (C) O2 (D) 5e—

102. In the equation :

Cr2O72—Fe2+H+Cr3+Fe3++H2O
the coefficients of Fe2+ and H+ are respectively
(A) 6, 7 (B) 6, 14 (C) 5, 7 (D) 5, 14
103. Oxidation number of sulphur in H2SO5 is -

(A) +2 (B) +4 (C) +8 (D) +6
104. Which of the following process represents disproportionation ?

(A) Cu+4HNO3Cu(NO3)2+2NO2+2H2O (B) 3I2+6OH—IO3—+5I—+3H2O
(C) Cl2+I2  2ICl (D) Zn+2HCI  ZnCl2 +H2
105. In alkaline medium, KMnO4, reacts as follows

2KMnO4+2KOH  2K2MnO4+H2O+O
Therefore, the equivalent mass of KMnO4 will be
(A) 31.6 (B) 52.7 (C) 7.0 (D) 158.0
106. A meallic oxide contains 60% of the metal is

(A) 12 (B) 24 (C) 48 (D) 72
107. 30 mL of diabasic acid is neutralized by 15 mL of 0.2 N NaOH. The molarity of the acid is
(A) 0.05 M (B) 0.2 M (C) 0.3 M (D) 0.4 M
108. 100 mL of a mixture of NaOH and Na2SO4 is neutralized by 10 mL of 0.5 M H2SO4 .The amound
of NaOH in 100 mL solution is
(A) 0.2 g (B) 0.4 g (C) 0.6 g (D) 0.8 g
109. A 1.0 g sample of H2O2 solution contains x% by mass and requires x mL of KMnO4 in acidic
solution for complete oxidation. The normality of KMnO4 is -
(A) 0.58 (B) 0.116 (C) 0.25 (D) 0.3
110. Equivalent mass of FeC2O4 in the reaction

FeC2O4  Fe+3CO2 is -
(A) M (B) M/2 (C) M/3 (D) 2M/3
111. Electrolysis of hot aqueous solution of NaCl gives NaClO4, i.e., sodium perchlorate,
NaCl + 4H2O  NaClO4 + 4H2 
Now many faraday are required to obtain 1000 g of sodium perchlorate ?
(A) 65.3 (B) 40.3 (C) 18.3 (D) 31.6
112. Salt of A (atomic mass 15), B (atomic mass 27) and C (atomic mass 48) were electrolysed
using same amount of charge. It was found that when 4.5 g of A was deposited, the mass of
B and C deposited were 2.7 g and 9.6 g. The valencies of A, B and C were respectively :
(A) 1, 3 and 2 (B) 3, 1 and 3 (C) 3, 1 and 2 (D) 2, 3 and 2
+ 2+
113. 2Ag (aq) + Cu(s) Cu (aq) + 2Ag(s)
The standard potential Eº for this reaction is 0.46 V. Which change will increase the potential
the most ?
(A) Doubling the [Ag+]
(B) Halving the [Cu2+]
(C) Doubling the size of the Cu(s) electrode
(D) Decreasing the size of the Ag electrode by one-half
114. The plot of cell potential (Ecell) against log10 Q may be given as :
Ecell
log Q
Which of the following is /are correct about the plot ?
0.059
(A) Slope of line = – (B) Intercept = Eºcell
n
(C) Slope of line = Eºcell (D) (A) & (B) Both
115. The relationship between osmotic pressure at 273 K when 10 g of glucose (P1) ; 10 g of urea
(P2) and 10 g of sucrose (P3) are dissolved in 250 mL of water is :
(A) P1 > P2 > P3 (B) P3 > P1 > P2 (C) P2 > P1 > P3 (D) P2 > P3 > P1
116. FeCl3 on reaction with K4[Fe(CN)6] in aqueous solution gives blue colour. These are separated
by a semipermeable membrane AB as shown. Due to osmosis there is :
A
0.1 M
0.01 M FeCl3
K4Fe(CN)6
Side X Side Y
B
(A) blue colour formation in side X
(B) blue colour formation in side Y
(C) blue colour formation in both of the sides X and Y
(D) no blue colour formation
117. Solubility of oxygen gas in water follows Henry's law. When the solubility is plotted against
partial pressure at a definite temperature we get following plots.
T4
T3
Solubility of T2
O2 in water T1
Partial Pressure
of O2
Which of the following sequence of temperatures is correct ?

(A) T1 = T2 = T3 = T4 (B) T1 > T2 > T3 > T4 (C) T1 < T2 < T3 < T4 (D) T1 > T2 < T3 > T4

118. The number of maganess ions in tetrahedral and octahedral sites, respectively in Mn3O4 are :
(A) one Mn2+ and two Mn3+ ions (B) one Mn3+ and two Mn2+ ions
(C) two Mn3+ and one Mn2+ ions (D) two Mn2+ and one Mn3+ ions
119. Xenon crystallizes in face centered cubic unit cell with edge length of 620 pm then radius of
xenon atom is :
(A) 268 pm (B) 219.20 pm (C) 436.6 pm (D) 526.8 pm
B
A
120.
If all the atoms, on the shaded plane are removed then the molecular formula of the solid will
be :
(A) A5 B7 (B) A7 B5 (C) AB (D) A3 B4
121. The rate constant of a reaction depends on

(A) Temperature (B) Initial concentrations of the reactants
(C) Extent of reaction (D) None of these
122. In the following reaction, how is the rate of appearance of the underlined product related to
the rate of disappearance of the underlined reactant
BrO3–(aq) + 5Br–(aq) + 6H+ (aq)  3Br2() + 3H2O(aq)
d[BrO3 ] d[Br2 ] d[BrO3 ] d[Br2 ]

(A)   (B)  1 
dt dt 3 dt dt
 d[BrO3 ] 1 d[Br2 ]
(C)  (D) None of these
dt 3 dt
123. Which of the following expressions is correct for zero order and first order respectively
[where a is initial concentration] ?
1
(A) t1 / 2  a; t1 / 2  (B) t1 / 2  a; t1 / 2  aº
a
1
(C) t1 / 2  aº ; t1 / 2  a (D) t1 / 2  a; t1 / 2  2
a
124. Which one has highest co-agulation power to co-agulate the ferric hydroxide sol -
(A) NaCl (B) MgSO4 (C) Ca3 (PO4)2 (D) all equal
125. Milk is -
(A) liquid in liquid (B) solid in solid (C) liquid in solid (D) solid in liquid
x
126. When graph is plotted between log10 & log10 P then value of intercept & slope will be
m
1 1
(A) n, log K (B) log K (C) , log K (D) log K, n
n n
127. 18.0 sec are required for the diffusion of x mol of O2 through some porous partition. Another
gas G requires 45.0 sec ofr the diffusion of x mol through the saem partition under similar
conditions, the molar mass of G is
2 2 2 2
 45   45  (32)   18   18  1
(A)    (32) (B)   (C)   ×32 (D)   
 18   18   45   45  32
128. The r.m.s. speed of molecules of a gas of density 4.0 kg m–3 and pressure 1.2×105 Nm–2 is-
(A) 300 m s–1 (B) 900 m s–1 (C) 600 m s–1 (D) 400 m s–1
129. The kinetic energy of 2.8 g of nitrogen gas at 127°C in nearly -

(A) 249.3 J (B) 200.4 J (C) 498.8 J (D) 20.5 J
130. Rates of essusion of hydrogen and deuterium under similar conditions are in the ratio;
(A) 1:1 (B) 2 :1 (C) 2:1 (D) 1:4
131. Ideal gas obeying kinetic theory of gases can be liquefied if -

(A) T>TC (B) P>PC
(C) P>P and T<TC (D) It cannot be liquefied at any value of P and T
132. 2 moles fo an ideal gas are compressed isothermally (100°C) and reversibly from a pressure of
10 atm. The value of Wrev. is _
(A) –200 R log 2/5 (B) 746 R In 2/5 (C) +200 R log 5/2 (D) 746 R In 5/2
133. If Hlattice and Hhydration of NaCl are respectively 778 and –774.3 kJ mol–1 and Sdissolution of NaCl
at 298 K is 43 J mol–1. The value of G° for dissolution of 1 mole of Nacl is -
(A) –9.114 kJ (B) –11.14 kJ (C) –7.114 kJ (D) +9.114 kJ
134. Which of the following equaton represents the value for Hf of AgI
1
(A) Ag+ (aq)+I—(aq) AgI(s) (B) Ag(g)+ I (g) AgI(s)
2 2
1
(C) 2Ag(s)+I2(g) 2AgI(s) (D) Ag(s)+ I (s)  AgI(s)
2 2
135. Given the bond energies of NN, and N–H bonds as 945, 436 and 391 kJ/mol respectively, the
enthalpy of reaction N2(g)2NH3(g) is
(A) 102 kJ (B) 90 kJ (C) –93 kJ (D) 105 kJ
136. In a chemical reaction, the rate constant for the backward reaction is 7.5×10–4 and the
equilibrium constant is 1.5. The rate constant for the forward reaction is –
(A) 5×10–4 (B) 2×10–3 (C) 1.125×10–3 (D) 9.0×10–4

137. A quanity of PCl5 was heated in a 2 litre vessel at 525 K. It dissociates as

PCl5(g) PCl3(g)+Cl2(g)
At equilibrium 0.2 mol each of PCl5, PCl3 and Cl2 is found in the reaction mixture. The equilib-
rium constnat KC for the reaction is -
(A) 0.2 (B) 0.5 (C) 0.1 (D) 0.05
138. For the equilibrium

NH4HS(s) NH3(g)+H2S(g)
KC=1.8×10 –4
at 298 K. The value of Kp at 298 K would be -
(A) 0.108 (B) 4.4×10–3 (C) 1.8×10–4 (D) 4.4×10–4
139. If K for the reaction 2HI(g) H2(g) + I2(g), is 0.025 at a certain temperature, the value of
K for the reaction H2(g)+I2(g) 2HI(g) at the same temperature would be -
(A) 10 (B) 40 (C) 30 (D) 40

140. The dissociation constants of two acids HA1 and HA2 are 3.0×10–4 and 1.8×10–5 respectively.
The relative strenghts of the acids will be appoximately
(A) 1:4 (B) 4:1 (C) 1:16 (D) 16:1
141. The solubility product Ksp fo the sparingly solubel salt Ag2CrO4 is 4×10–12. The solubility of the
salt is -
(A) 1×10–12 mol L–1 (B) 2×10–6 mol L–1 (C) 1×10–6 mol L–1 (D) 1×10–4 mol L–1
142. If Ka=10–5 for a weak acid, then pKb for its conjugate base would be -
(A) 10–10 (B) 9 (C) 10–9 (D) 5
143. A solution is prepared by mixing equal volumes of 0.4 M CH3COOH and 0.2 M CH3COONa. Ka for
CH3COOH = 10–6. the pH of the resulting solution would be.
(A) 6 (B) 5.69 (C) 6.69 (D) 6.5
144. A 0.01 M ammonia solution is 5% ionized, the concentration of OH— ion is

(A) 0.005 M (B) 0.0001 M (C) 0.0005 M (D) 0.05 M
145. Select the incorrect statement for CsCl crystal.

(A) Co-ordination number for Cs+ and Cl– is 6
r 
Cs
(B) r = 0.732
–
Cl
(C) The structure changes to NaCl at 760 K

(D) Cl– ions are present at cubic sites
146. The number of atoms in 100 gm of an fcc crystal with density d = 10 g/cm3 and cell edges as
200 pm is equal to -
(A) 3 × 1025 (B) 5 × 1024 (C) 1 × 1025 (D) 5.96 × 10–3
147. The correct statement regarding defects in solids is -

(A) Frenkal defect is favoured by a very small difference in the size of cation & anion
(B) Frenkal defect is not a dislocation defect
(C) Trapping of e– in lattice leads to the formation of F-center
(D) Schottky defects ahve no effect on the physical properties of solid
148. What will be order of reaction and rate constant for a chemical change having log t50% v/s log
cnc. (a) curve as.
log t50%
45º
log a
(A) 0, 1/2 (B) 1, 1 (C) 0, 1 (D) 3, 1
dx
149. For a reaction = K[H+]. If pH of reaction medium changes from two to one the rate
dt
becomes 100 times of value at pH = 2, The order of reaction is -
(A) 1 (B) 2 (C) 0 (D) 3
Questions based on statements (Q. 150 - 167)

Each of the questions given below consist of Statement – I and Statement – II. Use the
following Key to choose the appropriate answer.
(A) If both Statement - I and Statement - II are true, and Statement - II is the correct
explanation of Statement- I.
(B) If both Statement-I and Statement - II are true but Statement - II is not the correct
explanation of Statement-I.
(C) If Statement-I is true but Statement - II is false.
(D) If Statement-I is false but Statement - II is true.
150. Statement - I : All the members of any class of hydrocarbon (alkane, alkene, alkyne or
arene) have the same, empirical formula.
Statement - II : Compounds having the same general formula may have different empirical
formula.
151. Statement - I : For reaction : 2A(g) + 3B(g)  4C(g) + D(g), the vapour density remain
constant throughout the progress of reaction.
Statement - II : In all the gaseous chemical reactions, the vapour density remains constant.
152. Statement - I : When any hydrocarbon is burnt, the moles of oxygen needed for complete
combustion is always greater than the moles of hydrocarbon burnt.
Statement - II : Complete combustion of any substance requires more moles of oxygen than
the moles of substance burnt.

153. Statement - I : At 273 K, hydrogen and helium gases have positive slope at all pressure in PV
vs P graph.
Statement - II : Complete combustion of any substance requires more moles of oxygen than
the moles of substance burnt.
154. Statement - I : Above critical temperature, a substance can not exist in liquid state.
Statement - II : Above critical temperature, the average kinetic energy of gas molecules is
always greater than the maximum kinetic energy of a molecule possible in liquid state.
155. Statement - I : Only metallic, never ionic or covalent substances, form crystals exhibiting
the maximum coordination number of twelve among like-sized atoms.
Statement - II : In metallic crystals, the forces are non- directional and hence arrangement
of atoms frequently corresponds to the closest packing of spheres.
156. Statement - I : KCl is more likely to show Schottky defect while LiI is more likely to show
Frankel defect.
Statement - II : Schottky defect is more likely in ionic solids in which cations and anions are
of comparable size while Frankel defect is more likely in ionic solids in which cations and
anions have large differences in their ionic sizes.
157. Statement - I : The melting point of diamond is very high.
Statement - II : Diamond has very high packing efficiency.
158. Statement - I : The final temperature of an ideal gas in adiabatic expansion is less in
reversible expansion than in irreversible expansion against a constant external pressure.
Statement - II : The magnitude of work done by an ideal gas in adiabatic expansion is more
in reversible process than that in irreversible process.
159. Statement - I : Standard enthalpy of isomerisation of an enantiomer into the other is zero.
Statement - II : The two enantiomers of any chiral compound have the same enthalpy of
formation.
160. Statement - I : In an adiabatic expansion of an ideal gas, the entropy of the surrounding
remains unchanged independent whether the expansion is reversible or irreversible.
Statement - II : In an adiabatic process, the surrounding does not exchange heat with the
system and the process may be reversible or irreversible for system but it always remain
reversible for the sorrounding.
161. Statement - I : When an ideal binary solution of liquids A and B is distilled, the boiling point of
the distillate becomes lower than that of the parental liquid solution.
Statement - II : When an ideal binary solution of liquids A and B is distilled, the distillate
contains relatively larger amount of the more volatile liquid.
162. Statement - I : The time of completion of reactions of type : A  products (order < 1) may
be determined.
Statement - II : Reactions with order > 1 are ether too slow or too fast and hence, the time
of completion can not be determined.
163. Statement - I : The active mass of pure solid and pure liquid is taken as constant
Statement - II : The active mass of pure solid and liquid depends on density and molecular
mass. The density and molecular mass of pure liquids and solids are constant.
164. Statement - I : For adsorption of gases on solids, G, S and

Statement - II : Adsorption is a spontaneous exothermic process in which randomness
decreases due to force of attraction between adsorbent and adsorbate.
165. Statement - I : Electrode potential of any electrode will change on changing any of its
intensive properties.
Statement - II : Any intensive property of system changes on changing any of its properties
whether intensive or extensive.
166. Statement - I : For Hydrogen spectrum all Balmer lines in the emission spectrum have longer
wavelengths than that of any line of Lyman series.
Statement - II : Transition energy is always greater when electrons come to an orbit with
lower orbit number than an electron come to an orbit with higher orbit number, irrespective to
higher orbit from which electron is coming.
167. Statement - I : If a nucleus may undergo positron decay as well as K-capture, the amount of
energy released in positron decay is more than that in K-capture.
Statement - II : The loss in K-capture is equal to the difference in atomic masses of parent
nucleus and the daughter nucleus but in positron decay, additional mass loss equal to the
mass of two electrons also occur.

2 Organic
EXERCISE
168. Which of the following would give iodoform test?
(A) CH2(OH)CH2(OH) (B) (CH3)3C(OH) (C) CH3CH2CH2CH2OH (D) CH3CH(OH)CH2CH3
169. Aspirin is an example of :

(A) A hydroxy ester (B) Keto ester
(C) An aromatic acid ester (D) A phenolic compound
170. An unknown compound dissolves in H2SO4, but does not decolourise Br2 water and does not
react with Na. Which of the following classes of molecules would behave in this manner ?
(A) Alkene (B) Alcohol (C) Phenol (D) Ether
171. The reaction of C6H5OH with CHCl3 in presence of NaOH at 340 K, followed by acidification
to form salicyladehyde is called:
(A) Kolbe-Schmidt reaction (B) Sandmeyer’s reaction
(C) Reimer-Tiemann reaction (D) Kolbe’s electrolytic method
172. An alcohol C5H11OH on dehydration gives an alkene, which on oxidation yield mixture of a
ketone and an acid. The alcohol is :
(A) CH3 – CH – CH – CH3 (B) (CH3)3–CCH2OH
CH3 OH
OH
(C) CH3CH2CH(OH)CH2CH3 (D) CH3–CH–CH2–CH2–CH3
173. Which of the following does not react with per-iodic acid ?
CH2OH CH2OH CHO CH2OH
CHOH C=O CHOH CH2
(A) (B) (C) (D)
CH2OH CH2OH CH2OH CH2OH
174. Which of the following alcohols undergo dehydration fast ?
CH3 CH3
(A) OH (B) OH (C) (D)
OH OH
175. Consider the following reaction:

+
CH 2OH H
A, A is;
H
(A) (B) (C) (D) None of these

CH2OH
176. The main product of the reaction CH3CH2Br and AgCN is :

(A) CH3CH2CN (B) H3CCH2N+C– (C) CH3CH2CH2Br (D) H2C = CH2
177. The reaction
Cu2X2/HX
N NCl X + N2
X=Cl,Br
is called :
(A) Etard reaction (B) Sandmeyer’s reaction
(C) Wurtz reaction (D) Reimer-Tiemann reaction
178. The products of reaction of alcoholic silver nitrite with ethyl bromide is/are:
(A) Ethane (B) Ethene
(C) Nitroethane and ethylnitrite (D) Ethyl alcohol
179. Carbon halogen bond is strongest among the following :

(A) CH3Cl (B) CH3Br (C) CH3F (D) CH3I
180. What is the product of the following reaction :
Cl Mg
Et2O ?
Br
MgCl Cl
(A) Br (B) MgBr (C) (D) None of these
181. What is the product of the reactions?
Cl CH3 + NaSH ?
(A) HS (B) Cl CH2SH
(C) Cl CH2Na (D) No reaction occurs
182. DDT is prepared by the reaction of chlorobenzene with :

(A) Chloral (B) Chloroform (C) Dichloromethane (D) CCl4
CH=O
183.  A , Identify major product.

50%KOH
CH=O
OO
CH2-OH COOK CH2-OH CH2OH
(A) (B) (C) OO (D) OO

CH2-OH OO COOK
COOK OK
184. The isomeric alcohol which has a chiral carbon atom is

(A) n-butyl alcohol (B) iso-butyl alcohol (C) sec-butyl alcohol (D) tert-butyl alcohol
185. The pair of enantiomers among the following compound is

CH3 CH3
CH3 H
Ph H H Br Ph Br Br CH3
Br Ph H Ph
I III IV
II
(A) I and IV (B) II and IV (C) II and III (D) I and II

186. Due to benzene having a cloud of delocalised electrons, the molecule is more stable. This
stability generated by delocalisaion is known as what type of energy ?
(A) lonisation (B) Kinetic (C) Resonance (D) Potential
187. The molecule benzene can undergo a chemical reaction known as nitration.The carry out this
reaction there is need for the presence of two concentrated acids. Nitric acid is one,but
what is the other ?
(A) Citric acid (B) Sulphuric acid (C) Hydrochloric acid (D) Propanoic acid
188. During the nitration of benzene, the two acids involved react to form a cation. The formula
+
of this positive ion is NO2 , but what is the name of this ?
(A) Nitronium (B) Polonium (C) Deuterium (D) Nitroglycerin
189. Arenediazonium salts are formed by reaction of

(A) an arometic amine with hydrogen and palladium
(B) an arometic amine sodium dichromate
(C) an arometic amine with nitrous acid
(D) an arometic amine with potassium nitrosodisulfonate
190. A Friedel-Craft reaction is a type of :

(A) nucleophilic substitution (B) addition reaction to alkenes
(C) electrophilic aromatic substitution (D) acid-base reaction
    
191. CH2  CH  CH  CH  N H3 C H2  CH  CH  C H  N H3 C H2  CH  CH  CH  NH3
(I) (II) (III)
Which of these structures is not a valid resonance structure ?
(A) I (B) II (C) III (D) B and C both
OO - H OH OH
|| CH 3 | CH3 | O CH
192. CH 3 - C - N CH3 - C - N CH3- C N
3
CH3 O CH3 CH3

(I) (II) (III)
The correct stability order of the given resonance structure is :
(A) I > II > III (B) III > I > II (C) I > III > II (D) II > III > I
193. Which of the following is / are D-carbohydrate.

CHO CH2OH OH CHO
H OH H OH HO H
H CHO
(A) HO H (B) HO H (C) (D) H OH
CH2-OH CHO CH2-OH CH2 -OH
194. Which of the following reactant on reaction with conc. NaOH followed by acidification gives
the following lactone as the only product ?
O
C-OCH3 CO2H CHO CO2H

(A) (B) (C) (D)
CO2H CHO CHO CO2H
195. Total number of carbon in the parent chain of given compound is ?
(A) 5 (B) 6 (C) 7 (D) 8
196. How many moles of Gignard will consume when it reacts with following compound?
CHO
HO C-CI
H-S C-O-Et
C
N
(A) 6 (B) 7 (C) 8 (D) 9
197. What product (s) would you expect to obtian from the following reaction?
CH3
+ AlCl 3,
Br
CH3
CH3 CH3
CH3
H3C
(A) Br (B) Br +
Br
CH3 CH3
CH3 CH3 CH3
(C) H3C (D) H3C

Br Br
198. The maximum concentration of zwitter ion of given amino acid will be at

NH3  CH2  CO2H
pKa9.8  pKa1  2.3 
(A) 1 (B) 11 (C) 6(app.) (D) 5(app.)
CH3
199. In the given reaction conc H2 SO4
CH3    A . The product A is-
OH OH
CH3 CH3
CH3 CH3
(A) (B) (C) (D) CH3
O CH3 CH3 COOCH3
O
200. In which of the following reaction maximum character of reactant in Transistion State is ?
(A) CH 4  F   (B) CH4  Cl   (c) CH 4  Br  (D) CH 4  I  

Br2 (monobromination) Na
201. (A)  (B). Products B is
hv Dryether
(A) (B) (C) (D)
202. Which of the following compound is not resonance stabillized?
(A) (B) (C) (D)
NH Br
203. C 4H7 OCI 
3
 C4H9 ON 
2
 CH3 CH2 CH2NH2
KOH
(x)
Compound (X) is
O O
(A) (B) (C) OH (D)
Cl Cl
(I) ( )2 CuLi
204. O ‘P’
(II)
Br
Product ‘P’ of the given
(A) O (B) O (C) (D)

O O
CH3 Cl
205.
Cl CH 3
How many atoms will be bisect during plane of symmety?
(A) 2 (B) 4 (C) 6 (D) 8
206. Which of following compound can show geometrical isomerism?
F Et CH 3 CH3
(A) C C (B) CH C
Cl Et 3 CH 3
Br Cl C CH3
(C) C C (D)
I Cl CH3
207. In which of following reaction to 2 alcohol will not formed ?

O O
|| ||
(A) H  C O  Et  2 PhMgBr  (B) H  C Cl  2 PhMgBr 
2 H
 
 2 H
 
O O
|| ||
(C) CH  C H  PhMgBr  (D) H  C H  PhMgBr 
3 2 H  2 H
 
O
||
NaHCO
208. Ph  C  O  H  
3
 ( A ) gas, molecular mass of gas A is :
(A) 2 (B) 32 (C) 44 (D) 28
Cl
209.
Cl
Br
Stereoisomers of given compound is :
(A) 4 (B) 6 (C) 8 (D) 2
H
C CH
3
210. CH3 Stereocenter in given compound is/are :

H
H CH3
(A) 2 (B) 3 (C) 4 (D) 5
Br
Cis - 2 - butene CCl
2
211.  (D) products
4
Find out the correct statement(s) about the products

(A) Products are enatiomeric pair
(B) Product is meso compound
(C) Product is monobromoalkane
(D) Product is formed by nucleophilic addition reaction
Br
Br
212.
Total stereoisomers of given compound are A. (ii) Double Bond Equavalent in given compound
is B.
The value of A +B is :
(A) 3 (B) 4 (C) 5 (D) 6
O O
|| ||
(i ) dil. NaOH
213. CH 3  C CH 2  CH 2  C CH 3   major product will be
(ii ) 
O
O CH3 OH
(A) (B) (C) (D)

C - CH3
CH3
214. The IUPAC name of the following is-
(A) 3-methoxy ethylpropanoate (B) ethyl-4-methoxy butananoate

(C) 1,4-diethoxybutane (D) 4-methoxy-ethylbutanoate

215.
Correct IUPAC name of the following compound is-

(A) 4-(1,1dimethylethyl)-5-ethyloctane (B) 5-ethyl-4-(1,1-dimethylethyl)octane
(C) 5-(1,1-dimethylethyl)-4-ethyloctane (D) 4-ethyl-5-(1,1-dimethylethyl)octane
216. The most acidic among the following compounds is:
(A) CI  CH 2  CH2  OH (B) (C) (D)
217. Which of the following compound will undergo addition reaction?
(A) (B) CH 3  C  N (C) (D) All
218. Give the major product of the following reation :
2 NaOH
 Major

(A) (B)
(C) (D)
219. Give the product from the following reaction sequence :

H
PCC
 EtMgBr
  
H 2O
(A) (B) (C) (D)
220. Give the major product of the following reaction :
CH
3COCI

 Major
AICI 3
(A) (B)
(C) (D)
221. The most characteristic reactions of benzenoid arenes arethe substitution reactions that
occur when they react with electrophilic reagents. These reactions are of the general type
shown below.
E
Ar  H  E  A  Ar  E  H  A or EA +H-A
a
OO D
b C
Identify the position where EAS (Electrophilic Aromatic Substitution)reaction takes place.
(A) a (B)b (C)c (D)d
222. Correct order of EAS (Electrophilic Aromatic Substitution) of given compound will be :
Cl O OCH3
C - O - CH3
O
(a) (b) (c) (d)
(A) a  b  c d (B) b  a  c d (C) db c a (D) db ac
223. Which of the following is O/P director of EAS (Electrophilic Aromatic Substitution) ?
O O
O
NH-O-CH3 C-NH-CH3 NO2
CH3
(A)
O (B)
O (C) O (D) O
224. Which of the following reaction does not give chloro benzene as a product ?
 
(A) CHCl
 3 HO
 (B) CHBrCl
 2 HO

 
(C) CH
Br
2 Cl,HO
 (D) CH
FClBr, HO


225. Which of the following compound easily undergo decarboxylation on heating ?

O
O O
CO 2H O
(A) (B) (C) (D)
COOH CO2H
CO 2H
HO 2C
226. Total number of substituents present in following compound are ?

O
(A) 3 (B) 4 (C) 5 (D) 6
227. The total number of all structural isomers of molecular formula C 4 H10 O will be.
(A) 5 (B) 6 (C) 7 (D) 8
228. Give the major product of the following reaction
MnO
2  Major product
OH O
O OH
OH
(A) (B) (C) (D)
OH O O
229. dil
NaOH
  Identify major product :

O
(A) (B) (C) (D)
230. How many products will be formed in these reaction?
(i) cold
 dil KMnO 4
 (x) products
(ii) cold
 dil KMnO 4
 (y) products
Sum of (x + y)
(A) 2 (B) 3 (C) 4 (D) 5
231. Which of the following compound give positive isocyanide test?

NH-CH2 NH2 O
CH3 CH 3
(A) (B) (C) N (D) CH–
3
N
CH3 CH 3
232. Order of the below reaction is

OH O
O H O
H O
C=O OH H H H
H
O
O OH
CH3OH  Fast
+ CH3  O 
H O H O
(A) 0 (B) 1 (C) 2 (D) 3
CHO
H2SO 4
233.    (A) Δ (B), Product (B) is
Conc . NaOH
Δ
CHO
O
(A) (B) O (C) O (D) None

O
O O
O conc . KOH
234. OMe   P
Δ
H O
Find out the product ‘P’ of the following reaction
(A) O O (B) O O
OMe OMe OMe OMe
O O O
CO2 K OH CO2 K CO2 K
(C) O O (D) O O
OMe OMe OCO2 K
O
CO2 K CH 2OH
OH
235. Which of the following compound react with only one mole of RMgX followed by reaction with
HOH to form alcohol
O O O
|| || O
||
(A) CH3  C  OEt (B) CH3  C  Cl (C) H C  O Et (D) H-C
236. Which of the following compound will not undergo Hoffmann bromamide reaction ?
O
O O O
|| || ||
N H
(A) CH3  C  NH2 (B) Ph C NH  Br (C) Ph  C  NH  CH3 (D)
O

237. Among the following. How many compounds have plane of symmetry a well as centre of
symmetry
Cl Cl
Cl
Cl
CH3
CH3
(A) 2 (B) 3 (C) 4 (D) 5
238. How many isomers of given compound rotate plane polarised light ?
(A) 4 (B) 6 (C) 8 (D) 10
239. Find out P & Q in the following reaction
CCl4 CCl4
(P) (Q)
RLi RLi
Cl Cl
Cl
(A) Cl
Cl Cl
Cl
(B)
Cl
Cl
(C) Cl
Cl Cl
(D)
Cl Cl
CH3
NH3 KOBr |
240. (A) (B) ; structure of (A) is
CH3  CH  NH2
Cl Cl
H
(A) (B) (C) (D)
Cl Cl Cl
241. How many pairs of diastreomer are possible for 2-bromo 3-chloro butane?
(A) 1 (B)2 (C)3 (D) 4
O
|| Ag2O
242. Major - product of the reaction is HO – CH2 – CH2 – CH2 – C – CHN2 (A) , product
(A) is
O O O O
O O O NH
(A) (B) (C) (D)
CH2–Cl
KCN Ph-CHO
243. (A) (B)
Product (B) of the reaction is :

(A) Ph – CH2 – CH = CH – Ph (B) Ph  CH C  Ph
|
CN
(C) Ph  C  CH  CH2  Ph (D) Ph  CH  C  CH2  Ph
| |
CN CN
244. C6H5 – CH = CH – CHO + CH3 – CH = CH – CHO
base/EtOH
Major product (A) is

(A) Ph – (CH = CH)2 – CHO (B) Ph – CH = CH – CHO
(C) Ph – (CH = CH)3 – CHO (D) Ph – (CH = CH)4 – CHO
OH
(i) Hg(OAc)2
245. A
(ii) NaBH4, OH
OH
HO
O O
(A) (B) (C) (D)
246. Which of the following compound give Reimer Teimann reaction.

NO2
OH
NO2
OMe
(A) (B) (C) (D)
NO2

247. Electrophile in the above reaction is/are
OH
..
(A) (C) CHCl2 (C) CCl2 (D) ArCHCl2
..
248. Which is more reactive towards Reimer Tiemann reaction.(Assume r.d.s. step is atteck of
Nucleophilic )
OH
OH OH
OH
OH
(A) (B) (C) (D)
OH
OH
249. In which of the following reactions Geometrical isomer will not formed as product.
O
H
+ ||
(A) (B) Ph – C – H + NH2 – OH H+
OH
CO2H CO2H
O
||
(C) (D) CH – C – H (1) KCN
3
(2) H +
CH3 H
250. Correct IUPAC name of the given compound is :
CH3
O2N NO2
NO2
(A) 2,4,6-trinitrotoluene (B)1,3,5-trinitrotoluene

(C) 1,3,6-trinitrotoluene (D)2,3,6-trinitrotoluene
251. Correct IUPAC name of the given compound is :
(A) pent-1-en-3-yne (B) pent-1-ene-4yne (C) pent-4-yn-1-ene (D) pent-1-en-4-yne
252. Which of the following is a most acidic compound?
OH
OH O OH
||
C – OH
(A) (B) (C) (D)
NO2
CH3
253. Which of the following compounds might be useful to seprate recemic mixture?
HO2C
CO2H
(A) (B)
HO CO H
HO2C
CO2H
(C) (D)
CO H
254. Which of the following is a most stable carbocation compound?

OCH3 + OCH3 CH3 + CH3
+ +
(A) (B) (C) (D)
O O
(i) CH3ONa
255. (ii) CH3–I
(P) Major Product
OCH3
Product (P) is :
O O
O O
(A) (B) OCH3
CH3 CH3
+
O O Na CH O
3
(C) (D)
OCH3 CH2– CH3
256. In which of the following reaction 3° alcohol will formed ?

O
O
(1) PhMgBr (excess) O S (1) PhMgBr (excess)
(A) EtO – C – O – Et + (B) +
(2) H (2) H
O
(1) PhMgBr (excess)
(C) Cl – C – O – Et + (D) All
(2) H

257. In which of the following reaction formation of 2° alcohol will take place?
O O
(1) PhMgBr (excess) (1) PhMgBr (excess)
(A) H – C – O – Et + (B) CH3 – C – H +
(2) H (2) H
O
(1) PhMgBr (excess)
(C) H – C – Cl + (D) All
(2) H
258. Product (A) is
Cl
Mg
(A)
Ether
(A) (B) (C) (D)
259. Functional group is not present in given compund are ?

O
OH
O
NH2
(A) Alcohol (B) Ketone (C) carboxylic acid (D) amide
260. Intermediate product during given reaction will be :
+
H3O
Intermediates O
O OH
+
H
(A) +
(B) O (C) OH (D) All
O O H O
261. Which of the given compound do not undergo acid catalysed hydrolysis
(A) Ph – O – Ph (B) Ph – O – CH = CH2
(C) Ph – O – CH2 – Ph (D) CH3 – O – CH2CH3
262. The number of open chain structure isomers for the compound with molecular formula C3FCIBrI is:
(A) 3 (B) 7 (C) 4 (D) 8
263. Which of the following reagents may be used to distinguish between phenol and benzoic acid?
(A) Aqueous NaOH (B) Tollen’s reagent (C) Molisch reagent (D) Nautral FeCl3
264. The strongest acid among the following compound is :

(A) CH3COOH (B) HCOOH
(C) CH3CH2CH(Cl)CO2H (D) ClCH2CH2CH2COOH
265. Identify the compound the exhibits tautomerism.

(A) 2-Butene (B) Lactic acid
(C) 2-Pentanone (D) Phenol
(1 mole)
266. CHCl3 ‘P’
t-BuOK
Product ‘P’ is
Cl H
(A) (B)
Cl Cl
Cl H
(C) Cl (D) Cl
OH
Me
(i) CHCl3.KOH
267. ‘P’
(ii) H 3O+
Me
the product ‘P’ is
OH
OH O
OH
(A) (B)
O OH
OH OH
(C) (D)
O OH O OH
268. Which of the following carbene is most electrophilc.
OMe Me
(A) : CH2 (B) : CHOCH3 (C) : C (D) : C

OMe Me

OH OH
CHO NH2 N C
(x) (y)
269. ;
In given reactions missing reagent (X) and (Y) is :

(A) x = CHCl3 / KOH, y = CHCl3 / KOH (B) x = CCl4 / KOH, y = CHCl3 / KOH
+
(C) x = CHCl3 / KOH, y = Br2/ KOH, (D) x = CHCl3 / KOH, y = CCl4 / H
270. Total number of  - hydrogen in given compound is
H3C
(A) 7 (B) 8 (C) 9 (D) 10
CH3 Cl
H2O
271.
Total number of SN1 products formed during given reaction will be

(A) 2 (B) 3 (C) 4 (D) 5
272. Ozonolysis of an oganic compound given formaldehyde as one of the products. This confirms
the presence of :
(A) two ethylenic double bonds (B) a vinyl group
(C) an isopropyl group (D) an acetylenic triple bond
273. Sodium ethoxide has reacted with ethanoyl chloride. The compound that is produced in the
above reaction is
(A) Diethyl ether (B) 2-Butanone
(C) Formaldehyde (D) Benzophenone
274. Which is true about aerial distance between chlorine atom
Cl Cl
H Cl Cl H
(A) 1= 2 (B) 2 > 1 (C) 1 > 2 (D) None
275. possible geometrical isomers are
(A) 4 (B) 6 (C) 8 (D) 16
dil KOH
276. 2CH3CHO A (Aldol condensation product) How many geometrical isomers is
possible for compound A
(A) 1 (B) 2 (C) 3 (D) 4
277. Enol form of which of the given compound will form racemic mixture.
O
O O
O
(A) (B) (C) (D)
278. How many five membered parent chain alkanes are possible for molecular formula C7H16 ?
(A) 3 (B) 5 (C) 2 (D) 4
279. Given the major product of the following reaction sequence :

OH
|| (i) Br2
O Trace of red P
(A) C6H5 CH Br COOH (B) C6H5CH2CO Br

(C) p-Br-C6H4CH2COOH (D) m-Br-C6H4CH2COOH
280. Monomer used to prepare Orlon is :

(A) CH2 = CHCN (B) CH2 = CH – Cl (C) CH2 = CHF (D) CH2 = CCl2
281. A tripeptide has ........ preptide bonds :

(A) three (B) two (C) four (D) one
282. Periodic acid splits glucose and fructose into formic acid and formaldehyde. Ratio of formic
acid and formaldehyde from glucose and frustose is :
(A) 5/1 and 4/2 (B) 5 / 1 and 5 / 1 (C) 4/2 and 4/2 (D) 5/1 and 3/2
283. Consider the reaction

OH N2 Cl
OH–
+ X : here x is
NH2
OH
OH
N=
N N
=
(A) (B) NH2 N
NH2
OH
(C) (D) None

284. Which of folloowing is essential amino acid ?

(A) Glycine (B) Alanine (C) Valine (D) None
285. The Keq. values of HCN addition of following aldehydes are in the order :
O O O
|| || ||
H H H
MeO Me2N
I II III
(A) I > II > III (B) II > III > I (C) III > I > II (D) II > I > III
Br2
286. cis-2-butene
CCl4
How many products will obtained in this reaction
(A) 1 (B) 2 (C) 3 (D) 4
287. CH3 – CH = CH2 IBr Product (A) is :
Br I I Br
(A) (B) (C) (D)

I I Br Br
Br2
288. Isomers of butene (x) (y) products (including streoisomer) sum of x + y =
CCl4
(A) 8 (B) 9 (C) 10 (D) 11
289. Which of the following will show geometrical isomerism.
H
H H
H Cl
(A) (B)
Cl Cl
Cl
H
H C Cl
Cl F
(C) (D) C C
I F
Cl
290. A compound was synthesized by a student, but its structure was not identified. However, his
wonderfully helpful instructor in MOTION IIT -JEE told him that it was a meso compound with
5 carbons and 2 stereogenic centers. Which of the following structures should not consider
by student as possibilities for this compound ?
Br
OH CO2H
OH OH
(A) Br (B) (C) (D)
OH
HO2C
Br Br
CH2 – CH3
|
Ph – C – Cl
291. |
CH3
The total number of E2 (elimination bimolecular product) when above compound react with
alcoholic KOH ?
(A) 2 (B) 3 (C) 4 (D) 5
292. Hydrogenation of benzoyl chloride in the presence of Pd on BaSO4 gives

(A) Benzyl alcohol (B) Benzaldehyde (C) Benzoic acid (D) Phenol
293.
N
How many times of Hoffmann exhaustive methylation takes place to remove nitrogen from
given compound.
(A) 1 (B) 2
(C) 3
(D) 4
O
dil. NaOH
294. C (A) (B)

CH3 CH3
Product (A) and type of reaction from A  B is
O O
O OH O OH
(A) , E1 cB (B) , E2 (C) , E1 cB (D) , E2
OH OH
CH3
H Br
– +
O K
O
295. OH,  (A) major, Product A is
O
H
CH3 CH2 Br CH3 CH3

Br
(A) O (B) O (C) O (D) O

O O O O
Br2
A
296. CCI2 (excluding stereoisomer)
cis
Draw A in fischer projection

(A) Total number of stereoisomers of A is 2 (B) A poses center of symmetry
(C) A posses plane of symmetry (D) A poses axis of symmetry

297. In which of following reaction diastereomers will formed as a product ?

NaOH conc. KOH
(A) CH 3 - CH = O (B) Ph - CH = O
 
(i) CH3I(excess)
NaOH,I2
(C) CH3 – CH =O (D) (ii) Moist Ag2O
NH2 (iii) 
O
298. Reaction-1 : PCl5 x NaNH 2 CH3l
Ph-C-CH3 Ph-CC-CH3
Br
y NaNH2
Reaction-2 : CH3-CC-CH3
Br
Ph - CH - CH2 z NaNH 2 Et-l

Ph-CC-Et
Reaction-3 :
Cl Cl
Calculate the value of x + y + z (in moles) :
(A) 5 (B) 6 (C) 7 (D) 8
299. How many isomers of C4H10O reacts with Na metal evolve H2gas ? (including stereoisomer)
(A) 3 (B) 4 (C) 5 (D) 6
300. An organic compound with molecular formula, C 7 H 8 O dissolves in NaOH and characteristics
colour with neutral FeCl3. On treatment with bromine–water, it gives a tribromo derivative,
C7H5OBr3. The compound is
(A) benzyl alcohol (B) o-cresol (C) p-cresol
(D)m-cresol
301. Which of the following is not reducing sugar ?

(A) Sucrose (B) Maltose
(C) Lactose (D) -D-Glucopyranose
OH
302. HNO2
(P)(Major)
NH2OH(1eq.)
(Q)(Major)
(A) P & Q both are identical products

(B) P & Q are structural isomers
(C) Possible products of P is two (ortho/para) & possible products of Q are three
(D) Posible products of P is only one & possible products of Q is two (ortho/para)
303. x and y is the number of times of H.E.M. takes place to remove Nitrogen from the compound.
(HEM = offmann Hxhaustive Methylation)
=x(); N =y() Sum of x + y =

N
CH3
(A) 4 (B) 5 (C) 6 (D) 7
304.
(a) Number of H which show Hyperconjugation in the given above compound (x)
(b) Number of plane of symmetry is (y)
Sum of (x + y) = ?
(A) 3 (B) 4 (C) 5 (D) 6
305. Which of the following compound is non-resolvable (meso)

Br
Br OH Br H
Br Me OH H H
(A) H (B) H (C) (D) All of these
H Br
H H H
Br
306. Which of the following compound is not anti-aromatic
(A) (B) (C) (D)

N
307. Which of the following compound is non aromatic
(A) (B) (C) (D)

O
308. Compare rate of reaction with AgNO3

I
I I
(I) (II) (III)

O
(A) | > || > ||| (B) | > ||| > || (C) || > ||| > | (D) || > | > |||
309. Which of following on acid catelyst hydrolysis give two product both give positive lodoform
test.
O
(A) O (B)

CH 3 CH = CH O –C = CH 2
(C) O (D)
CH3

H3O
310. O (A) + (B)
(A) & (B) is differentiated by.

(A) NaHSO3 (B) 2, 4-DNP (C) Fehing test (D) Idoform test
311. Choose from the indicated protons, the one that is most acidic.
H H O
H H 4
CH3
H
H H H
2 3
(A) 1 (B) 2 (C) 3 (D) 4
312. In which of reaction formation of (1° amine) take place ?

O O
NH2 KOBr CH3 NaOl

(A) (B)
CH3 CH3
O
NaNO2
CH3–C CH–CH3 NaOH
(C) HCl (D) Ph– C – NH – CH3
OH NH2
313. Which of following pair is differentiated by lodoform and Tollen’s reagent ?

O
(A) Ph COOCH3 ; Ph – CHO (B)
H – C – CH3 ; CH3 – CH2 – CHO
(C) ; CH3 – CH2 – CHO (D) H – C – H ; Ph – CH = O

O
O
314. How many homocyclic isomers are possible for C4H8O (including stereoisomers).
(A) 6 (B) 7 (C) 8 (D) 9
315. How many structural isomers are posible for C4H9Cl ?

(A) 3 (B) 4 (C) 5 (D) 6
316. Which of the following reaction is most exothermic ?

(A) Propane + Cl2/hv  2-chloro propane + HCl
(B) Propane + Br2/hv  2-bromopropane + HBr
(C) Isobutane + Cl2/hv  t-butyl chloride + HCl
(D) Isobutane + Br2/hv  t-butyl bromide + HBr
317. Which of the following is non reducing sugar ?

(A) Sucrose (B) Cellulose (C) Protein (D) Terylene

O O
18 18
conc. H SO
318. Statement -1 : Me3C – C – OH + MeOH 2 4
Me3C – C – OMe (major)
Statement - 2 : During esterification, removed water molecule contains H of alcohol and
OH of carboxylic acid.
319. Statement -1 :
Me Me Me
conc. H2SO4
Me – C – CH2 – C – Me Me3 C – CH = CMe2 + Me2C – CH 2 – C = CH 2
P1 P2
Me OH
Major
Statement - 2 : P1 is having 6  H while P2 is having 5  H so P1 is Saytzef’s alkene.
320. Statement -1 : Rate of nitration is C6H6  C6D6  C6 T6

Statement - 2 : Formation of wheland intermediate is rate determining step in nitration of
benzene, not the breaking of C – H or C – D bond.
OHOH
(i) PhCO3H
321. Statement -1 : Product of reaction is
(ii) H3O
(Optically inactive)
Statement - 2 : In reactions involving epoxidation followed by hydrolysis, the overall
addition is Anti oriented.
322. Statement -1 : +
O
Statement - 2 : 2-butene
O
is more stable than 1-butene as it is having more -H.
H – :O: H H3C H
323. Statement -1 : The reactivity of (I) is slower compared to (II)
CH3 Cl H – :O: Cl
towards nucleophilic substitution reaction.

Statement - 2 : I gives two step SN reaction where as II gives single step SN reaction.
324. Statement -1 : S-configuration change into R-configuration and vice versa in SN2 reaction
mechansim.
Statement - 2 : Walden inversion takes place in SN2 reaction mechansim.
325. Statement -1 : 1,1,1-trideutero-2-propanol reacts with conc. H2SO4 at high temperature

to give only one alkene, 3,3,3-trideutero propene.
because
Statement - 2 : C – D bond is stronger than C – H bond.
326. Statement -1 : R-1-bromo-1-fluoro ethane reacts with MeONa to give S-1-fluoro-1-

methoxy ethane.
Statement - 2 : Walden inversion takes place during SN2 reaction.

327. Statement -1 : CH 3 – CH2 – NaI Acetone

CH3 – CH2 – I + NaCl
Above reaction is
Finkelstein reaction.
Statement - 2 : Acetone is polar protic solvent and solubility order of sodium halides
decreases dramatically in order NaI > NaBr > NaCl. The last being virtually insoluble in this
solvent and a 1º and 2º chloro alkane in acetone is completely driven to the side of
Iodoalkane by the precipitation reaction.
OH
328. Statement -1 : gives turbidity with ZnCl2/HCl in 5 minutes.
Statement - 2 : 2º alcohol usually gives turbidity in 5 minutes.

O
N–H
329. Statement -1 : does not give bromamide reaction.
O
Statement - 2 : Secondary amides does not give bromamide reaction.
Peroxide
330. CH = CH – CH3 + HX CH3 – CH – CH2 – CH3
X
Statement -1 : The stereochemistry of product is same whether HCl or HBr is used as
reactant.
Statement - 2 : The reaction mechanism with HCl and HBr are same in above conditions.
NO2
OH
PCl5
331. Statement -1 : C=N O2N C – NH OMe
O
OMe OMe
Statement - 2 : Migratory aptitude of group is greater than migratory aptitude
of group during cation rearragements.
NO2
COOH
332. Statement -1 : Me Et is optically inactive, it is taken in a glass contianer and plane
polarized light (PPL) isCOOH

passed through it after heatingt it for several minutes. The PPL
shows significant opticall rotation.
Statement - 2 : Like -keto acid, gem dicarboxylic acid eliminates CO2 on heating.
O
NaOH
333. Statement -1 : Cl 3C – C – H Cl3C – CH2OH + Cl3C – COONa
Statement - 2 : There are no - H in this compound, so it can’t give aldol.
HBr
+
334. Statement -1 : In the reaction 35ºC
Br
(P2)
Br
(P1) major
Statement - 2 : P1 is formed by more stable carbocation intermediate.
3 Inorganic
EXERCISE
335. The bond order in O2– ion is
(A) 2 (B) 1 (C) 2.5 (D) 1.5
336. Which of the following molecules has the smallest bond angle?
(A) NH3 (B) H2O (C) H2Se (D) H2S
337. Unusually high boiling point of water is the result of

(A) Intermolecular hydrogen bonding
(B) Both intra and inter molecular hydrogen bonding
(C) High specific heat
(D) Intramolecular hydrogen bonding
338. Dissolution of ionic solid in water is accompanied by release of energy represented by Hsoluiton
. This implies that
(A) Hlattice > Hhydration (B) Hlattice = Hhydration
(C) Hhydration > Hlattice (D) Hlattice : Hhydration = 1 : 2
339. In which of the following molecules, the central atom does not follow the octet rule?
(A) H2O (B) H2S (C) BF3 (D) CO2
340. d2sp3 hybridization of atomic orbitals gives

(A) Triangular structure (B) Tetragonal structure
(C) Square planar structure (D) Octahedral structure
341. Which of the following statements is true?

(A) The dipole moment of NH3 is zero.
(B) The dipole moment of NF3 is equal to NH3
(C) The dipole moment of NF3 is zero
(D) The dipole moment of NF3 is less than NH3
342. Which one of the following has zero dipole moment ?

(A) ClF (B) ClF3 (C) SiF4 (D) CFCl3
343. Which of the following is an electron deficient molecule?

(A) C2H6 (B) B2H6 (C) SiH4 (D) PH3
344. Which of the following is paramagnetic with bond order 0.5 ?

(A) H2+ (B) O2– (C) B2 (D) F2
345. Which type of bond is not present HNO2 molecule ?

(A) Covalent (B) Coordinate
(C) Ionic (D) Ionic as well as corrdinate

346. Which of the following molecules has trigonal planar geometry?

(A) BF3 (B) NH3 (C) PCl3 (D) IF3
347. Which of the following would have a permanent dipole moment?

(A) SiF4 (B) SF4 (C) XeF4 (D) BF3
348. In TeCl4, the central atom, tellurium, involves hybridization.

(A) dsp2 (B) sp3 (C) sp3d (D) sp3d2
349. In which of the following pairs, the two species are isostructural ?
(A) SF4 and XeF4 (B) SO32– and NO3– (C) BF3 and NF3 (D) BrO3– and XeO3
350. The correct sequence of increasing covalent character is represented by

(A) LiCl < NaCl < BeCl (B) BeCl2 < LiCl < NaCl
(C) NaCl < LiCl < BeCl2 (D) BeCl2 < NaCl < LiCl
351. What is the correct order of the strength of hydrogen bonds?

(A) NH -- N < OH -- O < FH -- F (B) ClH -- Cl > NH -- N > OH -- O
(C) ClH -- Cl < NH -- N < OH -- O (D) NH -- N > OH -- O > FH -- F
352. Bond angle of 109º28’ is found in
(A) NH3 (B) H2O (C) CH3 (D) NH4
353. Which of the following molecules has almost negligible tendency to form hydrogen bonds?
(A) NH3 (B) H2O (C) HF (D) HI
354. Identify the correct sequence of increasing number of -bonds in the structures of the
following molecules.
(I) H2S2O6 (II) H2SO3 (III) H2S2O5
(A) I, II, III (B) II, III, I (C) II, I, III (D) I, III, II
355. First compound of intert gases was prepared by scientist Neil Barthleta in 1962. This com-
pound is
(A) XePtF6 (B) XeO3 (C) XeF6 (D) XeOF4
356. Which bond angle,  would result in the maximum dipole moment for the triatomic molecule
XY2 shown below:
Y
X
(A)  = 120º (B)  = 90º (C)  = 145º (D)  = 175º
357. Which of the following has the highest bond order ?

(A) N2 (B) O2 (C) He2 (D) H2
358. The energy of hydrogen bond is of the order of

(A) 40 kJ mol–1 (B) 140 kJ mol–1 (C) 400 kJ–1 (D) 4 kJ mol–1
359 In the formation of N2+ from N2, the electron is removed from a
(A) -orbital (B)-orbital (C) -orbital (D) -orbital
360. Which of the followng is diamagnetic ?

(A) H2+ (B) O2 (C) Li2 (D) He2+
361. How many types of S – F bonds are present in SF4 ?

(A) 5 (B) 4 (C) 3 (D) 2
362. The pair of species having identical shapes for molecules of both species is
(A) CF4, SF4 (B) XeF2, CO2 (C) BF3, PCl5 (D) PF5, IF5
363. Consider two reactions

I. Zn + conc. HNO3 (hot)  Zn(NO3)2 + X + H2O
II. Zn + dil. HNO3 (cold)  Zn(NO3)2 + Y + H2O
Compounds X and Y are respectively
(A) N2O, NO (B) NO2, N2O (C) N2, N2O (D) NO2, NO
364. The correct order regarding the electronegativity of hybrid orbitals of carbon is
(A) sp < sp2 > sp3 (B) sp < sp2 < sp3 (C) sp > sp2 > sp3 (D) sp > sp2 > sp3
365. Correct order of dipole moment is
OH Cl CH3
NO2 Cl CH3
(1) (2) (3)
(A) 1 = 2 = 3 (B) 3 < 2 < 1 (C) 1 < 2 < 3 (D) 2 < 3 < 1
366. The maximum number of hydrogen bonds that a molecule of water can have is
(A) 3 (B) 4 (C) 1.3 (D) 2.4
367. The number of lone pairs of electrons present in central atom of CIF3 is :
(A) 0 (B) 1 (C) 2 (D) 3
368. In [Ag(CN)2]– the number of  bonds is

(A) 2 (B) 3 (C) 4 (D) 6
369. Among the following compounds, the one that is polar and has the central atom with sp2
hybridization is
(A) SiF4 (B) BF3 (C) HClO2 (D) H2CO3
370. Bond order of nitric oxide is

(A) 1 (B) 2.5 (C) 2 (D) 1.5
371. Which one of the following compounds on strong heating evolves ammonia gas ?
(A) (NH4)2SO4 (B) HNO3 (C) (NH4)2Cr2O7 (D) NH3NO3
372. Which combination of atomic orbitals is not allowed according to MO theory?

(A) px – px (B) px – py (C) py – py (D) pz – pz
373. Which one of the following species is diamagnetic in nature?

(A) H2– (B) H2 (C) H2+ (D) He2+
374. Which of the following molecules is planar ?

(A) CH4 (B) NH3 (C) C2H4 (D) SiCl4

375. The number of unpaired electrons in a paramagnetic diatomic molecule of an element with
atomic number 16 is:
(A) 4 (B) 1 (C) 2 (D) 3
376. The paramagnetism of O2+ is due to the presence of an odd electron in the MO
(A) 2s (B) 2py (C) 2pz (D) 2py
377. Which of the following molecules/ions does not contain unpaired electrons?
(A) O22– (B) B2 (C) N2+ (D) O2
378. In which of the following molecules, all the bonds are not equal ?
(A) AlF3 (B) NF3 (C) CIF3 (D) BF3
379. PCl5 in solid state splits into

(A) PCl6+ and PCl4– (B) PCl4+ and PCl6– (C) PCl3 and Cl2 (D) PCl4 and Cl–
380. How many sigma and pi bonds are present in toluene ?

(A) 3 + 6 (B) 3 + 8 (C) 6 + 6 (D) 3 + 15
381. The hybrid state of central iodine atom is I3+ and I3– are, respectively
(A) sp3, sp3d (B) sp3d, sp3 (C) sp3d, sp3d (D) sp2, sp3d
382. The correct order of the lattice energies of the following ionic compounds is
(A) NaCl > MgBr2 > CaO > Al2O3 (B) Al2O3 > CaO > MgBr2 > NaCl
(C) NaCl > CaO > MgBr2 > Al2O3 (D) MgBr2 > Al2O3 > CaO > NaCl
383. The following compounds are to be arranged in order of their increasing thermal stabilities.
Identify the correct order :
(I) K2CO3 (II) MgCO3 (III) CaCO3 (IV) BeCO3
(A) I < II < III < IV (B) IV < II < III < I (C) IV < II < I < III (D) II < IV < III < I
384. Which of the following set contains species having same angle around the central atom?
(A) SF4, CH4, SeF4 (B) NF3, BCl3, NH3 (C) BF3, NF3, AlCl3 (D) BF3, BCl3, BBr3
385. The magnetic moment of KO2 at room temperature is :

(A) 1.43 BM (B) 2.64 BM (C) 2.41 BM (D) 1.73 BM
386. The electronic configuration of four elements are as follows.

a : 1s2 2s2 2p4 b : 1s2 2s2 2p5 c : 1s2 2s2 2p6 3s1 d : 1s2 2s2 2p6 3s2
Now decide the possible formulae of ionic compounds that could be formed between them.
(A) a2c, da, cb, d2b (B) ac, da, cb, cb (C) c2a, da, cb, db2 (D) ac, d2a, c2b, db
387. The molecular shapes of diborane is shown :

Consider the following statements for diborane :
1. Boron is approximately sp3 hydbridised
2. B–H–B angle is 180º
3. There are two terminal B–H bonds for each boron atom
4. There are only 12 bonding electrons available Of these statements :
H H 1. 3
3Å .19Å
1
H
B B
H H H
(A) 1, 3 and 4 are correct (B) 1, 2 and 3 are correct
(C) 2, 3 and 4 are correct (D) 1, 2 and 4 are correct
388. The correct order of increasing bond angles in the following triatomic species is
(A) NO2+ < NO2 < NO2– (B) NO2+ < NO2– < NO2
(C) NO2– < NO2+ < NO2 (D) NO2– < NO2 < NO2+
389. The correct order in which the O – O bond length increases in the following is
(A) O2 < H2O2 < O3 (B) O3 < H2O2 < O2 (C) H2O2 < O2 < O3 (D) O2 < O3 < H2O2
390. A precipitate of calcium oxalate will not dissolve in

(A) acetic acid (B) HCl (C) HNO3 (D) aquaregia
391. The bond order in NO is 2.5 while that in NO+ is 3. Which of the following statements is true
for these two species?
(A) Bond length in NO+ is greater than in NO (B) Bond length in NO is greater than in NO+
(C) Bond length in NO+ is equal to NO (D) Bond length is unpredictable
392. The sequence that correctly describes the relative bond strength pertaining to oxygen mol-
ecule and its cation or anion is :
(A) O22– > O2– > O2 > O2+ (B) O2 > O2+ > O2– > O22–
(C) O2 > O2 > O2 > O2
+ 2– –
(D) O2+ > O2 > O2– > O22–
393. The dipole moments of methane ant its halogen derivatives are in the order.
(A) CH4 < CH2Cl2 < CHCl3 < CH3Cl (B) CH3Cl < CH2Cl2 < CHCl3 < CH4
(C) CH4 < CHCl3 < CH2Cl2 < CH3Cl (D) CH4 < CH3Cl < CH2Cl2 < CHCl3
394. The correct order of increasing bond angles is

(A) OF2 < H2O < Cl2O < ClO2 (B) ClO2 < OF2 < Cl2O < H2O
(C) ClO2 < Cl2O < H2O < OF2 (D) OF2 < Cl2O < H2O < ClO3
395. The hydration energy of Mg2+ is-

(A) more than that of Mg3+ ion (B) more than that of Na+ ion
(C) more than that of Al3+ ion (D) more than that of Be3+ ion
396. The golden yellow colour associated with NaCl to Bunsen flame can be explained on the basis
of-
(A) low ionisation potential of sodium (B) emission spectrum
(C) photosensitivity of sodium (D) sublimation of metallic sodium of yellow vapours
397. Consider the following molecules or ions.

(I) CH2Cl2 (II) NH4+ (III) SO42– (IV) ClO4– (V) NH3
sp hybridization is involved in the formation of
3
(A) I, II, V only (B) I, II only

(C) I, II, III, IV only (D) I, II, III, IV, V
398. The correct increasing bond angle among BF3, PF3 and ClF3 follows the order
(A) BF3 < PF3 <ClF3 (B) PF3 < BF3 < ClF3
(C) ClF3 < PF3 < BF3 (D) BF3 = PF3 = ClF3
399. The decreasing order of the boiling points of the following hydrides is
(I) NH3 (II) PH3 (III) AsH3
(IV) SbH3 (V) H2O
(A) (V) > (IV) > (I) > (III) > (II) (B) (V) > (I) > (II) > (III) > (IV
(C) (II) > (IV) > (III) > (I) > (V) (D) (IV) > (III) > (I) > (II) > (V)
400. KO2 finds use in oxygen cylinders used for space and submarines. The fact(s) related to such
use of KO2 is/are-
(A) it produces O2 (B) it produces O3
(C) it absorbs CO2 (D) it absorbs both CO and CO2

401. Among the following, the species having square planar geometry for central atom are :
(I) XeF4 (II) SF4 (III) [NiCl4]2– (IV) [PdCl4]2–
(A) I and IV (B) I and II (C) II and III (D) III and IV
402. Which of the following types of bonds are present in CuSO4 . 5H2O ?
(I) Electrovalent (II) Covalent (III) Coordinate
Select the correct answer using the codes given as :
(A) I and II only (B) I and III only (C) I, II and III (D) II and III only
403. The number of sigma and pi-bonds in the compound (CN)2C = C(CH3)(MCO)3 is
(A) 16  and 10  bonds (B) 15  and 11  bonds
(C) 17  and 11  bonds (D) 16  and 11  bonds
Cl
404. The dipole moment of is X. The dipole moment of :
Cl Cl
Cl Cl Cl
(A) is 4X 3 (B) is 3X
Cl Cl Cl
Cl Cl
Cl Cl
Cl
(C) is 6X 2 (D)
Cl Cl Cl Cl
405. The formation of O2– (g) starting from O (g) is endothermic by 603 kJ mol–1. If electron affinity
of O(g) is –141 kJ mol—1, the second electron affinity of oxygen would be :
(A) + 744 kJ mol–1 (B) –744 kJ mol–1 (C) +462 kJ mol–1 (D) –462 kJ mol–1
406. The correct order of first ionization potential is

(A) F > He > Mg > N > O (B) He > F > N > O > Mg
(C) He > O > F > N > Mg (D) N > F > He > O > Mg
407. The correct sequence of the ionic radii of the following is

(A) I– > S2– > Cl– > O2– > F– (B) S2– > I– > O2– > Cl– > F–
(C) I– > Cl– > S2– > O2– > F– (D) I– > S2– > Cl– > F– > O2–
CO2
408. (Mily Cloud) C  A  Na2CO3  B  C
The chemical formulae of A and B are-
(A) NaOH and Ca(OH)2 (B) Ca(OH)2 and NaOH
(C) NaOH and CaO (D) CaO and Ca(OH)2
409. Which of the following statements are correct?

(I) HF is a stronger acid than HCl
(II) Among halide ions, iodide is the most powerful reducing agent.
(III) Fluorine is the only halogen that does not show a variable oxidation state.
(IV) HOCl is a stronger acid than HOBr.
(A) II and IV (B) II and III (C) I , II and III (D) II, III and IV
410. Identify the correct order in which the ionic radius of the following ionis increases:
(I) F– (II) Na+ (III) N3–
(A) III, I, II (B) I, II, III (C) II, III, I (D) II, I, III
411. Which one of the following orders is not in accordance with the property stated against it?
(A) SO3 < Cl2O7 (acidic strength)
(B) F2 > Cl2 > Br2 > I2 ; bond dissociation energy
(C) F2 > Cl2 > Br2 > I2 ; oxidzing power
(D) HI > HBr > HCl > HF ; acidic property in water
412. Sodium forms Na+ ion but it does not form Na2+ ion but it does not from Na2+ because
(A) Very low value of (IE)1 and (IE)2.
(B) Very high value of (IE)1 and (IE)2.
(C) Very high value of (IE)1 and low value of (IE)2.
(D) Low value of (IE)1 and high value of (IE)2.
413. Which of the following order is wrong?

(A) NH3 < PH3 < AsH3 ––acidic (B) Li < Be < B < C –– (IE)1
(C) Al2O3 > MgO < Na2O < K2O –– Basic (D) Li+ < Na+ < K+ < Cs+ –– ionic radius
414. Amongst the following elements (whose electronic cnfigurations are given), the one having
the highest ionization energy is :
(A) [Ne] 3s2 3p1 (B) [Ne] 3s2 3p3 (C) [Ne] 3s2 3p2 (D) [Ar] 3d10 4s2 4p3
415. The outermost electronic configuration of the most electronegative element is

(A) ns2 np3 (B) ns2 np4 (C) ns2 np5 (D) ns2 np6
416. Which one of the following is the strongest base ?

(A) AsH3 (B) PH3 (C) NH3 (D) SbH3
417. Which one of the following fluoride of alkali metals metals has the highest lattice energy ?
(A) LiF (B) CsF (C) NaF (D) KF
418. The first ionization potential of Na, Mg, Al and Si are in the order
(A) Na > Mg > Al < Si (B) Na > Mg > Al > Si
(C) Na < Mg < Al < Si (D) Na < Mg > Al < Si
419. The electronegativity of the following elements increase in the order

(A) Si, P, C, N (B) N, Si, C, P
(C) P, Si, N, C (D) C, N, Si, P
420. A pair of substances which gives the same products on reaction with water is-
(A) Mg and MgO (B) Sr and SrO (C) Ca and CaH2 (D) Be and BeO
421. MgBr2 and MgI2 are soluble in acetone because of

(A) Their ionic nature (B) Their coordinate nature
(C) Their metallic nature (D) Their covalent nature
422. Mercury is a liquid at 0°C because of-

(A) very high ionisation energy (B) weak metallic bonds
(C) high heat of hydration (D) high heat of sublimation
423. The formation of the oxide ion O2– (g) requires first an exothermic and the an endothermic
step as shown here :
O(g) + e–  O– (g) ; Hº = – 142 kJ mol-1
O (g) + e  O (g) ;
– – 2–
Hº = – 844 kJ mol-1
This is because
(A) Oxygen is more electronegative
(B) Oxygen has high electron affinity
(C) O– ion has comparatively larger size than oxygen atom
(D) O- ion will tend to resist the addition of another electron

424. In which of the following arrangements, the order is according to the property indicated
against it.
(I) I < Br < F < Cl Increasing electron gain enthalpy
(II) Li < Na < K < Rb increasing metallic radius
(III) B < C < N < O Increasing first ionization energy
(IV) Al3+ < Mg2+ < Na+ < F– Increasing ionic size
(A) I, II and III (B) I and III only (C) I, II and IV (D) I and II only
425. Among Al2O3, SiO2, P2O3 and SO2 the correct order of acid strength is
(A) Al2O3 < SiO2 < P2O3 < SO2 (B) SO2 < P2O3 < SiO2 < Al2O3
(C) SiO2 < SO2 < Al2O3 < P2O3 (D) Al2O3 < SiO2 < SO2 < P2O3
426. The amount of energy released when 106 atoms of iodine in vapour state is converted into I–
ion is 4.8 × 10–13 J. What is the electron affinity of iodine in kJ/mole?
(A) 489 kJ (B) 289 kJ (C) 259 kJ (D) 389 kJ
427. The electron affinities of N, O, S and Cl are

(A) O  Cl < N  S (B) O < S < Cl < N (C) N < O < S < Cl (D) O < N < Cl < S
428. An element (X) which occurs in the first short period has as outer electrnoc structure s2p1.
What is the formula and acid - base character of its oxides ?
(A) XO3, basic (B) X2O3 , acidic (C) X2O3, Basic (D) XO2 acidic
429. In the descending order of a group in modern periodic table which of this following would be
true?
(I) All the atoms have the same number of valence electrons
(II) Gram atomic volume increases
(III) Electronegativity decreases.
(IV) Metallic character decreases and the basic nature of their oxides decrease
Select the correct anser by using the following codes.
(A) I, II and III (B) II, III and IV (C) II and III (D) I and III
430. The electronic configuration of elements A, B and C are [He] 2s1, [Ne] 3s1 and [Ar] 4s1
respectively. Which one of the following order is correct for the first ionization potentials (in
kJ mol–1) of A, B and C ?
(A) A > B > C (B) C > B > A (C) B > C > A (D) C > A > B
431. During estimation of oxalic acid Vs KMnO4, self indicator is-

(A) KMnO4 (B) oxalic acid (C) K2SO4 (D) MnSO4
432. Fluorine is a better oxidizing agent than iodine. The most probable reason is
(A) Fluorine is less stable than iodine (B) Flurine has smaller atomic radius than iodine
(C) Fluorine is more reactive than iodine.
(D) F– ions have greater electron attracting power than I– ions.
433. The electronic configurations of four elements are given here. Arrange these elements in the
correct order of the magnitude (without sign) of their electron affinity.
(I) 2s2 2p5 (II) 3s2 3p5
(III) 2s 2p
2 4
(IV) 3s2 3p4
Select the correct answer using the codes given under :
(A) III < IV < II < I (B) III < IV < I < II (C) I < II < IV < III (D) II < I < IV < III
434. The aqueous solution of CuCrO4 is green because it contains-

(A) green Cu2+ ions (B) green CrO42– ions
(C) blue Cu ions and green CrO4 ions
2+ 2–
(D) blue Cu2+ ions and yellow CrO42– ions
435. In which one of the following pairs, the radius of the second species is greater than that of
the first?
(A) O2–, N3– (B) Na, Mg (C) Al, Be (D) Li+, Be2+
436. The electron affinity of chlorine is 3.7 eV. How much energy in kcal is released when 4g of
chlorine is completely converted into Cl– ion in a gaseos state. (Given : 1 eV = 23.06 kcal mol–
1
).
(A) 9.6 kcal (B) 19.6 kcal (C) 4.8 kcal (D) 11.6 kcal
437. The first and second ionization energies of Mn are in the ratio 0.475 : 1. If the sum of the two
energy values is 2226 kJ/mol, calculate the second ionization neergy (in kJ/mol).
(A) 1095 (B) 1960 (C) 1069 (D) 1509
438. The second ionization energies of the C, N, O and F atoms are such that
(A) O>N>F>C (B) F>O>N>C (C) C>O>N>F (D) O>F>N>C
439. Which of the following has the maximum number of unpaired electrons?
(A) Mg2+ (B) Ti3+ (C) V3+ (D) Fe2+
440. Which of the following ions has a magnetic moment 5.93 BM? (At. no. V = 23, Cr = 24, Mn = 25, Fe
= 26)
(A) Cr2+ (B) V3+ (C) Mn2+ (D) Fe2+
441. Assign the hybridization, shape and magnetic moment of K2[Cu(CN)4].

(A) dsp2 , square planar, 1.73 BM (B) sp3, tetrahedral, 1.73 BM
(C) dsp , square planar, 2.44 BM
2
(D) sp3, tetrahedral, 2.44 BM
442. IUPAC name of the compound K3[Fe(CN)3CO] is

(A) Potassium pentacyanocarbonylferrate (III)
(B) Potassium carbonylpentacyanoferrate (III)
(C) Potassium pentacyanocarbonylferrate (II)
(D) Potassium carbonylpentacyanoferrate (II)
443. The aqueous solution of the following salts will be coloured in the case of
(A) Zn(NO3)2 (B) LiNO3 (C) Co(NO3)2 (D) Potash alum
444. which one of the following high spin complexes has the largest C. F. S. E. (crystal field
stabilization energy)?
(A) [Cr(H2O)6]2+ (B) [Cr(H2O)6]3+ (C) [Mn(H2O)6]2+ (D) [Mn(H2O)6]3+
445. The equivalent weight of MnSO4 is half of its molecular weight when it is converted to
(A) Mn2O3 (B) MnO2 (C) MnO4– (D) MnO42–
446. The number of chloride ion produced by complex tetraamminechloroplatinum(IV) chloride in an

aqueous solution is
(A) 1 (B) 2 (C) 3 (D) 4
447. The compounds which does not show paramagnetism is

(A) [Cu(NH3)4]Cl2 (B) [Ag(NH3)2]Cl (C) NO (D) NO2
448. Amongst the following ions which one has the highest paramagnetism?
(A) [Cr(H2O)6]3+ (B) [Fe(H2O)6]2+ (C) [Cu(H2O)6]2+ (D) [Zn(H2O)6]2+
449. Which one of the following octahedral complexes will not show geometric isomerism ? A and B
are monodentate.
(A) (MA4B2) (B) (MA5B) (C) (MA2B4) (D) (MA3B3)

450. The formula of tetrachloro diamine platinum (IV) is

(A) [Pt(NH3)2]Cl4 (B) [Pt(NH3)2Cl4] (C) [Pt(NH3)2Cl2]Cl2 (D) K4[Pt(NH3)2Cl4]
451. Which of the following statements is not correct?

(A) The complexes (NiCl4)2– and [Ni(CN)4]2– differ in geometry.
(B) The complexes (NiCl4)2– and [Ni(CN)4]2– differ in primary valencies of nickel.
(C) Nickel ion has the same secondary valency in the complexes (NiCl4)2– and [Ni(CN)4]2–.
(D) The complexes (NiCl4)2– and [Ni(CN)4]2– differ in the state of hybridization of nickel.
452. Both Co3+ and Pt4+ have a coordination number of six. Which of the following pairs of com-
plexes will how approximately the same electrical conductance for their 0.0001 M aqueous
solutions?
(A) CoCl3. 6 NH3 and PtCl4. 5 NH3 (B) CoCl3. 6 NH3 and PtCl4. 3 NH3
(C) CoCl3. 5 NH3 and PtCl4. 6 NH3 (D) CoCl3. 4 NH3 and PtCl4. 4 NH3
453. In the complexes [Fe(H2O)6]3+, [Fe(CN)6]3–, [Fe(C2O4)3]3– and [FeCl6]3– more stability is shown
by
(A) [Fe(H2O)6]3+ (B) [Fe(C2O4)3]3+ (C) [FeCl6]3– (D) [Fe(CN)6]3–
454. From the stability constant (hypothetical values) given below, predict which is the strongest
ligand.
(A) Cu2+ + 4H2O [Cu(H2O)4]2+ K = 9.5 × 108
(B) Cu2+ + 2en [Cu(en)2]2+ K = 3.0 × 1015
(C) Cu + 4en
2+
[Cu(CN)4]2+
K = 2.0 × 1027
(D) Cu2+ + 4NH3 [Cu(NH3)4]2+ K = 4.5 × 1011
455. Which of the following complex ions will not show optical activity?
(A) [Co(en)(NH3)2Cl2]+ (B) [Cr(NH3)4Cl2]+
(C) [Pt(Br)(Cl)(I)(NO2)(Py)NH3] (D) cis – [Co(en)2Cl2]+
456. The number of d-electrons in [Cr(H2O)6]3+ (at. no. of Cr = 24 ) is

(A) 2 (B) 3 (C) 4 (D) 5
457. The number of ions produced from one molecule of [Pt(NH3)5Br]Br3 in the aqueous solution will
be
(A) 4 (B) 5 (C) 6 (D) 7
458. The stability constants of the complexes formed by a metal ions (M2+) with NH3, CN–, H2O and
‘en’ are of the order of 1011, 1027, 1015 and 108 respectively. Then
(A) en is the strongest ligand.
(B) These values cannot predict the strength of the ligand.
(C) CN– is the strongest ligand.
(D) All ligands are equally strong.
459. The complex with spin only magnetic moment of  4.9 B. M. is

(A) [Fe(CN)6]3+ (B) [Fe(H2O)6]3+ (C) [Fe(CN)6]4– (D) [Fe(H2O)6]2+
460. The value of magnetic moment for a complex ion is 1.73 BM. The complex ion is
(A) [Mn(CN)6]4– (B) [Co(NH3)6]3+ (C) (MnF6)3– (D) [Fe(CN)3NO]2–
461. A metal M which is not affected by strong acids like conc. HNO3, conc. H2SO4 and conc.
solution of alkalies like NaOH, KOH forms MCl3 which finds use for toning in photography. The
metal M is-
(A) Ag (B) Hg (C) Au (D) Cu
462. Why is [Ni(en)3]2+ nearly 1010 times more stable than [Ni(NH3)6]2+ ?
(A) NH3 is the weakest ligand
(B) ‘en’ is a chelating ligand and forms thermodynamically more stable complexe
(C) Six NH3 ligands cause steric hindrance around the Ni2+ centre.
(D) NH3 evaporates easily and causes instability to the [Ni(NH3)6]2+ complex.
463. Find out the wrong statement for an octahedral complex.

(A) An ion with d5 configuration has one unpaired electron both in weak and strong fields.
(B) A central metal ion with d8 configuration has two unpaired electrons
(C) An ion with d6 configuration is diamagnetic in a strong field.
(D) In d4, d5, d6 and d7 configuration, weak and strong field complexes have different numbers
of unpaired electrons.
464. What is the effective atomic number, (EAN) of Cr and /or Cu in their complexes, [Cr(CN)6]3–
and [Cu(CN)4]3– ? (Atomic numbers : Cr = 24, Cu = 29)
(A) 36 for both (B) 36 for neither
(C) 36 for Cr in [Cr(CN)6]3– (D) 36 for Cu in [Cu(CN)4]3–
465. Which of the following is not a bidentate ligand?

(A) Acetyl acetonate (acac)
(B) Bis (dimethyl glyoximato) system (dmg H)
(C) Bis (diphenyl phosphino) ethane (dppe)
(D) Glyme, CH3–O–CH2–CH2–O–CH3
466. A certain complex ion, with octahedral geometry has six different ligands: (ML1, L2 L3, L4, L5,
L6)n+. How many isomeric structures are possible counting optical isomers separately?
(A) 15 (B) 30 (C) 45 (D) 120
467. Which of these gives precipitate with K2CrO4?

(A) Pb2+, Ag, Ba2+ (B) Hg22+, Pb2+, Ag+, Ba2+
(C) Pb2+, Ba2+ (D) Ag+, Ba2+
468. The magnetic moment of a transition metal of 3d series is 6.92 BM. Its electronic configura-
tion would be:
(A) 3d16 (B) 3d5 4s0 (C) 3d4 4s2 (D) 3d5 4s1
469. Which of the following set represents only coloured ions ?

(I) Fe3+ (II) Sc3+ (III) Cu2+ (IV) Cr3+
(A) I and III only (B) II, III and IV (C) I, II and III (D) I, III and IV
470. Choose the correct statements.

1. Geometry of the coordination entity can be predicted if its magnetic behaviour is known.
2. [Ni(CN)4]2– involves dsp2 hybridization.
3. For analogous entities within a group, 0 value follows 3d > 4d > 5d.
4. [Pt(CN)4]2– ion is square planar and diamagnetic.
(A) 1, 2 and 3 (B) 2 and 4 (C) 2, 3 and 4 (D) 1, 3 and 4
471. Which of the following statement is/are correct?

I. The ligand thiosulphato, S2O32– can give rise to linkage isomers.
II. In metallic carbonyls the ligand CO molecule acts both as donor and acceptor.
III. The complex [Pt(py)(NH3(NO2)ClBrI] exists in eight different geometrical isomeric forms.
IV. The complex ferricyanide does not follow effective atomic number (EAN) rule.
(A) 1 and 2 only (B) 2 and 4 only (C) 1, 2 and 3 (D) 1, 2 and 4

472. Amongst CuF2, CuCl2 and CuBr2

(A) only CuF2 is ionic
(B) both CuCl2 and CuBr2 are covalent
(C) CuF2 and CuCl2 are ionic but CuBr2 is covalent
(D) CuF2, CuCl2as well as CuBr2 are ionic
473. Amongst the following species, maximum covalent character is exhibited by-
(A) FeCl2 (B) ZnCl2 (C) HgCl2 (D) CdCl2
474. CuSO4(aq) + 4NH3  X, then X is-

(A) [Cu(NH3)4]2+ (B) paramagnetic
(C) coloured (D) of a magnetic moment of 1.73 BM
475. The oxidation number of Fe in [Fe(CN)6]4– Cr in [Cr(NH3)3(NO2)3] and Ni in [Ni(cO)4] are, respectively.
(A) 0, +3, +2 (B) +3, +3, 0 (C) +3, 0, +3 (D) +2, +3, 0
476. In the complex [Cu(CN)4]3– the hybridization state, oxidation state and number of unpaired
electron are, respectively.
(A) dsp2, + 1, 1 (B) sp3, +1, zero (C) sp3, + 2, 1 (D) dsp2, +2, zero
477. Consider the following complex:

[Cr(NH3)5CO3]ClO4
The coordination number, oxidation number, number of d-electrons and number of unpaired d-
electrons on the metal are, respectively.
(A) 6, 3, 3, 3 (B) 6, 3, 6, 3 (C) 6, 0, 6, 3 (D) 6, 2, 6, 3
478. Which of the following will have three stereoisomeric forms ?

I. [Cr(NO3)3(NH3)5] II. K3[Co(C2O4)3] III. K3[Co(C2O4)2Cl2] IV. [Co(en2)ClBr]
(Here en = ethylene diamine)
(A) 1 and 2 (B) 1 and 3 (C) 1 and 4 (D) 3 and 4
479. Which of the following pairs of isomers and types of isomerism are correctly matched?
(I) [Co(NH3)5(NO2)]Cl2 and [Co(NH3)5(ONO)]Cl2 ............Linkage
(II) [Cu(NH3)4][PtCl4] & [Pt(NH3)4] [CuCl4] ........... Coordinations
(III) [Pt(NH3)4Cl2]Br2 & [Pt(NH3)4Br2]Cl2 .............Ionization
Select the correct answer using the codes given below :
(A) 1 and 2 (B) 2 and 3 (C) 1 and 3 (D) 1, 2 and 3
480. KMnO4  HCl  H2 O  X(g), X is a

(acidified)
(A) red liquid (B) violet gas (C) greenish yellow gas (D) yellow-brown gas
481. Select the correct increasing order of 10 Dq value for chromium complexes using the given codes.
(I) [Cr(en)3]3+ (II) [Cr(ox)3]3–
(III) (CrF6)3– (IV) [Cr(dtc)]3+
(Here, dtc = dithiocarbamate)
(A) 1 < 2 < 3 < 4 (B) 3 < 4 < 2 < 1 (C) 4 < 1 < 2 < 3 (D) 3 < 1 < 4 < 2
482. A salt on reaction with dilute H2SO4 gives a reddish brown gas. The salt is:
(A) KNO2 (B) ZnBr2 (C) NaNO3 (D) ZnCO3
483. Matte contains

(A) Cu2S, FeO and Silica (B) Cu2S, FeS and Silica
(C) Cu2S, Cu2O and Silica (D) Cu2S, CuO and Silica
484. By which of the following reactions is blister copper obtained?

(A) Cu2S + FeS  2Cu + FeS2 (B) Cu2+ + Fe  Fe2+ + Cu
(C) Cu2S + FeO  2Cu + FeO (D) Cu2S + 2Cu2O  6 Cu + SO2

485. Statement - I : Aqueous solution of Na2SO4 on electrolysis gives H2 and O2 gases in cathode
and anode respectively.
Statement - II : Discharge potential on H is less than Na+ but discharge potential of OH– is
more than SO42–.
486. Statement - I : Number of P–O–P bonds in cyclotrimetaphosphoric acid is 3.
Statement - II : Number of P = O bonds in cyclo trimetaphosphoric acid is three.
487. Statement - I : The solid N2O5 is ionic.
Statement - II : In solid state N2O5 exist as [NO3]+ [NO2]–
488. Statement - I : The formation of ozone gas from gaseous oxygen is a non spontaneous
process.
Statement - II : The formation of ozone is initiated by the formation of atomic oxygen.
489. Statement - I : PCl5 is possible but PH5 is not possible.
Statement - II : Hydrogen is not sufficiently electronegative to hybridise among 3s, 3p and
3d atomic orbitals of phosphorus.
490. Statement - I : In group III metal ion analysis we should not use only NH4OH without
saturating by NH4Cl.
Statement - II : In the highly alkaline solution Mn2+ and Ca2+ both precipitated together.
491. Statement - I : Prussion blue and Turns bull's blue are formed by different reagents, yet they
are identical are formed by different reagents, yet they are identical.
Statement - II : They have molecular formula as Fe[Fe(CN)6]–.
492. Statement - I : The reaction [Mn(CO)5]– + NOCl [Mn(CO)4NO] + Cl– + CO is a
feasible.
Statement - II : The complex [Mn(CO)5]– and [Mn(CO)4NO] both are stable as per EAN rule.
493. Statement - I : In the begining for the transition element 4s orbital has lower energy than 3d
orbital. But on the addition of some 3d electrons the energy of 3d level becomes lower than
4s elements.
Statement - II : In the second series transition element 4s orbital has higher energy than 3d
orbital.
494. Statement - I : The square planar complex, [Mabed]n+ type shows geometrical isomerism.
Statement - II : Restricted rotation around the single bond is present within the above
complex.
495. Statement - I : The value of 0 for M3+ complexes are always much higher than value for M2+
complexes.
Statement - II : The crystal field stabilization energy of [Co(NH3)6]3+ < [Rh(NH3)6]3+
496. Statement - I : Magnesia is used for the lining of steel making furnace.
Statement - II : Dolomite contains Magnesia.
497. Statement - I : HF is not stored in glass bottles.
Statement - II : HF is only the liquid halogen acid.
498. Statement - I : The hydrogen carbonates of the alkali metals are soluble in water, but are
less soluble than the corresponding normal carbonates.
Statement - II : The hydrogen carbonates of the alkali metals have H-bonding.
499. Statement - I : dP–F is greater than dP–Cl in PF2Cl3.
Statement - II : Axial orbital has no s-character while equatorial orbital is having 33.33 %
s-character in TBP geometry.
500. Statement - I : (CH3)3Si —OH is more acidic than (CH3)3C—OH.
Statement - II : (CH3)3 Si—OH has back bonding.

ANSWER KEY
PHYSICAL
1. A 2. B 3. B 4. D 5. C 6. D
7. C 8. C 9. C 10. A 11. C 12. C
13. A 14. B 15. D 16. B 17. C 18. D
19. C 20. C 21. B 22. C 23. A 24. A
25. C 26. C 27. C 28. D 29. D 30. D
31. D 32. B 33. D 34. C 35. A 36. B
37. A 38. D 39. B 40. D 41. D 42. C
43. B 44. A 45. A 46. A 47. B 48. A
49. D 50. D 51. A 52. C 53. C 54. C
55. B 56. B 57. C 58. C 59. A 60. C
61. C 62. C 63. A 64. C 65. A 66. B
67. A 68. A 69. D 70. A 71. D 72. B
73. C 74. B 75. C 76. C 77. C 78. D
79. B 80. A 81. D 82. C 83. A 84. C
85. C 86. D 87. C 88. D 89. B 90. C
91. D 92. A 93. B 94. A 95. C 96. A
97. B 98. A 99. A 100.C 101. B 102. B
103. D 104. B 105. D 106. A 107. A 108. B
109. A 110. C 111. A 112. C 113. A 114. D
115. C 116. D 117. B 118. A 119. B 120. C
121. A 122. C 123. B 124. C 125. A 126. B
127. 128. 129. 130. 131. 132.
133. 134. 135. 136. 137. 138.
139. 140. 141. 142. 143. 144.
145. 146. 147. 148. 149. 150. D
151. C 152. C 153. A 154. A 155. A 156. A
157. C 158. A 159. A 160. A 161. A 162. C
163. A 164. A 165. C 166. A 167. A
ORGANIC
168. D 169. C 170. D 171. C 172. A 173. D
174. B 175. C 176. B 177. B 178. C 179. C
180. C 181. D 182. A 183. C 184. C 185. C
186. C 187. C 188. A 189. C 190. C 191. C
192. B 193. D 194. C 195. D 196. C 197. B
198. C 199. D 200. A 201. A 202. C 203. A
204. A 205. D 206. B 207. D 208. C 209. C
210. C 211. A 212. D 213. B 214. B 215. A
216. C 217. D 218. D 219. D 220. B 221. B
222. D 223. A 224. D 225. C 226. B 227. C
228. A 229. A 230. B 231. B 232. D 233. B
234. C 235. D 236. C 237. A 238. C 239. D
240. C 241. D 242. C 243. B 244. C 245. C
246. B 247. C 248. C 249. D 250. A 251. D
252. C 253. B 254. A 255. B 256. D 257. D
258. A 259. C 260. D 261. A 262. D 263. D
264. C 265. C 266. C 267. C 268. A 269. A
270. C 271. C 272. B 273. D 274. B 275. D
276. D 277. A 278. B 279. A 280. A 281. B
282. D 283. A 284. C 285. D 286. B 287. A
288. C 289. B 290. C 291. B 292. B 293. C
294. C 295. B 296. D 297. A 298. D 299. C
300. D 301. A 302. A 303. B 304. D 305. D
306. c 307. D 308. B 309. A 310. C 311. C
312. A 313. C 314. C 315. B 316. c 317. B
318. D 319. D 320. A 321. A 322. D 323. D
324. D 325. D 326. D 327. C 328. D 329. D
330. C 331. B 332. D 333. D 334. D

INORGANIC
335. D 336. C 337. A 338. C 339. C 340. D
341. D 342. C 343. B 344. A 345. D 346. A
347. B 348. C 349. D 350. C 351. A 352. D
353. D 354. B 355. A 356. B 357. A 358. A
359 A 360. C 361. D 362. A 363. B 364. D
365. D 366. B 367. C 368. C 369. D 370. B
371. A 372. B 373. B 374. C 375. C 376. D
377. A 378. C 379. B 380. D 381. A 382. D
383. B 384. D 385. D 386. C 387. A 388. D
389. D 390. A 391. B 392. D 393. C 394. A
395. B 396. A 397. D 398. C 399. A 400. AC
401. A 402. C 403. C 404. D 405. A 406. B
407. A 408. B 409. D 410. D 411. B 412. D
413. B 414. B 415. C 416. C 417. A 418. D
419. A 420. C 421. D 422. AB 423. D 424. C
425. A 426. B 427. C 428. B 429. A 430. A
431. A 432. D 433. B 434. D 435. A 436. A
437. D 438. D 439. D 440. C 441. C 442. D
443. C 444. B 445. B 446. D 447. B 448. B
449. B 450. B 451. B 452. A 453. B 454. C
455. B 456. B 457. A 458. C 459. D 460. A
461. C 462. B 463. A 464. D 465. B 466. B
467. B 468. D 469. D 470. B 471. D 472. AB
473. C 474. ABCD 475. D 476. B 477. A 478. C
479. D 480. C 481. B 482. A 483. B 484. D
485. C 486. B 487. C 488. B 489. A 490. C
491. C 492. A 493. B 494. C 495. B 496. C
497. B 498. A 499. D 500. A
HINTS & SOLUTIONS : PHYSICAL

1. A 7. [C]
Both the metals are 0.008% by mass and A + 2B
no. of metal atoms in each molecule must 2C
be integer. Initial conc. 2 3
2
ZMg  24 at eqm. 2.5 4
For Mg : 0.008 =  100 1
M
 M = 300000 ZMg 2.5 4
Molar  1.25 2
2 2
Z Ti  24
For Ti : 0.008 =  100 1
M  0.5
2
 M = 600000 ZTi
[0.5]2
2. B K  0.05
[1.25]  [2]2
Only 1 mole of NH3 gas is formed
Soluiton requires 1 mole HCl and hence, 8. C
only 1 mole of NH3 is formed. Express charle's Law in ºC
HCl + NH3  NH4Cl For thermal expansion of any substance :
Vt = V0(1+t)
1 mole 1 mole
From Charle's law application for all the
For NH3 formation gases :
N2 + 3H2  2NH3  t 
Vt = V0 1  
initial moles 1 4 0  273 
Final mole 1–x 4–3 x 2x =1  The coefficient of cubic expansion for
1
=0.5 =2.5 x=0.5 all the gases, g = /ºC = constant
273
 Mole-fraction of H2 gas in the final
gaseous mixture 9. [C]
It is weak electrolyte because it is slightly
nH2 ionized.
= n n (NH3 will dissolve in water ) 10. [A]
N2 H2
H2 + I2= 2HI
Intial conc. 4.5 4.5 0
2.5 5
=  x x x
0.5  2.5 6 from question 2x=3
3
3. [B] x=  1.5
2
0.005 M H2SO4 =0.01 MH+ = 10–2 MH+, So conc. at eqm. 4.5–1.5 of H2
= 4.5–1.5 of I2 and 3 of HI
4. [D]
[HI]2 33
Buffer solution is formed. So the pH will K=  1
not change. [I2 ][H2 ] 3  3
11. C
5. [C] Gaseous molecules are travelling randomly
pH=.82 = – log [H+] in in all direction.
 [H+] = 1.5×10–4 mole/litre. As all the molecular collisions are perfectly
elastic,
6. [D]
K
V x
Vx 
Monobasic acid [H+] = 0.1 M : a2 : 12. [C]
C A+B C+D for this reaction
2 Initial 1 1 0 0
 0.0001 
K=a2×C=    0.1 remaining at equilibrium 0.4 0.4 0.6 0.6
 100  [C][D] 0.6  06 36
K    2.25
K=10–13. [A][B] 0.4  04 16

13. A 18. [D]

For Vanderwal gas, at any temperature :
19. [C]
Vm a Here: Tb = 0.323K
Z = V  b  V RT
m m w=0.5143g weight of Anthracence.
 a  W= 35g weight of chloroform

For Vanderwal gas:  P  2  (Vm–b) = RT
T Kb= Molal elevation constant (3.9 K–Kg/
 Vm 
mol)
PVm Vm a Kb  W  100 35
 Z = RT  V  b  V RT M=  =177.42g/mol
m m 0.323 0.5143
20. [C]
Z=
Vm a Vm b b
2 21. [B]
   1
Vm  b a Vm  b Vm Vm(Vm  b) 22. [C]
Vm.R.
Rb
First calculate CH per mol and then
14. [B] convert it inot per gm.
When adding HCl in CH3COOH solution the The required thermochemical equation is
concentration of H + is increased. So
5x
reaction is proceed in reverse direction 6x C(s)+5x H2 (g)+ O (g)  (C6H10O5)x;
and the concentration of CH3 COO– is 2 2
decreased. fH= ?
15. [D] Now, fH=  6 x    CH C (s )  5x    CH H 2 (g)



In reaction CO+3H2 CH4+H2O – [ CH(C6H10O5 )x ]
Volume is decreasing in forward direction
so on increasing pressure the yield pf = 6x × (–94.05)+5x × (–68.32) –(– 4.18)
product will increase. × 162x
= – 228.74 x Kcal/mol =
16. B 228.74x
– = – 1.41 Kcal/gm
For BCC : 3 = 4r 162x
23. [A]
BCC crystal : 3 = 4r
On cheavage of one -bond, one -bond
 Di stance between two nearest
is formed in the polymerisation reactions.
neighbour,
H=B.E.C–C  bond
3
2r = = (B.E.CC–B.E.C=C) – (B.E.C–C)
2
= (835–610) – 348 = – 123 kJ/Mol
17. C
24. [A]
In AB AB AB......... type paking, exactly in
between A & B layers, there are octahedral For the-ideal solution Smix is not equal to
voids and exctly in between a layer and zero.
octahedral voides, there are tetrahedral
25. [C]
voides.
Molar concentration of cone sugar
A
5 1000 50
  
Tetrahedral voids 342 100 342
Octahedral voids Mol ar conc entrat i on of s ol ut i on =

1 1000 10
Tetrahedral voids  
m 100 m
B
5h/8 10 50
 or m=68.4
Tetrahedral voids m 342
7h/8
Octahedral voids 26. [C]
3h/8 27. [C]
Tetrahedral voids
h/8 P0 – P n
A Raoult's law : 0

P nN
28. [D] New equilibrium (100–a+x) mm (400+3x)mm

Total of 10 moles of liquids will move in (1000–2x) mm
vapour form. Apply Raoult's law on liquid Partial pressure= PN2 = 700 mm = 800 mm
well as vapour composition
 x=100
Final composition
P2NH3
Vapour form Liquid Now, KP= P P 3 = constant
N2 H2
A x 10–x
1000 2 8002
B 10x x or,  P
100  400 3 PN2  700  N2 =11.94 mm
Now, P= XAPA0+XBPB0
36. B
10  x x [B] [c]
=  200   100 K1 = and K2=
10 10 [A] [A]
Now, mole-fraction of
or, P=200 – 10x ........(1)
[A] [A] 1
A= [A]  [B]  [C]  [A]  K [A]  K [A]  1  K  K
1 YA YB x / 10 (10 – x) / 10 1 2 1 2
And, P  0  0 = 
37. [A]
PA PB 200 100
38. [D]
2000
or, P  ........(2) 1
20 – x When v ol um e i s red uc ed t o ,
4
From (1) & (2) : P = 141.4 torr concentrations becomes four times.
39. [B]
29. [D] k t  10 rt  10
 2
Kt rt
30. [D]
For an increase of temperature to 90° C
c 3  108 i.e. 9 times. the rate increases by 29 times
   3.75  108 i.e. 512 times.
v 8  1015
40. [C]
=3.75×10–8×109 nm = 4×101 nm.
0.693
t1/2 = K  K
31. [D] 1 2
Atomic number is 36 and element is kr. 0.693 0.693

t1 / 2   = 13.86 min
K1  K 2 0.02  0.03
32. [B]
h h h 41. [D]
 or or de-Broglie equation. eq. (i)+eq. (ii) gives S is same and H is
p mv mc
–ve.
33. D 42. [C]
For negative sol, I should be in excess.
— Given :
(i) CH4+2O2  CO2+2H2O, H=+20 kcal
For negative sol, [I—] > [Ag+]
(ii) C+O2  CO2.H =–40 kcal.
34. [C] 1
(iii) H2+ O2  H2O . H= –10 kcal
2
35. A
Atm : C+2H2  CH4
N2+3H2 2NH3 (ii) +2×(iii) –(i) gives.
On removing N2 gas, reaction will shift in H = –40+2 (–10)–(+20) = – 80 kcal.
back direction. 43. [B]
N2 + 3H2 2NH3 V2
W=2.303 nRT lot V
Equilibrium 100 mm 400 mm 1000 mm 1
Partical pressure 20
= 2.303×1×8.314×107×298log
10
Partial pressure (100-a)mm 400mm 1000 mm
just on removing N2 = 298×107×8.314×2.303 log 2.

44. [A] m= (Nuclear mass of 5B8)–(nuclear mass

Ksp = a.Sx 0
of 4Be8+ e )
If Ksp << 1, then increase in 'x' will increase 1
the solubility of salt. = (m5p+m3n)–(m4p+m4d+me)
For different salts, Ksp may be generalised as = (m5p+m3n+m5e)–(m4p+m4n+m4e+m2e)
Ksp= a.SX = At mss of 5B8 –At. mass of 4Be8 –
If Ksp << 1, then the solubility, S, of salt 2×mass of electron
increases with the increase in value of 'x'.
51. [A]
45. [A] Max. uncertainity is through body diagonal
Heat evolved in the Ist case = 40×5=200
cal.
Heat evolved in the IInd case =10 times
because
amounts taken are 10 times =10×200=2000 cal.
4r = 3a
= 400× T or t=5° C.
Max. Uncertainity = 3a
46. A
RT C1 = 3 × 10
E° = nF . ln C
2 = 1.732 × 100
= 17.32 cm
RT C 0.059
E° = . ln 1  ×log 106 = 0.177V = 0.1732 m
nF C2 2
h
V =
47. [B] 4mx
0.2 mole will neutralize 0.2 mole of HNO3, 6.6  10 34
=
heat 4  3.14  9.1  10 31  0.1732
evolved = 57×0.2=11.4 kJ. = 3.34 × 10–3
48. A 52. [C]
4
Last – IP. = 13.6 Z2ev
3 13.6 × Z2 = 217.6
217.6
Z2 = = 16
2 13.6
Z=4
1 Z = 4 = Be  4Eb9
A B C D n=5
For minimum spectral lines, only possibility is A.
Hence, min. no. of spectral lines = 1 53. C
For maximum spectral lines, any two We Know
possibility mya be considered 1
K.E. = – P.E
Hence Max no. of spectral lines = 4 2
49. [D] 1 1 2
= – 2  2 mKr 
The maximum number of electrons in any  
sub-shell is 2(2l+1) 1 1
The maximum number of electrons in any =– mKr2 = mv2
4 2
sub-shell is 2(2l+1). Hence, the total 1 2
number of electrons in an energy level is v2 = – Kr
2
l (n 1) nh n2h2
mv r = m2 v2 r2 =
 2(2l  1)
l0
2
2 2
4
2
 1 2 2 n h
m2   2 Kr  r  2
  4
50. [D]
m for nuclear reaction may be presented r 4  n2
in terms of atomic mass from their nuclear
r n
masses
54. [C] 59. [A]

n = 1  = 0, 1, 23 Eqv. of metal X = Eqv. of metal Y
s, p, d
w1 w2
n = 2  = 0, 1, 2, 3 
E1 E2
n = 3  = 0, 1, 2, 3, 4
1s 1p 1d
w1
 E1 = w × E2
2
2s 2p 2d 2f
60. C
3s 3p 3d 3f 3g
Eqv. of oxide = Eqv. of metal
2 6 2 10 6 2
1s 1p 2s 1d 2p 3s 3.15 gm 1.05

I Period elements = 8 E8 E
II Period elements = 18 E=4
55. [B] 61. C
CO + C  No Rxn Eqv. of CuSO4 .5H2O = Eqv. of Hypo
v1 (s) w
CO + C  2 CO = N × V(lit)
E
v2 (s)
V1 + v2 = 2 ' x' gm 100 ml  (2) ( 1) 
 0.1  CuSO  Cu I 
250 1000  4 2 2
v1 + 2v2 = 2 × 1.4 = 2.8
M
v2 = 0.8 x = 2.5 gm E=
I
v1 = 1.2
62. [C]
1.2
% CO = × 100 = 60 % AgNO3 + NaCl  AgCl + NaNO3
2
No Change in O.S
0.8
% CO2 = × 100 = 40 %  Rxn is non-redox
2
56. [D] 63. [A]
MnO4– + 8H+ + ne–  Mn+2 + 4H2O
1  a  1  35 
K log e    log e   Charge Balance
t  a  x  15  35  9  –1 + 8 + n × (–1) = +2; n = 5
1  35  64. [C]
 log e  
15  26  (+7)
KMnO4
57. C  MnO4–2 (O.S = +6); e– transfer = 1
54 ml = 54 gm  MnO2 (O.S = +4); e– transfer = 3
54  Mn2O3 (O.S = +3); e– transfer = 4
Mole (H2O) = = 3 mole
18  Mn+2 (O.S = +2); e– transfer = 5
H2O
65. A
n = 1H1 + 8O16 = 8
VH TH MO
8 × 3 = 24 NA 2
 2
 2
VO TO MH
2 2 2
58. C
Mass of metal sulphate 50 32
 =1
Mass of metal 2 800
2
eq. mass of M  eq. mass of SO4 66. B
=
eq. mass of M pressure of dry gas = pressure of moist
100 E  48 gas
 = 5E = E + 48
20 E – vapour pressure of water
4E = 48 of E = 12 = 775 – 14 = 761 mm
As metal sulphate is isomorphous with Initial conditions NTP conditions
ZnSO4 7H2O, Valency of M = Valency of V1 = 900 mL V2 = ?
Zn = 2 p1 = 761 mm p2 = 760 mm
Hence, At. mass of M = E mass × valency T1 = (273 + 15) T2 = 273 K
= 12 × 2 = 24 = 288, K

p1V1 p2V2 77. [C]

From, 
T1 T2  H3PO4 is Tri basic acid So it contains three
replaceable H+ ion
p1V1T2 761  900  273
So, V2 = 
T1p2 288  760 78. [D]
pkw = –log kw
= 854.24 mL
pkw = 13
67. A pH + pOH = pkw
Rate of diffusion of H2 is more than CH4 79. [B]
 balloon will have enlarged. N1V1 = N2V2
68. A 0.1 × 1 = N2 × 1000
Tc  liquefication ease  0.1

N2 = = 10–4
1000
69. D pH = 4
Solid component will not affect the equilibrium
80. [A]
70. [A] Let solubility of Ag2CO3 in presence of
Gº = –2.303 RT log Kp. Na2CO3 is x,
Gº=–2.303×8.314 × 298 log 4.00 × 104 Ag2CO3 (s) 2 Ag+ + CO32–
= –26.25 KJ mol–1 2x (x + 0.1) 0.1
Ksp = [Ag+]2 [CO32–]
71. [D] 4 × 10–13 = (2x)2 × 0.1
1 x = 10–6
N (g) + O2(g) NO2(g) × 2 K1
2 2
81. [D]
2 NO2(g) N2O4(g) K2 Numberical value of m cannot be greater
+ + + than that of l
N2(g) + 2O2(g) N2O4 K
82. [C]
K = K1 × K 2
2
When a body carrying charge equal to that
1
 for given eqn Keq = K2K of electron is accelerated by a potential
1 2 difference of 1 volt, its kinetic energy is
72. [B] equal to 1 eV.
As Temp  % yeild  83. [A]

1 1 
73. [C] v  R  2  2 cm 1
 2 3 
1 1
Keq = Kp  5 84. [C]
1.44  10
19
k : 1s2, 2s2, 2p6, 3s2, 3p6, 4s1
74. [B]

As steam is converted into water S
Valence shell
become -ve
For which n = 4
75. [C] l=0
When HCl is produced in gaseous state m= 0
H is –92.3 KJ 1 1
s=+ or –
2 2
76. C
Molar heat of combustion of H2(g) 85. [C]
1 z2
H2(g) + O (g)  H2O() E = – 13.6 eV and
2 2 n2
Hºcomb = Hºf (H2O) () for H –atom Z = 1
93. [B]
86. [D]
K4[Fe(CN)6] Ions
Work function 1 5
hc
W0 = hv0 =  Molecules
0 23
(0.8×2) × 6.02×10 ?
87. [C] = 4.8 × 1024
h
From x.v =
4m 94. [A]
BaCO3 O-atoms
6.6  10 27 1 mol 3 mol
x =
 0.011 
4  (3.14)  (9.1  10  28 )  1.0  10 4   Molecules :
 100 
? 1.5 mol
88. D
= 0.5 mol
3rd I.E. of Li = I.E. of Li2+
from I.E. of any single electron species 95. [C]
=13.6 ×z2 eV Dulong petit's law
= 13.6 × 32 eV At. wt. x sp-heat (cal g–1 per degree)
= 122.4 eV  6.4
89. [B]
96. [A]
Orbital angular momentum = (  1)h Caffeine
for p-electron,  = 1
28.9 g
194 g 194×
90. [C] 100
28.9 194
CaCO3(s) CO2(g) + CaO(s)  g
194 g ? 100 NA
NA
Sto
Given :
0.289  194 1
  NA atoms
100 kg 44 kg NA 14
97. [B]
48 ×10 kg ?
100 X Y
mol 50/10 50/20
= 3.52 kg
=1 0.5
91. [D]  X : Y = 1 : 0.5
Molecules : =2:1
SO3 atoms
1 4 98. [A]
11.2
48 × 6.02×1023 ? n=  0.5
100 22.4
= 6.02 × 1023
99. A
92. [A]
HIO4 ; (+1) + x + 4 (–2)
SO3 moles =0
64g 1 x=+7
Mass :
?
100. [C]
6.4 g
(+4) (+4)
= 0.1 mol 2NO2 N2O4

101. B
ClO3– + 6H+ + 6e–  Cr3+ + 3H2O 110. [C]
(+2)(+3) (+4)
102. B FeC2O4 Fe3+ + CO 2
Cr2O72–+6Fe2++14H+  Cr3+ + 6Fe3+ + 7H2O v.f. (FeC2O4) = 1 + 2 + 3
103. [D] M.M.

E=
O v.f.
H–O–O–S–O–H 111. [A]

no. of eq. of NaClO4 = no. of faraday's
O
112. [C]
104. [B]
4.5 2.7 9.6
(0) (+5) : :
– – – 15 27 48
3I2 + 6OH IO 3 + 5I + 3H2O
113. [A]
Oxidation
2
0.0591 | Cu |
Reduction Ecell = Eºcell  log
114. [D]
2 Ag  
 2
105. D 0.0591
Ecell = Eºcell  log Q
2
M.M 158
E= = y = c +mx
Valence factor 1
115. [C]
(+7) (+6)
KMnO4 K2MnO4 C
116. [D]
v.f.=1 In osmosis solvent molecules migrate
across the membrane
106. [A]
117. [B]
Eq. mass of a metal in its oxide
1
wt. of metalin oxide Solubility  Temp.
= 8
wt. of O in oxide
118. [A]
60 Mn2+ + 2Mn3+ = 4O2–
=  8  12
40 119. [B]
107. [A] 2 a  4r
Meq.(Acid) = Meq. (NaOH) 120. [C]
30×(M×2) = 15 × 0.2
A : B
M = 5 × 10–2 M 1 1 5 1 5
Milli equivalent 4  4  10  
8 2 2 4 2
108. [B]
121. [A]
Eq.(NaOH) = Eq.(H2SO4)
122. [C]
w
= (0.5×2)×(10×10–3) rate =

 d BrO3


1 d Br2  
40 / 1 dt 3 dt
 w = 0.4 g 123. [B]
1
t1 / 2  n1
109. [A] a
Eq.(KMnO4) = Eq(H2O2) 124. [C]
Fe(OH)3 /Fe+3 is positively charged colloidal
sol. So
 x 
1   coagulation power   ch arg e
 N × (x × 10–3) =  100 
34 / 2 125. [A]
Fact
 N = 0.58
126. [B] 138. [A]

Kp = Kc(RT)ng
x
= K p1/n
m
139. [B]
x 1 1 1 1
log = log P + log K, slope = 
m n n = 40
K 0.025
intercept = log K
140. [B]
127. [A]
t(O2 ) M(O2 ) st. of HA1 K a1
 
t(g) M(g) st. of HA 2 K a2
128. [A]
3P 141. [D]
u
d Ksp = 4s3
129. [C]
142. [B]
3
KE = nRT
2 K w 10 14
Kb =  = 10–9
130. [B]
Ka 10 5
1
r  143. [B]
M
[Salt]
131. [D] pH = pKa + log
[Acid]
Ideal gas can't be liquefied.
144. [C]
132. [B] [OH–] = C
P1
Wrev. –nRT n P 145. [B]
2
a 3
133. [A] r+ + r– =
2
Hdiss. = HL + HHyd. 2r– = a
= 778 + (–774.3) = 3.7 kJ
146. [B]
Gdiss. = Hdiss. – T Sdiss
Volume of autric cell = (200×10–10)3 cm3
= 8 ×10–24 cm3
134. [D]
Factual 147. [C]
148. [A]
135. [C]
t1/2  as conc. 
Hr = (B.E)R – (B.E)P
zero order
Intercept = 0
136. [C]
= log 2K = 0
Kf 2k = 1
K=
Kb k = 1/2
149. [B]
137. [C] Conc. become 10 times rate become 100
[PCl3 ][Cl2 ]
times
K= [PCl5 ] which means order with respect to [H+] is 2.

150. [D] 158. [A]

All members of any class of hydrcarbon Wadi rev  Wadi irr.
do not have same empirical formula.
159. [A]
151. [C]
The two enanti omers fo any chiral
All moles remains constant vapour density compound have the same enthalpy of
remains constant. formation.
152. [C] 160. [A]

 3n  1  In an adiabatic process, the surrounding
CnH2n+2+   O  nCO (n+1)H O
does not exchange heat with the system
 2  2 2 2
(Alkane) and the process may be reversible or

irreversible for system but it always remain
reversible for the surrounding.
 3n 
CnH2n+   O  nCO2 +nH2O 161. [A]
 2  2
When an ideal binary solution of liquids A
(Alkane) and B is distilled, the contains relatively
larger amound of the more volatile liquid.
 3n  1 
CnH2n–2+   O  nCO2 +(n–1)H2O 162. [C]
 2  2
order of reactions cannot give idea about
(Alkane) slow or fast reaction.
moles of hydrocarbon < moles of O2
163. [A]
153. [A] The active mass of pure solid and liquids
Boyle temperature of hydrogen and helium depends on density and molecular mass.
gases are less than 273 K. The density and molecular mass of pure
liquids and solids are constant.
154. [A]
Above critical temperature gas state 164. [A]
exists. Adsorption is a spontaneous exothermic
process in which randomness decreases
155. [A] due to force of attracti on between
In metallic crystale like-sized atoms have adsorbent and adsorbate.
arrangement of atoms corresponds to the
closet packing. 165. [C]
156. [A] 166. [A]

Transition energy is always greater when
Schottky defects is more likely in ionic
electrons come to an orbit with lower orbit
solids in which cations and anions are of
number than electron come to an orbit
comparable size. Frankel defect is more with higher orbit number, irrespective to
likely in ionic solids in which cations and the higher orbit from which is coming.
anions have large differences in their ionic
size. 167. [A]
The loss in mass in K-capture is equal to
157. [C] the difference in atomic masses of parent
Diamond is having very high melting point nucleus and the daughter nucles but in
due to its closely packed tetrahedral positron decay, additional mass loss equal
to the mass of two electrons also occur.
structure.
HINTS & SOLUTIONS : ORGANIC

168. [D] 177. [B]
It is sandmey's reaction
OH
oxidise to 2-butanone
CH3–CH–CH2–CH 3 178. [C]
which gives idoform test.
169. [C]
Ag–O–N=O
CH3 – CH2 – Br CH3–CH2–NO2
(covalent)
O (major)
CH 3 (Nitro ethane)
O –C–
O +
C–OH is Asprin CH3–CH2–O–N=O
(Ethyl nitrite)
179. [C]
170. [D] Bond s trengt h  bond orde r 
Ether React with H2SO4 and form salt  It
1
dissolve but It does not react with Br2,HOH
or Na. bond length
180. [C]
171. [C]
It is Reimer Tiemann Reaction. Cl Cl
Mg
Et2O
172. [A]
Br MgBr
Br
– Mg
Cl
dimerisation
173. [D]
Viccinal diol, -hydroxy carbonyl can re- Benzyne
act with HIO4 but not Isolated diol.

181. [D]
174. [B] SH
Cl CH 3 No reaction
R at e of D ehyrat i on  st ab i l i ty of NO
1 2
carbocation SN , Or SN
175. [C] 182. [A]
Cl Cl
H Ring expension
:
CH2–OH –H2O CH2 H H,

H
HSO4 – H2O
H O H
CCl3– C – H
Chloral
176. [B]
183. [C]
Ag–C N Intramlecular cannizaro reaction.
CH3 – CH2 – Br CH3–CH2–N–C
(covalent)

184. [C] 194. [C]

Chiral carbon
* CH=O CH2–OH
Con. NaOH
OH Intramolecular
Secondary butyl alcohol. CH=O cannizaro

C–OH
O
185. [C]
H
CH3 CH3 CH3 H
S S R S ester O
Ph H H Br Ph Br Br CH3
Br Ph H Ph O
I II III IV
{II & III are enantiomers pair }

lactone
186. [C]
195. [D]
longest carbon chair has 8 carbons.
(Resonance) 196. [C]
187. [B] H
Conc. HNO3 + Conc. H2SO4  O
C=O
NO2 + H2O + HSO4 HO C–Cl
Nitronium
HS C–O Et
188. [A] C O
NO2 Nitronium N
189. [C]
197. [B]
Orther and para prodcut.
NH 2 N N
HNO2
198. [C]
Max zwitter ion exist at isoelectric point
pKa1  pKa2 9.8  2.3
pI =  6
2 2
190. [C]
It is electrophilic substitution reaction.
199. [D]
191. [C]
Maximum covalency of nitrogen is 4. CH
CH
–H2O
192. [B] OH OH OH
electronegativity of O > N {I & III have
same no. of covalent bond }
+ change on electronegative atom is less –H
stable
Hence, III > I. O O–N
 III > I > II.
193. [D]
–OH  is present R.H.S. at last chiral car-
bon so It is D-torm
200. [A] 205. [D]
H H
T.S.
C
CH4+F H
H
P.E.
CH3+NF
H
H
C
F° is les stable and more reactive Than H H
.X°
201. [A]
206. [B]
CH 3 CH3
Br
C C
Br2 Na Dry ether CH3 CH3
m whrt3 reaction
Geometrical isomers
207. [D]
202. [C]
208. [C]
209. [C]
O
No participation due to resonance. 210. [C]
203. [A]
H
O C CH
3
E/Z
X = CH3 - CH2 – CH2 – C – NH2 CH3 *
Compound X is obtain from acid chloride H *
i.e. butanoyl chloride. H CH3
total stereocentres are 4.

211. [A]
204. [A]
CH3 CH3 CH3 CH3

C=C Br2 Br H
(CH 2=CH–CH 2) 2–CuLi H Br
H H CCl4 +
H Br Br H
anti
addition CH3 CH3
O
1,4-addition Enationeric pair
O Li
CH 2=CH–CH2–Br
212. [D]
Br Br CH3
CH=C
* H
+ LiBr
O
stereocentre =2
22=4
DBE = 1 ring +1  bond = 2
A+B = 4+2 = 6

213. [B] 220. [B]

Friedal craft acylation which gives p-prod-
uct
OH
H O O O O 221. [B]
dil NaOH
CH2–C–CH2–CH2–C–CH3 CH2–C–CH2–CH2–C–CH3
–H 2O O
O O O
H
O
H a
OO D
OH
b C
HOH activated
CH3 CH3 CH 3 –OH CH3
OH OH O ring
So EAS reaction takes place at p position

(b).
214. [B] 222. [D]

4 Because –OCH3 group shows +M effect.
2
OC2H 5
1
O
3 223. [A]
O Because l.P. of N participate in conjuga-
ethyl-4-methoxy butananoate tion. So o &-p position become e— rich so
215. [A]
O
3
1
NH–C–CH3
7 5
4
8
is o&p director of EAS.
6 2
4-(1,1dimethylethyl)-5-ethyloctane
216. [C] 224. [D]

due to –M effect of –NO2 group. F
In this Reaction :C is carbene &
Cl
217. [D]
F
Becasue all compounds have  bond. Which
converts into  bond after addition. is product
218. [D]
225. [C]
 keto acid so decarboxylation Reaction
+ H
takes place
H –H2O
OH 226. [B]
2
O
O
H OH
O HO 4
HOH
–OH
four substituents are
1
3
O H OH O H
present.
227. [C]
Three ethers & four alcohols so total iso-
219. [D] mers =7
O O O O
228. [A]
PCC
Oxidation
H2O
+
Allylic alcohol is oxidised in presence of
H
OH of alcohol
CH EtMgBr CH–Et CH–Et MnO2
O Oxidation OMgBr OH
of alcohol
238. C
229. A
O SC
H *
dil NaOH
+
–H
O O O *
H
+
total steriogenic centre =3
total sterio isomers = 2n =23 = 8
COCH 3
H 239. D
OH
240. C
–H2O
241. D
COCH3
242. C
243. B
CH–Ph
230. B
CH2–Cl CH2–CN C–CN
KCN Ph–CHO
231. B
Due to the presence of –NH2 group.
244. C
232. D C6H5–CH=CH–CHO + CH3–CH=CH–CHO
2 moles of aldehyale & 1 mole of alcohol
Base/EtOH
so order of Reaction is 3
C6H5–CH=CH–CH=CH–CH=CH–CHO+H2O
233. B
CHO
Conc . NaOH
  
CH2OH 245. C
Δ
O
CHO Cannizaro
COOH H2SO 4
reaction –H2O Hg(OAc)
O
OH O
Hg(OAc) 2 NaBH4,OH
234. C
235. D
246. B
R-Mgx
CH–R
HOH
CH–R + Mg X Phenolic compounds gives Reimer Teimann
C–H
OH
OH reaction. Thus,
O O–Mgx
OH
OMe
236. C
O will give Reimer Teimann reaction.
Ph–C–NH–CH 3 does not give but other 247. C

are give. Hoffmann bromamide Reaction. CCl4 is used in reimer teimann reaction and
:CCl2 acts as an electrophile.
237. A
248. C
OH
and
In
OH
both ortho and para positions are unoc-
cupied.

249. [D] 256. [D]

+
H OH
O
OH (1) PhMgBr (excess) C
EtO – C – O – Et Ph Ph
Can show geometrical isomerism. (2) H
+
Ph
CO2 H CO2H CO2H H O
OH
O S (1) PhMgBr (excess) C
Ph Ph
+
(2) H Ph
CH3 H CH3 H
O OH
Can show geometrical isomerism. (1) PhMgBr (excess) C
Cl – C – O – Et Ph Ph
+
O O (2) H Ph
(i) KCN
CH3–C—H CH3–C—COOH
(ii) H
257. [D]
does not show geometrical isomerism
O OH
250. [A] (1) PhMgBr (excess)
H – C – O – Et CH
(2) H + Ph Ph
CH3
1
O2N 2
NO2
6
O OH
5 3 2,4,6-trinitrotoluene (1) PhMgBr (excess)
4
CH3– C – H CH
+
NO2 (2) H Ph Ph
O OH
251. [D] (1) PhMgBr (excess)
2 4 H – C – Cl CH
+
5 (2) H Ph Ph
1
Pent-1-en-4-yne
3
252. [C] 258. [A]

H of –COOH group is most acidic than H of
Cl
O
Mg
C–OH ether
–OH group. Thus,
(free-radical mechanism)
is most acidic.
259. [C]
253. [B]
Meso compounds are usefull to separate
O Ketone
recemic mixture.
254. [A]
–OCH3 group is more electron donating O
group than –CH3. Thus, –OCH3 will stabilise
carbocation more than –CH3.
Alcohol
OH
255. [B]
O
O O O O NH2 amide
(i) CH3ONa
OCH3 (ii) CH3–I
OCH3
CH3
260. [D] 267. [C]

OH OH
Me Me
: :
(i) CHCl3, KOH
H H2O H (ii) H 3O+
O Me Me
O O O H
COOH
OH
Me COOH
(1) tauto.
O OH
(2) H O Me
OH
is more sterically hindered. So, it will not form.
268. [A]
261. [A] –OCH3 and –CH3 both are electron donat-
Ph–O–Ph do not undergo acid catalysed ing groups. Thus they are decreasing the
hydrolysis because lone pair of O is in con- electron deficiency of carbon.
jugation with both benzene rings. SO Ph-
O bond with not break. 269. [A]
262. [D]
270. [C]
Cl I Cl Br Cl F
C=C=C C=C=C C=C=C
F Br I F Br I 2
H3C 1
Cl F F F 3
F–C C–C–Br Cl–C C–C–Br Br–C C–C–Cl I–C C–C–Cl

I I I Br 1
2
263. [D]
Phenol give violet color with neutral FeCl3.
271. [C]
264. [C] CH3 Cl CH3 CH3
due to –I effect of –Cl group CH3–CH2– H2O
CH(Cl)–COOH is strong acid among the
given compounds.
HOH HOH
2 products 2 products
265. [C] (minor) (major)
O OH
CH3–C–CH2–CH2–CH3 CH2=C–CH2–CH2–CH3 272. [B]
2-Pentanone
H O H
O3
266. [C] CH2 = CH – C C
H
(1mole)
O O
CHCl 3 Cl
t-B4OH Cl + HCl
273. [D]
– NaCl
C2H5ONa + C2H5– C – Cl C2H5– O– C – C2H5
O O

274. [B] 279. A
OH (i) Br2
Cl Cl || –HBr
O
H Cl Cl H C6H5 CH Br COOH
( cis ) < ( trans )

280. [A]
so, 2 > 1
Acrylonitile (CH2 = CHCN) is Monomer used
275. [D] to prepare Orlon.
281. [B]
A tripeptide has 3 Amide and 2 preptide
bonds
282. [D]
283. [A]
geometrical isomers, 24 = 16
276. [D] O
dil KOH OH N2 Cl N +
2CH3CHO N
OH–
+
CH3 – C – H + H – CH2 – C – H –H2O
O O NH2
NH2
CH3 – CH – CH2 – C – H
OH O OH
Total geometrical isomer is = 4 N=
N
277. [A]
O OH NH2
(Keto) (Enol) 284. [C]

Valine is one of the 20-essential amino
acid for metabotism.
278. [B]
285. [D]
(1) (1) H
(1)
1
Keq Electrophilicity
+m effect
(2)
286. [B] 293. [C]
CH3 CH3 CH3 CH3

Br2 N
C=C Br H H Br
H H CCl4 CH3 CH
H Br Br H CH3 3
anti
addition CH3 CH3 294. [C]
Enationeric pair
295. [B]
CH 3
287. [A] H CH2
Br
Br +O Kt
–
O O
I/Br +OH,
CH 3–CH=CH 2 O – HBr O
H
I
296. [D]
288. [C]
CH3 CH3
289. [B] Br2 H Br Br H
CCl2 Br H H Br
(CHH) (CHH)
H CH 3 CH 3
H anti addition
Cl
(ClCH) (CHH) A process axis of symmetry
Cl
297. [A]
290. [C] H
NaOH
CH3–CH=O CH3 – C – CH 2 – C – H
OH CO2H Br
OH OH OH O
* * *
* * HOH
* OH S * S
* HCO2
Br Br CH3 – CH = CH – C = O
Br
diastereomers But from other option you
All of them having 2 stereogenic centers will not get diastereomers
but option (C) does not have plane of sym- 298. [D]
metry so it is not meso compound.
O Cl
291. [B] PCl 5
Ph – C – CH3 Ph – C – CH3
CH2– CH3 CH – CH3 CH2– CH3
| || | CH3–I Cl
Ph – C – Cl Ph – C – Cl + Ph – C – Cl
| | || Ph – C C – CH3
CH3 CH3 CH2
E/Z Br
Total No. of E2 (elimination bimolecular 2NaNH2
CH3 – C C – CH3
products)
Br
292. [B] + 2NaBr + 2NH3
O 3NaNH2
Ph– CH – CH Ph – C C Na
C–Cl COH Cl Cl Et–I
Pd/BaSO4
Ph – C C Et
+ NaI
Total count of x + y + z = 3 + 2 + 3 = 8

299. [C] 305. [D]

CH3 – CH2 – CH2 – CH2 – OH POS is present all of them and all are meso.
CH3 – CH – CH2 – CH2 – OH
306. [C]
CH3
compound (C) have 10 e– so it will aro-
* matic.
CH3 – CH – CH2 – CH2 – CH3
OH 307. [D]
CH3 (D) because of repulsion between hydrozen
so it is non planner, and it will be aromatic
CH3 – C – CH3
OH 308. [B]
Total = 5 Stailibity order aromatic > non aromatic >
anti aromatic
300. [D] I > III > II
CH3 CH3
Br Br
Br2/H2O 309. [A]
OH OH 310. [C]
Br
m-meso tribromoderivative 311. [C]
It has penenulic – OH and dissolves in NaOH Formed carbocation is most stable because
and characteristics colour with nevtral it is in conjugation with benzene ring
FeCl3.
312. [A]
301. [A]
O
302. [A] C – NH2 NH2
O O KOBr + CO2 + KBr
NH2OH (1eq)
O N – OH 313. [C]
tautomerisation
314. [C]
OH
315. B]
Cyclohexene will react with Br2/H2O and
cyclohexane will not react with Br2/H2O.
N=O
303. [B]
316. [C]
304. [D]
NaNH2
2 H CH3 – C C–H CH3 – C C Na
CH3 – I
CH3 – CH=CH – CH 3 Li/L
i q.
NH
(b) 3
CH3 – C C – CH3
O3
-C aC
CH3 – CH=CH – CH 3 H 2/
Pd (a)
1 H (c)
2 H
x=5
Plane of symmetry (y) = 1 Both (b) & (c) are diastereomers.
sum of ( x + y ) = 5 + 1 = 6
317. [B] 327. [C]

CH 2– OCH3 Statement-1 : True SN2
O
Statement-2 : False CH 3–C–CH 3 is
Because – OCH3 group is not in conjuga- polar solvent and remaining paragraph is
tion with benzene ring so + M of –OCH3 correct
will not operate.
318. [D] 328. [D]
Me3C–COOH undergoes AAC’ and where
major product in ether not ester. 329. [D]
319. [D]
P2 is the major product O
320. [A]
N–H give bromamide reaction
H NO2
RDS NO2 –H
+ NO 2 fast O
Nitration of benzene do not show KI efect,

so C6H6 ~ C6D6 ~ C6T6 330. [C]
Peroxide
CH3–CH=CH–CH3+HBr Free radical
mechansim
321. [A]
(Trans - Anti Addition  Meso) CH3–CH–CH2–CH 3
Br (+)
O +
(i) PhCO3H H +H2O Peroxide
Meso CH3–CH=CH–CH3+HCl lonic
mechansim
CH3–CH–CH2–CH 3
Cl (+)
322. [D]
(Pyrolysis of ester) Hoffmann lakene
331. [B]
+ is major product
332. [D]
O major
Racemic product obtained which shows no
optical rotation
O
333. [D]
323. [D] O O O
324. [D] NaOH
325. [D] Cl3C–C–H H–C–OH + CCl3 H–C–O + CHCl3
+
H fast
D3C–CH–CH3 –H2Or.d.s D3C–CH–CH3
OH
D2C=CH–CH3+CD3–CH–CH2 334. [D]
Breaking of C–H or C–D bond is not RDS
so both alkene are formed.
326. [D] HBr
+ More stable
35ºC
Br product
H H
(P1) (P2)
Br
MeO
CH3 Br SN2
MeO CH 3
Br
F F
R-form R-form
Inversion is taking place known as Walden More stable
inversion but here R form is producing R
Carbocation
form only

HINTS & SOLUTIONS : INORGANIC

335. [D]
344. [A]
The electronic configuration of O2–
(A) H2+ total e– = 1
O2– 1s2 1s2 2s2 2s2 pz2 2px2
2py2 (2py)1 B.O. = 1/2 [1, 0]
Bond order = 1/2 [Nb – Na] B = 1/2×1 = 0.5
= 1/2 [10 – 7] = 3/2 = 1.5 (B) O2– total e– = 17
336. [C] 2 2
 
As the no. of N.P. on central atom in- 2 2
B. O. = 1/2  = 1/2 [6 – 3]
creases, bond angle decreases. 6 3
So, NH3 has maximum bond angle. = 1/2 × 3 = 1.5
Also, if no. of lone pair is same then if (C) B2 total e– = 10
E. N. of central atom increases B. A. also
increases. 2 2
 
H2Se has smallest bond angle. 2 2
B. O. = 1/2  = 1/2[2 – 0]= 1
2 0
337. [A]
Due to intermolecular hydrogen bond in (D) F2 , total e– = 18
H2O, its molecules are associated with each 2 2
other which is responsible for unusually  
2 2
high boiling point of water. B. O = 1/2  = 1/2 [6 – 4] = 1
6 4
338. [C]
339. [C] 345. [D]
In BF3, the central atom (boron) has six H – O – N = O. only covalent bonds are
electrons in the valence shell. present.
340. [D] 346. [A]
341. [D] F
(A) B , sp2 trigonal ploner
F F
N N
N
F F N N (B) H H , sp trigonal pyromidal
3
F N H
2 > 1 P
The dipole moment of NF3 is less than NH3. (C) Cl Cl sp Trigonal pyromidal
3
Cl
342. [C]
SiF4 has symmetrical tetrahedral structure
so individual bond moments cancel each (D) I sp3d, T-shaped
other resulting in zero dipole moment. F F
343. [B] F
BF3 is sp2 hybridized. Hence, it is trigonal
H planner.
H H 347. [B]
B B
(A) SiF4, sp3 .p. = 0
H H
H  symmetrical structure
=0
(Banana bond)
 momeutanrity gain of octet F
 assumed incomplete octet. S
(B) sp3d see-saw
 electron deficient compound. F F
F
The compound of which central atom is =0
octetless is known as electrodeficient
compound. Hence, B2H6 is electron defi- (Because of unsymmetrical structure in-
dividual bond moments can not cancel
cient compound.
each other)
F F
sp3, trigonal pyramidal
Xe O Xe O
(C) sp3d2 sq. planer
(isostructural)
F F
350. [C]
=0 Be2+ < Li4+ < Na+ (ionic size)
F Be2+ > Li+ > Na+ (polonsing power of cat-
ion)
(D) B sp2 trigonal planer polarsing of cation < covalent character
 BeCl2 > LiCl > NaCl
F F
(covalent character)
=0
As difference of electronegativity in-
SF4 is sp2 hybridized. Hence, it is trigonal
creases, percentage ionic character in-
planner.
creases and covalent character decreases
348. [C] i.e., negativity difference decreases and
covalent character increases.
Cl Cl Na is more + ve than Li and Li is more + ve
than Be.
Te
351. [A]
Cl Cl Order of strength of hydrogen bonds
NH --- N < OH --- O < FH --- F
S.N. = 1 + 4 = 5
13 18 40 kJ mol
 Hybridisation  sp3d
As greater the difference in the electrone-
349. [D] gativity, greater is the strength of the H
– bond.
F F
352. [D]
Xe +
NH4 is sp3 hybridised with tetrahedral
(A) sp3d, see-saw
shape
F F
 bond angle = 109º28’
As it is sp3d hybridized with tetrahedral
F I shape.
Xe
sp3d2 squore planer 353. [D]
F F Molecule having almost negligible tendency
to form hydrogen bonds is HI as hydrogen
O
bonding dependes on two factors.
S
(B) sp3, pyramidal 354. [B]
O O
O O
O O
N sp2 trigonal planer (I) H – O – S – S – O – H
O O O
F No. of -bond = 4
(C) B sp2 trigonal planer O

F F (II)
HO – S – OH
N No. of - bond = 1
F sp trigonal pyramidal
3
F O O
F
(III) H – O – S – S – O – H
O O O
Br
(D) sp3, trigonal pyramidal
No. of -bond = 3
O II < III < I

355. [A] 364. [D]

N2, total e– = 14
PtF6 I noble gas compound
st
Xe
1s2, 1s2, 2s2, 2s2, 2py, 2px2, 2pz
356. [B] 2py, 2px, 2pz
 since 2px is highest occupied molecu-

 12   22  21 2 cos   lar orbital (HOMO) hence e– will be re-
if  = 90º,  maximum. moved from 2px for the formation of N2+
from that of N2.
357. [A]
365. [D]
As bond order of N2, O2, He2, H2 are 3, 2,
In (1) hydrogen bonding decreases  <
0, 1, respectively
60º
358. [A]
In (2) dipole-dipole repulsion increases 
Hydrogen bond is weak bond.
> 60º
359 [A]
In (3)  remains 60º
N2, total e– = 14
Hence, the correct order is 2 < 3 < 1.
1s2, 1s2, 2s2, 2s2, 2py, 2px2, 2pz
2py, 2px, 2pz 366. [B]
 since 2px is highest occipied molecu- The mlecular of water consists of two hy-
lar orbital (HOMO) hence e– will be re- drogen atoms bonded to oxygen atom by
moved from 2px for the formation of N2+ covalent bonds. Because of the polar na-
from that of N2. ture of water molecular, the water mol-
360. [C] ecules are held together by intermolecu-
If sum of total e– = even lar hydrogen bonds. In this arrangement,
each oxygen is tetrahedrally surrounded
 species will be diamagnetic (exception)
by four hydrogen atom ; two by covalent
 16e– and 10e– system are paramag-
bond and two hydrogen bonds.
netic
367. [C]
361. [D] F
F Cl F
F
S F sp3d TBP F
No. of L.P. = 2
F 368. [C]
 asial and equitorial, two types of F – S
C N
– F bonds are present in the molecule SF4.
Ag
362. [A]
F C N
No. of - bond = 4
F S F sp3 tetrahedral
369. [D]
F
O
F F
S H C H
sp3d, see-saw O O
F F
Since structure is not symmetrical hence
bond moment can not concel each other.
(B) F Xe F sp3d, linear 370. [B]
No. (nitric oxide) total e– = 15
O = C = O sp, linear 2 2
(C) BF3 sp2, trigonal planer PCl5 sp3d, TBP 2 2
As both are linear in shape. B. O. = 1/2 = 1/2 (6–1) = 2.5
6 1
363. [B]
Zn + Conc HNO3 371. [A]
Zn(NO3)2 + NO2 + H2O (NH4)2SO4 NH3 + H2SO4
Zn + dil. HNO3 HNO3 H2O + NO2 + O2
Zn(NO3)2 + N2O + H2O (NH4)2Cr2O7 N2 + Cr2O3 + H2O
NH4NO3 N2O + H2O
372. [B]
380. [D]
px – py combination is not possible
H
373. [B] H–C–H
(A) H2– total e– = 3  paramagentic
H H
(B) H2 , total e– = 2  diamagntic
(C) H2+ total e– = 1 paramagentic
H H
(D) He2+ total e– = 1  paramagentic
H
374. [C]
No. of -bond = 15
Ethylene is a planar molecule in which car-
bon atom is sp2 hybridized. No. of -Bond = 3
375. [C] 381. [A]
S2 molecule is paramagnetic like O2 as both
have two unpaired electrons. I3+ I sp3
I I
376. [D]
1s2, 1s2, 2s2, 2s2, 2p2x, 2py, 2py
I3– I sp3d
2pz, 2pz I I
 e– is removed from 2py for mormation 382. [D]
of O2+. Smaller the size of ions and more the
carge, more is the lattice energy.
377. [A]
383. [B]
O22  18(e—) all e— paired
For polyationic anions
B2 10 e—  unpaired electron
1
 Paramagnetic T.S. × Ionic choraetler ×

O2 13 e  unpaired e—  × size of cator
 Paramagnetic  Be2+ < Mg2+ < Ca2+ < K+
O2 16 e—  unpaired e— (Polarsing power)
 Paramagnetic  BeCO3 > MgCO3 > CaCO3 > K2CO3
378. [C]  IV > II > III > I
(A) AlF3 (all Bonds equal ionic Bond e×,sl) 384. [D]
:
N Bond Anqle of too species will be same

(B) F F sp3, Pyramidal only if Both have some hybridizatio and
F have symmetrical strecture
F
Cl sp2, 120°
(C) F sp3d B
F F
F F
 axial and equitorial Bond exist so all Cl
Bonds are not equal B sp2, 120°
F Cl Cl
(D) B sp2 385. [D]

F F KO2  K+O2—
 all Bond length equal  O2– total e– = 17
2
Chlorine atom in ClF3 is sp3d hybridized. 1s2,*1s2, 2s2, *2s2,  2pn ,
hence bonds are not equal as it has dis-
torted T–shape.
, 1 *2px
379. [B]
+ – unpaired e—= 1
PCl5 PCl4+PCl6
Magnetic moment = n  (n  2)
 1  3 BM
= 1.73 BM

386. [C] O2+, Total e—= 15  15  B.O. = 2.5

Here, A, B, C and D are O, F, Na and Mg,  O2+ > O2 > O2— > > O22—
respectively hence the compounds formed (Order of Bond strength)
by them are C 2 A (Na 2 O), DA(MgO),
CB(NaF) and DB2 (MgF2), respectively. 393. [C]
387. [A] Correct order of dipole moments
CH4<CHCl3 < CH2Cl2<CH3Cl
H H H
121.5º
83º 394. [A]
B 97º B
H sp
2
H H sp
3
sp
3
sp
3
388. [D] O O O : Cl=O

R Q F Cl Q2 Cl H Q3 H
O=N=O
1
O
 Q4 > O2 > Q3 > Q1
N=O
– O=N=O 395. [B]
O–N=O
O Hydration energy polarising power
1 Na+ < Mg2+ < Mg3+ < Be3+ < Al3+
no. of lp=1 no. of l.P = no. of l.p. =O
2
396. [A]
There for
In fram e te st t he rm al e xc i t at i on
 NO2+> NO2> NO2– (Bond Agle) deexcitation takes place in cation with low
389. [D] Ionisation potential
O2, B.O=2 397. [D]
H2O2  O22–, total e— = 18
H H
2 2
(I) Cl C Cl sp3, (II) H N H sp3
1 2 2 1 1
B.O. = = (6–4) = ×2 = H H
2 6 4 2 2
(1) O O
– + B.O.
Total w.of Bond (III) O S O sp3 (IV) O=Cl=O sp3
O–O=O =
Total  Bond O O
3
= = 1.5
2
O2 O22– O3 (V) H N H sp3
H
B.O. (2) (1) (1.5)
398. [C]
1
 B.O. × B.l. F
B sp2
 O22– > O3> O2 (B.l.) F F
 H2O2 > O3 > O2 (Bond length) P
390. [A] F F sp3
F
391. [B]
F
As bond length  1/bond order
Bond length is inversely proportional to  BF3 > PF3>ClF3 C F sp3d
bond order. F
Bond order in NO+ = 3 399. [A]
Bond order in NO = 2.5 Order of B.P.
H2O>SbH3>NH3>AsH3>PH3
Hence, bond length in NO > NO+
V > IV > I > III > II
392. [D] (Order of Boiling points)
As Bond strength × Bond order 400. [AC]
O2, Total e— = 16  B.O. = 2 1
KO2 K2 O + O
O2— Total e—=17  B.O. = 1.5 2 2
O22—, Total e—= 18  B.O. = 1 KO2 + H2O 0°C KOH + O2
401. [A] 405. [A]

O(g) + 2e–  O2– (g), H = 603 kJ mol–1 (i)
F F O(g) + e–  O– (g), H = –141 kJ mol–1
(I) Xe sp3d2, eq. planer (ii)
F F
Equation (i) and (ii) gives :
F O– + e–  O2– (g), H = 603 – (–141)
F = 744 kJ mol–1
(II) S F sp3d sec saw 406. [B]
F 407. [A]
Radii of anions carrying same charge de-
WFL
crease from left to right in a period and
(III) sp3, Tetrahedral
[NiCl4]
2–
increase down the group.
2– 408. [B]
[PdCl4]
(IV) sp2, eq. planer A Ca(OH)2
(2nd T.S. element)
 for 2nd T.S. element, all ligends are SFL. Lime water
402. [C] Ca(OH) 2 + CO2 CaCO3 + H2O

Lime White ppt
Ionic Bond water (C)
C CaCO3
Covalent Ca(OH) 2 + Na 2CO3 CaCO3 + NaOH
Bond H c
H O
B
O H – 409. [D]
H 2+
H O O
Cu O S As HF is not stronger acid than HCl be-
H H H O – cause fluorine is more electronegative than
O O
O chlorine therefore hydrogen does not do-
H H H-Bond nate easily in than in HCl.
Coordinote
Bond 410. [D]
 Electrovalent, covalent, Coordinate and H- 411. [B]
Bond, all are present in CuSO4 SH2O As bond dissociation energy decreases in
403. [C] the order :
Cl2 > Br2 > F2 > I2
404. [D]
Cl 412. [D]
413. [B]
Cl
As the correct order of ionization energy is
(A) u net=0 Li < B < Be < C
Cl
414. [B]
Cl Both B and D have exactly half - filled
Cl configuration, but B has smaller size than
Cl Cl D, hence it has higher I.E.
415. [C]
(B) u net= 416. [C]
Cl Cl
Nitrogen, being smallest in size, can given
Cl
up its lone pair of electrons most easily.
Cl 417. [A]
1
(C) Lattice energy   —
r r
Cl Cl 418. [D]
 Moment at 120° will cancel each other
IE1 of Mg is higher than that of Na be-
 net = 0
cause of increased nuclear charge and also
Cl
that of Al because in Mg a 3 s-electron
Cl Cl has to be removed while in Al it is the 3p-
 electron. The IE1 of Si is, however, higher
(D)
Cl Cl than those of Mg and Al because of it
increased nuclear charge. Hence, the or-
= x net  0 der is
Na < Mg > Al < Si

428. [B]
419. [A]
Si and P are in the 3rd period while C and 429. [A]
N are in the 2nd period. Elements in 2nd
period have higher electronegativities than 430. [A]
those in the 3rd period. Since N has msaller As ionization energy decreases with the
size and hgiher nuclear charge than C, its increases in number of orbits or down the
electronegativity is higher than that of Si. group.
Thus, the order is Si, P, C, N.
431. [A]
420. [C] KMnO4 acts as self indicator.
Ca + H2O  Ca(OH)2 + H2O
432. [D]
CaH2 + H2O  Ca(OH)2 + H2
hydroith Since fluorine atom has a smaller size than
iodine, it has greater electron attracting
421. [D] power and so it is a better oxidizing agent.
Like dissolues like as acetone
433. [B]
has high covalent character dissoluves
relatively covalent compound. 434. [D]
422. [AB] Cu2+  blue
Weak metallic bond as due to poor shield- CruO42–  yellow
ing of d & f orbital its ionisation energy 435. [A]
became high & kernel formation becomes
difficult. 436. [A]
Cl + e–  Cl– + 3.7 eV
423. [D]
It is because of the electronic repulsion. 35.5 3.7×23.06 kcal
As energy released for conversion of 4 g
424. [C] gaseous chlorine into Cl– ions.
As in (III) the correct order of increasing
the first ionization enthalpy is B < C < O < 3.7  23.06
=  4 = 9.6 kcal
N. 35.5
425. [A] 437. [D]
As acidic nature increases left to right in a E1 : E2n = 0.475 : 1
period with increases in electronegativity.
Using the proportinally constant k,
426. [B] E1k+E2k = 2226 kJ mol.
Electron affinity = While, E1k/ E2k = 0.475/1.
Energy released x N0 On solving.
Number of atom ionized E2k = 2226×1/1.475 = 1509 kJ/mol.
4.8  10 13  6.023  1023 438. [D]

= 6
10 Half-filled 2p3 subshell of O+ is more stable
than 2p4 subshell of F+ So IE2 of O will be
= 28.9104 × 104 J = 289 kJ.
greater than that of F+.
427. [C] 439. [D]

Chlorine being the group 17 element has Mg+2 has electronic configuration 1s 2
maximum electronegativity. ‘N’ has zero 2s22p6; no unpaired electrons
electron affinity because extra stability is Ti3+ has electronic configuration (Ar) 3d1
22
associated with exactly half - filled orbit- ; one unpaired electron.
als. Sulphur has more electron affinity than V3+ has electronic configuration (Ar) 3d2 ;
‘O’ because the effect of small size of O two unpaired electrons.
atom is more than by the repulsion of elec-
Fe2+ has electronic configuration (Ar) 3d6
tron already present in 2p-orbitals of O
; four unpaired electrons .
atom.
440. [C] (D) K2SO4.H2(SO4)3. 24H2O
n(n  2) = 5.93  
 Unpaired unpaired e– = 0
n=5
(A) Cr  [Ar]4s13d5 e =0
–
 Cr2+ [Ar] 4s03d4  Co(NO3)2 would be compond.

 no. of unpaired electron = 4
444. [B]
(B) V  [Ar] 4s2, 3d3
for Cr3+
V3+  [Ar] 3d1
 H2O acts as SFL.
 unpaired electron = 1
(C) Mn  [Ar] 4s2, 3d5  [Cr(H2O)6]3+ has
Mn2+  [Ar] 4s0, 3d5 highest SFL
 unpaired electron = 5 445. [B]
(D) Fe  4s2, 3d6
+2 +4
Fe2+  [Ar] 4s0, 3d6
MnSO4 MnO2
unpaired electron = 4
There is transfer of two electrons
441. [C]
K2[Cu(CN)4]  Cu2+ Molecular mass
Eq.mass=
Cu  4s1 3d10 Number of electrons transferred
 Cu2+  4s0 3d9
Molecular mass
=
2
_ _ _ _ _
_ _ _ _ _ 446. [D]
 hyb  dsp2 Formul a of the comp l e x sal t i s
mganetic moment 1  3 {unpai red [Pt(NH3)4Cl]Cl3
[Pt(NH3)4Cl]Cl3 [Pt(NH3)4Cl]+ + 3Cl–
excited in 4}
= 1.73 BM Total ion = 4
Cu[(CN)4]2– is a square planar complex. 447. [B]
Cu in this complex is n + 2 (d9) oxidatin
Ag+ has d10 configuration with no unpaired
state. There is only one unpaired electron
electron.
(n = 1).
448. [B]
442. [D]
K3[Fe(CN)5CO] Fe2+ has d6 configuration and is expected
to be most paramagnetic with four un-
Potassium carbonylpentacyanoferrate (II)
paired electrons.
As there are two ligands, carbonyl and cy-
ano hence these must be arranged alpha- 449. [B]
betically and iron has oxidation state + 2 . (MA5B) will not show geometrical isomerism.
443. [C]
450. [B]
The compound containing unpaired elec-
tron in metal cation would be coloured The coordination entity has four chloride
ions,
(A) Zn(NO3)2
 Zn2+ 451. [B]
 4s 3d0 10 [NiCl4]2–
 unpaired electron = 0  Ni2+ 4s0, 3d8
(B) LiNO3 _ _ _ _ _
 Li +
3d 4s 4p
 1s2  Hyb sp , tetrahedral
3
 unpaired electron = 0 [Ni(CN)4]2– Ni2+ 4s0, 3d8

(C) Co(NO3)2 CN  SFL
 Co2+ _ _ _ _
 4s0 3d7 3d 4s 4p
 unpaired electron = 3

 Hyb dsp2 sq. planer

 n(n  2) = 4.9  n = 4
Primary valency = 0.5 of transition metal
Secondary valency = C.N. of T.M.  unpaired electron
(A) [Fe(CN)6]3–  Fe3+ 4s0 3d5
452. [A] unpaired = 1
(A) [Co(NH3)6]Cl3  [Co(NH3)6]3+ + 3Cl– (B) [Fe(H2O)6]3+  Fe3+ 3d5
Total ion = 4 unpaired electron = 5
[Pt(NH3)5]Cl3  Total ion = 4 (C) [Fe(CN)6]4–  Fe3+ 3d6
(B) [Co(NH3)6]Cl3 unpaired electron = 0
Total ion = 4 (D) [Fe(H2O)6]2+  Fe3+ 3d 4s 4p
[Pt(NH3)3Cl3]Cl unpaired electron = 4
Total ion = 2 spin = 4.9 BM
(C) [Co(NH3)5Cl]Cl2 460. [A]
Total ion = 3 M.M. = 1.73 BM
[Pt(NH3)6]Cl4
 n(n  2) = 1.73
total ion = 5
(D) [Co(NH3)4Cl2]Cl n=1
Total ion = 2 (A) [Mn(CN)6]4–
[Pt(NH3)4Cl2]Cl2  M2+ 3d5
Total ion = 3 unpaired electron = 1
Same no. of ion = same electrical con- (B) [Co(NH3)6]3–
ductance.  Co2+ 3d6
unpaired electron = 0
453. [B]
(C) [MnF6]3–
C2O42– is ligand
 Mn3+
and a chelating ligand and hence most
stable complex compound would be formed
in can C2O42–. 
454. [C] 3d 4s 4p
More than value of K, more forward the unpaired electron = 4
reaction would be indicating the strong
nature of ligand 461. [C]
Noble metal blue Au, Pt, Ir are not effect
455. [B] by conc HNO3 or conc H2SO4 they are
[Cr(NH3)4Cl2]+ has POS will be optically in- only affected by aqua regia. Au is used in
active photography (present in photograph) Ag
+ AuCl3  AgCl + Au
456. [B]
[Cr(H2O)6]3+ 462. [B]
Cr  4s1 3d5 463. [A]
Cr3+  3d3 4s0 d5
 No. of unpaired electron = 3 11111
457. [A] with SFL, unpaired e = 1
[Pt(NH3)5Br]Br3  [Pt(NH3)5Br]3+ + 3Br– with WFW, unpaired e = 5
Total no. of ion produced = 4 (B) 11
SFL or WFL, no unpaired e = 2
458. [C]
(C) d6
Value of stability constant  strength of
the ligand 1111
 CN– would be strongest ligand 3d 4S 4p
with SFL unpaired e= 0
459. [D]
(D) correct as in care of dA, to d7, no. of
spin = 4.9 ungain evhor depar upon the nature of hige
a*
464. [D]
Cr(CN)6 3  RAN = 24+12–3

n+ n+
M M
= 33
3
  
Cu(CN)4  EAN=29+4×2  Co douater L.P. from its *2s and alro
  conoccept electron from filled orbital of
= 36 T.M. into is ABmo
(III) exist as 15 geomerical isomer
465. [B]
[Fe(CN)6]3–
466. [B] EAN = 26+6×2–3
a = 35
b c d e
 does not follow EAN Rule.
M M M M M
b,c,d,e,f d,e,f e,f f
472. [AB]
c,d,e,f
(5) (4) (3) (2) (1) F– has low polarisbility & hence CuF is ion
but Br– & Cl– ion has high polarisibity &
Total isomar = 15 CuCl2 & CuBr2 are ionic in nature.
(G.I.)
473. [C]
 all will be oplically active due to bseuce of
PO 5° Hg2+ (Xe) 4f10 5d10
Total dsomer = 30 Most polarsing cation due to high zeff as
shielding of d & f-orbital is very poor
467. [B]
474. [ABCD]
Consider the following spatial arrangements
of the octahedral complex ion [Co(NH3)4Br]+. Cu(SO4) + NH3 [Cu(NH3)4]SO4
(1) (2) (3) (4) Blue
dsp2
lunpired
468. [D] electron
n(n  2) = 6.92 475. [D]

[Fe(CN)6]4– 0.5. of Fe = +2
 n=6 Þ no. pf upaired = 6
[Cr(NH3(NO2)3]  O.S. of Cr=+3
 which is possibe only incare of (D)
476. [B]
469. [D]
[Cu(CN)4]3–
d° and d10 colourless cations
 Cu+ 3d10
(I) Fe3+ 3d5
 Fe3+, Þ d°, colourless  4s 4p
3d
(II) Sc3+,  d°, colourless Hyb  sp 3
(III) Cu2+  3d9 coloured no. of unpair e— =0

(IV) Cr3+  3d3 coloured O.S. of Cu = +1
 (I), (III) and (IV) are coloured ions. 477. [A]
470. [B] [Cr(NH3)5CO3CO]ClO4
471. [D] C.N. = 6
S O.S. of fr = +3
O
J Cr3+  3d3
(I) O
unpaired e=3
O
 thiosulphato-O are teriosuatio-S are link- 478. [C]
age isomer
(II) CO acts as synergic ligand 479. [D]
(I) NO2 and Q No are ambideutali ligaue
and have lintage isomer

(II) it occurs by partial or complete Around the atomic number 25 the 4s or-
e xc uaug e of l i q aud be tw ee n tw o bital has higher energy than 3d orbital.
coordiuation spuare,
(III) diff ion produced by dissoling the iso-
mers in water
4s
Energy
480. [C]
KMnO4 + HCl  KCl+MnCl2+H2O + Cl2 3d
25 50 75
(green yellow
gan) 494. [C]
481. [B] 495. [B]
482. [A] 496. [C]
483. [B] 497. [B]

Due to itching of glass it can not be stored
484. [D]
in glass vessel
485. [C] 4HF + SiO2  SiF4 + 2H2O
498. [A]
486. [B]
In Alkali metal bicrbonates intermolecular
O O O
hydrogen bonding involed and therefore
P P more energy is required to dissociate metal
HO OH
bicrbonate lattice by H2O.
O O
P 499. [D]
O OH
PF2Cl3  sp3d hybridized  T.B.P. ge-
ometry.
487. C sbp + O lb=5
N2O5(s) exist as [NO2]+[NO3]— F axial bond
Cl
488. B
3O2  2O3 r H is positive and rS is nega- P Cl
tive therefor the formations of ozone from
O2(g) is a non spontaneous process. equatorial bond
By the application of UV or electrical dis- Cl
F
charge the formation of atomic oxygen
F–II period P–Cl B.L. > P–F. B.L.
occur from gaseous oxygen Which initiate
the formation of ozone. Cl – IIIrd period
hv
O2(g)  2O (g) 500. [A]
O2(g) + O(g)  O3(g) Back bonding
489. [A] H3C
H3C Si OH More aci di c
490. [C]
H3C
If NH4OH is used Mn2+ is precipitated as
MnO2 due to availability of vacant d-orbital
491. [C] H3C

(A) is correct but (R) is incorrect H3C C OH No back bondding
Fe3++Fe(CN)64–  prussian blue H3C
Fe2++Fe(CN)63–  Turnsbull’s blue Does not act as Lewis acid due to non-
availability of vacant orbital.
492. [A]
493. [B]

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S.No. Topic Page No.

Answer Key & Solutions

IIT - JEE SYLLABUS

(C) 2k1 [NO2]2 – k2 [N2O4] (D) (2k1–k2) [NO2]

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24. Which of the following in not correct for dieal solution

29. Which of the following sets is possible for quantum numbers

34. Be's 4th electron will have four quantum numbers

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37. The data for the rection A+B  C is

50. The mass defect of the nuclear reaction: 5B84Be8+e+ is

57. The total no. of neutrons present is 54 ml H2O () are –

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62. Which of the following is not a redox reaction?

63. The value of n in

68. Gas CO CH4 HCl SO2

69. In the heterogeneous equilibrium:

70. What is Gº for the following reaction?

The preparation of ammonia by Haber's process an exothermic reaction. If the preparation

For which of these processes is the value of S negative ?

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76. The heat of formation (Hºf) of H2O() is equal to:

77. Which salt can furnish H+ in its aqueous solution:

81. Which of the following sets of quantum numbers is not possible ?

84. The four quantum numbers of valence electron of potassium are

85. The energy of an electron in nth orbit of hydrogen atom is

13.6 13.6 13.6 13.6

89. For a 'p'-electron the orbital angular momentum is

(A) 6 h (B) 2 h (C) h (D) 2 h

91. The number of atoms in 20 g of SO3 is approximately -

92. The number of moles of SO2 in 6.4 g is

93. The number of ions present in 2.0 L of a solution of 0.8 M K4[(FeCN)6] is

98. No. of moles in 11.2 L of CO2 at NTP is -

99. The oxidation number of I in HIO4 is -

101. In the following equation :

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102. In the equation :

103. Oxidation number of sulphur in H2SO5 is -

104. Which of the following process represents disproportionation ?

105. In alkaline medium, KMnO4, reacts as follows

106. A meallic oxide contains 60% of the metal is

110. Equivalent mass of FeC2O4 in the reaction

Which of the following is /are correct about the plot ?

Which of the following sequence of temperatures is correct ?

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121. The rate constant of a reaction depends on

d[BrO3 ] d[Br2 ] d[BrO3 ] d[Br2 ]

129. The kinetic energy of 2.8 g of nitrogen gas at 127°C in nearly -

131. Ideal gas obeying kinetic theory of gases can be liquefied if -

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137. A quanity of PCl5 was heated in a 2 litre vessel at 525 K. It dissociates as

138. For the equilibrium

(A) 10 (B) 40 (C) 30 (D) 40

144. A 0.01 M ammonia solution is 5% ionized, the concentration of OH— ion is

145. Select the incorrect statement for CsCl crystal.

(C) The structure changes to NaCl at 760 K