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    التكنولوجيا الحيوية التطبيقية - الاسبوع السادس

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    hsjsg jdhek
    The document discusses catalytic reactions kinetics and provides information about catalysts including their classification as homogeneous or heterogeneous. It also discusses catalyst poisons and provides an example reaction pathway to explain how catalysts work.

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    التكنولوجيا الحيوية التطبيقية - الاسبوع السادس

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    hsjsg jdhek
    8 views21 pages
    The document discusses catalytic reactions kinetics and provides information about catalysts including their classification as homogeneous or heterogeneous. It also discusses catalyst poisons and provides an example reaction pathway to explain how catalysts work.

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    التكنولوجيا الحيوية التطبيقية_الاسبوع السادس

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    The document discusses catalytic reactions kinetics and provides information about catalysts including their classification as homogeneous or heterogeneous. It also discusses catalyst poisons and provides an example reaction pathway to explain how catalysts work.

    Copyright:

    © All Rights Reserved
    Download as PDF, TXT or read online from Scribd
    Download as pdf or txt
    8 views21 pages

    التكنولوجيا الحيوية التطبيقية - الاسبوع السادس

    Uploaded by

    hsjsg jdhek
    The document discusses catalytic reactions kinetics and provides information about catalysts including their classification as homogeneous or heterogeneous. It also discusses catalyst poisons and provides an example reaction pathway to explain how catalysts work.

    Copyright:

    © All Rights Reserved
    Download as PDF, TXT or read online from Scribd
    Download as pdf or txt
    You are on page 1of 21

    Lec 6

    Catalytic reactions kinetics


    “Fall 2023-2024”
    Instructor :Dr / Safaa Fouda

    Email: safaarushdy120@gmail.com
    safaa.fouda@bie.edu.eg
    Reversible or opposing reaction
    Catalysis
    ⧫A catalyst:-is a substance which alters the rate of
    reaction, but it cannot initiate a reaction.
    ⧫A catalyst is unchanged at the end of reaction
    ⧫A very small amount of catalyst will bring about
    the reaction of indefinite amounts of the reactants
    ⧫Finally, a catalyst cannot alter the equilibrium
    position of a reversible reaction, since; it cannot
    alter the energy content of the system.
    Classification of catalysts
    o Homogenous catalysts
    Is one which is present in the same phase as the reactants.
    For example, water vapor catalysis many reactions,
    hydrogen and chlorine will not react if they are first carefully
    dried.
    o Heterogeneous catalysts
    Is one which is present in a different phase from the
    reactants
    For example:-
    Finely divided nickel (rainy nickel) will catalyzed
    the hydrogenation of multiple bonds, especially
    c=c, in organic chemistry. This process is used for
    the hardening of vegetable oils to make margarine.
    Finely divided iron mixed with alumina to prevent
    the ion particles from sintering together, is used as
    the catalyst in the Haber process:
    Catalyst Poisons
    The adsorption theory throws some light on the
    phenomenon known as the (poisoning) of catalysts in
    the contact process.
    Arsenical impurities have carefully removed from the
    sulfur dioxide, as they cause very rapid loss of activity
    in the platinum catalyst.
    Here, C represents the catalyst
    S the substrate
    X is the intermediate complex
    Y some substance which is formed in addition to it
    W is a molecule which reacts with the complex
    to give the product or products P with elimination of a
    molecule Z.

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