Thermal and Statistical Physics

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Transfer of heat

Medium
Conduction required

Conduction occurs at the molecular level—from one body to another—when heat energy is
absorbed by a surface and causes the molecules of that surface to vibrate about their mean
position . In the process, they transfer the energy into their neighbors a process which
continues as long as heat is still being added.

Medium
Convection required

When a liquid is heated at the bottom, fluid particles acquire energy from the source and density of
fluid there decreases. The fluid particle moves upward and hence heat energy is transferred.

Radiation No Medium

This method uses electromagnetic waves which transfer heat from one place to the other.
Thermal Conductivity -- The ability of a substance to conduct heat energy is measured by thermal
conductivity

Metals

Wood, glass

Insulators :
mica
The process of heat conduction depends on four basic factors: the temperature
gradient, the cross section of the materials involved, their path length, and the
properties of those materials.

EXPRESSION OR THERMAL CONDUCTIVITY


Consider a slab of material of length x meter and area of cross section A as shown in the figure.
One end of the slab is maintained at a higher temperature θ1 and the other end at a lower temperature is θ1. Heat
flows from the hot end to the cold end. It is found that the amount of heat(Q) conducted from one end to another
end is
Directly proportional to the area of cross-section(A)
Directly proportional to the temperature difference between the end θ1- θ2
Directly proportional to the time of conduction(t)
Directly proportional to the length of (x).
Where K is the proportionality constant. It is known as coefficient of thermal conductivity or simple or
thermal conductivity. Its value depends upon the nature of the material.

Thermal conductivity is defined as the amount of heat conducted per second normally across unit area
of cross-section of the material per unit temperature difference per unit length.
The quantity (θ1- θ2) / x denote the rate of fall of temperature with respect to distance. It is know as
temperature gradient.

The negative sign indicates the fall of temperature with distance.


Thermal resistance

Q= K A (θ1-θ2)/x (per sec)


Q = (θ1-θ2)/(x/KA)
Q = Temperature difference/Resistance
Thermal resistance R =x/KA
Q =(θ1-θ2)/R
Lees disc experiment : thermal conductivity of bad conductors
Radiation
Nature of thermal radiation and properties
● It can travel in vacuum
● Like light it travels in straight line
● The intensity is inversely proportional to the square of the distance from the
source.
● It obeys laws of reflection refraction and total internal reflection
● It exhibits interference, diffraction and polarisation.
● It manifest as heat unlike light
● It is a part of em radiation spectrum
Energy flux : Thermal energy crossings surface in unit time . It is measured in watts

Intensity: Thermal energy passing per unit area in unit time . It is measured in watts/m2

Radiant emittance: Thermal energy emitted per unit area in unit time of
a radiating body in all direction within limits of a solid angle 2π.

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