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SAFETY DATA SHEET

Ariel Laundry Cleanser

SECTION 1: Identification of the substance/mixture and of the company/undertaking

1.1. Product identifier

Product name Ariel Laundry Cleanser

Product number BLE481

UFI UFI: C9A1-A0PP-900U-KUS7

1.2. Relevant identified uses of the substance or mixture and uses advised against
Identified uses Laundry Cleanser

Uses advised against Use only for intended applications.

1.3. Details of the supplier of the safety data sheet

Supplier Star Brands Limited
Unit E
Millshaw Business Living
Global Avenue
Leeds
LS11 8PR
England
+44 (0) 113 2666 300
+44 (0) 113 2666 690
sds@starbrandsltd.co.uk

Contact person sds@starbrandsltd.co.uk

1.4. Emergency telephone number

Emergency telephone +44 (0) 113 2666 300 (09.00-17.00 Mon-Fri)

National emergency telephone 111 (24hours UK)

number

SECTION 2: Hazards identification

2.1. Classification of the substance or mixture

Classification (EC 1272/2008)
Physical hazards Not Classified

Health hazards Skin Irrit. 2 - H315 Eye Irrit. 2 - H319

Environmental hazards Aquatic Chronic 3 - H412

2.2. Label elements

Hazard pictograms

Signal word Warning

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Hazard statements H315 Causes skin irritation.

H319 Causes serious eye irritation.
H412 Harmful to aquatic life with long lasting effects.

Precautionary statements P101 If medical advice is needed, have product container or label at hand.
P102 Keep out of reach of children.
P103 Read label before use.
P264 Wash contaminated skin thoroughly after handling.
P273 Avoid release to the environment.
P280 Wear protective gloves and eye protection
P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove
contact lenses, if present and easy to do. Continue rinsing.
P332+P313 If skin irritation occurs: Get medical advice/ attention.
P337+P313 If eye irritation persists: Get medical advice/ attention.
P501 Dispose of contents/ container in accordance with national regulations.

2.3. Other hazards

This product does not contain any substances classified as PBT or vPvB.

SECTION 3: Composition/information on ingredients

3.2. Mixtures

Tetrasodium Glutamate Diacetate 5-10%

CAS number: 51981-21-6 EC number: 257-573-7

Classification
Not Classified

Citric Acid Monohydrate 1-5%

CAS number: 5949-29-1 EC number: 201-069-1

Classification
Eye Irrit. 2 - H319

Didecyldimethylammonium chloride 1-5%

CAS number: 7173-51-5 EC number: 230-525-2
M factor (Acute) = 10

Classification
Acute Tox. 4 - H302
Skin Corr. 1B - H314
Eye Dam. 1 - H318
Aquatic Acute 1 - H400
Aquatic Chronic 2 - H411

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Laurylamine Dipropylenediamine 1-5%

CAS number: 2372-82-9 EC number: 219-145-8
M factor (Acute) = 10 M factor (Chronic) = 1

Classification
Acute Tox. 3 - H301
Skin Corr. 1A - H314
Eye Dam. 1 - H318
STOT RE 2 - H373
Aquatic Acute 1 - H400
Aquatic Chronic 1 - H410

C12-14 Pareth- 7 <1%

CAS number: 68439-50-9 EC number: 500-213-3
M factor (Acute) = 1

Classification
Eye Dam. 1 - H318
Aquatic Acute 1 - H400
Aquatic Chronic 3 - H412

The Full Text for all R-Phrases and Hazard Statements are Displayed in Section 16.

SECTION 4: First aid measures

4.1. Description of first aid measures

Inhalation Move affected person to fresh air at once. Get medical attention if any discomfort continues.

Ingestion Keep affected person warm and at rest. Do not induce vomiting unless under the direction of
medical personnel. Rinse mouth thoroughly with water. Give plenty of water to drink. Get
medical attention if any discomfort continues. If in doubt, get medical attention promptly.

Skin contact Remove contamination with soap and water or recognised skin cleansing agent. Get medical
attention if symptoms are severe or persist.

Eye contact Remove any contact lenses and open eyelids wide apart. Rinse cautiously with water for
several minutes. Get medical attention immediately. Continue to rinse.

4.2. Most important symptoms and effects, both acute and delayed
General information The product is considered to be a low hazard under normal conditions of use. See Section 11
for additional information on health hazards.

Inhalation The product is considered to be a low hazard under normal conditions of use.

Ingestion The product is considered to be a low hazard under normal conditions of use. May be harmful
if swallowed.

Skin contact Causes skin irritation. Skin irritation should not occur when used as recommended.

Eye contact Causes serious eye irritation.

4.3. Indication of any immediate medical attention and special treatment needed
Notes for the doctor Treat symptomatically.

Specific treatments No recommendation given, but first aid may still be required in case of accidental exposure,
inhalation or ingestion of this chemical. If in doubt GET MEDICAL ATTENTION PROMPTLY!

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SECTION 5: Firefighting measures

5.1. Extinguishing media

Suitable extinguishing media The product is not flammable. Use fire-extinguishing media suitable for the surrounding fire.
Extinguish with the following media: Foam, carbon dioxide or dry powder.

5.2. Special hazards arising from the substance or mixture

Specific hazards The product is non-combustible. The product is not flammable.

Hazardous combustion Oxides of carbon. Thermal decomposition or combustion may liberate carbon oxides and
products other toxic gases or vapours.

5.3. Advice for firefighters

Special protective equipment Wear positive-pressure self-contained breathing apparatus (SCBA) and appropriate protective
for firefighters clothing.

SECTION 6: Accidental release measures

6.1. Personal precautions, protective equipment and emergency procedures

Personal precautions Avoid inhalation of vapours. Avoid contact with eyes and prolonged skin contact. Use
recommended protective equipment, see section 8.
Ensure good ventilation.

For non-emergency personnel Remove persons for safety reasons

For emergency responders Wear breathing apparatus if exposed to vapours/spray/gases

6.2. Environmental precautions

Environmental precautions Harmful to aquatic life with long lasting effects. Avoid discharge into drains or watercourses or
onto the ground.

6.3. Methods and material for containment and cleaning up

Methods for cleaning up Absorb spillage with non-combustible, absorbent material. Collect and place in suitable waste
disposal containers and seal securely. Dispose of contents/container in accordance with local
regulations.

6.4. Reference to other sections

Reference to other sections For personal protection, see Section 8. For waste disposal, see Section 13.

SECTION 7: Handling and storage

7.1. Precautions for safe handling

Usage precautions Avoid contact with eyes and prolonged skin contact. Avoid inhalation of vapours and
spray/mists. Provide adequate ventilation.

Advice on general When using do not eat, drink or smoke. Wash contaminated skin thoroughly after handling.
occupational hygiene

7.2. Conditions for safe storage, including any incompatibilities

Storage precautions This product should be kept inaccessible to small children and well separated from products
intended to be consumed. Store cool and only in original packaging.

Storage class Unspecified storage.

7.3. Specific end use(s)

Specific end use(s) The identified uses for this product are detailed in Section 1.2.

SECTION 8: Exposure controls/Personal protection

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8.1. Control parameters

Citric Acid Monohydrate (CAS: 5949-29-1)

PNEC PNEC Fresh water 0.44 mg/l (/)

PNEC Marine water 0.044 mg/l (/)
PNEC Fresh water sediment 3.46 mg/kg (/)
PNEC Marine sediment 34.6 mg/kg (/)
PNEC Soil 33.1 mg/kg (/)
PNEC STP >1000 mg/l (/)

8.2. Exposure controls

Protective equipment

Appropriate engineering Avoid inhalation of vapours and spray/mists. Provide adequate ventilation.
controls

Eye/face protection Wear eye protection.

Hand protection Wear protective gloves made of the following material: Nitrile Gloves Nitrile rubber. Polyvinyl
chloride (PVC). It should have a minimum thickness of 0.55mm Gloves should be discarded
and replaced if there is any indication of degradation or chemical breakthrough.

Other skin and body Wear appropriate clothing to prevent any possibility of skin contact.
protection

Hygiene measures Wash hands thoroughly after handling. Do not smoke in work area.

Respiratory protection No specific requirements are anticipated under normal conditions of use.

Environmental exposure Ensure all engineering measures mentioned in section 7 of this SDS are in place
controls

SECTION 9: Physical and chemical properties

9.1. Information on basic physical and chemical properties

Appearance Clear liquid.

Colour Blue.

Odour Floral.

Odour threshold No specific test data are available.

pH pH (concentrated solution): 8.00-9.00

Melting point Not applicable.

Initial boiling point and range Not available.

Flash point This product does not sustain combustion.

Evaporation rate No information available.

Evaporation factor Not available.

Flammability (solid, gas) Not applicable.

Upper/lower flammability or Not applicable.

explosive limits

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Other flammability Not applicable.

Vapour pressure Not known.

Vapour density Not known.

Relative density 1.050 - 10605

Bulk density Not determined.

Solubility(ies) Soluble in water.

Partition coefficient Data lacking.

Auto-ignition temperature Not known.

Decomposition Temperature Not determined.

Viscosity Not applicable.

Explosive properties Not applicable.

Explosive under the influence Not considered to be explosive.

of a flame

Oxidising properties Does not meet the criteria for classification as oxidising.

Comments Information given is applicable to the product as supplied.

9.2. Other information

Refractive index No information required.

Particle size No specific test data are available.

Molecular weight No information required.

Volatility Not available.

Saturation concentration Not applicable.

Critical temperature Not applicable.

Volatile organic compound No information required.

SECTION 10: Stability and reactivity

10.1. Reactivity
Reactivity There are no known reactivity hazards associated with this product.

10.2. Chemical stability

Stability No particular stability concerns.

10.3. Possibility of hazardous reactions

Possibility of hazardous No specific material or group of materials is likely to react with the product to produce a
reactions hazardous situation.

10.4. Conditions to avoid

Conditions to avoid There are no known conditions that are likely to result in a hazardous situation.

10.5. Incompatible materials

Materials to avoid No specific material or group of materials is likely to react with the product to produce a
hazardous situation.

10.6. Hazardous decomposition products

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Hazardous decomposition No known hazardous decomposition products.

products

SECTION 11: Toxicological information

11.1. Information on toxicological effects

Toxicological effects We have not carried out any animal testing for this product. Any ATE figures quoted below are
from Toxicity Classifications that
have been carried out using ATE (Acute Toxicity Estimate) Calculation Method using LD50 or
ATE figures provided by the Raw
Material Manufacturer.

Acute toxicity - oral

Notes (oral LD₅₀) Based on available data the classification criteria are not met.

ATE oral (mg/kg) 4,528.16

Acute toxicity - dermal

Notes (dermal LD₅₀) Based on available data the classification criteria are not met.

Acute toxicity - inhalation

Notes (inhalation LC₅₀) Based on available data the classification criteria are not met.

Skin corrosion/irritation
Skin corrosion/irritation Causes skin irritation.

Serious eye damage/irritation

Serious eye damage/irritation Causes serious eye irritation.

Respiratory sensitisation
Respiratory sensitisation Based on available data the classification criteria are not met.

Skin sensitisation
Skin sensitisation Based on available data the classification criteria are not met.

Germ cell mutagenicity

Genotoxicity - in vitro Based on available data the classification criteria are not met.

Carcinogenicity
Carcinogenicity Based on available data the classification criteria are not met.

Reproductive toxicity
Reproductive toxicity - fertility Based on available data the classification criteria are not met.

Specific target organ toxicity - single exposure

STOT - single exposure Based on available data the classification criteria are not met.

Specific target organ toxicity - repeated exposure

STOT - repeated exposure Based on available data the classification criteria are not met.

Aspiration hazard
Aspiration hazard Based on the available information, classification criteria are not met.

Toxicological information on ingredients.

Citric Acid Monohydrate

Acute toxicity - oral

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Acute toxicity oral (LD₅₀ 5,040.0

mg/kg)

Species Mouse

Notes (oral LD₅₀) LD₅₀ 5400 mg/kg, Oral, Mouse

ATE oral (mg/kg) 5,040.0

Acute toxicity - dermal

Acute toxicity dermal (LD₅₀ 2,001.0

mg/kg)

Species Rat

ATE dermal (mg/kg) 2,001.0

Didecyldimethylammonium chloride

Acute toxicity - oral

Acute toxicity oral (LD₅₀ 238.0

mg/kg)

Species Rat

ATE oral (mg/kg) 500.0

Acute toxicity - dermal

Acute toxicity dermal (LD₅₀ 3,342.0

mg/kg)

Species Rabbit

ATE dermal (mg/kg) 3,342.0

Laurylamine Dipropylenediamine

Acute toxicity - oral

ATE oral (mg/kg) 100.0

C12-14 Pareth- 7

Acute toxicity - oral

Notes (oral LD₅₀) LD₅₀ 2,000 (OECD 401) mg/kg, Oral, Rat

Acute toxicity - dermal

Notes (dermal LD₅₀) LD₅₀ 2,000 (OECD 402) mg/kg, Dermal, Rabbit

Acute toxicity - inhalation

Notes (inhalation LC₅₀) LC50 1.6 ( OECD 403) mg/l, Inhalation, Rat

SECTION 12: Ecological information

12.1. Toxicity
Toxicity The product is classified as harmful to aquatic life with long lasting effects.

Ecological information on ingredients.

Citric Acid Monohydrate

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Acute aquatic toxicity

Acute toxicity - fish LC₅₀, 96 hours: 440-706 mg/l, Fish

Acute toxicity - aquatic LC₅₀, 1535 : mg/l, Daphnia magna

invertebrates

Acute toxicity - aquatic LC₅₀, 440 : mg/l, Algae

plants

Didecyldimethylammonium chloride

Acute aquatic toxicity

LE(C)₅₀ 0.01 < L(E)C50 ≤ 0.1

M factor (Acute) 10

Acute toxicity - fish LC₁₀₀, LC₅₀, 96 hours: 0.06 mg/l, Fish

Acute toxicity - aquatic EC₅₀, 48 hours: 0.03 mg/l, Daphnia magna

invertebrates

Acute toxicity - aquatic IC₈₀, 72 hours: <1 mg/l, Algae

plants

Laurylamine Dipropylenediamine

Acute aquatic toxicity

LE(C)₅₀ 0.01 < L(E)C50 ≤ 0.1

M factor (Acute) 10

Chronic aquatic toxicity

M factor (Chronic) 1

C12-14 Pareth- 7

Acute aquatic toxicity

LE(C)₅₀ 0.1 < L(E)C50 ≤ 1

M factor (Acute) 1

Acute toxicity - aquatic NOEC, : 0.77 mg/l, Daphnia magna

invertebrates

12.2. Persistence and degradability

Persistence and degradability The product is biodegradable.

12.3. Bioaccumulative potential

Bioaccumulative potential The product is not bioaccumulating.

Partition coefficient Data lacking.

12.4. Mobility in soil

Mobility The product is miscible with water and may spread in water systems.

12.5. Results of PBT and vPvB assessment

Results of PBT and vPvB This substance is not classified as PBT or vPvB according to current EU criteria.
assessment

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12.6. Other adverse effects

Other adverse effects Do not flush into surface water or sanitary sewer system.
Avoid subsoil penetration.

SECTION 13: Disposal considerations

13.1. Waste treatment methods

General information The generation of waste should be minimised or avoided wherever possible. Dispose of waste
product or used containers in accordance with local regulations

Disposal methods Dispose of waste to licensed waste disposal site in accordance with the requirements of the
local Waste Disposal Authority.

Waste class The waste code classification is to be carried out according to the European Waste Catalogue
(EWC).

SECTION 14: Transport information

General The product is not covered by international regulations on the transport of dangerous goods
(IMDG, IATA, ADR/RID).

Road transport notes Not regulated.

Rail transport notes Not regulated.

Sea transport notes Not classified.

Air transport notes Not classified.

14.1. UN number
Not applicable.

14.2. UN proper shipping name

Not applicable.

14.3. Transport hazard class(es)

Not regulated.

14.4. Packing group

Not applicable.

14.5. Environmental hazards

Environmentally hazardous substance/marine pollutant

No.

14.6. Special precautions for user

Ensure that persons transporting the product know what to do in the event of an accident or spillage. Always transport in
closed containers that are upright and secure.

14.7. Transport in bulk according to Annex II of MARPOL and the IBC Code
Transport in bulk according to Not relevant.
Annex II of MARPOL 73/78
and the IBC Code

SECTION 15: Regulatory information

15.1. Safety, health and environmental regulations/legislation specific for the substance or mixture

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EU legislation Regulation (EC) No 1907/2006 of the European Parliament and of the Council of 18
December 2006 concerning the Registration, Evaluation, Authorisation and Restriction of
Chemicals (REACH) (as amended).
Regulation (EC) No 648/2004 of the European Parliament and of the Council of 31 March
2004 on detergents (as amended).
Regulation (EC) No 1272/2008 of the European Parliament and of the Council of 16
December 2008 on classification, labelling and packaging of substances and mixtures (as
amended).

15.2. Chemical safety assessment

No chemical safety assessment has been carried out.

SECTION 16: Other information

Abbreviations and acronyms ATE: Acute Toxicity Estimate.

used in the safety data sheet ADR: European Agreement concerning the International Carriage of Dangerous Goods by
Road.
ADN: European Agreement concerning the International Carriage of Dangerous Goods by
Inland Waterways.
CAS: Chemical Abstracts Service.
DNEL: Derived No Effect Level.
GHS: Globally Harmonized System.
LC₅₀: Lethal Concentration to 50 % of a test population.
LD₅₀: Lethal Dose to 50% of a test population (Median Lethal Dose).
PNEC: Predicted No Effect Concentration.
REACH: Registration, Evaluation, Authorisation and Restriction of Chemicals Regulation
(EC) No 1907/2006.
SVHC: Substances of Very High Concern.
vPvB: Very Persistent and Very Bioaccumulative.
IARC: International Agency for Research on Cancer.
MARPOL 73/78: International Convention for the Prevention of Pollution From Ships, 1973 as
modified by the Protocol of 1978.
cATpE: Converted Acute Toxicity Point Estimate.
EC₅₀: 50% of maximal Effective Concentration.
LOAEC: Lowest Observed Adverse Effect Concentration.
LOAEL: Lowest Observed Adverse Effect Level.
LOEC: Lowest Observed Effect Concentration.
DMEL: Derived Minimal Effect Level.
RID: European Agreement concerning the International Carriage of Dangerous Goods by
Rail.
IATA: International Air Transport Association.
IMDG: International Maritime Dangerous Goods.

Classification abbreviations Acute Tox. = Acute toxicity

and acronyms Aquatic Acute = Hazardous to the aquatic environment (acute)
Aquatic Chronic = Hazardous to the aquatic environment (chronic)
Asp. Tox. = Aspiration hazard
Carc. = Carcinogenicity
STOT RE = Specific target organ toxicity-repeated exposure
STOT SE = Specific target organ toxicity-single exposure
Eye Dam. = Serious eye damage
Met. Corr. = Corrosive to metals
Skin Corr. = Skin corrosion
Skin Irrit. = Skin irritation
Skin Sens. = Skin sensitisation

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SDS number 5990

Hazard statements in full H301 Toxic if swallowed.

H302 Harmful if swallowed.
H314 Causes severe skin burns and eye damage.
H315 Causes skin irritation.
H318 Causes serious eye damage.
H319 Causes serious eye irritation.
H373 May cause damage to organs through prolonged or repeated exposure.
H400 Very toxic to aquatic life.
H410 Very toxic to aquatic life with long lasting effects.
H411 Toxic to aquatic life with long lasting effects.
H412 Harmful to aquatic life with long lasting effects.

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