Revision date: 11/12/2019 Revision: 12 Supersedes date: 09/10/2019

SAFETY DATA SHEET

AD STENCIL REMOVER CONC.

SECTION 1: Identification of the substance/mixture and of the company/undertaking

1.1. Product identifier

Product name AD STENCIL REMOVER CONC.

1.2. Relevant identified uses of the substance or mixture and uses advised against
Identified uses Industrial use: Screen printing

Uses advised against The product should not be used for any purpose, other than that described above.

1.3. Details of the supplier of the safety data sheet

Manufacturer MacDermid Autotype Ltd
Grove Road, Wantage,
OX12 7BZ
UNITED KINGDOM
Tel: +44 (0) 1235 773240
Fax: +44 (0) 1235 771196
Email: wantsds@macdermid.com

1.4. Emergency telephone number

National emergency telephone +44 1235 239670 (NCEC Europe)
number

SECTION 2: Hazards identification

2.1. Classification of the substance or mixture

Classification (EC 1272/2008)
Physical hazards Not Classified

Health hazards Skin Corr. 1A - H314 Eye Dam. 1 - H318 STOT RE 1 - H372

Environmental hazards Not Classified

2.2. Label elements

Hazard pictograms

Signal word Danger

Hazard statements H314 Causes severe skin burns and eye damage.
H372 Causes damage to organs through prolonged or repeated exposure.

Precautionary statements P260 Do not breathe vapour/ spray.

P280 Wear protective gloves/ protective clothing/ eye protection/ face protection.
P301+P330+P331 IF SWALLOWED: Rinse mouth. Do NOT induce vomiting.
P303+P361+P353 IF ON SKIN (or hair): Take off immediately all contaminated clothing.
Rinse skin with water or shower.
P304+P340 IF INHALED: Remove person to fresh air and keep comfortable for breathing.
P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove
contact lenses, if present and easy to do. Continue rinsing.

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Supplementary precautionary P264 Wash contaminated skin thoroughly after handling.

statements P270 Do not eat, drink or smoke when using this product.
P310 Immediately call a POISON CENTER/ doctor.
P314 Get medical advice/ attention if you feel unwell.
P321 Specific treatment (see medical advice on this label).
P363 Wash contaminated clothing before reuse.
P405 Store locked up.
P501 Dispose of contents/ container in accordance with national regulations.

2.3. Other hazards

This product does not contain any substances classified as PBT or vPvB. The product may affect the acidity (pH) of water
which may have hazardous effects on aquatic organisms.

SECTION 3: Composition/information on ingredients

3.2. Mixtures

SODIUM PERIODATE 10-<20%

CAS number: 7790-28-5 EC number: 232-197-6 REACH registration number: 01-
2119980983-20-XXXX
M factor (Acute) = 1

Classification
Ox. Sol. 1 - H271
Skin Corr. 1C - H314
Eye Dam. 1 - H318
STOT RE 1 - H372
Aquatic Acute 1 - H400

SULPHURIC ACID ...% 5-<10%

CAS number: 7664-93-9 EC number: 231-639-5 REACH registration number: 01-
2119458838-20-XXXX

Classification
Skin Corr. 1A - H314

The full text for all hazard statements is displayed in Section 16.

SECTION 4: First aid measures

4.1. Description of first aid measures

Inhalation Unlikely route of exposure as the product does not contain volatile substances. If spray/mist
has been inhaled, proceed as follows. Move affected person to fresh air and keep warm and
at rest in a position comfortable for breathing. Get medical attention.

Ingestion Rinse mouth thoroughly with water. Give plenty of water to drink. Give milk instead of water if
readily available. Keep affected person under observation. Do not induce vomiting. If vomiting
occurs, the head should be kept low so that vomit does not enter the lungs. Get medical
attention immediately. Show this Safety Data Sheet to the medical personnel.

Skin contact Rinse immediately with plenty of water. Remove contaminated clothing. Get medical attention.
Show this Safety Data Sheet to the medical personnel.

Eye contact Rinse immediately with plenty of water. Remove any contact lenses and open eyelids wide
apart. Get medical attention. Show this Safety Data Sheet to the medical personnel.

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4.2. Most important symptoms and effects, both acute and delayed
Inhalation Severe irritation of nose and throat.

Ingestion May cause chemical burns in mouth and throat.

Skin contact May cause serious chemical burns to the skin.

Eye contact May cause blurred vision and serious eye damage.

4.3. Indication of any immediate medical attention and special treatment needed
Notes for the doctor No specific recommendations.

SECTION 5: Firefighting measures

5.1. Extinguishing media

Suitable extinguishing media Extinguish with foam, carbon dioxide, dry powder or water fog.

Unsuitable extinguishing None known.

media

5.2. Special hazards arising from the substance or mixture

Hazardous combustion Sulphurous gases (SOx). Oxygen.
products

5.3. Advice for firefighters

Special protective equipment Wear positive-pressure self-contained breathing apparatus (SCBA) and appropriate protective
for firefighters clothing. Severe corrosive hazard. Wear chemical protective suit.

SECTION 6: Accidental release measures

6.1. Personal precautions, protective equipment and emergency procedures

Personal precautions Avoid contact with skin and eyes. Wear protective clothing as described in Section 8 of this
safety data sheet.

6.2. Environmental precautions

Environmental precautions Do not discharge into drains or watercourses or onto the ground.

6.3. Methods and material for containment and cleaning up

Methods for cleaning up Stop leak if possible without risk. DO NOT touch spilled material! Absorb spillage with non-
combustible, absorbent material. Flush contaminated area with plenty of water.

6.4. Reference to other sections

Reference to other sections For personal protection, see Section 8. For waste disposal, see section 13.

SECTION 7: Handling and storage

7.1. Precautions for safe handling

Usage precautions Avoid spilling. Avoid contact with skin and eyes. Do not eat, drink or smoke when using the
product. Promptly remove any clothing that becomes wet or contaminated. Wash promptly if
skin becomes contaminated.

7.2. Conditions for safe storage, including any incompatibilities

Storage precautions Store in tightly-closed, original container in a dry and cool place.

7.3. Specific end use(s)

Specific end use(s) The identified uses for this product are detailed in Section 1.2.

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SECTION 8: Exposure controls/Personal protection

8.1. Control parameters

Occupational exposure limits
SODIUM PERIODATE
Long-term exposure limit (8-hour TWA): WEL 10 mg/m3 total dust
Short-term exposure limit (15-minute): WEL 4 mg/m3 resp.dust
SULPHURIC ACID ...%
Long-term exposure limit (8-hour TWA): WEL 0,05 mg/m³
Short-term exposure limit (15-minute): WEL
WEL = Workplace Exposure Limit

Ingredient comments WEL = Workplace Exposure Limits

SODIUM PERIODATE (CAS: 7790-28-5)

DNEL Workers - Dermal; Short term systemic effects: 0.2 mg/kg/day

Workers - Dermal; Long term systemic effects: 0.06 mg/m³
Workers - Inhalation; Short term systemic effects: 0.3 mg/m³
Workers - Inhalation; Long term systemic effects: 0.1 mg/m³
General population - Dermal; Short term local effects: 0.09 mg/kg/day
General population - Dermal; Long term systemic effects: 0.03 mg/m³
General population - Inhalation; Short term systemic effects: 0.09 mg/m³
General population - Inhalation; Long term systemic effects: 0.03 mg/m³
General population - Oral; Short term systemic effects: 0.03 mg/kg/day
General population - Oral; Long term systemic effects: 0.01 mg/kg/day

PNEC Fresh water; 0.00018 mg/l

marine water; 0.000018 mg/l
Intermittent release; 0.0018 mg/l
Sediment (Freshwater); 0.000702 mg/kg
Sediment (Marinewater); 0.0000702 mg/kg
STP; 2.2 mg/l
Soil; 0.000035 mg/kg

SULPHURIC ACID ...% (CAS: 7664-93-9)

DNEL Workers - Inhalation; Short term local effects: 0.1 mg/m³

Workers - Inhalation; Long term local effects: 0.05 mg/m³

PNEC Fresh water; 0.0025 mg/l

marine water; 0.00025 mg/l
Sediment (Freshwater); 0.002 mg/kg
Sediment (Marinewater); 0.002 mg/kg
STP; 8.8 mg/l

8.2. Exposure controls

Appropriate engineering Provide adequate ventilation. Avoid inhalation of vapours and spray/mists. Observe any
controls occupational exposure limits for the product or ingredients.

Eye/face protection Wear tight-fitting, chemical splash goggles or face shield.

Hand protection Wear protective gloves. It is recommended that gloves are made of the following material:
Butyl rubber. It is recommended that gloves are made of the following material: Neoprene. It is
recommended that gloves are made of the following material: Nitrile rubber.

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Other skin and body Wear appropriate clothing to prevent any possibility of skin contact.
protection

Hygiene measures Provide eyewash station and safety shower.

Respiratory protection No specific recommendations. Respiratory protection may be required if excessive airborne
contamination occurs.

SECTION 9: Physical and chemical properties

9.1. Information on basic physical and chemical properties

Appearance Liquid.

Colour Colourless to pale yellow.

Odour Odourless.

Odour threshold Not available.

pH pH (concentrated solution): 1 ± 1

Melting point Not applicable.

Initial boiling point and range 100°C/212°F

Flash point Not applicable.

Evaporation rate Not available.

Upper/lower flammability or Not applicable.

explosive limits

Vapour density Not applicable.

Relative density 1.25 g/ml @ 20°C/68°F

Solubility(ies) Miscible with water.

Auto-ignition temperature Not available.

Decomposition Temperature Not available.

Viscosity Not available.

Explosive properties None.

Oxidising properties Does not meet the criteria for classification as oxidising.

Comments Information declared as "Not available" or "Not applicable" is not considered to be relevant to
the implementation of the proper control measures.

9.2. Other information

Volatile organic compound This product contains a maximum VOC content of 0 g/litre.

SECTION 10: Stability and reactivity

10.1. Reactivity
Reactivity The following materials may react violently with the product: Strong alkalis.

10.2. Chemical stability

Stability Stable at normal ambient temperatures and when used as recommended.

10.3. Possibility of hazardous reactions

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Possibility of hazardous None known.

reactions

10.4. Conditions to avoid

Conditions to avoid Avoid excessive heat for prolonged periods of time.

10.5. Incompatible materials

Materials to avoid Strong alkalis.

10.6. Hazardous decomposition products

Hazardous decomposition None at ambient temperatures.
products

SECTION 11: Toxicological information

11.1. Information on toxicological effects

Toxicological effects No data recorded.

Acute toxicity - oral

Notes (oral LD₅₀) Prolonged or repeated exposure may cause the following adverse effects:

Skin corrosion/irritation
Animal data Corrosive to skin.

Serious eye damage/irritation

Serious eye damage/irritation Corrosive to skin. Corrosivity to eyes is assumed. No testing is needed.

Skin sensitisation
Skin sensitisation Based on available data the classification criteria are not met.

Germ cell mutagenicity

Genotoxicity - in vitro Does not contain any substances known to be mutagenic.

Carcinogenicity
Carcinogenicity Does not contain any substances known to be carcinogenic.

Reproductive toxicity
Reproductive toxicity - fertility Does not contain any substances known to be toxic to reproduction.

Medical symptoms Symptoms following overexposure may include the following: Severe stomach pain. Vomiting
of blood. Symptoms following overexposure may include the following: Chemical burns.
Symptoms following overexposure may include the following: Irritation, burning, lachrymation,
blurred vision after liquid splash.

SECTION 12: Ecological information

12.1. Toxicity
Toxicity There are no data on the ecotoxicity of this product.

12.2. Persistence and degradability

Persistence and degradability The product contains only inorganic substances which are not biodegradable.

12.3. Bioaccumulative potential

Bioaccumulative potential The product does not contain any substances expected to be bioaccumulating.

12.4. Mobility in soil

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Mobility Mobile. The product is miscible with water. May spread in water systems.

12.5. Results of PBT and vPvB assessment

Results of PBT and vPvB This product does not contain any substances classified as PBT or vPvB.
assessment

12.6. Other adverse effects

Other adverse effects The product may affect the acidity (pH) of water which may have hazardous effects on aquatic
organisms.

SECTION 13: Disposal considerations

13.1. Waste treatment methods

Disposal methods Dispose of waste via a licensed waste disposal contractor. Flush away spillage with plenty of
water.

Waste class EWC 06 01 06

SECTION 14: Transport information

14.1. UN number
UN No. (ADR/RID) 3264

UN No. (IMDG) 3264

UN No. (ICAO) 3264

UN No. (ADN) 3264

14.2. UN proper shipping name

Proper shipping name CORROSIVE LIQUID, ACIDIC, INORGANIC, N.O.S.
(ADR/RID)

Proper shipping name (IMDG) CORROSIVE LIQUID, ACIDIC, INORGANIC, N.O.S.

Proper shipping name (ICAO) CORROSIVE LIQUID, ACIDIC, INORGANIC, N.O.S.

Proper shipping name (ADN) CORROSIVE LIQUID, ACIDIC, INORGANIC, N.O.S.

14.3. Transport hazard class(es)

ADR/RID class 8

ADR/RID classification code C1

ADR/RID label 8

IMDG class 8

ICAO class/division 8

ADN class 8

Transport labels

14.4. Packing group

ADR/RID packing group III

IMDG packing group III

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ICAO packing group III

ADN packing group III

14.5. Environmental hazards

Environmentally hazardous substance/marine pollutant

No.

14.6. Special precautions for user

IMDG Code segregation 1. Acids
group

EmS F-A, S-B

ADR transport category 3

Emergency Action Code 2X

Hazard Identification Number 80

(ADR/RID)

Tunnel restriction code (E)

14.7. Transport in bulk according to Annex II of MARPOL and the IBC Code
SECTION 15: Regulatory information

15.1. Safety, health and environmental regulations/legislation specific for the substance or mixture
EU legislation Regulation (EC) No 1907/2006 of the European Parliament and of the Council of 18
December 2006 concerning the Registration, Evaluation, Authorisation and Restriction of
Chemicals (REACH) (as amended).

UFI VNMY-8078-U00G-4J0Y

15.2. Chemical safety assessment

No chemical safety assessment has been carried out.

SECTION 16: Other information

Revision comments NOTE: Lines within the margin indicate significant changes from the previous revision.

Revision date 11/12/2019

Revision 12

Supersedes date 09/10/2019

SDS number 11061

Hazard statements in full H271 May cause fire or explosion; strong oxidiser.
H314 Causes severe skin burns and eye damage.
H318 Causes serious eye damage.
H372 Causes damage to organs through prolonged or repeated exposure.
H400 Very toxic to aquatic life.

This information relates only to the specific material designated and may not be valid for such material used in combination
with any other materials or in any process. Such information is, to the best of the company's knowledge and belief, accurate
and reliable as of the date indicated. However, no warranty, guarantee or representation is made to its accuracy, reliability or
completeness. It is the user's responsibility to satisfy himself as to the suitability of such information for his own particular use.

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