XI-Chemistry Chapter test-13-Hydrocarbons-Solutions

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NEET CHAPTER TEST

CHEMISTRY
CHEMISTRY Topic : Hydrocarbons [SOLUTIONS]

(1) (4). Boiling point  molecular weight. (13) (3).


C6H5 C6H5
(2) (3). Correct statements are :
Br
The C–C chain in alkane can be zigzag. + Alc. KOH
All alkanes do not exhibit all kinds of H
isomerism. (14) (4). Of all the conformations of ethane, the
Na/C H OH staggered form has the least torsional strain
(3) (2). CH3 + H2 
2 5  CH + H
4 and the eclipsed form, the maximum
Zn Cu
CH3 + 2H 
 CH4 + H torsional strain.
Couple
Rotation about carbon-carbon single bond
(4) (4). It is the test for unsaturation in molecule. in ethane is almost free for all practical
(5) (2). purposes.
CH3 Br
CH3
| |

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|
CH 3  C  CH 3 
Cl2

CH 3 C  CH 2  Cl
 (15) (1).CH3 – C CH + 2HBr  CH3  C  CH 2
|
| CH3
CH3
monochloro alkane Br
(6) (4). Branched alkane have lower surface area HBr
|
so they posses low Boiling point.   CH 3  C  CH 3
(7) (3). Optical active molecule |
LA Br
H
(16) (3). CH3 – CH = CH – CH3 + O3 
CH3 – C* – chiral C atom O
CH3–CH CH–CH3 Zn
C2H5  2CH3CHO H 2O2
O O H 2O [B]
[A]
(8) (2). CH3  C  CH  CH 2  CH 3 Ozonide product

| Zn + H2O2  ZnO + H2O


CH3 So, B is CH3 – CHO
CH3
[O]
  CH3 – CH2 – COOH +
A
C=O

Cl
(1). CH  CH  HOCl  |
CH3
(17)
(9) (2). CH2 = CH – CH2 – CH3 CH  CH  OH
Pd/H

2  CH – CH – CH – CH
3 2 2 3
Conc. H SO  CHCl2 – CHO
(10) (3). R – CH2 – OH 
2 4  H 2O
Protonation (18) (2). Acetylene does not react with NaOH.
B

 
 (19) (3). CH  C  C  H  CH  Mg  X
3 3
R  CH 2  O  H ––– CH4 + CH3 – C  C – Mg – X
|
H (20) (1). 1-alkynes are react with sodium because
(11) (1). CH2 = CHCH = CH2 + HBr  they have acidic hydrogen.
Liq. NH
CH3 – CH2 – C CH + Na 
3

CH3 – CH2 – C CNa + ½ H2


 CH3  CHCH  CH 2 + CH3CH = CHCH2Br
| (21) (1). C6 H5 N 2  Cl  HBF4 

Br
C6 H5 N 2 BF4  HCl
(12) (3). Acid catalyzed hydration of alkenes except
ethene leads to the formation of mixture of C6 H5 N 2 BF4 
 C6 H5F  N 2  BF3
secondary and tertiary alcohols.

CLASSES BY ANKUR SIR 7983744732


(22) (1). C6H5 – Mg – Br + CH3 – OH  (30) Li/NH3
(2). CH3  CH 2  CH 2  C  C  CH3  
Br
 C6H6 + Mg 2-Hexyne Birch reduction
OCH3 CH3 – CH2 – CH2 H
(23) (3).
CH3 CH3 C=C
Cl
FeCl3/Cl2
+
H CH3
Trans-2-Hexene
Cl
(31) (1).
o- & p-chloro toluene
Cl Cl
H3C – C Cl + 6Ag + Cl C – CH3
(24) (1). Twist boat conformations of cyclohexane
Cl Cl
is chiral.
(25) (2). For the compounds with same molecular
H3C – C  C – CH3 + 6AgCl 
mass, boiling point decreases with increase 2-butyne

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in branching. Boiling point also increases (32) (1).
with increase in molecular mass.
CH3CH 2  C  O  O  C  CH 2  CH3  
(26) (3). 2-butene is symmetrical alkene | |
CH3 – CH = CH – CH3 CH3 CH2 H

3 O
2.CH3CHO 
Zn/H 2O CH3  CH 2  C  CH  CH 2  CH3
LA
Molar mass of CH3CHO is 44 u. |
CH2 CH3
(27) (3). (33) (3). The order of reactivity of the hydrogen
H
halides is HI > HBr > HCl. As the size of
H2C = HC C2H5 halogen increases, the strength of H–X
bond decreases and hence, reactivity
CH3 increases.
Only 3-methyl-1-pentene has a chiral (34) (4). CH3CH2C CH + O3
carbon.
 O
Cl
   CH3 CH2C — CH H 2O
| *  
A
CH 2  CH  CH 2  CH3 O O
(28) (3). |
CH3 HCOOH + CH3CH2COOH
(R  S) (35) (3). NO2

Cl HNO Br
| 
3 
2 
B

H 2SO4 FeBr3
CH3  CH  CH  CH3 (50C)
| * NO2 NH2
Sn
CH3  
(R  S) HCl
Br Br
Four monochloro derivatives are chiral.
(29) (4). Boiling point of alkanes increases with (36) (4). The reaction is Wurtz reaction and
increase in molecular mass and for the proceeds as follows:
same alkane the boiling point decreases
CH3  CH 2CH 2  CH  Br  2Na
with branching. Thus, the decreasing order |
of their boiling points is : CH 2
n-Pentane > 2-Methylbutane |
(III) (II) CH3
> 2,2-Dimethylbutane > n-Butane
(IV) (I)

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 Br  CH  CH 2CH 2CH3 

ether Order of stability :
R R R R
| C=C > C=C
CH2 R R R H
| R R R H
> C=C > C=C
CH3 R H
R H
8 7 6 5 4 3 2 1 R R R H
CH3CH 2CH 2  CH  CH  CH 2CH 2CH3 C=C > C=C
| | H H R H
CH2 CH2 (42) (2). CH3 – C  C – CH2 – CH3
| | O
CH3 CH3 CH3 – C – C – CH2 – CH3
4,5-Diethyloctane
O O
(37) (3). Cl2 is added to benzene ring in presence of O3
 Pentyne ozonide

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sunlight to give benzene hexachloride.
Cl
2H O
CH3  CO
Cl Cl 
2
|  H 2O2
sunlight
+ 3Cl2 
 CH3CH 2CO
Cl Cl
Methylethylglyoxal
Cl
(C6H6Cl6) O

 CH3COOH  CH3CH 2COOH
HBr
(38) (2). CH3C  CH   CH3  C  CH 2 Acetic acid Propionic acid
LA | The glyoxal formed as an intermediate is
Br oxidised by H2O2 to give the acids.
Br (43) (3). This reaction occurs according to
|

HBr
 CH3  C  CH3 Markonikov’s rule which states that when
| an unsymmetrical alkene undergo
Br hydrohalogenation, the negative part goes
2,2-Dibromopropane to that C-atom which contain lesser
(39) (3). Halogens are electron withdrawing groups number of H-atom.
due to electronegative nature hence they
deactivate benzene ring for electrophilic
A
substitution but are o, p-directing. CH3CH2  C  CH  HCl  CH3  CH 2  C  CH 2
|
O Cl
(40) (3). CH3 – CH2 – CH = CH2 
3

O I
CH3 – CH2 – CH CH2 HI
|
Hydrolysis

  CH3  CH 2  C  CH 2
B

O O |
CH3 – CH2 – CHO + HCHO Cl
O3
Propionaldebyde Formaldebyde (44) (4). H3C  C  CH  CH3 
(41) (2). Heat of hydrogenation of alkene  |
CH3
1
  
Stability of alkene O O
Hence the alkene which will react fastest || ||
CH3  C  CH3 + CH3  C  H
with H2 will be the least stable. Among the Acetone Acetaldehyde
given options the compound having least (45) (4).
number of alkyl groups (R) will be the Anhy. AlCl CH3
least stable. Further the relative rates of + CH3Cl 
3

+ HCl
hydrogenation decrease with increase of
steric hindrance. Toluene

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