XI-Chemistry Chapter test-13-Hydrocarbons-Solutions
XI-Chemistry Chapter test-13-Hydrocarbons-Solutions
XI-Chemistry Chapter test-13-Hydrocarbons-Solutions
CHEMISTRY
CHEMISTRY Topic : Hydrocarbons [SOLUTIONS]
JI
|
CH 3 C CH 3
Cl2
CH 3 C CH 2 Cl
(15) (1).CH3 – C CH + 2HBr CH3 C CH 2
|
| CH3
CH3
monochloro alkane Br
(6) (4). Branched alkane have lower surface area HBr
|
so they posses low Boiling point. CH 3 C CH 3
(7) (3). Optical active molecule |
LA Br
H
(16) (3). CH3 – CH = CH – CH3 + O3
CH3 – C* – chiral C atom O
CH3–CH CH–CH3 Zn
C2H5 2CH3CHO H 2O2
O O H 2O [B]
[A]
(8) (2). CH3 C CH CH 2 CH 3 Ozonide product
(19) (3). CH C C H CH Mg X
3 3
R CH 2 O H ––– CH4 + CH3 – C C – Mg – X
|
H (20) (1). 1-alkynes are react with sodium because
(11) (1). CH2 = CHCH = CH2 + HBr they have acidic hydrogen.
Liq. NH
CH3 – CH2 – C CH + Na
3
JI
in branching. Boiling point also increases (32) (1).
with increase in molecular mass.
CH3CH 2 C O O C CH 2 CH3
(26) (3). 2-butene is symmetrical alkene | |
CH3 – CH = CH – CH3 CH3 CH2 H
3 O
2.CH3CHO
Zn/H 2O CH3 CH 2 C CH CH 2 CH3
LA
Molar mass of CH3CHO is 44 u. |
CH2 CH3
(27) (3). (33) (3). The order of reactivity of the hydrogen
H
halides is HI > HBr > HCl. As the size of
H2C = HC C2H5 halogen increases, the strength of H–X
bond decreases and hence, reactivity
CH3 increases.
Only 3-methyl-1-pentene has a chiral (34) (4). CH3CH2C CH + O3
carbon.
O
Cl
CH3 CH2C — CH H 2O
| *
A
CH 2 CH CH 2 CH3 O O
(28) (3). |
CH3 HCOOH + CH3CH2COOH
(R S) (35) (3). NO2
Cl HNO Br
|
3
2
B
H 2SO4 FeBr3
CH3 CH CH CH3 (50C)
| * NO2 NH2
Sn
CH3
(R S) HCl
Br Br
Four monochloro derivatives are chiral.
(29) (4). Boiling point of alkanes increases with (36) (4). The reaction is Wurtz reaction and
increase in molecular mass and for the proceeds as follows:
same alkane the boiling point decreases
CH3 CH 2CH 2 CH Br 2Na
with branching. Thus, the decreasing order |
of their boiling points is : CH 2
n-Pentane > 2-Methylbutane |
(III) (II) CH3
> 2,2-Dimethylbutane > n-Butane
(IV) (I)
JI
sunlight to give benzene hexachloride.
Cl
2H O
CH3 CO
Cl Cl
2
| H 2O2
sunlight
+ 3Cl2
CH3CH 2CO
Cl Cl
Methylethylglyoxal
Cl
(C6H6Cl6) O
CH3COOH CH3CH 2COOH
HBr
(38) (2). CH3C CH CH3 C CH 2 Acetic acid Propionic acid
LA | The glyoxal formed as an intermediate is
Br oxidised by H2O2 to give the acids.
Br (43) (3). This reaction occurs according to
|
HBr
CH3 C CH3 Markonikov’s rule which states that when
| an unsymmetrical alkene undergo
Br hydrohalogenation, the negative part goes
2,2-Dibromopropane to that C-atom which contain lesser
(39) (3). Halogens are electron withdrawing groups number of H-atom.
due to electronegative nature hence they
deactivate benzene ring for electrophilic
A
substitution but are o, p-directing. CH3CH2 C CH HCl CH3 CH 2 C CH 2
|
O Cl
(40) (3). CH3 – CH2 – CH = CH2
3
O I
CH3 – CH2 – CH CH2 HI
|
Hydrolysis
CH3 CH 2 C CH 2
B
O O |
CH3 – CH2 – CHO + HCHO Cl
O3
Propionaldebyde Formaldebyde (44) (4). H3C C CH CH3
(41) (2). Heat of hydrogenation of alkene |
CH3
1
Stability of alkene O O
Hence the alkene which will react fastest || ||
CH3 C CH3 + CH3 C H
with H2 will be the least stable. Among the Acetone Acetaldehyde
given options the compound having least (45) (4).
number of alkyl groups (R) will be the Anhy. AlCl CH3
least stable. Further the relative rates of + CH3Cl
3
+ HCl
hydrogenation decrease with increase of
steric hindrance. Toluene