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SECTION A

Answer ALL the questions in this section.

You should aim to spend no more than 20 minutes on this section.

For each question, select one answer from A to D and put a cross in the box X. If you change
your mind, put a line through the box and then mark your new answer with a cross X.

1 A student measures the enthalpy change of combustion, ACH,

of methanol, CH30H using the apparatus shown.
,

thermometer

stirrer

copper calorimeter
3
containing 50.0 cm
of water

spirit burner
containing methanol

After burning 0.20g of methanol, the temperature of the water increases by 16.0 oc.

(a) The measurement uncertainty in the thermometer used in the experiment

is 0.5 oc for each reading.

What is the percentage uncertainty in the temperature change of 16.0 oc ?

(1)
A 1.60/0

B 3.1%

c 6.3%

D 12.5%

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(b) The student repeats the experiment but burns 0.30g of methanol and uses
75.0 cm3 of water in the copper calorimeter.

What is the expected temperature change in this repeat experiment?

(1)

A 7.1 oc

B 10.7 oc

c 16.0 oc

D 36.0 oc

(c) The student's calculated enthalpy change of combustion of methanol is more

exothermic than a data book value.

What is a possible reason for this?

A heat loss to the surroundings

B incomplete combustion of methanol

C evaporation of methanol from the wick of the spirit burner

D use of the molar mass of ethanol, C2H50H, in the calculation

(Total for Question 1 = 3 marks)

2 Which equation represents the standard enthalpy change of atomisation, AatH+

of bromine?

A 1/2Br2(l) Br(g)

B 1/2Br2(g) Br(g)

2Br(g)

D Br2(g) 2Br(g)

(Total for Question 2 = 1 mark)

Use this space for any rough working. Anything you write in this space will gain no credit.

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3 The enthalpy change of reaction, AH , for the equation shown can be calculated
using bond enthalpy data.

1/2H2(g) + 1/2C12(g) + HCl(g)

Bond Bond enthalpy/ kJ mol

436

Cl Cl 242

H Cl 431

The expression that should be used in the calculation is

A (0.5 x 436 + 0.5 x 242) - 431

B (2 x 431) - (436 + 242)

c 431 - (0.5 x 436 + 0.5 x 242)

D (436 + 242) x 431)

(Total for Question 3 = 1 mark)

4 Which compound has London forces as the only intermolecular force?

B OF2

C PF3

(Total for Question 4 = 1 mark)

Use this space for any rough working. Anything you write in this space will gain no credit.

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5 Which compound has intermolecular hydrogen bonding?

A (CH3)3N

B (CH3)3CF

c (CH3)3COH

D (CH3)3CCHO

(Total for Question 5 = 1 mark)

6 Which sequence shows the hydrogen halides in order of decreasing

boiling temperature?

HCI HBr > HI

HI HBr HCI

C HI HCI

D HI HCI

(Total for Question 6 = 1 mark)

7 Which ion contains vanadium with an oxidation number of +4?

A v02+

D v034

(Total for Question 7 = 1 mark)

8 What is the formula of potassium manganate(Vl)?

A KMn04

B K2Mn04

c K3Mn04

D K6Mn206

(Total for Question 8 = 1 mark)

Use this space for any rough working. Anything you write in this space will gain no credit.

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9 Compound Q produces
a red colour in a flame test

a white precipitate when aqueous potassium sulfate is added to a solution of

the compound.

What is compound Q?

A LiCl

B NaN03

D BaC12

(Total for Question 9 = 1 mark)

10 Which reaction produces more than one product?

A Mg + 02

B Ca + C12

C Sr + H20

D Bao + H20
(Total for Question 1 mark)

11 Which equation shows a redox reaction that would not be expected to occur, based
on the trend in reactivity of the halogens?

A 12(aq) + 2At-(aq) At2(aq) + 21-(aq)

B 2Br-(aq) + C12(aq) —Y 2Cl-(aq) + Br2(aq)

C C12(aq) + 21-(aq) 12(aCl) + 2Cl-(aq)

D 2F-(aq) + At2(aq) + F 2(aCl)

(Total for Question 11 = 1 mark)

Use this space for any rough working. Anything you write in this space will gain no credit.

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12 A fixed amount of concentrated H2S04 is reacted separately with an excess of four

solid potassium halides.

In which reaction would the greatest number of moles of halide be oxidised?

A 2KF(s) + H2S04(aq) + K2S04(aq) + 2HF(g)

B KCl(s) + H2S04(aq) + KHS04(aq) + HCl(g)

C 2KBr(s) + 3H2S04(aq) 2KHS04(aq) + + S02(g) + 2H20(l)

D 8K1(s) + 9H2S04(aq) 8KHS04(aq) + 4126) + H2S(g) + 4H20(l)

(Total for Question 12 = 1 mark)

13 Silver nitrate in aqueous ethanol is added separately to four halogenoalkanes.

Which would form a silver halide precipitate in the shortest time?

A (CH3)3C1

B (CH3)3CCl

c CH3CH2CH2CH21

D CH3CH2CH2CH2Cl

(Total for Question 13 = 1 mark)

14 CH3CH2CHBrCH2CH2CH3 is heated with ethanolic potassium hydroxide.

How many alkene products are possible?

A one

B two

C three

D four

(Total for Question 14 = 1 mark)

15 Which compound is least likely to have a prominent peak at m/ z = 43 in its

mass spectrum?

A CH3COCH2CH3
B CH3CH2NHCH3

D CH3CH2CH2CH3

(Total for Question 15 = 1 mark)

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16 Which compound has peaks at 3415 cm-l and 2250 cm-l in its infrared spectrum?
Refer to the Data Booklet.

A H2NCH2CH2C=N
B CH3CH2CH2COOH

c CICH2CH2C=CH
D

(Total for Question 16 = 1 mark)

Use this space for any rough working. Anything you write in this space will gain no credit.

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17 The distribution of molecular energies for a sample of gas in a sealed container

is shown.

Number of
particles with
energy, E

Energy, E

(a) Why does the distribution of energies start at the origin, (0,0)?
(1)

A some molecules have no energy

B all molecules possess some energy

C the temperature is 0K

D some molecules do not have enough energy to react

(b) Some of the gas is removed and then the container is resealed and the gas
is cooled.

How does the new distribution of molecular energies compare to the

original sample?
(1)

Area under the curve Position of peak

A does not change shifts to the left

B decreases shifts to the left

c does not change shifts to the right

decreases shifts to the right

(Total for Question 17 = 2 marks)

TOTAL FOR SECTION A = 20 MARKS

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SECTION B

Answer ALL the questions. Write your answers in the spaces provided.

18 Calcium hypochlorite, is used for water treatment in swimming pools.

It is produced in the reaction between and C12.

+ 2c12(g) + CaC12(aq) + 2H20(l)

(a) State the type of reaction occurring in the production of

Justify your answer using oxidation numbers.
(3)

(b) Calculate the percentage atom economy by mass for the production of
in this reaction.

(2)

10

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(c) A swimming pool has the dimensions 50m x 25m x 2.0m.

The water in this swimming pool has a concentration of 4.2 mg dm -3
(i) Calculate the mass, in kg, of required to treat the water needed to
completely fill this swimming pool.
(3)

(ii) Calculate the volume of C12, at room temperature and pressure, needed to
make the mass of calculated in (c)(i).

(3)

(Total for Question 18 = 11 marks)

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19 This question is about alcohols with the molecular formula C6H140.

(a) Draw the skeletal formula of each of the three tertiary alcohols with the
formula QI--1140.

(3)

tertiary alcohol 1

tertiary alcohol 2

tertiary alcohol 3

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(b) Two primary C6H140 alcohols, A and B, are shown.

OH
OH

alcohol A alcohol B

(i) Give the IUPAC name of alcohol A.

(1)

(ii) Explain why alcohol B has a higher boiling temperature than alcohol A.
(2)

(iii) Explain why alcohol B is completely soluble in ethanol but only slightly
soluble in water.
A detailed description of the forces involved is not required.
(3)

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(c) Give the structure of the organic product of each reaction shown.
(3)

Reaction 1

K2Cr207, H2S04

OH
heat under reflux

Reaction 2

K Cro H2S04

OH heat under reflux

Reaction 3

red phosphorus and iodine

OH
heat under reflux

(Total for Question 19 = 12 marks)

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20 This question is about the synthesis of propylamine, CH3CH2CH2NH2.

Three routes for the synthesis of CH3CH2CH2NH2 are shown.

Step X KCN
CH2 CH3CH2Cl organic compound W

H2(g) , Pt catalyst

CH3CH2CH2NH2

Step Z
H2(g) , Pt catalyst

Step Y
CH3CH2CH2Br CH3CH2CH2N3

(a) Identify, by name or formula, the reagent used in Step X.

(1)

(b) Give the structure of organic compound W.

(1)

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(c) The reagent used in Step Y is potassium azide, KN3.

This is a source of the azide ion, N; , which acts as a nucleophile.

(i) Complete a possible dot-and-cross diagram for N;.

Show outer electrons only.
(2)

N N N

(ii) Complete the mechanism for Step Y.

Include curly arrows, and any relevant lone pairs and dipoles.
(3)

CH3CH2 c

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(d) Step Z is carried out by reacting ammonia with I-bromopropane.

(i) Give the conditions for this reaction.

(2)

(ii) Suggest why the yield of CH3CH2CH2NH2 obtained using Step Z is low.
(1)

(Total for Question 20 = 10 marks)

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