Davies 5 700 Liquid Tile Primer White Sds

SAFETY DATA SHEET
PRODUCT IDENTIFICATION DAVIES® LIQUID-TILE PRIMER WHITE

I. IDENTIFICATION
PRODUCT DESCRIPTION
An acrylic solvent based primer specially formulated for concrete and wood surfaces. It promotes better
adhesion to substrate being painted thus, providing solid foundation for succeeding finish coats
PRODUCT CODE DV-5-700

DATE CREATED 12 May 2016
DATE REVISED 14 October 2019
Supplier's name: Davies Paints Philippines, Inc. Telephone Number: (02) 8641-7101
Address: 1387 Mercedes Ave., San Miguel Mobile Numbers: 0917-5721458 / 0922-8886491
Pasig City, Metro Manila Email: customercare@daviespaints.com.ph
1600 Philippines Website: www.daviespaints.com.ph
II. HAZARDOUS A. EMERGENCY OVERVIEW

IDENTIFICATION Highly flammable liquid; vapor may cause flash fire.
Harmful or fatal if swallowed - Can enter lungs and cause damage.
Can cause eye, skin or respiratory tract irritation.
Overexposure can cause central nervous system (CNS) depression and/or other target organ effects.
Breathing high concentrations can cause irregular heartbeats which may be fatal.
Xylene, all isomers (or a component) may cause harm to the human fetus based on tests with laboratory animals.
Ethylbenzene has been shown to cause cancer in laboratory animals. The relevance of this to humans is not clear.
Exposure to respirable crystalline silica may cause silicosis. Lung cancer is associated with occupational exposures to crystalline silica, specifically
quartz and cristobalite.
Harmful to aquatic organisms.
B. POTENTIAL HEALTH EFFECTS
INHALATION Breathing high concentrations may be harmful. Mist or vapor can irritate the throat and lungs. Breathing this material
may cause central nervous system depression with symptoms including nausea, headache, dizziness, fatigue,
drowsiness, or unconsciousness. Breathing high concentrations of this material, for example, in an enclosed space
or by intentional abuse, can cause irregular heartbeat.
Exposure to respirable crystalline silica may cause silicosis. Lung cancer is associated with occupational exposures
to crystalline silica, specifically quartz and cristobalite.
EYE CONTACT Can cause eye irritation with tearing, redness, or a stinging or burning feeling. Further, it can cause swelling of the
eyes with blurred vision. Effects may become more serious with repeated or prolonged contact.
SKIN CONTACT May cause mild skin irritation with redness and/or an itching or burning feeling. Effects may become more serious
with repeated or prolonged contact. It is likely that some components of this material are able to pass into the body
through the skin and may cause similar effects as from breathing or swallowing it.
INGESTION Swallowing this material may be harmful. Swallowing this material may cause stomach or intestinal upset with pain,
nausea, and/or diarrhea. This material can get into the lungs during swallowing or vomiting. Small amounts in the
lungs can cause lung damage, possibly leading to chronic lung dysfunction or death. Swallowing this material may
cause effects similar to those described in the inhalation section (see "inhalation" above).
III. COMPOSITION / List of hazardous ingredient(s)

INFORMATION ON Chemical Abstract Service (CAS)
HAZARDOUS Chemical Name % Concentration
Registry Number (RN)
INGREDIENTS Solvent naphtha (petroleum), light aromatic 64742-95-6 10 - 20
Xylene, all isomers 1330-20-7 10 - 20
Dioxotitanium 13463-67-7 5 - 15
Ethylbenzene 100-41-4 1-5
Crystalline silica, quartz 14808-60-7 0.1 - 1.0
Page 1 of 9
DAVIES® LIQUID-TILE PRIMER WHITE
IV. FIRST AID

MEASURES List of ingredient(s) with no available hazard classifications
Chemical Abstract Service (CAS)
Chemical Name % Concentration
Registry Number (RN)
Limestone 1317-65-3 10 - 20
Talc 14807-96-6 1 - 10
Quaternary ammonium compounds, bis(hydrogenated
68953-58-2 1-5
tallow alkyl)dimethyl, salts with bentonite
Other ingredients do not present health or environment hazard: 10 - 20%
EYE CONTACT Immediately flush with water for at least 15 minutes. It is also recommended to have medical personnel check your
eyes afterwards.
SKIN CONTACT Remove severely contaminated clothing immediately and flush skin with large amounts of water until irritation
subsides. If irritation persists, get medical attention.
INHALATION Remove to fresh air and if not breathing, give mouth to mouth resuscitation. If breathing is difficult, give oxygen. Call
a physician.
INGESTION Do not induce vomiting. Keep rest. Get prompt medical attention.
NOTES TO PHYSICIAN INHALATION: Inhalation overexposure can produce toxic effects. Monitor for respiratory distress. If cough or
difficulty in breathing develops, evaluate for upper respiratory tract and pneumonitis. Administer supplemental
oxygen with assisted ventilation, as required.
This material (or a component) sensitizes the heart to the effects of sympathomimetic amines. Epinephrine and
other sympathomimetic drugs may initiate cardiac arrhythmias in individuals exposed to this material. Administration
of sympathomimetic drugs should be avoided.
INGESTION: If ingested, this material presents a significant aspiration and chemical pneumonitis hazard. Induction
of emesis is not recommended. Consider activated charcoal and/or gastric lavage. If patient is obtunded, protect the
airway by cuffed endotracheal intubation or by placement of the body in a Trendelenburg and left lateral decubitus
position.
V. FIRE FIGHTING
MEASURES
Flash Point and Method 12.9 ºC / 55.2 ºF(Closed Cup)

Flammability Limit, by volume (LEL-UEL) 0.8 - 6.7 %
Autoignition Temperature 235 ºC (ASTM D2155)
GENERAL HAZARD:
Highly flammable liquid; may release flammable vapors when temperatures are at or over the flash point. Toxic gases will form upon
combustion.
FIRE FIGHTING INSTRUCTIONS:
VI. ACCIDENTAL Allow fire to burn out under controlled conditions or fight fire from a safe distance, extinguishing with foam, dry chemical, carbon dioxide or dry
RELEASE sand. Do not use directly "WATER" to extinguish to avoid the danger of fire spread that may be caused by floating flammable material on the
MEASURES water surface. But if possible to do without hazard, use water spray to cool fire exposed surface and isolate material from heat.
EXTINGUISHING MEDIA:
Carbon dioxide, foam, dry chemical or dry sand.
FIRE FIGHTING EQUIPMENT:
VII. HANDLING Respiratory and eye protection required for fire fighting personnel. Full protective equipment (Bunker Gear) and a self-contained breathing
AND STORAGE apparatus (SCBA) should be used for all indoor fires and significant outdoor fires. For small outdoor fires, which may easily be extinguished with
a portable fire extinguisher, use of an SCBA may not be required.
HAZARDOUS COMBUSTION PRODUCT:
Smokes, fumes and oxide of carbon.
VIII. EXPOSURE
CONTROLS / Provide maximum ventilation. Personal protection should be used. Remove all sources of ignition. Contain spilled liquid with sand or earth. Avoid
PERSONAL runoff into storm sewers and ditches which lead to waterways. Take up spilled material with vermiculite, dry sand (Don't use organic material to take
PROTECTION up or wipe for example: sawdust, cotton cloth or paper which cause fire by spontaneous chemical reaction with air and paint and organic materials)
and place in a disposal container.
Page 2 of 9
Handle in sufficiently ventilated areas.

Handling in closed areas requires local exhaust ventilation with a minimum capture velocity of 0.5 m/sec, at the point of vapor evolution.
Keep container closed. Loosen closure cautiously before opening.
Store in a cool, well ventilated place away from incompatible materials.
Keep away from heat, sparks and flame. Protect material from direct sunlight.
The face, eyes, head, hands, and all other exposed parts of the bodies of employees handling paints shall be protected. All footwear shall be non-
sparking, such as rubbers, rubber boots or rubber soled shoes without nails. Coveralls or other outer clothing shall be of cotton. Rubber, rather than
plastic, gloves shall be used because of the danger of static sparks.
No matches, lighted cigarettes, cigars, or pipes, and no cigarette lighters or ferrous articles shall be taken into the area where work is being done.
All employees continuously in a compartment in which painting is being performed shall be protected by air line respirators in accordance with the
requirements of the Occupational Safety & Health Administration (OSHA) and by suitable protective clothing. Employees entering such
compartments for a limited time shall be protected by filter cartridge type respirators in accordance with the requirements of the OSHA. All
employees doing exterior paint spraying shall be protected by suitable filter cartridge type respirators in accordance with the requirements of the
OSHA and by suitable protective clothing.
Do not eat, drink, or smoke while handling it. Thoroughly wash the hands with soap and water before meals and at the end of the work shift.
EXPOSURE GUIDELINE:
Chemical Name Threshold Limit Value
Solvent naphtha (petroleum), light aromatic 100 mg/m3 (TWA8, HSPA occupational exposure limits [OELs])
Limestone 10 mg/m3 (TWA8, ACGIH)
Xylene, all isomers 100 ppm (TWA8, ACGIH)
Dioxotitanium 10 mg/m3 (TWA8, ACGIH)
2 mg/m3 (TWA8, American Conference of Governmental
Talc
Industrial Hygienists, ACGIH)
Ethylbenzene 20 ppm (TWA8, ACGIH)
Quaternary ammonium compounds, bis(hydrogenated tallow alkyl)dimethyl,
not established
salts with bentonite
Crystalline silica, quartz 0.025 mg/m3 (TWA, ACGIH)
IX. PHYSICAL AND Appearance White liquid

CHEMICAL Odour Solvent smell
PROPERTIES Odour threshold Not available
pH Not available
Freezing point -94.9 ºC (-138.8 ºF)
Initial boiling point and boiling range Typical 135 - 145 ºC
Flash point 12.9 ºC / 55.2 ºF (Closed Cup)
Evaporation rate (butyl acetate = 1) 0.09 (ASTM D3539)
Flammability (solid, gas) Not applicable because product is liquid
Upper/lower flammability or explosive limits, % volume 0.6 - 7.0
Vapour pressure 0.76 mmHg (0.101 kPa) at 20ºC
Vapour density (air = 1) 3.7
Relative density (water = 1) 1.33
Solubility in water Negligible
Partition coefficient: n-octanol/water Not available
Auto-ignition temperature 235 ºC (ASTM D2155)
Decomposition temperature Not available
Viscosity 95 - 100 Krebs Unit, KU (Krebs Viscometer)
Volatile Organic Compound (VOC) 524.71 g/L
X. STABILITY AND STABILITY

REACTIVITY (Conditions to avoid) Avoid open flame electrical equipment sparks and other sources of ignition which induce fire.
This product is considered stable under normal and anticipated storage and handling conditions.
INCOMPATIBILITY
Page 3 of 9 (Specific materials to avoid) Acid and alkali which contact may cause reaction (polymerization with heat).
XI. TOXICOLOGICAL Solvent naphtha (petroleum), light aromatic

INFORMATION ROUTES OF EXPOSURE: Solvent naphtha (petroleum), light aromatic can affect the body if it is inhaled, if it comes in contact with the eyes or
skin, or if it is swallowed.
SYMPTOMS OF EXPOSURE: Respiratory irritation signs and symptoms may include a temporary burning sensation of the nose and throat,
coughing, and/or difficulty breathing. Breathing of high vapour concentrations may cause central nervous system (CNS) depression resulting in
dizziness, light-headedness, headache, nausea and loss of coordination. Continued inhalation may result in unconsciousness and death. If
material enters lungs, signs and symptoms may include coughing, choking, wheezing, difficulty in breathing, chest congestion, shortness of
breath, and/or fever. Defatting dermatitis signs and symptoms may include a burning sensation and/or a dried/cracked appearance.
Auditory system effects may include temporary hearing loss and/or ringing in the ears.
TARGET ORGANS: Skin. Respiratory system. Central nervous system (CNS).
BASIS FOR ASSESSMENT: Information given is based on product testing, and/or similar products, and/or components.
ACUTE ORAL TOXICITY: The oral LD50 value for Sprague-Dawley rats was greater than 5000 mg/kg, therefore, it not classified because it is
out of category.
ACUTE DERMAL TOXICITY: Classified as Category 5 since the dermal LD50 value for New Zealand White rabbits was greater than 2000
mg/kg.
ACUTE INHALATION TOXICITY: Set as out of category based on the inhalation LC50 value for Sprague-Dawley rats of greater than 5.61 mg/L
(considered as mists).
SKIN CORROSION / IRRITATION: Classified as Category 2 Skin Irritant based on OECD Guideline 404 (Acute Dermal Irritation / Corrosion)
on New Zealand White rabbits with mean erythema score of 2.56.
SERIOUS EYE DAMAGE / EYE IRRITATION: With reference to test made on similar product, solvent naphtha (petroleum), light aromatic is
not classified since it is considered to be non-irritating to eyes.
RESPIRATORY /SKIN SENSITIZATION: Respiratory sensitization: Classification is not possible due to lack of data.
Skin sensitization: Not classified as a skin sensitizer for the reason that the Buehler Test on Hartley Albino guinea pigs showed solvent naphtha
(petroleum), light was not a contact sensitizer.
GERM CELL MUTAGENICITY: Solvent naphtha (petroleum), light was not classified as a germ cell mutagen since the result of germ cell
mutagenicity tests on similar product was negative.
CARCINOGENICITY: Not classified as a carcinogen since test guideline equivalent or similar to OECD Guideline 451 (Carcinogenicity Studies)
to a similar product was not expected to display carcinogenic properties.
REPRODUCTIVE TOXICITY: Causes foetotoxicity in animals at doses which are maternally toxic, thus, classified as Category 2.
EFFECTS ON OR VIA LACTATION: Classification is not possible due to lack of data.
SPECIFIC TARGET ORGAN TOXICITY - SINGLE EXPOSURE: Classification is not possible due to lack of data.
SPECIFIC TARGET ORGAN TOXICITY - REPEATED EXPOSURE: It is not classified but has the following effects on repeated exposure:
Auditory system: prolonged and repeated exposures to high concentrations have resulted in hearing loss in rats. Solvent abuse and noise
interaction in the work environment may cause hearing loss. Kidney: caused kidney effects in male rats which are not considered relevant to
humans.
ASPIRATION HAZARD: Classified as Category 1 Aspiration toxicant based on the report that aspiration of solvent naphtha (petroleum), light
aromatic may be fatal if swallowed and enters airways and since the chemical is a hydrocarbon.
Limestone
ROUTES OF EXPOSURE: The substance can be absorbed into the body by inhalation, skin and/or eye contact.
SYMPTOMS: Irritation of eyes, skin, mucous membrane; cough, sneezing, rhinorrhea (discharge of thin nasal mucus); lacrimation (discharge of
tears)
TARGET ORGANS: Eyes, skin, respiratory system
ACUTE ORAL TOXICITY: Classification is not possible due to lack of data.
ACUTE DERMAL TOXICITY: Classification is not possible due to lack of data.
ACUTE INHALATION TOXICITY: Classification is not possible due to lack of data.
SKIN CORROSION / IRRITATION: Classification is not possible due to lack of data.
SERIOUS EYE DAMAGE / EYE IRRITATION: Classification is not possible due to lack of data.
RESPIRATORY / SKIN SENSITIZATION: Respiratory sensitization: Classification is not possible due to lack of data.
Skin sensitization: Classification is not possible due to lack of data.
GERM CELL MUTAGENICITY: Classification is not possible due to lack of data.
CARCINOGENICITY: Classification is not possible due to lack of data.
REPRODUCTIVE TOXICITY: Classification is not possible due to lack of data.
SPECIFIC TARGET ORGAN TOXICITY - REPEATED EXPOSURE: Classification is not possible due to lack of data.
ASPIRATION HAZARD: Classification is not possible due to lack of data.
Page 4 of 9
Xylene, all isomers

ROUTES OF EXPOSURE: Xylene can affect the body if it is inhaled, if it comes in contact with the eyes or skin, or if it is swallowed. It may
enter the body through the skin.
SYMPTOMS OF EXPOSURE: Dizziness, excitement, drowsiness, incoordination, staggering gait, impaired reaction time, impaired short-term
memory; headache; eye, nose, throat irritation; corneal vacuolization; anorexia; nausea, vomiting, abdominal pain; dryness and scaling of the
skin, dermatitis; reversible liver and kidney damage after exposure to sudden high concentrations.
INGESTION ACUTE: Burning sensation in mouth and throat; abdominal pain.
TARGET ORGANS: CNS, eyes, skin, respiratory system, GI tract, blood, liver, kidneys.
ACUTE EXPOSURE: The signs and symptoms of acute exposure to xylene include headache, fatigue, irritability, lassitude, nausea, anorexia,
flatulence, irritation of the eyes, nose, and throat, and motor incoordination and impairment of equilibrium. Flushing, redness of the face, a
sensation of increased body heat, increased salivation, tremors, dizziness, confusion, and cardiac irritability have also been reported.
CHRONIC EXPOSURE: The signs and symptoms of chronic exposure to xylene may include conjunctivitis; dryness of the nose, throat, and
skin; dermatitis; and kidney and liver damage.
ACUTE ORAL TOXICITY: Based on the rat LD50 (oral route) value of 3,500 mg/kg, it is classified as Category 5.
ACUTE DERMAL TOXICITY: Classification is not possible because the data available is not enough for classification.
ACUTE INHALATION TOXICITY: Not classified based on the rat LC50 (4 hour inhalation exposure) value of 29.08 mg/L (MOE Risk
Assessment Vol.1, 2002) (equivalent to 6,700ppm) was lower than 90% of the saturated vapor concentration (8,000ppm) under a saturated
vapour pressure of 0.8 kPa (20 ºC), the substance was considered as "vapour containing substantially no mist" and was set as out of category.
SKIN CORROSION / IRRITATION: Moderately irritating to rabbit's skin following a 24-hour exposure to 0.5 mL mixed xylenes under semi-
occlusive conditions. Hence, it is classified as Category 2.
SERIOUS EYE DAMAGE / EYE IRRITATION: Moderately irritating to rabbit's eyes. Two drops of xylene into the eyes of rabbits resulted in
slight conjunctival irritation and very slight transient corneal injury, therefore it is classified as Category 2A.
RESPIRATORY /SKIN SENSITIZATION: Respiratory sensitization: Classification is not possible due to lack of data.
GERM CELL MUTAGENICITY: Xylene is not classified as a germ cell mutagen based on the negative data on human multi-generation
epidemiological studies and somatic cell mutagenicity tests in vivo (micronucleus/chromosome tests) and the absence of data on heritable
mutagenicity tests, germ cell mutagenicity tests in vivo and germ cell genotoxicity tests in vivo.
CARCINOGENICITY: For the reason that xylene is classified as Category A4 by American Conference of Governmental Industrial Hygienists
(ACGIH), Group 3 by International Agency for Research on Cancer (IARC), and Group D by United States Environmental Protection Agency
(EPA), it is set as out of category.
REPRODUCTIVE TOXICITY: Several human studies examined exposure to organic solvents (including mixed xylenes) and developmental
effects. An increased potential for spontaneous abortions among the wives of occupationally exposed men was reported. However, no
conclusions can be drawn from these studies because they all involved concurrent exposure to multiple chemicals. Mixed xylenes have been
shown to produce developmental effects, such as an increased incidence of skeletal variations in fetuses, delayed ossification, fetal resorptions,
and decreased fetal body weight in animals via inhalation exposure. Some studies observed maternal toxicity as well. Thus, xylene is classified
as presumed human reproductive toxicant (Category 1B).
SPECIFIC TARGET ORGAN TOXICITY - SINGLE EXPOSURE: Based on the human evidence including "throat irritation, severe pulmonary
congestion, alveolar hemorrhage, pulmonary edema, congestion accompanying hepatomegaly, centrilobular vacuolation of hepatocytes, nerve
cell damage associated with dot hemorrhage, swelling and disappearance of Nissl bodies, limb cyanosis, a transient increase in serum
transaminase activity, an increase in the blood level of urea, a decrease in endogenous creatinine clearance in the urine, liver damage, severe
kidney damage, amnesia, coma" and "pulmonary congestion, pulmonary edema, focal alveolar hemorrhage," it is classified as Category 1
Target organ toxicant and the evidence from animal studies including "strong narcotic effect," it is classified as Category 3 Target organ toxicant.
The basis for the classification includes data on xylene with unknown composition or containing other substances.
SPECIFIC TARGET ORGAN TOXICITY - REPEATED EXPOSURE: Based on the human evidence including "eye/nose irritation, thirst" and
"chronic headache, chest pain, abnormal electroencephalogram, dyspnea, cyanosis of the hands, fever, a decrease in WBC count, discomfort,
impairment of pulmonary function, a decrease in working capacity, physical/mental disorders," it is classified as Category 1 Target organ
toxicant.
ASPIRATION HAZARD: Classified as Category 2 Aspiration toxicant based on the report that aspiration of xylene or acute exposure to high
vapor concentrations of this substance may cause chemical pneumonitis, hemorrhage into the air spaces, and pulmonary edema. A worker
exposed to the vapors of a solvent containing 75 percent xylene (approximate airborne xylene concentration of 60 to 350 ppm) developed
giddiness, anorexia, and vomiting. After inhalation of high (not further specified) concentrations of xylene, workers may become flushed, feel hot,
and experience confusion, dizziness, tremors, and other signs or symptoms of central nervous system toxicity.
Dioxotitanium
ROUTES OF EXPOSURE: The substance can be absorbed into the body by inhalation.
INHALATION RISK: A nuisance-causing concentration of airborne particles can be reached quickly when dispersed.
SYMPTOMS: Lung fibrosis; [potential occupational carcinogen]
Page 5 of 9 TARGET ORGANS: respiratory system
ACUTE ORAL TOXICITY: The oral LD50, female rat is greater than 5,000 mg/Kg body weight and the oral LD50, male rat is greater than 11,000
mg/Kg body weight which is outside the classification category of acute toxicity hazard. Thus, dioxotitanium is not classified.
ACUTE DERMAL TOXICITY: The dermal LD50 of rabbit is greater than 10,000 mg/Kg body weight which is set as outside of the acute toxicity
hazard categories, thus dioxotitanium is not classified.
ACUTE INAHALATION TOXICITY: The approximate LC50 of dioxotitanium in male rats exposed head-only for 4 hours, is greater than 6.82
mg/L (the highest test concentration practical). Ergo, it is not classified.
SKIN CORROSION / IRRITATION: It was classified as out of Category considering the statement of slightly irritating, and not irritating in rabbit
examination.
SERIOUS EYE DAMAGE / EYE IRRITATION: Causes eye irritation and was classified as Category 2B (mildly irritating to eyes).
Skin sensitization: It was not classified based on a not sensitizing result of a patch test in humans.
GERM CELL MUTAGENICITY: The substance was not classified considering the negative results in a mouse bone marrow micronucleus test
and a chromosomal aberration test by intraperitoneal administration (in vivo somatic cell mutagenicity tests). Another relevant data to be
considered is the report of a negative Chinese hamster SCE test (in vivo somatic cell genotoxicity test). There are also reports of negative Ames
tests and negative chromosomal aberration and mouse lymphoma tests from in vitro mutagenicity tests.
CARCINOGENICITY: In International Agency for Research on Cancer (IARC) Monograph Volume 93 (updated on 10 March 2006), it is stated
that there is inadequate evidence in humans for the carcinogenicity of dioxotitanium but there is sufficient evidence in experimental animals for
the carcinogenicity of dioxotitanium. Dioxotitanium is possibly carcinogenic to humans (Group 2B). Dioxotitanium as powder is classified as
Category 2 Carcinogen (Suspected of causing cancer). Moreover, no significant exposure to dioxotitanium is thought to occur during the use of
products in which dioxotitanium is bound to other materials, such as in paints.
SPECIFIC TARGET ORGAN TOXICITY - SINGLE EXPOSURE: Classification is not possible because the available data were insufficient to
warrant a classification.
SPECIFIC TARGET ORGAN TOXICITY - REPEATED EXPOSURE: Classification is not possible because the available data were insufficient
to warrant a classification.
Talc
INHALATION RISK: Evaporation at 20°C is negligible; a harmful concentration of airborne particles can, however, be reached quickly when
dispersed.
SYMPTOMS: Fibrotic pneumoconiosis, irritation eyes
TARGET ORGANS: Eyes, respiratory system, cardiovascular system
EFFECTS OF SHORT-TERM EXPOSURE: Data not available.
EFFECTS OF LONG-TERM OR REPEATED EXPOSURE: The substance may have effects on the lungs, resulting in talc pneumoconiosis.
Depending on the degree of exposure, periodic medical examination is suggested.
SKIN CORROSION/IRRITATION: Classification is not possible due to lack of data.
SERIOUS EYE DAMAGE/IRRITATION: Classification is not possible due to lack of data.
GERM CELL MUTAGENICITY: Classification is not possible due to lack of data.
CARCINOGENICITY: The American Conference of Governmental Industrial Hygienists (ACGIH) reported talc is not classifiable as human
carcinogen and the International Agency for Research on Cancer (IARC) concluded there is Animal & Human Inadequate Evidence (Group 3).
Therefore, it is not classified as a carcinogen.
SPECIFIC TARGET ORGAN TOXICITY - REPEATED EXPOSURE: Classification is not possible due to lack of data.
Ethylbenzene
ROUTES OF EXPOSURE: The substance can be absorbed into the body by inhalation, ingestion, skin and/or eye contact.
SYMPTOMS: Irritation eyes, skin, mucous membrane; headache; dermatitis; narcosis, coma
Page 6 of 9 TARGET ORGANS: Eyes, skin, respiratory system, central nervous system
INHALATION RISK: A harmful contamination of the air will be reached rather slowly on evaporation of this substance at 20°C.
EFFECTS OF SHORT-TERM EXPOSURE: The substance is irritating to the eyes , the skin and the respiratory tract. Swallowing the liquid may
cause aspiration into the lungs with the risk of chemical pneumonitis. The substance may cause effects on the central nervous system. Exposure
above the occupational exposure limit (OEL) could cause lowering of consciousness.
EFFECTS OF LONG-TERM OR REPEATED EXPOSURE: This substance is possibly carcinogenic to humans. The substance may have
effects on the kidneys and liver, resulting in impaired functions Repeated contact with skin may cause dryness and cracking.
ACUTE ORAL TOXICITY: The LD50 (Rat, oral) calculated was 3,500 mg/kg. It is classified as Category 5 according to the GHS Classification
and Labelling of Chemicals.
ACUTE DERMAL TOXICITY : The acute dermal LD50 for ethylbenzene in New Zealand White rabbits was calculated as 15,415 mg/kg body-
weight. Hence, it is not classified.
ACUTE INHALATION TOXICITY: The acute inhalation LC50, vapor, 4 hours for ethylbenzene in Carworth Wistar rats was calculated as 17.8
mg/L (4,000 ppm) body weight. For this fact, it is classified as Category 4.
SKIN CORROSION/IRRITATION: Undiluted ethylbenzene has been shown to produce moderate irritation when applied to the uncovered skin
of rabbits. The application of undiluted ethylbenzene to the ear and to the shaved abdomen of rabbits up to 20 times during a 4-week period
resulted in moderate irritation. There was erythema and edema with superficial necrosis and exfoliation of large patches of skin. From this fact,
ethylbenzene is classified as Category 3 (Mild skin irritant).
SERIOUS EYE DAMAGE/IRRITATION: Drop application to rabbit eyes caused slight irritation and no corneal injury demonstrable by
fluorescein staining. Standard testing on rabbit eyes gave an injury grade of 2 on a scale of 10. Ethylbenzene is classified as Category 2B (mildly
irritating to eyes).
RESPIRATORY / SKIN SENSITIZATION: Respiratory sensitization: The available data are insufficient to draw conclusions, hence,
classification is not possible.
Skin sensitization: The available data are insufficient to draw conclusions, hence, classification is not possible.
GERM CELL MUTAGENICITY: In a National Toxicology Program study, ethylbenzene was not mutagenic in Salmonella tests and did not
induce chromosomal aberrations or sister chromatid exchange in Chinese hamster ovary (CHO) cells in vitro , although it did induce trifluoro-
thymidine resistance in mouse lymphoma cells at the highest concentration tested (80 mg/litre). There was no increase of micronuclei in the
peripheral blood of mice exposed to ethylbenzene. Based on these data, ethylbenzene is not classified as mutagenic.
CARCINOGENICITY: IARC reported that there is inadequate evidence in humans for the carcinogenicity of ethylbenzene but there is sufficient
evidence in experimental animals for the carcinogenicity of ethylbenzene. Thus, ethylbenzene is possibly carcinogenic to humans (Group 2B).
ACGIH classified ethylbenzene as A3; Confirmed animal carcinogen with unknown relevance to humans. From these facts, ethylbenzene is
classified as Category 2 (Suspected human carcinogen).
REPRODUCTIVE TOXICITY: Based on the description of mice/rat teratogenicity tests: Toxic effects on the embryo (urinary malformation) are
observed at dosing levels not toxic to maternal animals, it is classified as Category 1B (Presumed human reproductive toxicant).
SPECIFIC TARGET ORGAN TOXICITY - SINGLE EXPOSURE: Single high exposures to ethylbenzene through inhalation cause irritation of
the mucous membranes and central nervous system effects (2,180 ppm). Ethylbenzene is classified as Category 2 (central nervous system) and
Category 3 (respiratory tract irritation).
SPECIFIC TARGET ORGAN TOXICITY - REPEATED EXPOSURE: The available data are insufficient to draw conclusions, hence, classi-
fication is not possible.
ASPIRATION HAZARD: Classified as Category 1 Aspiration toxicant based on the description in International Chemical Safety Cards (ICSC):
Ethyl benzene, if swallowed, may cause chemical pneumonia due to misswallowing. The substance is a hydrocarbon, the kinematic viscosity of
which stands at 0.6 mm2/s (25 ºC).
Quaternary ammonium compounds, bis(hydrogenated tallow alkyl)dimethyl, salts with bentonite

ROUTES OF EXPOSURE: The substance can be absorbed into the body by inhalation, ingestion, skin and/or eye contact.
ACUTE ORAL TOXICITY: The acute oral LD50 as reported in the SIDS Dossier of this substance was > 5000 mg/Kg body weight of the tested
animal and in this case was the albino rat. Since the result was out of category, it was not classified.
ACUTE INHALATION TOXICITY: The acute inhalation LC50 of this substance in rats was > 12.7 mg/L exposed for four hours based on OECD
Guideline 403 (Acute Inhalation Toxicity). Since no deaths was reported after the study and the value was greater than the inhalation toxicity cut-
off values, it was not classified.
SKIN CORROSION / IRRITATION: It was not irritating on rabbit's skin based on the result that there were no signs of erythema or edema on
the tested animals as reported in the SIDS Dossier of the substance, therefore, it was not classified.
SERIOUS EYE DAMAGE / EYE IRRITATION: It was not irritating in rabbit's eyes since the reported result in the SIDS Dossier of this
substance was that there were no signs of irritation on the tested animals, ergo, it was not classified.
RESPIRATORY / SKIN SENSITIZATION: Respiratory sensitization: Classification is not possible because the available data were insufficient
for classification.
Skin sensitization: Classification is not possible because the available data were insufficient for classification.
Page 7 of 9 GERM CELL MUTAGENICITY: Classification is not possible because the available data were insufficient for classification.
CARCINOGENICITY: Classification is not possible due to lack of data.

SPECIFIC TARGET ORGAN TOXICITY - SINGLE EXPOSURE: Classification is not possible because the available data were insufficient for
classification.
SPECIFIC TARGET ORGAN TOXICITY - REPEATED EXPOSURE: Classification is not possible because the available data were insufficient
for classification.
Crystalline silica, quartz

SYMPTOMS: Cough, dyspnea (breathing difficulty), wheezing; decreased pulmonary function, progressive respiratory symptoms (silicosis);
irritation eyes; [potential occupational carcinogen]
TARGET ORGANS: Eyes, respiratory system
INHALATION RISK: A harmful concentration of airborne particles can be reached quickly when dispersed.
EFFECTS OF SHORT-TERM EXPOSURE: May cause mechanical irritation.
EFFECTS OF LONG-TERM OR REPEATED EXPOSURE: The substance may have effects on the lungs, resulting in fibrosis (silicosis). This
substance is carcinogenic to humans. Depending on the degree of exposure, periodic medical examination is suggested. Do NOT take working
clothes home.
SKIN CORROSION/IRRITATION: Classification is not possible due to lack of data.
SERIOUS EYE DAMAGE/IRRITATION: Classification is not possible due to lack of data.
GERM CELL MUTAGENICITY: The available data are insufficient, thus, classification is not possible.
CARCINOGENICITY: Crystalline silica in quartz form is considered as Category 1A (Known to have carcinogenic potential for humans). The
classification is based on the following reviews and reports: IARC classified silica is carcinogenic to humans (Group 1) based on sufficient
evidence in humans for the carcinogenicity of inhaled crystalline silica in the form of quartz or cristobalite from occupational sources and
sufficient evidence in experimental animals for the carcinogenicity of quartz and cristobalite; NTP Report on Carcinogens (RoC), Twelfth Edition
(2011) stated that respirable crystalline silica, primarily quartz dusts occurring in industrial and occupational settings, is known to be a human
carcinogen based on sufficient evidence of carcinogenicity from studies in humans. Respirable crystalline silica was first listed in the Sixth Annual
Report on Carcinogens in 1991 as reasonably anticipated to be a human carcinogen based on sufficient evidence of carcinogenicity from studies
in experimental animals; the listing was revised to known to be a human carcinogen in the Ninth Report on Carcinogens in 2000.
SPECIFIC TARGET ORGAN TOXICITY - SINGLE EXPOSURE: Cause damage to organs (respiratory) and is classified as Category 1. There
were reports that its short-term exposure also affects the respiratory system in humans in case of high inhalation concentration although there is
much little data compared with repeated exposure. Based on this, it was classified into Category 1 (respiratory system).
SPECIFIC TARGET ORGAN TOXICITY - REPEATED EXPOSURE: Causes damage to organs (respiratory organs, kidneys) through
prolonged or repeated exposure. There is a description that the respiratory system and the kidney are affected in humans, and based on this, it
was classified into Category 1 (respiratory system, kidney).
XII. ECOLOGICAL This has the potential to be toxic in environments. Do not leak or waste in the environments without adequate waste disposal handling.
INFORMATION
XIII. DISPOSAL Empty containers and material (including waste thinner for cleaning and flushing of containers or application equipment) must be disposed in
CONSIDERATION accordance with government and local environmental control regulations.
Do not heat or cut empty container with electric or gas torch due to residue.
XIV. TRANSPORT UN Number: UN1263

Page 8 of 12 UN Proper Shipping Name: PAINT
INFORMATION
Transport hazard class(es): Class 3
Page 8 of 9
Packing group: II
Environmental hazards:
Marine pollutant according to IMDG Code: No
Environmentally hazardous according to UN Model Regulations: No
Environmentally hazardous according to ADR: No
Environmentally hazardous according to RID: No
Environmentally hazardous according to ADN: No
Special precautions for user:
EmS Guide: F-E, S-E
Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code: Y (containing xylenes/ ethylbenzene (10% or
more) mixture
Philippines Inventory of All components of this product are registered in the Philippines Inventory of Chemicals and Chemical
XV. REGULATORY
Chemicals and Chemical Substances (PICCS).
INFORMATION
Substances (PICCS)
TSCA Inventory List All components of this product are listed on the Toxic Substances Control Act (TSCA) inventory.
Montreal Protocol
No component of this product is listed on the Montreal Protocol on Substances that Deplete the Ozone Layer.
Stockholm Convention No component of this product is listed on the Stockholm Convention on Persistent Organic Pollutants.
Rotterdam Convention No component of this product is listed on the Rotterdam Convention on the Prior Informed Consent Procedure
for Certain Hazardous Chemicals and Pesticides in International Trade.
XVI. OTHER Legend to abbreviations and acronyms used:

INFORMATION LFL - UFL means lower flammability limit - upper flammability limit
TWA8 means 8-hour time weighted average
LD 50 means the amount of a chemical, given all at once, which causes the death of 50% (one half) of a group of test animals
LC 50 (50% lethal concentration) means the concentration of a chemical in air or of a chemical in water which causes the death of 50% (one
half) of a group of test animals
GHS means the Globally Harmonized System of Classification and Labelling of Chemicals
IUCLID means the International Uniform Chemical Information Database
HSDB means the Hazardous Substance Data Bank
SIDS means the Screening Information Dataset
EHC means the Environmental Health Criteria
OECD means the Organisation for Economic Co-operation and Development
ECHA means the European Chemical Agency
UN means the United Nations
IMDG Code means the International Maritime Dangerous Goods code
ADR means the European Agreement concerning the International Carriage of Dangerous Goods by Road
RID means the Regulations concerning the International Carriage of Dangerous Goods by Rail
ADN means the European Agreement concerning the International Transport of Dangerous Goods by Inland Waterways
EMS Guide means the Emergency response procedures for Ships Carrying Dangerous Goods
MARPOL 73/78 means the International Convention for the Prevention of pollution from Ships, 1973, as modified by the Protocol of 1978
relating thereto, as amended
IBC Code means the International Code for the Construction and Equipment of Ships carrying Dangerous Chemicals in Bulk (International Bulk
Chemical Code)
The information herein is given in good faith but we cannot guarantee that these are the only hazards which exist. Final determination of suitability
of any material is the sole responsibility of the user. All materials may present unknown hazards and should be used with caution.
Page 9 of 9

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SAFETY DATA SHEET

PRODUCT IDENTIFICATION DAVIES® LIQUID-TILE PRIMER WHITE

PRODUCT CODE DV-5-700

II. HAZARDOUS A. EMERGENCY OVERVIEW

III. COMPOSITION / List of hazardous ingredient(s)

IV. FIRST AID

Flash Point and Method 12.9 ºC / 55.2 ºF(Closed Cup)

Handle in sufficiently ventilated areas.

IX. PHYSICAL AND Appearance White liquid

X. STABILITY AND STABILITY

XI. TOXICOLOGICAL Solvent naphtha (petroleum), light aromatic

Xylene, all isomers

Quaternary ammonium compounds, bis(hydrogenated tallow alkyl)dimethyl, salts with bentonite

CARCINOGENICITY: Classification is not possible due to lack of data.

Crystalline silica, quartz

XIV. TRANSPORT UN Number: UN1263

XVI. OTHER Legend to abbreviations and acronyms used:

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