11CHE02 QP

KENDRIYA VIDYALAYA SANGATHAN ERNAKULAM REGION

SESSION ENDING EXAMINATION 2023-24

केन्द्रीय विद्यालय संगठन एर्ााकुलम संभाग

संत्रात परीक्षा : 2023-24

CHEMISTRY THEORY (043)
Max. Marks:70 Time: 3:00 hours
General Instructions:
Read the following instructions carefully.
(a) There are 33 questions in this question paper with internal choice.
(b) SECTION A consists of 16 multiple -choice questions carrying 1 mark each.
(c) SECTION B consists of 5 short answer questions carrying 2 marks each.
(d) SECTION C consists of 7 short answer questions carrying 3 marks each.
(e) SECTION D consists of 2 case - based questions carrying 4 marks each.
(f) SECTION E consists of 3 long answer questions carrying 5 marks each.
(g) All questions are compulsory.
(h) Use of log tables and calculators is not allowed.
SECTION A
1 The empirical formula of a compound of molecular mass 120gmol-1 is CH2O. The 1
M.F. of the compound is --------(C=12u, H=1u, O=16u)
(a) C3H6O2 (b) C3H6O3 (c) C4H8O4 (d) C8H8O4
2 What are the values of n and l for 2p orbital.
1
(a) n=2, l=1 (b) n=1, l=1 (c) n=2, l=0 (d) n=3, l=2
3 An atom of an element contains 29 electrons and 35 neutrons, the electronic 1
configuration of the element will be,
(a)[Ar] 4s23d9 (b) [Ar] 4s1 3d10 (c) [Ar] 4s1 3d9 (d) [Ar] 4s1 3d8

4 The equilibrium constant for a reaction is 10. what will be the value of ΔG0?
R=8.314JK-1mol-1, T= 300K 1
a)- 6.99kJmol-1 b) -5.74 kJmol-1 c) 5.74 kJmol- 1 (d) 6.99kJmol-1
5 Which one will have highest second ionisation enthalpy 1
a) 1s2, 2s2, 2p6,3s1 c) 1s2, 2s2, 2p4
b) 1s2, 2s2, 2p6 d) 1s2, 2s2, 2p6,3s2
6 In the long form of the periodic table, the valence shell electronic configuration of 5s2
5p4 corresponds to the element present in 1
a) Group 16 and period 6 b) Group 17 and period 6
c) Group 16 and period 5 d) Group 17 and Period 5
Write the relation between Kp and Kc for the reaction
7 2NOCl (g) <=> 2 NO(g) + Cl2(g)
1
a) Kp= Kc (RT)-1 b) Kp= Kc (RT)-2 c) Kp= Kc (RT) d)Kp= Kc (RT)2
8 The conjugate acid of the base HSO4- is 1
(a) H2SO4 (b) SO42- (c)SO32- (d) None of the above
9 Among the following identify the species with an atom in +6 oxidation state. 1
(a) MnO4- (b) NO3- (c) MnO2 (d) CrO2Cl2
10 Identify the molecule with 4 bond pairs of electrons and one lone pair of electrons on
the central atom. 1
(a) PCl5 (b) SF4 (c) CH4 (d) BrF5

11 The enthalpies of all elements in their standard states are: 1

(a)unity (b)zero (c) <0 (d) Different for each element
12 An alkene on ozonolysis gives methanal and ethanal. Name the alkene. 1
(a)Ethene (b) propene (c) But-1-ene (d) But-2-ene
In the following questions (Q. No. 13 - 16) a statement of assertion followed by a
statement of reason is given. Choose the correct answer out of the following choices.

A) Assertion and reason both are correct statements and reason is correct explanation for
assertion.
B) Assertion and reason both are correct statements but reason is not correct explanation
for assertion.
C) Assertion is correct statement but reason is wrong statement.
D) Assertion is wrong statement but reason is correct statement.
13 Assertion (A): Molarity is temperature independent. 1
Reason (R): Molarity depends on volume which varies with temperature.
14 Assertion(A): Electron gain enthalpy becomes more negative as we go down the group. 1
Reason(R): Size of the atom increase on going down the group and the added electron
move far from the nucleus.
15 Assertion (A) : Salt bridge is necessary in Daniel cell.
Reason (R) : Salt bridge completes the circuit and maintains potential difference 1
between two half cells.
16 Assertion (A) : BeF2 has a zero dipole moment 1
Reason (R) : The two equal and opposite B-F bond dipoles cancel each other.
SECTION B
17 Calcium carbonate reacts with aqueous HCl to give CaCl 2 and CO2 according to the
reaction; CaCO3 + 2HCl ---> CaCl2 + CO2 + H2O 2
What mass of CaCO3 is required to react completely with 25mL of 0.75M HCl?
18. Calculate the energy associated with the first orbit of He +. What is the radius of this 2
orbit.
19 At 473 K, equilibrium constant Kc for decomposition of phosphorus pentachloride, 2
PCl5 is 8.3 x 10-3• If decomposition is depicted as,
PCl5(g) ↔PCl3(g) + Cl2(g) ΔrH0 = 124.0 kJmo1-1
a) i) Write an expression for Kc for the reaction.
ii) What is the value of Kc for the reverse reaction at the same temperature?
OR
a) The value of Kc for the reaction 2A ↔ B + C is 2 x10-3. At a given time ,the
composition of the reaction mixture is [A] = [B] = [C] = 3 X10-4 M. In which direction
the reaction will proceed.
20 Balance the given redox reaction in acidic medium 2
MnO4- + Fe2+ --------> Mn2+ + Fe3+
OR
Balance the given redox reaction in acidic medium
Cr2O72- + SO32- ------> Cr3+ + SO42-
21 Write the chemical equation for the following reactions: 2
(a) Phenol heated with Zinc dust
(b) Addition of HBr on propene in the presence of peroxide.
SECTION C
22. a) Calculate the mass of sodium which contains the same number of atoms as there are 3
in 4g of Ca. (Atomic Mass: Ca=40u, Na=23u)
b) Define mole fraction.
23. (a) Among the elements B, Al, C and Si 3
(i) which element has highest first ionisation enthalpy.
(ii) Which element has most metallic character.
(b) Why Chlorine has more negative electron gain enthalpy than Fluorine?
(c) Give the IUPAC name and symbol of an element with atomic number 112.
24 (a) Calculate the standard enthalpy of formation of CH3OH(l) from the following data: 3
CH3OH (l) + 3 /2 O2 (g) → CO2 (g) + 2H2O(l) ∆rH 0 = –726 kJ mol–1
C(graphite) + O2(g) → CO2(g) ∆cH0 = –393 kJ mol–1
H2(g) + 1 /2 O2(g) → H2O(l) ∆fH0 = –286 kJ mol–1
(b) Will the entropy increase or decrease, during the following process
2NaHCO3(s) -----> Na2CO3(s) + CO2(g) + H2O(g)
OR
(a) Derive the relation Cp - Cv =R
(b) Will the entropy increase or decrease, when a liquid crystallises into a solid. Justify
your answer.
25 a) What are buffer solutions? Give one example. 3
b) State Le chatelier’s principle.
c) For the reaction, N2 (g) +3H2 (g) ⇌2NH3(g) ∆H= – 92.38 kJ mol –1
In which direction the equilibrium shifts with an
i) Increase in temperature. ii) Increase in Pressure.
26 a) Write the bondline representation of 2,3-Dimethylpentanal 3
b) Name the method to separate Aniline from Aniline -water mixture
c) Arrange the following species in the increasing order of their stabilities.
(CH3)2CH +, CH3+ ,(CH3)3C +, CH3-CH2+
27. (a) Write one example for Wurtz reaction. 3
(b) Draw the conformational isomers of ethane using Newman projection formula.
(c) Convert Benzene to Toluene.
28. a) Correct IUPAC name for the following compound is 3

b) Predict the hybridisation of each C atom in CH3 CN

c) Classify the given species as nucleophiles or electrophiles I) BF3 II) C2H5O-
 SECTION D
29. Aromatic compounds are a large class of chemical compounds characterized by one or 4
more planar rings of atoms joined by covalent bonds of two different kinds. The unique
stability of these compounds is referred to as aromaticity. Although the
term aromatic originally concerned odour, today its use in chemistry is restricted to
compounds that have particular electronic, structural, or chemical properties. Aromaticity
results from particular bonding arrangements that cause certain π (pi) electrons within
a molecule to be strongly held. Aromaticity is often reflected in smaller than expected
heats of combustion and hydrogenation and is associated with low reactivity.
Chemical bonding in benzene:
Benzene (C6H6) is the best-known aromatic compound and the parent to which numerous
other aromatic compounds are related. The six carbons of benzene are joined in a ring,
having the planar geometry of a regular hexagon in which all of the C-C bond distances
are equal. The six π electrons circulate in a region above and below the plane of the ring,
each electron being shared by all six carbons, which maximizes the force of attraction
between the nuclei (positive) and the electrons (negative). Equally important is the
number of π electrons, which, according to molecular orbital theory, must be equal to 4n +
2, in which n = 1, 2, 3, etc. For benzene with six π electrons, n = 1.

(a) Identify whether the following system is aromatic or non-aromatic.

(b) Benzene generally undergoes electrophilic substitution. Why ?

(c) Mention all the necessary conditions to be satisfied for a molecule to be aromatic.
OR
(c) Explain the effect of activating and deactivating group on benzene with example.
30. Every system is associated with a definite amount of energy, called the internal energy U 4
or (E) of the system. It is the sum of chemical, electrical, mechanical or any other form of
energy that anyone can may think of. However gravitational energy is generally
neglected. It is a state function, i. e. independent of the path followed
lt may change when
i) heat flows in or out of the system.
ii) work is done on or by the system.
iii) matter enters or leaves the system
It is an extensive property i.e. depends upon the mass of a substance. It depends only on
temperature. The absolute value of internal energy possessed by a substance cannot be
calculated because it is not possible to predict the exact values of different forms of
energy. Thus, we can just calculate the change in internal energy which is achieved by
changing the state of a system. First law of thermodynamics was proposed by Helmholtz
and Robert- mayer who stated that the energy in an isolated system is constant. i.e. energy
can neither be created nor be destroyed but can be converted from one form to another.
That's why it is also called law of conservation of energy. When a system undergoes
isothermal process, ΔU = zero i.e. there is no increase or decrease in the internal energy
of the system then the first law of thermodynamics reduces to 0 = q + w or q = -w.
a) What do you mean by free expansion of a gas?
b) Out of mass and density which is an intensive property and why?
 c) In a process, 701 J of heat is absorbed by a system and 394 J of work is done
by the system. What is the change in internal energy for the process?
OR
c) Express the change in internal energy of a system when, no heat is absorbed by the
system from the surroundings, but work (w) is done on the system. What type of wall
does the system have?
SECTION E
31 a) Write the chemical reactions involved in the Lassaigne’s test for detection of 5
Nitrogen in the organic compound.
b) If both nitrogen and sulphur are present in the organic compound what will be the
observation for the Lassaigne’s test and why? Write the chemical reaction.
c) Why nitric acid is added to sodium fusion extract before adding Silver nitrate during
Lassaigne’s test for halogens?
OR
a) Explain metamerism with an example.
b) How will you detect the presence of Carbon and Hydrogen in an organic compound.
c) In Dumas method for estimation of nitrogen, 0.3g of an organic compound gave
50mL of nitrogen collected at 300K temperature and 715mm pressure. Calculate the
percentage composition of nitrogen in the compound. Aqueous tension at 300K is
15mm of Hg)
32. a) Write the geometry and hybridisation of PCl5. 5
b) Write the molecular orbital electronic configuration of N 2 and calculate its bond
order.
c)What is hydrogen bond? What type of hydrogen bond exists in o-nitrophenol.
OR
(a) Write two points of difference between sigma bond and pi bond.
(b) Write MO configuration of O2 molecule and predict the magnetic behaviour.
(c) NH3 has higher dipole moment than NF3. Why?
(d) Arrange the following as per the increasing order of Bond order O2, O2+, O2-
33. (a) Write the electronic configuration of Cr2+ (atomic no. of Cr-24) 5
(b) State Hund’s rule of maximum multiplicity
(c) Sketch the boundary surface diagrams of the following orbitals (i) dxy (ii) dx2-y2
(d) Find the total number of nodes in i) 3d ii) 6p
OR
(a) Write electronic configuration of Co3+. (Z=27)
(b) Find out the number of unpaired electrons in Fe3+ (Z=26)
(c) Electronic energy in a particular orbit is expressed with a negative sign. Why?
(d) Calculate the number of radial and angular nodes in
i) 5p
ii) 4d

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