SAFETY DATA SHEET

ROUNDUP® ADVANCED™ READY-TO-USE 1/9

Version 1.0 / CDN Revision Date: 05/04/2021
102000057975 Print Date: 05/04/2021

SECTION 1: IDENTIFICATION OF THE SUBSTANCE/MIXTURE AND OF THE

COMPANY/UNDERTAKING

Product identifier
Trade name ROUNDUP® ADVANCED™ READY-TO-USE
Product code (UVP) 87353060
SDS Number 102000057975
PCP Registration No. 27933

Relevant identified uses of the substance or mixture and uses advised against
Use Herbicide
Restrictions on use See product label for restrictions.
Information on supplier
Supplier Bayer CropScience Inc
#200, 160 Quarry Park Blvd, SE
Calgary, Alberta T2C 3G3
Canada
Responsible Department Email: SDSINFO.BCS-NA@bayer.com
Emergency telephone no.
Emergency Telephone 1-800-334-7577
Number (24hr/ 7 days)
Product Information 1-888-283-6847
Telephone Number

SECTION 2: HAZARDS IDENTIFICATION

Classified in accordance with Part 2 of the Hazardous Products Regulations

Eye irritation: Category 2

Labelling in accordance with Part 3 of the Hazardous Products Regulations

Signal word: Warning

Hazard statements
Causes serious eye irritation.
Precautionary statements
Wash thoroughly after handling.
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Wear eye protection/ face protection.

IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present
and easy to do. Continue rinsing.
If eye irritation persists: Get medical advice/ attention.

Hazards Not Otherwise Classified (HNOC)

No physical hazards not otherwise classified.
No health hazards not otherwise classified.

SECTION 3: COMPOSITION/INFORMATION ON INGREDIENTS

Hazardous Component Name CAS-No. Concentration % by weight

Acetic acid 64-19-7 5 – 10
Citric acid 77-92-9 3–7
The specific chemical identity and/or concentration range is being withheld because it is trade secret
information.

SECTION 4: FIRST AID MEASURES

Description of first aid measures

General advice When possible, have the product container or label with you when
calling a poison control center or doctor or going for treatment.
Inhalation Move to fresh air. If person is not breathing, call 911 or an ambulance,
then give artificial respiration, preferably mouth-to-mouth if possible.
Call a physician or poison control center immediately.
Skin contact Take off contaminated clothing and shoes immediately. Wash off
immediately with plenty of water for at least 15 minutes. Call a
physician or poison control center immediately.
Eye contact Hold eye open and rinse slowly and gently with water for 15-20
minutes. Remove contact lenses, if present, after the first 5 minutes,
then continue rinsing eye. Call a physician or poison control center
immediately.
Ingestion Call a physician or poison control center immediately. Rinse out mouth
and give water in small sips to drink. DO NOT induce vomiting unless
directed to do so by a physician or poison control center. Never give
anything by mouth to an unconscious person. Do not leave victim
unattended.
Most important symptoms and effects, both acute and delayed
Symptoms Eye irritation, Skin irritation, Inhalation may provoke the following
symptoms:, Wheezing, Shortness of breath, Cough, Respiratory
irritation, If large amounts are ingested, the following symptoms may
occur:, Gastro-intestinal irritation
Indication of any immediate medical attention and special treatment needed
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Treatment Appropriate supportive and symptomatic treatment as indicated by the

patient's condition is recommended.

SECTION 5: FIREFIGHTING MEASURES

Extinguishing media
Suitable Water spray, Carbon dioxide (CO2), Foam, Dry chemical
Unsuitable High volume water jet

Special hazards arising Dangerous gases are evolved in the event of a fire.
from the substance or
mixture
Advice for firefighters
Special protective In the event of fire and/or explosion do not breathe fumes. Firefighters
equipment for firefighters should wear NIOSH approved self-contained breathing apparatus and
full protective clothing.
Further information Fight fire from upwind position. Keep out of smoke. Cool closed
containers exposed to fire with water spray. Contain the spread of the
fire-fighting media. Do not allow run-off from fire fighting to enter drains
or water courses.
Flash point The product is not flammable.
Auto-ignition temperature No data available
Lower explosion limit No data available
Upper explosion limit No data available
Explosivity No data available

SECTION 6: ACCIDENTAL RELEASE MEASURES

Personal precautions, protective equipment and emergency procedures

Precautions Keep unauthorized people away. Isolate hazard area. Avoid contact
with spilled product or contaminated surfaces.
Methods and materials for containment and cleaning up
Methods for cleaning up Soak up with inert absorbent material (e.g. sand, silica gel, acid
binder, universal binder, sawdust). Collect and transfer the product
into a properly labelled and tightly closed container. Clean
contaminated floors and objects thoroughly, observing environmental
regulations.
Additional advice Use personal protective equipment. If the product is accidentally
spilled, do not allow to enter soil, waterways or waste water canal. Do
not allow product to contact non-target plants.
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Version 1.0 / CDN Revision Date: 05/04/2021
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Reference to other sections Information regarding safe handling, see section 7.

Information regarding personal protective equipment, see section 8.
Information regarding waste disposal, see section 13.

SECTION 7: HANDLING AND STORAGE

Precautions for safe handling

Advice on safe handling Use only in area provided with appropriate exhaust ventilation. Handle
and open container in a manner as to prevent spillage.
Hygiene measures Wash hands thoroughly with soap and water after handling and before
eating, drinking, chewing gum, using tobacco, using the toilet or
applying cosmetics.
Remove Personal Protective Equipment (PPE) immediately after
handling this product. Remove soiled clothing immediately and clean
thoroughly before using again. Wash thoroughly and put on clean
clothing.
Conditions for safe storage, including any incompatibilities
Requirements for storage Store in a cool, dry place and in such a manner as to prevent cross
areas and containers contamination with other crop protection products, fertilizers, food, and
feed. Store in original container and out of the reach of children,
preferably in a locked storage area. Protect from freezing.
Advice on common storage Keep away from food, drink and animal feedingstuffs.

SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION

Control parameters
Components CAS-No. Control parameters Update Basis
Acetic acid 64-19-7 37 mg/m3/15 ppm 07 2009 CAD AB
(STEL) OEL

Acetic acid 64-19-7 25 mg/m3/10 ppm 07 2009 CAD AB

(TWA) OEL

Acetic acid 64-19-7 10 ppm 09 2011 CAD BC

(TWA) OEL

Acetic acid 64-19-7 15 ppm 09 2011 CAD BC

(STEL) OEL

Acetic acid 64-19-7 10 ppm 03 2011 CAD MB

(TWA) OEL

Acetic acid 64-19-7 15 ppm 03 2011 CAD MB

(STEL) OEL
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Acetic acid 64-19-7 10 ppm 11 2010 CAD ON

(TWA) OEL

Acetic acid 64-19-7 15 ppm 11 2010 CAD ON

(STEL) OEL

Acetic acid 64-19-7 10 ppm 05 2009 CAD SK

(8 HR ACL) OEL

Acetic acid 64-19-7 15 ppm 05 2009 CAD SK

(15 MIN ACL) OEL

Acetic acid 64-19-7 37 mg/m3/15 ppm 09 2017 OEL (QUE)

(STEL)
Acetic acid 64-19-7 25 mg/m3/10 ppm 09 2017 OEL (QUE)
(TWA)
Acetic acid 64-19-7 10 ppm OES BCS*
(TLV)
*OES BCS: Internal Bayer AG, Crop Science Division "Occupational Exposure Standard"
Exposure controls
Personal protective equipment
In normal use and handling conditions please refer to the label and/or leaflet. In all other cases the
following recommendations would apply.
Respiratory protection When respirators are required, select NIOSH approved equipment
based on actual or potential airborne concentrations and in
accordance with the appropriate regulatory standards and/or industry
recommendations.

Hand protection Chemical-resistant gloves (barrier laminate, butyl rubber, nitrile

rubber or Viton)
Eye protection Safety glasses with side-shields
Skin and body protection Wear long-sleeved shirt and long pants and shoes plus socks.
General protective measures Follow manufacturer's instructions for cleaning/maintaining PPE. If
no such instructions for washables, use detergent and warm/tepid
water.
Keep and wash PPE separately from other laundry.
Eye wash facility and safety shower should be available.

SECTION 9. PHYSICAL AND CHEMICAL PROPERTIES

Information on basic physical and chemical properties

Form clear to hazy liquid
Colour colourless
Odour amine-like, of acetic acid
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Odour Threshold No data available

pH 1.6 - 2.5 (100 %) (23 °C)
Melting point/range No data available
Boiling Point No data available
Flash point The product is not flammable.
Flammability No data available
Auto-ignition temperature No data available
Thermal decomposition Stable under normal conditions.

Minimum ignition energy No data available

Self-accelarating No data available
decomposition temperature
(SADT)
Upper explosion limit No data available
Lower explosion limit No data available
Vapour pressure No data available
Evaporation rate No data available
Relative vapour density No data available
Relative density No data available
Density 1.02 g/cm³ (20 °C)

Water solubility completely soluble

Partition coefficient: n- No data available

octanol/water

Viscosity, dynamic No data available

Viscosity, kinematic No data available
Oxidizing properties No data available
Explosivity No data available

SECTION 10: STABILITY AND REACTIVITY

Reactivity Stable under normal conditions.

Chemical stability Stable under recommended storage conditions.

Possibility of hazardous No dangerous reaction known under conditions of normal use.

reactions
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Conditions to avoid Extremes of temperature and direct sunlight.

Incompatible materials Strong bases, Strong oxidizing agents

Hazardous decomposition No decomposition products expected under normal conditions of use.

products

SECTION 11: TOXICOLOGICAL INFORMATION

Exposure routes Eye contact, Skin contact, Ingestion

Immediate Effects
Eye Causes eye irritation.
Skin Causes skin irritation.
Ingestion Not expected to produce significant adverse effects when
recommended use instructions are followed.
Inhalation May be harmful if inhaled.
Information on toxicological effects
Acute oral toxicity
No data available
Acute inhalation toxicity
No data available
Acute dermal toxicity
No data available
Skin corrosion/irritation
No data available
Serious eye damage/eye Irritating to eyes.
irritation
Respiratory or skin
sensitisation No data available
ACGIH
None.
NTP
None.
IARC
None.
OSHA
None.

Aspiration hazard
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Based on available data, the classification criteria are not met.

SECTION 12: ECOLOGICAL INFORMATION

Biodegradability No data available

Bioaccumulation No data available
Results of PBT and vPvB assessment
Additional ecological No further ecological information is available.
information
Environmental precautions Do not allow to get into surface water, drains and ground water.
Do not contaminate surface or ground water by cleaning equipment or
disposal of wastes, including equipment wash water.

SECTION 13: DISPOSAL CONSIDERATIONS

Waste treatment methods

Product Dispose in accordance with all local, state/provincial and federal
regulations.
Contaminated packaging Consult state and local regulations regarding the proper disposal of
container.
Follow advice on product label and/or leaflet.

SECTION 14: TRANSPORT INFORMATION

According to national and international transport regulations this material is not classified as dangerous
goods / hazardous material.

SECTION 15: REGULATORY INFORMATION

PCP Registration No. 27933

PMRA Information:
Read the label, authorized under the Pest Control Products Act, prior to using or handling the pest control
product.

This chemical is a pest control product regulated by Health Canada Pest Management Regulatory Agency
and is subject to certain labelling requirements under the Pest Control Products Act. These requirements
differ from the classification criteria and hazard information required for GHS-consistent safety data
sheets. The following is the hazard information required on the pest control product label:
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ROUNDUP® ADVANCED™ READY-TO-USE 9/9

Version 1.0 / CDN Revision Date: 05/04/2021
102000057975 Print Date: 05/04/2021

Signal word: Warning!

Hazard statements: Corrosive

Causes eye irritation.

There are Canada-specific environmental requirements for handling, use, and disposal of this pest control
product that are indicated on the label.

SECTION 16: OTHER INFORMATION

Abbreviations and acronyms

49CFR Code of Federal Regulations, Title 49
ACGIH US. ACGIH Threshold Limit Values
ATE Acute toxicity estimate
CAS-Nr. Chemical Abstracts Service number
CERCLA Comprehensive Environmental Response, Compensation, and Liability Act
EINECS European inventory of existing commercial substances
ELINCS European list of notified chemical substances
IARC International Agency for Research on Cancer
IATA International Air Transport Association
IMDG International Maritime Dangerous Goods
N.O.S. Not otherwise specified
NTP US. National Toxicology Program (NTP) Report on Carcinogens
OECD Organization for Economic Co-operation and Development
TDG Transportation of Dangerous Goods
TWA Time weighted average
UN United Nations
WHO World health organisation
NFPA 704 (National Fire Protection Association):
Health - 1 Flammability - 0 Instability - 1 Others - none
HMIS (Hazardous Materials Identification System, based on the Third Edition Ratings Guide)
Health - 1 Flammability - 0 Physical Hazard - 1 PPE -
0 = minimal hazard, 1 = slight hazard, 2 = moderate hazard, 3 = severe hazard, 4 = extreme hazard

Reason for Revision: New Safety Data Sheet.

Revision Date: 05/04/2021

This information is provided in good faith but without express or implied warranty. The customer assumes
all responsibility for safety and use not in accordance with label instructions. The product names are
registered trademarks of Bayer.