Phy (Unit 6) (Notes)
Phy (Unit 6) (Notes)
Phy (Unit 6) (Notes)
Syllabus
Non-Destructive Testing
Classification of Non-destructive testing methods
Principles of physics in Non-destructive Testing
Advantages of Non-destructive testing methods
Acoustic Emission Testing
Ultrasonic (thickness measurement, flaw detection)
Radiography testing
Nanotechnology
Introduction to nanotechnology
Quantum confinement and surface to volume ratio
Properties of nanoparticles: optical, electrical, mechanical
Applications of nanoparticles: Medical (targeted drug delivery), electronics, space and
defense, automobile
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5 Electric or Exposing the tested objects to electric (i) Measuring parameters of the
non-electric disturbance (e.g. electrostatic field, composition and structure of a
NDTmethods constant AC or DC field) or non-electric material
disturbance (e.g. infrared, mechanical, etc.) (ii) Finding geometrical dimensions
of a tested object
(iii) Finding moisture level
6 Eddy-Current The interaction between an external Testing item dimensions,
NDTmethods electromagnetic field and the measuring the diameter of wire,
electromagnetic field induced in the test rods and pipes, thickness of metal
object. plates and that of pipe walls
In addition to these, other types of NDT methods are vibration analysis, leak testing
and integrated ones.
In all the NDT methods, due to probable presence of defects in the tested object, the nature
of external appl ied field changes.
Principle: A mechanical load or rapid temperature or pressure is applied to the material under test
and resulting stress waves generated are sensed by sensors.
Method:
A localized external force such as an
abrupt mechanical load or rapid
temperature or pressure is applied to
the part of the material being tested.
A small material displacement or
plastic deformation is produced inside
the material.
• This results into generation of stress waves inside the material in the form of short-lived,
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high frequency elastic waves.
These stress waves are detected by sensors that have been attached to the materi al.
The stress waves show discontinuities in the material where flaws or irregularities inside the
materials.
When multiple sensors are used, the resulting data can be analyzed by a CRO to evaluate
locate discontinuities in the part.
Applications:
AET is applied to inspect and monitor pipelines, pressure vessels, storage tanks, bridges,
aircraft, and bucket trucks, and a variety of composite and ceramic components.
It is also used in process control applications such as monitoring welding processes.
Principle: X-rays or y-rays are passed through the material. The radiations are partially absorbed and
partially scattered by the medium and partially by the defects. The characteristics of the radiations
such as intensity get modified .
Method:
X-rays or y-rays are produces by a source of radiation (e.g. EJ ...,. Source of
radiation
Coolidge tube in x-rays).
The material under investigation is placed in the path of the
radiation and the photographic plate. Film
The beam of radiation is allowed to fall on the material.
Depending on the thickness and absorption characteristics of
the material, some amount of radiation will be absorbed and
scattered.
Absorption of radiations is different in regions inside the
material where defect is present and that are free of defect.
~
D~ enedarea(when proces~ )
I
The scattered radiations produce an image on the photographic plate. After developing the
photographic plate and its analysis, the defects inside the material can be identified.
With a single radiogram the presence of defect can be detected.
For getting exact position of the defect, the radiation should be passed through different
angles in the material and resulting set of radiogram is analyzed.
Applications:
Using radiography techniques various irregularities inside the material such as flaw, Cracks, presence
of Cavities, Porosity can be detected.
I
Ultrasonic Waves
object and reflection is received.
By knowing the t ime required to cover distance (between f--------------Ec
ho (Ref~lection)
transmitter and object) and velocity, distance of the object
t - - - - d=~-------,
from the transmitter can be determined. 2
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(Velocity of the ultrasonic waves) x (time required for reflection)
Distance of the object=
2
Method:
• The testing mechanism mainly consists of a Transmitter/Receiver
transmitting transducer, receiving transducer
and CRO.
Transducer
• A transmitting transducer sends ultrasonic Init ial Pulse
waves into the specimen. Reflected signals Back surface
echo
from back surface of the specimen are Crack
echo
detected by receiving transducer and are
input to a CRO.
0 2 4 6 B 10 12 Met al Block
• If there are no flaws in the specimen, output
of CRO screen shows normal peaks. If there is any flaw present inside the specimen then
CRO screen shows small peaks corresponding to the reflection of ultrasonic waves from flaw.
Applications:
• This method is used to evaluate the properties of a material without causing damage to t he
material.
• Flaw detector detects the flaws like holes, casting, flakes, cracks, tiny cavities etc in metal
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Questions on Non-Destructive Testing
6 marks
1. What is non-destructive testing? State types of non-destructive testing. Explain ultrasonic
testing technique for flaw detection. [Dec 19, 6ml
2. What is NDT? Differentiate between destructive testing and NDT.
3/4 marks
1. What is echo sounding technique? Using this technique explain non-destructive testing of
flaw detection using ultrasonic waves.
2. What is echo sounding technique? Using this technique explain non-destructive testing for
measurement of thickness of a metal sheet or block using ultrasonic waves.
3. What is NDT? State advantages as compared with destructive testing.
4. Differentiate between destructive testing and non-destructive testing.
5. Explain in brief how Acoustic Emission Technique is used in non-destructive testing.
Dec 19, 3m]
6. Discuss in brief Radiography Testing and its applications.
7. Discuss in brief applications of ultrasonic waves in flaw detection
8. Discuss in brief applications of ultrasonic waves in thickness measurement
Numerical on - Ultrasonic
Formulae:
velocity of Ultrasonic x time
Distance/Thickness
2
Example: Find the echo time of ultrasonic pulse which is traveling with the velocity 3.lx103 m/s in
mild steel. The correct thickness measured by gauss meter is 9mm.
Solution:
Data: v = 3.1x1O 3 m/s, t = 9 mm = 9x1O-3 m
velocity of Ultrasonic x time
Thickness =
2
. _ Thickness x2 9 x 10- 3 x 2 _ _ _
Time - . - 5.8 x 10 6 s - 5.8 µs
Ve1oc1ty 3.1 X 103
Example: An ultrasonic pulse of frequency 130 kHz is sent through a block of steel. The echo pulse is
received after 1. 695 microseconds. If velocity of ultrasonic wave in steel is 5900 m/s, calculate the
thickness of the steel block and the wavelength of the pulse. {Dec 19, 4m]
Solution: Data : v = 5900 m/s, t = 1.695 µs
6
Th1c ness o f t h e bl ock = -v xt = -
. k 5900xl.695x10-
- - - - - = O.005 = O.5 cm
2 2
5900
As v=fxA, Velocity of ultrasonic pulse, ,1, = ~ = = 0.045 m = 4.5 cm
f 130Xl0 3
Example: An ultrasonic pulse is sent through a block of steel. The echo is recorded after 1.512
microseconds. Calculate the thickness of the steel block and the wavelength of the pulse if the
frequency of ultrasonic pulse is 100 kHz and velocity of ultrasonic in steel is 5900 m/s.
Solution: Data : v = 5900 m/s, t = 1.512 µs
. V Xt 5900Xl.512Xl0-6 -3
Thickness of the block= - - = = 4.46 x 10 m = 0.446 cm
2 2
5900
As v=fxA, Velocity of ultrasonic pulse, ,1, = ~ = = 0.059 m = 5.9 cm
f 100X103
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Example: An ultrasonic pulse is sent through a copper block and echo is recorded after 4µs. If velocity
of ultrasonic waves in that metal is 5000 m/s, calculate the thickness of the copper block. At another
location in same block echo is recorded after 1.253µs. What is the location of flaw? [Dec 19, 4ml
Solution: Data : v =5000 m/s, t =4 µs
V X t 5000 X 4 X 10-6
Thickness of the block= - - = = 0.01 m = 1 cm
2 2
V X t 5000 X 1.253 X 10- 6
Location of flaw= - - = = 0.00313 m = 0.313 cm
2 2
Thus, the flaw is located at 0.313 cm from the top surface
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Unit 6: Nanotechnology
Quantum confinement: A bulk material or solid has three dimensions. If only one length of three-
dimensional nanostructure is in nanoscale (1-100 nm), the structure is known as a quantum well.
Instead if two sides are of nanoscale (1-100 nm), the resulting structure is known as quantum wire.
A nanoparticle is often referred to as a quantum dot as its all three dimensions are in the nanoscale
(1-100 nm).
Surface to volume ratio: As the size of materials approaches nanoscale, the percentage of atoms
at the surface of a material becomes significant. Nanoparticles have a very high surface area to
volume ratio.
surface area
volume
(m·•)
4/3 nr3
3/r
Many properties of solids such as optical, electrical, mechanical, etc depend on its size. As compared
to its bulk form, properties of materials change when at least one of the dimensions of material is
reduced to naosclale (1-100 nm), mainly due to following reasons:
(i) Upon reaching quantum confinement at nanoscale energy levels of nanoparticles become
discrete (as shown in the figure) . This increases or widens up the band gap and the band gap
energy. This results into change in the properties of material at nanoscale.
(ii) Nanoparticles have a relatively larger surface area when compared to its bulk form. Th is makes
the nanoparticles more chemically reactive compared to bulk form and it thus modifies its
properties.
(iii) Physical properties of materials such as electrical are characterized by the mean free path
(path of the electron collision due to atoms or ions). This mean free path changes at
nanoscale.
(iv) Bulk properties of materials such as hardness changes at nanoscale. Nanoparticles are much
harder and tougher as compared to their bulk form.
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6.2.3 Optical properties of Nanoparticles
I= ! 0 e-µ x
Where,
µ = !::!..V Cext is extinction coefficient ----- x ----➔
Length of the medium
N is number of particles in medium,
V- Volume of colloidal particles
Cext - extinction cross section of a particle
At nanoscale, as size of the nanoparticles change, there is change in the length of medium
and thus the values ofµ and x changes.
This changes the intensity of transmitted light and it depends on the wavelength of incident
light.
This changes the color of nanoparticles at different nanoscale region.
Mie theory successfully explained absorption of light of visible wavelength for nano-
particles, but for particle size less than ~10 nm, there is need to consider dielectric constant
which depends also on particle size.
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6.2.3 Electrical properties of Nanoparticles
Electrical properties are characterized by the mean free path of electron (path of the electron
collision due to atoms or ions). The mean free path changes at nanoscale due to collision and
tunneling within the conductor.
1-V Characteristics of bulk conductor: When voltage V is applied across the conductor, cu rrent I
flowing through it is governed by Ohm's Law and has a linear variation.
I Coulomb Staircase
I
Coulomb Blockadge
\
1-V Characteristics at nanoscale: If dimensions of conductor are in nanoscale (1-100 nm), there
appears a region around zero voltage for which there is no current. A single electron is tra nsferred
by tunneling when the voltage is ± e/2C. Therefore, when the voltage is less than t his electro n
cannot be transferred. This gives a region of zero current at low bias voltage and is known as
'Coulomb blockade region'. The electrons are transferred when the voltage is ± e/2C. The repeated
tunneling of single electron produces 'Coulomb staircase'.
Electrical resistivity: The materials of nano-sized grains have larger number of grain boundaries than
corresponding polycrystalline materials. Electrical resistivity of materials having nano-sized grain is
larger than the polycrystalline materials due to scattering of electrons at grain boundaries.
strongly differ from that of polycrystalline bulk material i.e. if stress is removed the recovery to
original shape/size is recovered more effectively.
Hardness of materials is also related to the grain size. In the nanometer size ra nge, t he hardness
increases with decrease of particle size. (Shown in figure for copper)
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6.2.4.1 Applications in medicine (targeted drug delivery)
The traditional drug delivery system, the drug is distributed to the affected tissues or organs
of the patient's body as well as to the healthy tissues or organs. This leads to the side
effects.
In the targeted drug delivery system, the drug is dissolved, entrapped, encapsulated or
attached to a nano particle. The system is then embedded in a capsule which is guided
towards the affected part of the body.
The capsule is opening at the specific tissues or organs controlled by externally applied
magnetic field or infrared light or physiologically. Then drug can be delivered in controlled
manner.
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5. Nanophotonics
In nanophotonics, nanostructures (quantum dots, nanowires or 2-D thin films) or
nanocomposites are used to produce light or detect light. They can be used for light
production, propagation, manipulation like amplification, filter, detection etc.
6. Display technologies for TV and monitor
The flat panel television or computer monitors are products of nanotechnology. Even the
coatings used on screens of TV or monitors can be of nanoparticles, which have better
properties in terms of color quality and resolution than micro particle coatings.
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3. Self cleaning glass for windows
Self cleaning glass can be made by dissolving small amount of titania (TiO2) nanoparticles
while manufacturing glass. Titania is able to dissociate organic dust in presence of UV light
available in the sunlight. Drops of waters on glass give hazy look, but TiO2-containing glass
can spread water evenly giving clear sight.
4. Small motor parts
Small motors are needed in vehicle (such as wipers, window glass movements, etc). Very
powerful electric motors are made using shape memory alloys using nanoparticles of
materials like Ni-Ti. They require less power and gives better performance.
5. Better tires
Tires of vehicles undergo wear and tear with use and also increase its weight. By using
nanoparticle clay, better, light weight, less rubber consuming thinner tires are possible that
can reduce the overall weight, increase in fuel consumption and speed.
6. Controlling harmful emission
Use of efficient nanomaterial catalysts is one solution to convert harmful emission into less
harmful gases. Large surface area of nanoparticles is useful to produce better catalysts. They
are capable of absorbing emission of particles and poisonous gases like CO and NO from
vehicle exhausts.
7. Hydrogen fuel
Instead of using conventional petro fuels, there are numerous advantages of using hydrogen
as a fuel. When hydrogen fuel is burned it can only produce harmless water vapor. Hydrogen
gas is normally stored in a metal cylinder under high pressure. Nanocylinders of carbon
nanotubes have potential to store hydrogen in very small space.
Questions on Nanotechnology
6 Marks
1. What is nanotechnology? Explain quantum confinement and surface to volume ratio in case
of nanoparticles. How this affects the properties of nanoparticles?
2. Explain electrical and mechanical properties of nanoparticles. {Dec 19, 6m]
3. What is nanotechnology? Explain any two properties of nanoparticles.
4. What are applications of nanotechnology? Explain any two applications of nanoparticles.
3/4 Marks
1. What is nanotechnology? Explain applications of nanotechnology in electron ics field .
[Dec 19, 4m)
What is quantum confinement? How does it affects the properties of nanoparticles?
{Dec 19, 3m]
2. Explain optical properties of nanoparticles.
3. Explain electrical properties of nanoparticles.
4. Explain mechanical properties of nanoparticles.
5. What are applications of nanotechnology? Explain any one application of nanoparticles.
Explain how nanotechnology is employed in targeted drug delivery. [Dec 19, 4ml
6. Explain applications of nanoparticles in automobiles.
7. Explain applications of nanoparticles in the field of space and defense.
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