Bezinal Belgo 2021 Metallic Coatings Betafence Meeting V3

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Bekaert metallic coatings

Betafence / Praesidiad meeting


2021/03
Bart Allaert
Confidentiality

This document remains the exclusive property of NV Bekaert SA.


Communication thereof is wholly confidential and does not extend beyond the technical staff of the
addressee, who is not authorized to duplicate this document nor to make known to a third party any
contents thereof.
NV Bekaert SA is exclusively entitled to apply for a patent for any patentable element contained in this
document.
NV Bekaert SA disclaims all liability which may arise out of the putting into use of the information
contained in this document, provided it did not assume control thereof. It also disclaims all liability for
infringements of industrial property rights which may arise out of the putting into use of the information
contained in this document.
All the information contained in this document is based on reasonable research, but does not
guarantee any result.

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Bekaert metallic coatings (end coated)
- Zinc
▪ Standard galvanizing protection

- Bezinal
▪ Zn-5%Al
▪ ~ 35 years experience, standard advanced product
▪ Improved formability (no alloy layer cracks), and improved corrosion performance proven in many set-ups

- Bezinal 2000
▪ Zn-10%Al
▪ ~ + 15 years experience
▪ Best formability and improved corrosion performance in several set-ups compared to Bezinal

- Bezinal 3000
▪ Zn-5%Al-Mg
▪ ~ +10 years experience
▪ Challenging in formability but superior in salt spray test even compared to Bezinal 2000.
▪ (note the difference with Magnelis that has a 10-fold higher Mg content and not (yet) feasible on wire due to formability
issues)

4 Strictly Confidential
Salt Spray performance

Salt Spray test: ISO 9227 : Continuous neutral 5% NaCl spray


- Bezinal outperforms Zinc in salt spray: times 3 and more

- Bezinal 2000 still outperforms Bezinal in salt spray ….


▪ 3000 hours for class A coated wire

- Bezinal 3000 even outperforms Bezinal 2000 (currently not in Bohumin plant)

Note all these values (from ‘active corrosion flyer’) are conservative, minimum values
5 easy to be used as rule of thumb. Most products in practice strongly outperform
Bekaert restricted information
Kesternich performance

Kesternich test: ISO 6988 (0,2 L SO2 per day)

- Bezinal outperforms Zinc in Kesternich performance: times 3

- Bezinal 2000 still outperforms Bezinal in Kesternich….


▪ Times 2 compared to Bezinal

6 Confidential
Weldability

Bezinal and Bezinal 2000 coated wires have a stronger performance in welding
compared to Zinc coated wires

- FeZn intermetallic layers for Zinc coatings have melting temperatures


lower than 800°C < Welding temperatures : Susceptible to corrosion

- FeAl3 and Fe2Al5 intermetallic layers of Bezinal and Bezinal 2000 have
melting points higher than 1150°C > Welding temperatures…. : Not
susceptible to corrosion

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Bending

- Bending of coating can lead to cracks.


▪ Zinc coatings have a very hard and brittle intermetallic layer or FeZn compounds (~ 250 µVickers)
compared to Bezinal and Bezinal 2000 coatings.
▪ Optical microscopy of the bends shows cracks in the intermetallic layers of Zinc after bending
▪ These cracks in the alloy layer can in some cases propagate to the surface and lead to cracking and
flaking at the top surface

- For the End Coated products Bezinal 2000 results in the best formability.

8 Strictly Confidential
Formability/ductility of Zn-5%Al: CRACKING

GI = Hot Dip Galvanized Zinc

Galfan = Zinc-5% Al coating = Bezinal

Zn-Al-Mg Alloy coatings: thermodynamic analysis and microstructure related properties ; Evy De Bruycker ; 2005
9 – Property of Bekaert- Bart Allaert
Bekaert formability on Wire: Powdering and flaking

❑ Tool contamination after production of 1050


springs → Mechanical defects
Bezinal 2000 is the preferred coating compared
to Zinc

Hot Dip Galvanized Zn-


Hot Dip Galvanized Zn
Al: Bezinal

10 – Property of Bekaert- Bart Allaert


Performance of coatings in aggressive atmospheric corrosion site

▪ Performance in aggressive atmospheric exposure site near a steel plant and near the sea
• Superior performance of Bezinal 2000 coating

Site near sea Wire pictures


after 3 years

Zn coating (79 g/m 2)


rusted after year 2

Bezinal
Zn
2000
Bezinal

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Performance in sea / ocean water

▪ Daily refreshed ocean water exposure performed in French Corrosion Institute


• + 2 years exposure shows superior performance of Bezinal 2000 without any red rust
‒ Zinc coated wires broken after 16-17 months

Wires submerged in daily


refreshed ocean water

12 Strictly Confidential
Performance of coatings in Ammonia

▪ Animal excrements create ammonia vapors which are aggressive towards the metallic coatings
• 2000 hours experiment in ammonia vapor shows superior performance of Bezinal 2000 coating

Zn Zn-5%Al Bezinal
2000

13 Strictly Confidential
Performance of coatings in soil

▪ ▪Wires
DD being in contact with soil
• 3 years experiment in loam soil shows superior performance of Bezinal 2000 coating

Wires buried in soil for long


term exposure

Bezinal
Zn Zn-5%Al 2000

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Gabions from the field

- In long term exposures of 15-20 years in contact with weathering and soil Bezinal coated welded
gabions from the field are strongly outperforming Zinc coated gabions.
▪ Remaining coating weight in graph 1 (gravimetrical): Much higher for Bezinal
▪ Optical Microscopy show also picture of remaining coating weight.

Soil
Soil

Zinc

Bezinal
Zinc Bezinal
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Performance in gabion application

▪ Proven experience in gabion industry


• Welded Bezinal 2000 coatings used in gabion industry analyzed after 15 years exposure in gabion applications
show excellent performance with no rust and high retained coating weights after those 15 years.
‒ Exposures started soon after the industrial introduction of Bezinal® 2000

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Bezinal® 5000

Latest Bekaert development !!!

Bezinal® 5000 state of the art for Gabions.


‒ Adjustment on the Bezinal® 2000 technology reaching 5000 hours on salt spray (ISO 9227)
‒ Always with the minimum 350 g/m2 coating weight !

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Duscussion

▪ …

18 Strictly Confidential

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