Imaje S.A.

SH-8188-C of 11 March 2008

Safety Data Sheet page 1/6

This information relates only to the specific material designated and may not be valid for such material used in combination with any other
materials or in any process. Such information is to the best of Imaje S.A. company’s knowledge and believed accurate and reliable as of the
date indicated. It is the user’s responsibility to satisfy himself as to the suitability and completeness of such information for his own particular
use. Finally, it remains the responsibility of the customer to provide a safe workplace and to comply with all applicable laws and regulations.

This safety data sheet is in accordance with Regulation (EC*) No. 1907/2006 and keeps in accordance with International Standard ISO* 11014-
1 (except for the order of the headings 2 and 3).

The changed headings in comparison with a previous version, if appropriate, are indicated with the symbol # in the left margin.

# 1. PRODUCT AND COMPANY IDENTIFICATION

1.1. IDENTIFICATION OF THE PRODUCT

Product name: 8188

Chemical family: ketone-based make-up
Former name: not applicable

1.2. COMPANY IDENTIFICATION

Head office: Supplier:

(if different from Imaje S.A.)
Imaje S.A.
9, rue Gaspard Monge - BP 110
26501 Bourg-lès-Valence cedex
France
Tel.: (33) 4 75 75 55 00 - Fax: (33) 4 75 82 98 10
http://www.imaje.com
E-mail: sds@fr.imaje.com

1.3. EMERGENCY TELEPHONE NUMBERS

Imaje S.A.: (33) 4 75 75 55 00

INRS* (Orfila): (33) 1 45 42 59 59

# 2. HAZARDS IDENTIFICATION

2.1. ADVERSE HUMAN HEALTH AND ENVIRONMENTAL EFFECTS

Irritating to eyes.
Repeated exposure may cause skin dryness or cracking.
Vapours may cause drowsiness and dizziness.

2.2. PHYSICAL AND CHEMICAL HAZARDS

Highly flammable.
Leaks of gas or spills of liquid can readily form flammable mixtures at temperatures at or above the flash point.

See also heading 11 “TOXICOLOGICAL INFORMATION”.

# 3. COMPOSITION / INFORMATION ON INGREDIENTS

Product: preparation

Hazardous CAS* EINECS* Index No. % Symbol(s) Nature of special risks

component No. No. (weight)

Butanone 78-93-3 201-159-0 606-002-00-3 > 90 F - Xi Highly flammable

Irritating to eyes
Repeated exposure may cause skin dryness or cracking
Vapours may cause drowsiness and dizziness

Reference: 8188

Designation: MAKE-UP

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The unlisted components are not considered to be hazardous according to amended Directive 67/548/EEC*.

4. FIRST-AID MEASURES

4.1. INHALATION

Using proper respiratory protection, immediately remove the affected victim from exposure. Administer artificial respiration if
breathing is stopped. Keep at rest. Call for prompt medical attention.

4.2. SKIN CONTACT

Flush with large amounts of water; use soap if available. Remove grossly contaminated clothing, including shoes, and launder
before reuse. Consult a doctor, if irritation persists.

4.3. EYE CONTACT

Immediately flush eyes with large amounts of water for at least 15 minutes. Get prompt medical attention.

4.4. INGESTION

If swallowed, do not induce vomiting. Keep at rest. Get prompt medical attention.

See also heading 8 “EXPOSURE CONTROLS / PERSONAL PROTECTION”.

5. FIRE-FIGHTING MEASURES

Use water spray to cool fire exposed surfaces and to protect personnel. Shut off “fuel” to fire. If a leak or spill has not ignited,
use water spray to disperse the vapours and to protect men attempting to stop a leak. Either allow fire to burn under controlled
conditions or extinguish with alcohol type foam or dry chemical extinguishers. Try to cover liquid spills with foam.
Do not use water extinguisher in case of printer fire.

See also heading 10 “STABILITY AND REACTIVITY”.

6. ACCIDENTAL RELEASE MEASURES

Eliminate sources of ignition. Warn occupants of downwind areas of fire and explosion hazard. Prevent liquid from entering
sewers, watercourses or low areas. Keep public away. Shut off source if possible to do so without hazard. Advise authorities if
product has entered a watercourse or sewer or has contaminated soil or vegetation. Take measures to minimize the effect on
the ground water. Contain spilled liquid with sand or earth. Dilute contained spill with water. Recover by pumping (use an
explosion-proof or hand pump) or with a suitable absorbent. If liquid is too viscous for pumping, scrape up with shovels or pails
and place in suitable containers for recycle or disposal. Consult an expert on disposal of recovered material and ensure
conformity to local disposal regulations.

See also heading 13 “DISPOSAL CONSIDERATIONS”.

7. HANDLING AND STORAGE

7.1. HANDLING

Handle containers with care. Open slowly in order to control possible pressure release. Do not handle or open near an open
flame, sources of heat or sources of ignition. Do not pressurize, cut, heat or weld containers. Empty product containers may
contain product residue. Do not reuse empty containers without commercial cleaning or reconditioning. Container remains
hazardous when empty. Continue to observe all precautions.

7.2. STORAGE

Keep container closed. Store in a cool, well-ventilated place away from incompatible materials. Do not store near an open
flame, sources of heat or sources of ignition. Protect material from direct sunlight. The floor of the premises must be
incombustible, impermeable and act like a reservoir so that in case of breaking, liquid will not spill outside.
Keep product in its original packaging.
Storage temperature: < 35 °C (95 °F).

See also heading 8 “EXPOSURE CONTROLS / PERSONAL PROTECTION”.

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8. EXPOSURE CONTROLS / PERSONAL PROTECTION

8.1. ENGINEERING MEASURES

The use of mechanical dilution ventilation is recommended whenever this product is used in a confined space, is heated above
ambient temperature or otherwise to maintain ambient concentration below the recommended threshold exposure limits. Use
explosion-proof ventilation equipment.

8.2. CONTROL PARAMETERS

European Community:

Limit value (8 hours) Limit value (short-term)

Butanone 200 ppm (600 mg/m3) 300 ppm (900 mg/m 3)

USA:

TLV*/TWA* TLV*/STEL*
Butanone 200 ppm (590 mg/m3) 300 ppm (885 mg/m 3)

8.3. PERSONAL PROTECTIVE EQUIPMENT

Respiratory protection:

Where concentrations in air may exceed the limits given in this section, it is recommended to use a half face filter mask to
protect from overexposure by inhalation.

Hand protection:

When handling this product, it is recommended to wear chemical resistant gloves (butyl rubber). Gloves should be replaced
immediately if sign of degradation is observed.

Eye protection:

When handling this product, it is recommended to wear splash resistant goggles.

Allow a washing solution for the eyes.

9. PHYSICAL AND CHEMICAL PROPERTIES

Physical state and colour: mauve liquid

Odour: ketone
pH (at 20 °C (68 °F)): not applicable
Melting point: < - 85 °C (- 121 °F)
Boiling point: > 75 °C (167 °F)
Flash point (in a closed cup): about - 9 °C (16 °F)
Autoignition temperature: > 500 °C (932 °F)
Explosion properties (volume % in air): 1.8 < < 11.5
Vapour pressure: 13.3 kPa at 25 °C (77 °F) (butanone)
Vapour density (/ air): >1
Density (at 20 °C (68 °F)): 0.80 < < 0.81
Water solubility: partial
n-octanol / water partition coefficient (log P(o/w)): 0.26 (butanone)

Nota: the flash point of the preparation has not been determined. The flash point indicated is the one of the solvent with the
lowest value.

10. STABILITY AND REACTIVITY

Stability: stable
Hazardous polymerization: no
Hazardous reactions with (incompatibility): strong oxidizing agents
Hazardous decomposition products: none

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11. TOXICOLOGICAL INFORMATION

11.1. ACUTE TOXICITY

Inhalation:

Vapour concentrations above recommended exposure levels may be irritating to the eyes and the respiratory tract, may cause
headaches and dizziness, could be anaesthetic and may have other central nervous system effects.

LC50* (rat, 4 hours) > 9000 ppm (butanone)

Skin contact:

Frequent or prolonged contact may defat and dry the skin, leading to discomfort and dermatitis.

LD50* (rabbit) = 13 g/kg (butanone)

Eye contact:

Irritating and will injure eye tissue if not removed promptly.

Ingestion:

Small amounts of liquid aspirated into the respiratory system during ingestion or from vomiting may cause bronchopneumonia or
pulmonary oedema.

LD50* (rat) = 3000 mg/kg (butanone)

11.2. CHRONIC TOXICITY

There is no evidence that exposure to butanone alone causes progressive or irreversible neurotoxic effects. However,
simultaneous over-exposure to butanone and n-hexane can potentiate the known irreversible effects of n-hexane.

11.3. OTHER INFORMATION

Avoid exposure for pregnant women.

12. ECOLOGICAL INFORMATION

12.1. BUTANONE

WGK* 1

Mobility:

This substance is relatively volatile.

Degradability:

Readily biodegradable.

Ecotoxicity:

LC50* (fishes, 96 hours) = 4600 mg/l

EC 50* (daphnia, 48 hours) = 7060 mg/l
EC 50* (bacteria, 16 hours) = 1150 mg/l

13. DISPOSAL CONSIDERATIONS

Empty containers should be taken for recycling, recovery or disposal through a suitably qualified or licensed contractor. This
product is not suitable for disposal by either landfill or via municipal sewers, drains, natural streams or rivers. This product can
be burned directly in appropriate equipment.
Care should in any case be taken to ensure compliance with national and local regulations.

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# 14. TRANSPORT INFORMATION

14.1. LAND (ADR*)

Name of substance: methyl ethyl ketone

UN* Class Classification Packing Label(s) Special Limited Packaging

No. code group provisions quantities Instructions Special Mixed packing
provisions provisions
1193 3 F1 II 3 LQ4 P001 / MP19
IBC02 /
R001

Transport Special provisions for carriage Hazard identification

category Packages Loading, unloading and handling Operation No.
2 S2 / S20 33

Total exemption: 3 L per inner packaging and 30 kg gross per package

Partial exemption: 333 L

14.2. SEA (IMDG* CODE)

Proper shipping name: methyl ethyl ketone

UN* Class Subsidiary Packing Special Limited Packing / IBC* Emergency schedule Stowage and
No. risk(s) group provisions quantities Instructions Provisions No. segregation
1193 3 - II - 1L P001 / IBC02 - / - F-E, S-D Category B

Marine pollutant: no

14.3. AIR (IATA* REGULATIONS)

Proper shipping name: methyl ethyl ketone

UN* Class Subsidiary Hazard Packing Passenger and cargo aircraft Cargo aircraft only Special ERG*
No. risk(s) label(s) group Packing Maxi net Packing Maxi net provisions code
instructions quantity / instructions quantity /
package package
1193 3 - 3 II Y305 / 305 1 L / 5 L 307 60 L - 3L

15. REGULATORY INFORMATION

15.1. EUROPEAN COMMUNITY

Governing Directives: amended Directive 67/548/EEC* (dangerous substances) and amended Directive 1999/45/EC*
(dangerous preparations)

Label name: 8188

Symbols and indications of danger:

F: Highly Xi: Irritant

flammable

Nature of special risks:

R11: Highly flammable

R36: Irritating to eyes
R66: Repeated exposure may cause skin dryness or cracking
R67: Vapours may cause drowsiness and dizziness

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Safety advice:

S9: Keep container in a well-ventilated place

S16: Keep away from sources of ignition – No smoking

15.2. USA

NFPA* Butanone
Health 1
Flammability 3
Reactivity 0

In the USA, the hazardous components of this product are mentioned in the following lists:
1F: Toxic Substance Control Act (TSCA) Section 8(d) Health and Safety Data Reporting Rule Substances
5B: Clean Air Act Section 111 Volatile Organic Compounds
5D: Clean Air Act Section 112 Statutory Air Pollutants (1990 Amendments)
6: National Institute for Occupational Safety and Health (NIOSH) Recommendation Substances
7A: Resource Conservation and Recovery Act (RCRA) Hazardous Substances
7B: RCRA Hazardous Constituents for Groundwater Monitoring
8A: Comprehensive Environmental Response, Compensation, and Liability Act (CERCLA) Hazardous Substances
8C: Superfund Amendments and Reauthorization Act (SARA) Title III Section 313 Toxic Chemicals
8D: SARA Title III Section 110 Priority List of CERCLA Hazardous Substances
9A: Occupational Safety and Health Administration (OSHA) Air Contaminants (Tables Z1, Z2 and Z3)
9D: American Council of Governmental Industrial Hygienists (ACGIH) Threshold Limit Value (TLV) Chemicals
9H: OSHA Table Z-1-A [revoked]
11B: Drug Enforcement Administration (DEA) Precursor and Essential Chemicals - Essential chemical
13A: Department of Transportation (DOT) Hazardous Materials
13B: DOT Hazardous Substances Other Than Radionuclides; and Radionuclides
MA1: Massachusetts Substance List
NJ1: New Jersey Right To Know Hazardous Substance List
PA1E: Pennsylvania Hazardous Substance List - Environmental hazard

In Canada, the hazardous components of this product are mentioned in the following lists:
CN1: Canadian Workplace Hazardous Materials Information System (WHMIS) Ingredient Disclosure List - Ingredient must be
disclosed at concentration of 1 %

The user of the product must refer to official regulations concerning his obligations.

# 16. OTHER INFORMATION

Abbreviations:

EC: European Community

ISO: International Organization for Standardization
INRS: Institut national de recherche et de sécurité
CAS: Chemical Abstracts Service
EINECS: European inventory of existing commercial chemical substances
EEC: European Economic Community
TLV: Threshold limit value
TWA: Time weighted average
STEL: Short-term exposure limit
LC50: Lethal concentration 50%
LD50: Lethal dose 50%
WGK: Wassergefährdungsklasse
EC 50: Effect concentration 50%
ADR: European Agreement concerning the international carriage of dangerous goods by road
UN: United Nations
IMDG: International Maritime Dangerous Goods
IBC: Intermediate bulk container
IATA: International Air Transport Association
ERG: Emergency Response Drill
NFPA: National Fire Protection Association

SH-8188-C