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Safety Data Sheet

acc. to OSHA HCS
Printing date 09/22/2016 Reviewed on 09/22/2016

1 Identification
· Product identifer
· Trade name: POLYFLEX 411B BLACK
· Article number: WP411B.79
· Details of the supplier of the safety data sheet
· Manufacturer/Supplier:
Wasser Corporation
4118 B PL NW, Suite B
Auburn, WA 98001, US
Phone 253-850-2967
· Information department: Product safety department
· Emergency telephone number:
EMERGENCY PHONE NUMBERS:
USA and Canada: 1-800 424-9300

2 Hazard(s) identification
· Classification of the substance or mixture
Acute Tox. 4 H302 Harmful if swallowed.
Skin Corr. 1C H314 Causes severe skin burns and eye damage.
Eye Dam. 1 H318 Causes serious eye damage.
Skin Sens. 1 H317 May cause an allergic skin reaction.
Carc. 2 H351 Suspected of causing cancer.
STOT SE 3 H335 May cause respiratory irritation.
STOT RE 2 H373 May cause damage to organs through prolonged or repeated exposure.
· Label elements
· GHS label elements The product is classified and labeled according to the Globally Harmonized System (GHS).
· Hazard pictograms

d
~
d d
~ 
~
GHS05 GHS07 GHS08

· Signal word Danger

· Hazard-determining components of labeling:
Polyoxyalkyleneamine
tetraethyl-N,N'-(methylenedicyclohexane-4,1-diyl)bis-DL-aspartate
diethylmethylbenzenediamine
diethyl fumarate
· Hazard statements
H302 Harmful if swallowed.
H314 Causes severe skin burns and eye damage.
H317 May cause an allergic skin reaction.
H351 Suspected of causing cancer.
H335 May cause respiratory irritation.
H373 May cause damage to organs through prolonged or repeated exposure.
· Precautionary statements
Keep out of reach from children.
P260 Do not breathe dusts or mists.
(Contd. on page 2)
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(Contd. of page 1)
P280 Wear protective gloves.
P280 Wear eye protection / face protection.
P264 Wash thoroughly after handling.
P270 Do not eat, drink or smoke when using this product.
P271 Use only outdoors or in a well-ventilated area.
P272 Contaminated work clothing must not be allowed out of the workplace.
P201 Obtain special instructions before use.
P202 Do not handle until all safety precautions have been read and understood.
P303+P361+P353 If on skin (or hair): Take off immediately all contaminated clothing. Rinse skin with water/
shower.
P305+P351+P338 If in eyes: Rinse cautiously with water for several minutes. Remove contact lenses, if present
and easy to do. Continue rinsing.
P310 Immediately call a POISON CENTER/doctor.
P321 Specific treatment (see on this label).
P301+P312 IF SWALLOWED: Call a POISON CENTER/doctor if you feel unwell.
P304+P340 IF INHALED: Remove person to fresh air and keep comfortable for breathing.
P363 Wash contaminated clothing before reuse.
P308+P313 IF exposed or concerned: Get medical advice/attention.
P333+P313 If skin irritation or rash occurs: Get medical advice/attention.
P301+P330+P331 If swallowed: Rinse mouth. Do NOT induce vomiting.
P314 Get medical advice/attention if you feel unwell.
P405 Store locked up.
P403+P233 Store in a well-ventilated place. Keep container tightly closed.
P501 Dispose of contents/container in accordance with local/regional/national/international
regulations.
· Classification system:
· NFPA ratings (scale 0 - 4)
Health = 3
1 Fire = 1
3 0 Reactivity = 0
· HMIS-ratings (scale 0 - 4)
HEALTH *3 Health = *3
FIRE 1 Fire = 1
REACTIVITY 0 Reactivity = 0

· Other hazards
· Results of PBT and vPvB assessment
· PBT: Not applicable.
· vPvB: Not applicable.

3 Composition/information on ingredients
· Chemical characterization: Mixtures
· Description: Mixture of the substances listed below with nonhazardous additions.
· Dangerous components:
9046-10-0 Polyoxyalkyleneamine 30-60%%
136210-30-5 tetraethyl-N,N'-(methylenedicyclohexane-4,1-diyl)bis-DL-aspartate 30-60%%
68479-98-1 diethylmethylbenzenediamine 5-10%%
623-91-6 diethyl fumarate 1-5%%
(Contd. on page 3)
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Trade name: POLYFLEX 411B BLACK

(Contd. of page 2)
1333-86-4 Carbon black 0.1-1%%

4 First-aid measures
· Description of first aid measures
· General information:
Immediately remove any clothing soiled by the product.
Symptoms of poisoning may even occur after several hours; therefore medical observation for at least 48 hours
after the accident.
· After inhalation:
Supply fresh air and to be sure call for a doctor.
In case of unconsciousness place patient stably in side position for transportation.
· After skin contact: Immediately wash with water and soap and rinse thoroughly.
· After eye contact: Rinse opened eye for several minutes under running water. Then consult a doctor.
· After swallowing: Immediately call a doctor.
· Information for doctor:
· Most important symptoms and effects, both acute and delayed No further relevant information available.
· Indication of any immediate medical attention and special treatment needed
No further relevant information available.

5 Fire-fighting measures
· Extinguishing media
· Suitable extinguishing agents: Use fire fighting measures that suit the environment.
· Special hazards arising from the substance or mixture
During heating or in case of fire poisonous gases are produced.
· Advice for firefighters
· Protective equipment: Mouth respiratory protective device.

6 Accidental release measures

· Personal precautions, protective equipment and emergency procedures
Mount respiratory protective device.
Wear protective equipment. Keep unprotected persons away.
· Environmental precautions: Do not allow to enter sewers/ surface or ground water.
· Methods and material for containment and cleaning up:
Use neutralizing agent.
Dispose contaminated material as waste according to item 13.
Ensure adequate ventilation.
· Reference to other sections
See Section 7 for information on safe handling.
See Section 8 for information on personal protection equipment.
See Section 13 for disposal information.

7 Handling and storage

· Handling:
· Precautions for safe handling
Thorough dedusting.
Ensure good ventilation/exhaustion at the workplace.
(Contd. on page 4)
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(Contd. of page 3)
Open and handle receptacle with care.
· Information about protection against explosions and fires: Keep respiratory protective device available.
· Conditions for safe storage, including any incompatibilities
· Storage:
· Requirements to be met by storerooms and receptacles: No special requirements.
· Information about storage in one common storage facility: Not required.
· Further information about storage conditions: Keep receptacle tightly sealed.
· Specific end use(s) No further relevant information available.

8 Exposure controls/personal protection

· Additional information about design of technical systems: No further data; see item 7.
· Control parameters
· Components with limit values that require monitoring at the workplace:
The following constituent is the only constituent of the product which has a PEL, TLV or other recommended
exposure limit.
At this time, the other constituents have no known exposure limits.
1333-86-4 Carbon black
PEL Long-term value: 3.5 mg/m³
REL Long-term value: 3.5* mg/m³
*0.1 in presence of PAHs;See Pocket Guide Apps.A+C
TLV Long-term value: 3* mg/m³
*inhalable fraction
· Additional information: The lists that were valid during the creation were used as basis.
· Exposure controls
· Personal protective equipment:
· General protective and hygienic measures:
Keep away from foodstuffs, beverages and feed.
Immediately remove all soiled and contaminated clothing.
Wash hands before breaks and at the end of work.
Store protective clothing separately.
Avoid contact with the eyes.
Avoid contact with the eyes and skin.
· Breathing equipment:
In case of brief exposure or low pollution use respiratory filter device. In case of intensive or longer exposure use
respiratory protective device that is independent of circulating air.
· Protection of hands:

S
_ Protective gloves

The glove material has to be impermeable and resistant to the product/ the substance/ the preparation.
Due to missing tests no recommendation to the glove material can be given for the product/ the preparation/ the
chemical mixture.
Selection of the glove material on consideration of the penetration times, rates of diffusion and the degradation
· Material of gloves
The selection of the suitable gloves does not only depend on the material, but also on further marks of quality and
varies from manufacturer to manufacturer. As the product is a preparation of several substances, the resistance of
the glove material can not be calculated in advance and has therefore to be checked prior to the application.
(Contd. on page 5)
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(Contd. of page 4)
· Penetration time of glove material
The exact break through time has to be found out by the manufacturer of the protective gloves and has to be
observed.
· Eye protection:

R
_ Tightly sealed goggles

9 Physical and chemical properties

· Information on basic physical and chemical properties
· General Information
· Appearance:
Form: Fluid
Color: Black
· Odor: Light
· Odor threshold: Not determined.
· pH-value: Not applicable.
· Change in condition
Melting point/Melting range: Undetermined.
Boiling point/Boiling range: 308 °C (586 °F)
· Flash point: 101 °C (214 °F)
· Flammability (solid, gaseous): Not determined.
· Ignition temperature: 420 °C (788 °F)
· Decomposition temperature: Not determined.
· Auto igniting: Product is not selfigniting.
· Danger of explosion: Product does not present an explosion hazard.
· Explosion limits:
Lower: Not determined.
Upper: Not determined.
· Vapor pressure: Not applicable.
· Density at 20 °C (68 °F): 1.03 g/cm³ (8.595 lbs/gal)
· Relative density Not determined.
· Vapor density Not applicable.
· Evaporation rate Not applicable.
· Solubility in / Miscibility with
Water: Insoluble.
· Partition coefficient (n-octanol/water): Not determined.
· Viscosity:
Dynamic: Not applicable.
Kinematic: Not applicable.
VOC content: 0.0 g/l / 0.00 lb/gl
(Contd. on page 6)
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(Contd. of page 5)

· Other information No further relevant information available.

10 Stability and reactivity

· Reactivity No further relevant information available.
· Chemical stability
· Thermal decomposition / conditions to be avoided: No decomposition if used according to specifications.
· Possibility of hazardous reactions No dangerous reactions known.
· Conditions to avoid No further relevant information available.
· Incompatible materials: No further relevant information available.
· Hazardous decomposition products: No dangerous decomposition products known.

11 Toxicological information
· Information on toxicological effects
· Acute toxicity:
· LD/LC50 values that are relevant for classification:
68479-98-1 diethylmethylbenzenediamine
Oral LD50 738 mg/kg (rat)
Dermal LD50 >2000 mg/kg (rat)
· Primary irritant effect:
· on the skin: No irritant effect.
· on the eye: Strong irritant with the danger of severe eye injury.
· Sensitization: Sensitization possible through skin contact.
· Additional toxicological information:
The product shows the following dangers according to internally approved calculation methods for preparations:
Harmful
Irritant
· Carcinogenic categories
· IARC (International Agency for Research on Cancer)
1333-86-4 Carbon black 2B
7631-86-9 silicon dioxide, chemically prepared 3
· NTP (National Toxicology Program)
None of the ingredients is listed.
· OSHA-Ca (Occupational Safety & Health Administration)
None of the ingredients is listed.

12 Ecological information
· Toxicity
· Aquatic toxicity: No further relevant information available.
· Persistence and degradability No further relevant information available.
· Behavior in environmental systems:
· Bioaccumulative potential No further relevant information available.
· Mobility in soil No further relevant information available.
(Contd. on page 7)
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(Contd. of page 6)
· Additional ecological information:
· General notes:
Water hazard class 2 (Self-assessment): hazardous for water
Do not allow product to reach ground water, water course or sewage system.
Must not reach bodies of water or drainage ditch undiluted or unneutralized.
Danger to drinking water if even small quantities leak into the ground.
· Results of PBT and vPvB assessment
· PBT: Not applicable.
· vPvB: Not applicable.
· Other adverse effects No further relevant information available.

13 Disposal considerations
· Waste treatment methods
· Recommendation:
Must not be disposed of together with household garbage. Do not allow product to reach sewage system.
· Uncleaned packagings:
· Recommendation: Disposal must be made according to official regulations.

14 Transport information
· UN-Number
· DOT, ADR, IMDG, IATA UN3066
· UN proper shipping name
· DOT Paint
· ADR 3066 Paint, ENVIRONMENTALLY HAZARDOUS
· IMDG PAINT (diethylmethylbenzenediamine), MARINE POLLUTANT
· IATA PAINT
· Transport hazard class(es)
· DOT

}
a
o
c̀
d
· Class 8 Corrosive substances
· Label 8
· ADR, IMDG

} ́
a
o
c̀
d d
· Class 8 Corrosive substances
· Label 8
(Contd. on page 8)
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(Contd. of page 7)

· IATA

}
a
o
c̀
d
· Class 8 Corrosive substances
· Label 8
· Packing group
· DOT, ADR, IMDG, IATA III
· Environmental hazards: Product contains environmentally hazardous substances:
diethylmethylbenzenediamine
· Marine pollutant: Symbol (fish and tree)
· Special marking (ADR): Symbol (fish and tree)
· Special precautions for user Warning: Corrosive substances
· Danger code (Kemler): 80
· EMS Number: F-A,S-B
· Stowage Category A
· Stowage Code SW2 Clear of living quarters.
· Transport in bulk according to Annex II of
MARPOL73/78 and the IBC Code Not applicable.
· Transport/Additional information:
· DOT
· Quantity limitations On passenger aircraft/rail: 5 L
On cargo aircraft only: 60 L
· ADR
· Excepted quantities (EQ) Code: E1
Maximum net quantity per inner packaging: 30 g
Maximum net quantity per outer packaging: 1000 g
· IMDG
· Limited quantities (LQ) 5L
· Excepted quantities (EQ) Code: E1
Maximum net quantity per inner packaging: 30 g
Maximum net quantity per outer packaging: 1000 g
· UN "Model Regulation": UN 3066 PAINT, 8, III, ENVIRONMENTALLY HAZARDOUS

15 Regulatory information
· Safety, health and environmental regulations/legislation specific for the substance or mixture
· Sara
· Section 355 (extremely hazardous substances):
None of the ingredients is listed.
· Section 313 (Specific toxic chemical listings):
1344-28-1 aluminium oxide
· TSCA (Toxic Substances Control Act):
All ingredients are listed.
(Contd. on page 9)
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(Contd. of page 8)
· Proposition 65
· Chemicals known to cause cancer:
1333-86-4 Carbon black
· Chemicals known to cause reproductive toxicity for females:
None of the ingredients is listed.
· Chemicals known to cause reproductive toxicity for males:
None of the ingredients is listed.
· Chemicals known to cause developmental toxicity:
None of the ingredients is listed.
· Carcinogenic categories
· EPA (Environmental Protection Agency)
None of the ingredients is listed.
· TLV (Threshold Limit Value established by ACGIH)
Carbon black A4
aluminium oxide A4
· NIOSH-Ca (National Institute for Occupational Safety and Health)
1333-86-4 Carbon black
· GHS label elements The product is classified and labeled according to the Globally Harmonized System (GHS).
· Hazard pictograms

d
~
d d
~ 
~
GHS05 GHS07 GHS08

· Signal word Danger

· Hazard-determining components of labeling:
Polyoxyalkyleneamine
tetraethyl-N,N'-(methylenedicyclohexane-4,1-diyl)bis-DL-aspartate
diethylmethylbenzenediamine
diethyl fumarate
· Hazard statements
H302 Harmful if swallowed.
H314 Causes severe skin burns and eye damage.
H317 May cause an allergic skin reaction.
H351 Suspected of causing cancer.
H335 May cause respiratory irritation.
H373 May cause damage to organs through prolonged or repeated exposure.
· Precautionary statements
P260 Do not breathe dusts or mists.
P280 Wear protective gloves.
P280 Wear eye protection / face protection.
P264 Wash thoroughly after handling.
P270 Do not eat, drink or smoke when using this product.
P271 Use only outdoors or in a well-ventilated area.
P272 Contaminated work clothing must not be allowed out of the workplace.
P201 Obtain special instructions before use.
P202 Do not handle until all safety precautions have been read and understood.
(Contd. on page 10)
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(Contd. of page 9)
P303+P361+P353 If on skin (or hair): Take off immediately all contaminated clothing. Rinse skin with water/
shower.
P305+P351+P338 If in eyes: Rinse cautiously with water for several minutes. Remove contact lenses, if present
and easy to do. Continue rinsing.
P310 Immediately call a POISON CENTER/doctor.
P321 Specific treatment (see on this label).
P301+P312 IF SWALLOWED: Call a POISON CENTER/doctor if you feel unwell.
P304+P340 IF INHALED: Remove person to fresh air and keep comfortable for breathing.
P363 Wash contaminated clothing before reuse.
P308+P313 IF exposed or concerned: Get medical advice/attention.
P333+P313 If skin irritation or rash occurs: Get medical advice/attention.
P301+P330+P331 If swallowed: Rinse mouth. Do NOT induce vomiting.
P314 Get medical advice/attention if you feel unwell.
P405 Store locked up.
P403+P233 Store in a well-ventilated place. Keep container tightly closed.
P501 Dispose of contents/container in accordance with local/regional/national/international
regulations.
· Chemical safety assessment: A Chemical Safety Assessment has not been carried out.

16 Other information
This information is based on our present knowledge. However, this shall not constitute a guarantee for any
specific product features and shall not establish a legally valid contractual relationship.
· Department issuing SDS: Product safety department
· Contact: HS REG.DEPART.REG.SS
· Date of preparation / last revision 09/22/2016 / -
· Abbreviations and acronyms:
ADR: Accord européen sur le transport des marchandises dangereuses par Route (European Agreement concerning the International
Carriage of Dangerous Goods by Road)
IMDG: International Maritime Code for Dangerous Goods
DOT: US Department of Transportation
IATA: International Air Transport Association
ACGIH: American Conference of Governmental Industrial Hygienists
EINECS: European Inventory of Existing Commercial Chemical Substances
ELINCS: European List of Notified Chemical Substances
CAS: Chemical Abstracts Service (division of the American Chemical Society)
NFPA: National Fire Protection Association (USA)
HMIS: Hazardous Materials Identification System (USA)
VOC: Volatile Organic Compounds (USA, EU)
LC50: Lethal concentration, 50 percent
LD50: Lethal dose, 50 percent
PBT: Persistent, Bioaccumulative and Toxic
vPvB: very Persistent and very Bioaccumulative
NIOSH: National Institute for Occupational Safety
OSHA: Occupational Safety & Health
TLV: Threshold Limit Value
PEL: Permissible Exposure Limit
REL: Recommended Exposure Limit
Acute Tox. 4: Acute toxicity – Category 4
Skin Corr. 1C: Skin corrosion/irritation – Category 1C
Eye Dam. 1: Serious eye damage/eye irritation – Category 1
Skin Sens. 1: Skin sensitisation – Category 1
Carc. 2: Carcinogenicity – Category 2
STOT SE 3: Specific target organ toxicity (single exposure) – Category 3
STOT RE 2: Specific target organ toxicity (repeated exposure) – Category 2
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