SDS - Epotec Yd 128

Download as pdf or txt
Download as pdf or txt
You are on page 1of 9

Page 1/9

Safety Data Sheet


acc. to OSHA HCS
Printing date 03/15/2018 Reviewed on 03/15/2018

* 1 Identification
· Product identifier
· Trade name: EPOTEC YD 128
· CAS Number:
25068-38-6
· NLP Number:
500-033-5
· Application of the substance / the mixture
Resin for coating, composite, civil, electrical, adhesive systems
· Details of the supplier of the safety data sheet
· Manufacturer/Supplier:
Aditya Birla Chemicals (Thailand) Ltd. (Epoxy Division)
No.2, I-5 Road, Maptaphut Industrial Estate, Maptaphut,
Muang, Rayong 21150
THAILAND
GRASIM INDUSTRIES LTD. (EPOXY DIVISION), Plot No. 1, GIDC, Vilayat Industrial Estate, Tehsil Vagra,
Dist. Bharuch - 392012, Gujarat, INDIA
· Information department:
epoxymktg@adityabirla.com
www.adityabirlachemicals.com
www.epotec.info
· Emergency telephone number:
During normal opening times: Thailand +66-38-685233
India +918154007544

* 2 Hazard(s) identification
· Classification of the substance or mixture

GHS09 Environment

Aquatic Chronic 2 H411 Toxic to aquatic life with long lasting effects.

GHS07

Skin Irrit. 2 H315 Causes skin irritation.


Eye Irrit. 2A H319 Causes serious eye irritation.
Skin Sens. 1 H317 May cause an allergic skin reaction.
· Label elements
· GHS label elements
The substance is classified and labeled according to the Globally Harmonized System (GHS).
· Hazard pictograms

GHS07 GHS09

· Signal word Warning


(Contd. on page 2)
US

46.0.4
Page 2/9
Safety Data Sheet
acc. to OSHA HCS
Printing date 03/15/2018 Reviewed on 03/15/2018

Trade name: EPOTEC YD 128

(Contd. of page 1)
· Hazard statements
H315 Causes skin irritation.
H319 Causes serious eye irritation.
H317 May cause an allergic skin reaction.
H411 Toxic to aquatic life with long lasting effects.
· Precautionary statements
P261 Avoid breathing dust/fume/gas/mist/vapors/spray
P264 Wash thoroughly after handling.
P272 Contaminated work clothing must not be allowed out of the workplace.
P273 Avoid release to the environment.
P280 Wear protective gloves / eye protection / face protection.
P302+P352 If on skin: Wash with plenty of water.
P305+P351+P338 If in eyes: Rinse cautiously with water for several minutes. Remove contact lenses, if
present and easy to do. Continue rinsing.
P321 Specific treatment (see on this label).
P333+P313 If skin irritation or rash occurs: Get medical advice/attention.
P337+P313 If eye irritation persists: Get medical advice/attention.
P362+P364 Take off contaminated clothing and wash it before reuse.
P363 Wash contaminated clothing before reuse.
P391 Collect spillage.
P501 Dispose of contents/container in accordance with local/regional/national/international
regulations.
· Classification system:
· NFPA ratings (scale 0 - 4)

1 Health = 2
2 0 Fire = 1
Reactivity = 0
· HMIS-ratings (scale 0 - 4)
HEALTH 2 Health = 2
FIRE 1
REACTIVITY 0
Fire = 1
Reactivity = 0
· Other hazards
· Results of PBT and vPvB assessment Not applicable.
· PBT: Not applicable.
· vPvB: Not applicable.

* 3 Composition/information on ingredients
· Chemical characterization: Substances
· CAS No. Description
25068-38-6 Reaction product: Bisphenol-A-(epichlorohydrin) epoxy resin(number average molecular weight
 700)
· Identification number(s) EC No. -
· NLP Number: 500-033-5
US
(Contd. on page 3)

46.0.4
Page 3/9
Safety Data Sheet
acc. to OSHA HCS
Printing date 03/15/2018 Reviewed on 03/15/2018

Trade name: EPOTEC YD 128

(Contd. of page 2)

4 First-aid measures
· Description of first aid measures
· General information: Immediately remove any clothing soiled by the product.
· After inhalation:
Supply fresh air and to be sure call for a doctor.
In case of unconsciousness place patient stably in side position for transportation.
Supply fresh air; consult doctor in case of complaints.
· After skin contact: Immediately wash with water and soap and rinse thoroughly.
· After eye contact:
Rinse opened eye for several minutes under running water. If symptoms persist, consult a doctor.
· After swallowing: Drink copious amounts of water and provide fresh air. Immediately call a doctor.
· Information for doctor:
· Most important symptoms and effects, both acute and delayed
No further relevant information available.
· Indication of any immediate medical attention and special treatment needed
No further relevant information available.

5 Fire-fighting measures
· Extinguishing media
· Suitable extinguishing agents:
CO2, extinguishing powder or water spray. Fight larger fires with water spray.
Use fire fighting measures that suit the environment.
· For safety reasons unsuitable extinguishing agents: Water with full jet
· Special hazards arising from the substance or mixture No further relevant information available.
· Advice for firefighters
· Protective equipment: Wear self-contained respiratory protective device.

* 6 Accidental release measures


· Personal precautions, protective equipment and emergency procedures
Wear protective equipment. Keep unprotected persons away.
· Environmental precautions:
Do not allow product to reach sewage system or any water course.
Inform respective authorities in case of seepage into water course or sewage system.
Do not allow to enter sewers/ surface or ground water.
· Methods and material for containment and cleaning up:
Dispose contaminated material as waste according to item 13.
Ensure adequate ventilation.
· Reference to other sections
See Section 7 for information on safe handling.
See Section 8 for information on personal protection equipment.
See Section 13 for disposal information.
· Protective Action Criteria for Chemicals
· PAC-1:
90 mg/m³
(Contd. on page 4)
US

46.0.4
Page 4/9
Safety Data Sheet
acc. to OSHA HCS
Printing date 03/15/2018 Reviewed on 03/15/2018

Trade name: EPOTEC YD 128

(Contd. of page 3)
· PAC-2:
990 mg/m³
· PAC-3:
5,900 mg/m³

7 Handling and storage


· Handling:
· Precautions for safe handling
Ensure good ventilation/exhaustion at the workplace.
Prevent formation of aerosols.
· Information about protection against explosions and fires: Keep ignition sources away - Do not smoke.
· Conditions for safe storage, including any incompatibilities
· Storage:
· Requirements to be met by storerooms and receptacles: Store in a cool location.
· Information about storage in one common storage facility:
Do not store together with oxidizing and acidic materials as well as heavy-metal compounds.
· Further information about storage conditions:
Keep receptacle tightly sealed.
Store receptacle in a well ventilated area.
· Specific end use(s) No further relevant information available.

8 Exposure controls/personal protection


· Additional information about design of technical systems: No further data; see item 7.
· Control parameters
· Components with limit values that require monitoring at the workplace: Not required.
· Additional information: The lists that were valid during the creation were used as basis.
· Exposure controls
· Personal protective equipment:
· General protective and hygienic measures:
Keep away from foodstuffs, beverages and feed.
Immediately remove all soiled and contaminated clothing.
Wash hands before breaks and at the end of work.
Avoid contact with the eyes and skin.
· Breathing equipment:
In case of brief exposure or low pollution use respiratory filter device. In case of intensive or longer
exposure use respiratory protective device that is independent of circulating air.
Use suitable respiratory protective device in case of insufficient ventilation.
· Protection of hands:

Protective gloves

The glove material has to be impermeable and resistant to the product/ the substance/ the preparation.
(Contd. on page 5)
US

46.0.4
Page 5/9
Safety Data Sheet
acc. to OSHA HCS
Printing date 03/15/2018 Reviewed on 03/15/2018

Trade name: EPOTEC YD 128

(Contd. of page 4)
Due to missing tests no recommendation to the glove material can be given for the product/ the
preparation/ the chemical mixture.
Selection of the glove material on consideration of the penetration times, rates of diffusion and the
degradation
· Material of gloves
The selection of the suitable gloves does not only depend on the material, but also on further marks of
quality and varies from manufacturer to manufacturer.
· Penetration time of glove material
The exact break through time has to be found out by the manufacturer of the protective gloves and has to
be observed.
· Eye protection:
Safety glasses

Tightly sealed goggles

· Body protection: Protective work clothing

* 9 Physical and chemical properties


· Information on basic physical and chemical properties
· General Information
· Appearance:
Form: Liquid
Color: Light yellow
· Odor: Light
· Change in condition
Melting point/Melting range: Undetermined.
Boiling point/Boiling range: >260 °C (>500 °F)
· Flash point: 252 °C (485.6 °F)
· Danger of explosion: Product does not present an explosion hazard.
· Vapor pressure at 20 °C (68 °F): 0.04 hPa (0 mm Hg)
· Density at 20 °C (68 °F): 1.16 g/cm³ (9.6802 lbs/gal)
· Solubility in / Miscibility with
Water: Insoluble.
· Other information No further relevant information available.

10 Stability and reactivity


· Reactivity No further relevant information available.
· Chemical stability
· Thermal decomposition / conditions to be avoided:
No decomposition if used and stored according to specifications.
· Possibility of hazardous reactions Reacts with alcohols, amines, aqueous acids and alkalis.
· Conditions to avoid No further relevant information available.
(Contd. on page 6)
US

46.0.4
Page 6/9
Safety Data Sheet
acc. to OSHA HCS
Printing date 03/15/2018 Reviewed on 03/15/2018

Trade name: EPOTEC YD 128

(Contd. of page 5)
· Incompatible materials: Acids, bases, amines and oxidizing agent.
· Hazardous decomposition products: Carbon monoxide and carbon dioxide

* 11 Toxicological information
· Information on toxicological effects
· Acute toxicity:
· LD/LC50 values that are relevant for classification:
25068-38-6 Reacti on product: Bisphenol-A-(epichloro hydrin) epoxy resin(number average
molecular weight  700)
Oral LD50 >2000 mg/kg (rat)
Dermal LD50 >2000 mg/kg (rabbit)
· Primary irritant effect:
· on the skin: Irritant to skin and mucous membranes.
· on the eye: Irritating effect.
· Sensitization: Sensitization possible through skin contact.
· Additional toxicological information:
· Carcinogenic categories
· IARC (International Agency for Research on Cancer)
Substance is not listed.
· NTP (National Toxicology Program)
Substance is not listed.
· OSHA-Ca (Occupational Safety & Health Administration)
Substance is not listed.

* 12 Ecological information
· Toxicity
· Aquatic toxicity:
25068-38-6 Reacti on product: Bisphenol-A-(epichloro hydrin) epoxy resin(number average
molecular weight  700)
EC50 1.8 mg/kg (daphnia)
· Persistence and degradability No further relevant information available.
· Behavior in environmental systems:
· Bioaccumulative potential No further relevant information available.
· Mobility in soil No further relevant information available.
· Ecotoxical effects:
· Remark: Toxic for fish
· Additional ecological information:
· General notes:
Water hazard class 2 (Assessment by list): hazardous for water
Do not allow product to reach ground water, water course or sewage system.
Danger to drinking water if even small quantities leak into the ground.
Also poisonous for fish and plankton in water bodies.
(Contd. on page 7)
US

46.0.4
Page 7/9
Safety Data Sheet
acc. to OSHA HCS
Printing date 03/15/2018 Reviewed on 03/15/2018

Trade name: EPOTEC YD 128

(Contd. of page 6)
Toxic for aquatic organisms
· Results of PBT and vPvB assessment Not applicable.
· PBT: Not applicable.
· vPvB: Not applicable.
· Other adverse effects No further relevant information available.

13 Disposal considerations
· Waste treatment methods
· Recommendation:
Must not be disposed of together with household garbage. Do not allow product to reach sewage system.
· Uncleaned packagings:
· Recommendation: Disposal must be made according to official regulations.

* 14 Transport information
· UN-Number
· DOT Void
· ADR/RID/ADN, IMDG, IATA UN3082
· UN proper shipping name
· ADR/RID/ADN UN3082 Environmentally hazardous substances, liquid,
n.o.s. (Reaction product: Bisphenol-A-(epichlorohydrin)
epoxy resin(number average molecular weight  700))
3082 ENVIRONMENTALLY HAZARDOUS SUBSTANCE,
L I Q UI D, N. O .S . (Re a c t i on p ro du c t : B i sp he n ol -A-
(epichlorohydrin) epoxy resin(number average molecular
weight  700))
· IMDG ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID,
N.O.S. (Reaction product: Bisphenol-A-(epichlorohydrin)
epoxy resin(number average molecular weight  700)),
MARINE POLLUTANT
· IATA ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID,
N.O.S. (Reaction product: Bisphenol-A-(epichlorohydrin)
epoxy resin(number average molecular weight  700))
· Transport hazard class(es)
· DOT
· Class Void
· Label Void
· ADR/RID/ADN, IMDG, IATA
· Class 9 Miscellaneous dangerous substances and articles
· Label 9
· Packing group
· DOT Void
· ADR/RID/ADN, IMDG, IATA III
(Contd. on page 8)
US

46.0.4
Page 8/9
Safety Data Sheet
acc. to OSHA HCS
Printing date 03/15/2018 Reviewed on 03/15/2018

Trade name: EPOTEC YD 128

(Contd. of page 7)

· Environmental hazards:
· Marine pollutant: Y
· Special precautions for user Warning: Miscellaneous dangerous substances and articles
· Danger code (Kemler): 90
· EMS Number: F-A,S-F
· Transport in bulk according to Annex II of
MARPOL73/78 and the IBC Code Not applicable.

* 15 Regulatory information
· Safety, health and environmental regulations/legislation specific for the substance or mixture
· Sara
· Section 313 (Specific toxic chemical listings):
Substance is not listed.
· TSCA (Toxic Substances Control Act):
Substance is listed.
· GHS label elements
The substance is classified and labeled according to the Globally Harmonized System (GHS).
· Hazard pictograms

GHS07 GHS09

· Signal word Warning


· Hazard statements
H315 Causes skin irritation.
H319 Causes serious eye irritation.
H317 May cause an allergic skin reaction.
H411 Toxic to aquatic life with long lasting effects.
· Precautionary statements
P261 Avoid breathing dust/fume/gas/mist/vapors/spray
P264 Wash thoroughly after handling.
P272 Contaminated work clothing must not be allowed out of the workplace.
P273 Avoid release to the environment.
P280 Wear protective gloves / eye protection / face protection.
P302+P352 If on skin: Wash with plenty of water.
P305+P351+P338 If in eyes: Rinse cautiously with water for several minutes. Remove contact lenses, if
present and easy to do. Continue rinsing.
P321 Specific treatment (see on this label).
P333+P313 If skin irritation or rash occurs: Get medical advice/attention.
P337+P313 If eye irritation persists: Get medical advice/attention.
P362+P364 Take off contaminated clothing and wash it before reuse.
P363 Wash contaminated clothing before reuse.
P391 Collect spillage.
(Contd. on page 9)
US

46.0.4
Page 9/9
Safety Data Sheet
acc. to OSHA HCS
Printing date 03/15/2018 Reviewed on 03/15/2018

Trade name: EPOTEC YD 128

(Contd. of page 8)
P501 Dispose of contents/container in accordance with local/regional/national/international
regulations.
· Chemical safety assessment: A Chemical Safety Assessment has not been carried out.

16 Other information
This information is based on our present knowledge. However, this shall not constitute a guarantee for any
specific product features and shall not establish a legally valid contractual relationship.
· Contact: E-mail : epoxymktg@adityabirla.com
· Date of preparation / last revision 03/15/2018 / -
· Abbreviations and acronyms:
ADR: Accord européen sur le transport des marchandises Dangereuses par Route (European Agreement concerning the International
Carriage of Dangerous Goods by Road)
IMDG: International Maritime Code for Dangerous Goods
DOT: US Department of Transportation
IATA: International Air Transport Association
EINECS: European Inventory of Existing Commercial Chemical Substances
CAS: Chemical Abstracts Service (division of the American Chemical Society)
NFPA: National Fire Protection Association (USA)
HMIS: Hazardous Materials Identification System (USA)
LC50: Lethal concentration, 50 percent
LD50: Lethal dose, 50 percent
PBT: Persistent, Bioaccumulative and Toxic
vPvB: very Persistent and very Bioaccumulative
OSHA: Occupational Safety & Health
TLV: Threshold Limit Value
PEL: Permissible Exposure Limit
REL: Recommended Exposure Limit
Skin Irrit. 2: Skin corrosion/irritation – Category 2
Eye Irrit. 2A: Serious eye damage/eye irritation – Category 2A
Skin Sens. 1: Skin sensitisation – Category 1
Aquatic Chronic 2: Hazardous to the aquatic environment - long-term aquatic hazard – Category 2
US

46.0.4

You might also like