FIITJEE

Quiz
GOC
TEST-1
SMCQ
Q1. Which of the following is the most stable resonance structure?

(A) H2C CH C OH (B) H2C CH C OH

CH CH

CHNH2 CHNH2

(C) H2C CH C OH (D) H2C CH C OH

CH CH
CHNH2 CH
NH2

Q2. The correct stability order of the following resonance structure is

(I) H2C N N (II) CH2 N N (III) CH2 N N (IV) CH2 N N

(A) (I) > (II) > (IV) > (III) (B) (I) > (III) > (II) > (IV)
(C) (II) > (I) > (III) > (IV) (D) (III) > (I) > (IV) > (II)
Q3. What is the correct IUPAC name of the following compound?
Cl
Br

Br
Cl
(A) 2, 5- dibromo-1, 4-dichlorobenzene
(B) 1, 4- dibromo-3, 5- dichlorobenzene
(C) 3, 5- dibromo-1, 4- dichlorobenzene
(D) 1, 4- dibromo-2, 5- dichlorobenzene

Q4. For which of the following molecule significant dipole moment is zero
Cl CN OH SH

(I) (II) (III) (IV)

Cl CN OH SH
(A) Only I (B) I & II
(C) Only III (D) III & IV

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Q5. The correct basicity order of the following compound is:

NH2 NH2

(P) (Q)

Me NO2
Me
N Me Me
N
(R) (S)
Me Me

(A) S > R > Q > P (B) S > R > P > Q

(C) P > Q > R > S (D) R > Q > P > S

Q6. Which of the following is not a valid resonance structure of P- aminobenzaldehyde.

O H O H
C C

(A) (B)

NH2 NH2
O H O H
C C

(C) (D)

NH2 NH2
Q7. Arrange the following in increasing order of acidic strength.
OH OH
OH
OH H3C CH3 NO2

H3C CH3

NO2 NO2
I II III IV
(A) I < II < III < IV (B) IV < III < II < I
(C) I < II < IV < III (D) I < III< II < IV

Ranchi (Lalpur) :7th Floor, Hari Om Towers, (Opp. Women’s College, Arts Block), Circular Road, Ranchi, Ph : 0651- 2563187/88/89/90.
Ranchi (SOP, Doranda): Samriddhi Complex, Ground Floor, Near St. Xavier’s School, South Office Para Doranda, Ranchi.
Jamshedpur : Om Plaza, 3rd Floor, Thakurbari Road, Aam Bagan, Sakchi, Jamshedpur
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Q8. The decreasing order of nucleophilicity of the following is

(I)F (II)RO  (III) R3N (IV)R3 C
(A) IV > III > I > II (B) IV > III > II > I
(C) III > I > II > IV (D) I > II > III > IV

Q9. Which is not an electrophile?

+
(A) H (B) BCl3
+
(C) BH 3 (D) NH 4

Q10. The aromatic character is maximum in which of these three compounds?

(I) (II) (III)

O N
H
(A) I (B) II
(C) III (D) Same in all

Q11. Which of the following reaction has zero activation energy?

  
(A) CH4  Cl  CH3  HCl (B) Cl2  2Cl
   
(C) CH3  CH3  CH3  CH3 (D) CH3  Cl  Cl  CH3  Cl  Cl

Q12. The number of possible enantiomer pairs that can be produced during monochlorination
of 2-methylbutane is;
(A) 2 (B) 3
(C) 4 (D) 1

Q13. Which of the following compounds on hydrolysis gives propyne?

(A) CaC2 (B) Mg 2C 3
(C) Al4C3 (D) Cu 2Cl2
Q14. An isomer of C 5H12 gives total six isomeric products on monochlorination. Calculate the
percentage yield of the primary monochloride which is chiral. Consider the following
relative reactivity of C – H bonds for chlorination.
Degree of C – H 10 CH 2 0 CH 30 CH
Relative reactivity 1 3 5
for chlorination
(A) 26.8% (B) 25%
(C) 30% (D) 50%

Q15.
CH3
Cl2/h
Ph CH2 CH CH3
(monochlorination)
Which statements is/are correct about photochemical chlorination of the above
compound?
(A) The major product will have chiral carbon atom and therefore optically active
(B) The intermediate free radical of the major product is resonance stabilized
(C) The intermediate free radical is tertiary for major product
(D) The intermediate free radical is planar, and stabilized by only hyperconjugation.
Q16 Consider the molecule

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Ranchi (SOP, Doranda): Samriddhi Complex, Ground Floor, Near St. Xavier’s School, South Office Para Doranda, Ranchi.
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H  CH2 CH CH CH CH2 C C H


H
The order of bond energy is;
(A)      (B)     
(C)      (D)     
Q17.

CH2 - Cl
Na
X
THF
H3 C
CH2 - Cl

X is;

(A) (B)

H3C CH3 CH3

CH3

CH3

(C) (D) B & C

H 3C

Q18. Among all isomers of hexane, which of the following isomer cannot be obtained in a good
yield by wurtz reaction;
(1) n-hexane (2) isohexane (3) 2,3-dimethyl butane (4) Neohexane
(A) 1, 4 (B) 2, 4
(C) 1, 3 (D) 3, 4
Q19.

Cl2/hv major product;

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(A) Cl (B)

Cl
Cl

(C) (D)

Cl Cl

Q20.

CH3 C NH2
Mg / dry ether
Br (X) O (Y)

The structures of (X) and (Y) respectively are;

(A) X = MgBr ; Y= OH

(B) X = Br ; Y= OH

Mg OH

(C) X = MgBr ; Y=

(D) X = BrMg MgBr ; Y = HO OH

Q21. The type of isomerism exhibited by the compound with formula C4H10O is:
(A) Chain and position
(B) Functional and position
(C) Metamerism
(D) Chain, position, functional , and metamerism
Q22. Which among the following is likely to show geometrical isomersm?
(A) CH3CH  CH2 (B) CH3 CH  N  OH
(C) CH3C(Cl)  C(CH3 )2 (D) CH2  CH  CH  CCl2

Q23. How many gem dihalides with different formulas are possible for C3H6CI2?
(A) 1 (B) 2
(C) 3 (D) 4
Q24. The total number of halogenated products likely to be formed by ethane is:
(A) 4 (B) 6
(C) 9 (D) 8

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Ranchi (SOP, Doranda): Samriddhi Complex, Ground Floor, Near St. Xavier’s School, South Office Para Doranda, Ranchi.
Jamshedpur : Om Plaza, 3rd Floor, Thakurbari Road, Aam Bagan, Sakchi, Jamshedpur
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Q25. The E-isomer among the following is:

Cl Br Cl C 2H 5
(A) C C (B) C C
H3C C2 H5 H3C CHO

H3C CH CH2 H CHCl2

(C) C C (D) C C
H CH3 H3C CHCl2

Q26. Which of the following will not show geometrical isomerism?

H3C H CH CH2
CIH 2C
(A) C (B) C
Cl CH CHCH3 H CH3

CH2 CH CH2Cl
(C) C (D) CH3CH CHCH2CH3
H CH CHCl

Q27. Predict the number of stereoisomers for 2,5- heptadiene.

(A) 4 (B) 8
(C) 2 (D) 2

Q28. Which of the following compounds will not show geometrical isomerism?
(A) 3-Phenyl-2-propenoic acid (B) 2-Butene
(C) 3- Methyl-2- butenoic acid (D) 3- methyl-2- pentenoic acid

Q29. The enolic form of acetone contains:

(A) 9 -bonds, 1-bonds, and 2 lone pairs.
(B) 8 -bonds, 2-bonds, and 2 lone pairs.
(C) 0 -bonds, 2-bonds, and 1 lone pairs.
(D) 9 -bonds, 2-bonds, and 2 lone pairs.

Q30. Arrange the following in the increasing order of expected enol content.
i. CH3COCH2CHO ii. CH3COCH3 iii. CH3CHO iv. CH3COCH2COCH 3
(A) iii < I < ii < iv (B) iii < ii < I < iv
(C) I < iv < ii < iii (D) iv < I < ii < iii

Ranchi (Lalpur) :7th Floor, Hari Om Towers, (Opp. Women’s College, Arts Block), Circular Road, Ranchi, Ph : 0651- 2563187/88/89/90.
Ranchi (SOP, Doranda): Samriddhi Complex, Ground Floor, Near St. Xavier’s School, South Office Para Doranda, Ranchi.
Jamshedpur : Om Plaza, 3rd Floor, Thakurbari Road, Aam Bagan, Sakchi, Jamshedpur
.