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    Chemistry Section A+B

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    Signor Plaban Gogoi

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    © All Rights Reserved
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    Chemistry Section A+B

    Uploaded by

    Signor Plaban Gogoi
    6 views3 pages

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    © © All Rights Reserved

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    6 views3 pages

    Chemistry Section A+B

    Uploaded by

    Signor Plaban Gogoi

    Copyright:

    © All Rights Reserved
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    Test Series for Class 12 Subject—Chemistry 70 Marks 3 hours

    Question Number 1 Carries one mark each 1 x 10 = 10


    a) write down the formula of Tetraamineaquachloridocobalt(III) chloride.
    b) Write the IUPAC names of the following coordination compound:
    [Pt(NH3)2Cl(NO2)]
    c) What will be the effect of temperature on rate constant ?
    d) what are monosaccharides?
    e) what are reducing sugars?
    f) Define the term Coordination number.
    g) what is meant by Unidentate ligand?
    h) How are polymers classified on the basis of structure?
    i) Define half life period of a reaction
    j) Write the unit of rate constant for a zero order reaction.
    2) Question Number 2 Carries two marks each 2 x 9 = 18

    a) Why H2 and 02 do not react at room temperature ? Write the rate equation
    for the reaction A2 + 3B2 - 2C, if the overall order of the reaction is zero. b) For a
    reaction : 2NH3 (g) --Pt-- N2 (g) + 3H2 (g) , rate is given by ,,,,,Rate = k
    (i) Write the order and molecularity of this reaction.
    (ii) Write the unit of k
    c) Write two differences between order and molecularity of a reaction.
    d) What are ambidentate ligands? Give an example.
    e) What happens when Glucose reacts with Bromine water?
    f) How do you explain the absence of aldehyde group in the pentaacetate of D-
    glucose?
    g) Write the hybridization state of central atom of the following co-ordination
    complexes along with their magnetic properties.
    [Cu(NH3)4]2- and [Ni(CO)4]
    h) [NiCl4]2– is paramagnetic while [Ni(CO)4] is diamagnetic though both are
    tetrahedral. Why?
    i) Classify the following as addition and condensation polymers: Terylene, Bakelite,
    Polyvinyl chloride, Polythene.

    3) Question Number 3 Carries three marks each 3x9 = 27


    a) A first order reaction has a rate constant of 0.0051 min-1. If we begin with 0.10 M
    concentration of the reactant, what concentration of reactant will remain in solution
    after 3 hours ?
    2.303 [R0]
    b) Show that the integrated rate for a first order reaction RP is k = log
    t [R]
    c) Draw the structure of D+ Glucose and D+ Glyceraldehyde.
    d) What is Fructose. Draw the structure of D(-) fructose.
    e) Explain [Co(NH3)6]3+ is an inner orbital complex whereas [Ni(NH3)6]2+ is an
    outer orbital complex.
    f) Explain the difference between Buna-N and Buna-S.
    g) Define thermoplastics and thermosetting polymers with two examples of each.
    h) How can you differentiate between addition and condensation polymerisation?
    i) Give evidence that [Co(NH3)5Cl]SO4 and [Co(NH3)5SO4]Cl are ionization isomers.
    4) Question Number 5 Carries five marks each 5x3 = 15
    a) For a certain chemical reaction variation In concentration, ln[R] Vs time (s) plot is given
    below. For this reaction write/draw:

    i). What is the order of the reaction? ii). What


    is the units of rate constant (k)? iii). Give the
    relationship between k and t1/2 (half life period). iv). What does the slope
    [ R 0]
    of above line indicate? v). Draw the plot of log
    [ R]
    vs time (s)
    b) Write the names and structures of the monomers of the following polymers: (i)
    Buna-S (ii) Buna-N (iii) Dacron (iv) Neoprene v) Polystyrene
    c) Indicate the types of isomerism exhibited by the following complexes and
    draw the structures for these isomers:
    (i) K[Cr(H2O)2(C2O4)2 (ii) [Co(en)3]Cl3
    (iii) [Co(NH3)5(NO2)](NO3)2 (iv) [Pt(NH3)(H2O)Cl2]

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