Actysurf 435 M SDS
Actysurf 435 M SDS
Actysurf 435 M SDS
1.2 Relevant identified uses of the substance and uses advised against
1.2.1 Relevant identified uses
Professional uses; Food beverage and pharmacies products, General surface cleaning products.
Address: Harmandere Mahallesi Ankara Caddesi No: 486 A Blok Daire 12 Airport Plaza Pendik/
İstanbul
Tel: 90 216 469 71 65 (Pbx)
Fax: +90 216 469 71 66
2. Hazard identification
2.1 Classification of the mixture
2.1.1 Classification according to Regulation
Eye Dam. 1
(EC) No 1272/2008 [CLP]
2.1.2 Classification according to 1999/45/EC Xi; R41
2.1.3 Additional information For full text of R-, H-phrases: see SECTION 16.
GHS05
Signal Word Danger
Hazard Statements H318 Causes serious eye damage
Precautionary statements
P280 Wear protective gloves/protective
Prevention
clothing/eye protection/face protection.
P305 + P351 + P338 IF IN EYES: Rinse
cautiously with water for several minutes.
Response
Remove contact lenses, if present and easy to
do. Continue rinsing.
P310 Immediately call a POISON CENTER or
doctor/physician.
Storage Not applicable
Disposal Not applicable
2.2.2 Labeling according to 1999/45/EC (DPD)
Symbols and Indications of Danger
Irritant
Risk phrases
Safety phrase R41 Risk of serious damage to eyes.
S25 Avoid contact with eyes.
S26 In case of contact with eyes, rinse
immediately with plenty of water and seek
medical advice.
S39 Wear eye/face protection.
Specific concentration limits
None
2.3 Other hazards
Not known to our knowledge.
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3. Composition/information on ingredients
3.1 Substances Not applicable
3.2 Mixtures
3.2.1 INCI name Ethylhexyl Glucoside
Classification Classification
Purity% according to according to
Name Product identifier
[weight] Directive Regulation (EC) No
67/548/EEC 1272/2008 [CLP]
D-Glucopyranose, (CAS No.)
63~67% Xi; R41 Eye Dam. 1
oligomeric,2- 161074-93-7 (EC No.)
ethylhexyl glycosides 500-529-1
1,2,3-Propanetricarboxylic (CAS No.)5949-29-1 1-4%
Xi; R41 Eye Dam. 1
acid, 2-hydroxy-, (EC No.) 611-842-9
monohydrate
(CAS No.) 7732-18-5 Not classified
Water 33~37% Not classified
(EC No.) 231-791-2
4. First-aid measures
4.1 Description of first aid measures
4.1.1 First-aid measures general No general information.
4.1.2 Following inhalation Use a bag valve mask or similar device to perform
artificial respiration (rescue breathing) if needed.
Get medical attention immediately.
4.1.3 Following skin contact Remove contaminated clothing immediately.
Wash with soap or mild detergent and large
amounts of water until
no evidence of chemical remains (at least 15-20
minutes).
Remove contaminated clothing immediately.
4.1.4 Following eye contact Wash eyes immediately with large amounts of
water.
Get medical attention immediately.
4.1.5 Following ingestion Contact local poison control center or physician
immediately.
Give large amounts of water. Allow vomiting to
occur.
4.2 Most important symptoms and effects, both acute and delayed
4.2.1 Symptoms/injuries No general information.
4.2.2 Symptoms/injuries after inhalation The material is not thought to produce either
adverse health effects or irritation of the respiratory
tract following inhalation (as classified by EC
Directives using animal models).
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Nevertheless, adverse systemic effects have been
produced following exposure of animals by at least
one other route and good hygiene practice requires
that exposure be kept to a minimum and that
suitable control measures be used in an
occupational setting. Inhalation of vapours may
cause drowsiness and dizziness. This may be
accompanied by sleepiness, reduced alertness,
loss of reflexes, lack of co-ordination, and vertigo.
4.2.3 Symptoms/injuries after skin contact Skin contact is not thought to have harmful health
effects (as classified under EC Directives); the
material may still produce health damage following
entry through wounds, lesions or abrasions.
There is some evidence to suggest that the
material may cause mild but significant
inflammation of the skin either following direct
contact or after a delay of some time. Repeated
exposure can cause contact dermatitis which is
characterized by redness, swelling and blistering.
Alkyl glycosides, as a family, are considered non-
irritating to the skin. Entry into the blood-stream,
through, for example, cuts, abrasions or lesions,
may produce systemic injury with harmful effects.
4.2.4 Symptoms/injuries after eye contact If applied to the eyes, this material causes severe
eye damage. Non-ionic surfactants can cause
numbing of the cornea, which masks discomfort
normally caused by other agents and leads to
corneal injury. Irritation varies depending on the
duration of contact, the nature and concentration of
the surfactant. At very high concentrations, alkyl
polyglycosides and polygalactosides are eye
irritants while some C8 alkyl glycoside solutions
may produce serious eye damage.
4.2.5 Symptoms/injuries after ingestion Accidental ingestion of the material may be
damaging to the health of the individual. Nonionic
surfactants may produce localised irritation of the
oral or gastrointestinal lining and induce vomiting
and mild diarrhoea.
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5. Fire-fighting measures
5.1 Extinguishing media
Suitable extinguishing media Carbon dioxide, Regular dry chemical, Water ,
Dry powder, Fight lager fires with water spray or
alcohol resistant foam (Large fire)
Unsuitable extinguishing media None Known.
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7. Handling and storage
7.1 Precautions for safe handling
7.1.1 Protective measures Avoid open flames.
Do not get in eyes or on skin or clothing.
Avoid breathing vapour or mist.
Put on appropriate personal protective equipment
(see section 8).
7.1.2 Advice on general occupational hygiene Do not to eat, drink and smoke in work areas.
Wash hands and face before eating, drinking and
smoking.
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DNEL Type DNEL Value Remark
DNEL acute inhalative (local) Assessment of hazard sufficiently
coverage by derivation of the
respective DNEL for long-term
exposure.
DNEL acute inhalative (systemic) Assessment of hazard sufficiently
coverage by derivation of the
respective DNEL for long-term
exposure.
DNEL long-term inhalative (local) Assessment of hazard not
assignable due to
missing/insufficient data.
DNEL long-term inhalative (systemic) 420 mg/m3
DN(M)EL General population:
DNEL short-term oral (acute) Assessment of hazard sufficiently
covered by derivation of the
respective DNEL for long-term
exposure.
DNEL long-term oral (repeated) 35.7 mg/kg
bw/day
DNEL acute dermal, short-term (local) Assessment of hazard sufficiently
covered by derivation of the
respective DNEL for long-term
exposure.
DNEL acute dermal, short-term (systemic) Assessment of hazard sufficiently
covered by derivation of the
respective DNEL for long-term
exposure.
DNEL long-term dermal (local) Only workers will come in contact
with the neat irritating substances.
DNEL long-term dermal (systemic) 357,000 mg/kg
bw/day
DNEL acute inhalative (local) Assessment of hazard sufficiently
covered by derivation of the
respective DNEL for long-term
exposure.
DNEL acute inhalative (systemic) Assessment of hazard sufficiently
covered by derivation of the
respective DNEL for long-term
exposure.
DNEL long-term inhalative (local) Assessment of hazard not
assignable due to
missing/insufficient data.
DNEL long-term inhalative (systemic) 124 mg/m3
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PNEC:
PNEC Type PNEC Value Assessment Remark
factor
PNEC aquatic, fresh water 0.1 mg/L 10
PNEC aquatic, marine water 0.01 mg/L 100
PNEC aquatic, intermittent releases 0.27 mg/L 100
PNEC sediment, fresh water 0.487 mg/kg N/A
PNEC sediment, marine water 0.048 mg/kg N/A
PNEC soil 0.654 mg/kg 1000
PNEC sewage treatment plant (STP) 560 mg/L 1
PNEC air
PNEC secondary poisoning 111.11 mg/kg 90
food
8.1.5 Risk management measures according to used control banding approach
Exposure Description General measures Specific Human Specific Environment
scenario Health risk risk management
management measures
measures
AISE Formulation (i) Procedural (i) Local Exhaust (i) Treatment of
: Granular and ventilation effluent in
Detergent/Maintenance technological (LEV) biological waste
Products, liquid control using water treatment
Detergents/Maintenance Best plant
Products Available (ii) Use of air
End use Technique emission
: Industrial use of (BAT) abatement
Facade/surface Cleaning equipments
Products, Laundry products such as
and Vehicle cleaning Products, incinerators and
etc. scrubbers are
Consumer use applicable as a
: Consumer use of air best practice
freshener products, polishes,
washing and cleansing
products, pest control products,
etc.
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8.2.3 Environmental exposure controls Treatment of effluent in biological waste water
treatment plant.
Use of air emission abatement equipments such
as incinerators and scrubbers are applicable as a
best practice
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11. Toxicological information
11.1 Information on toxicological effects
11.1.1 Acute toxicity
Oral Acute toxicity LD50 > 2000 mg/kg (Analogy) Skin Irritation : Not
Irritating (Analogy) Eye Irritation : Severely
Irritating (Analogy) In Vitro Mutagenicity: Not
Mutagenic (Analogy)
Dermal Acute toxicity No data available.
Inhalation Acute toxicity (Vapour) No data available.
Inhalation Acute toxicity (Dust/Mist) No data available.
11.1.2 Skin corrosion/irritation Not irritating (Rabbit, OECD Guideline 404)
11.1.3 Serious eye damage/irritation Highly irritating (Rabbit, OECD Guideline 405)
11.1.4 Irritation to respiratory tract No data available.
11.1.5 Respiratory or skin sensitization Not sensitizing (Guinea pig, male, OECD
Guideline 406)
11.1.6 Germ cell mutagenicity in vitro : mouse lymphoma L5178Y cells
(mammalian cell gene mutation assay, meta. Act. :
with and without) : negative
in vitro : S. typhimurium (Ames test, OECD
Guideline 471, met.act. : with and without) :
negative
in vitro : Chinese hamster lung fibroblasts
(mammalian chromosome aberration test, OECD
Guideline 473, met. Act. : with and without) :
negative
in vivo : mouse (CD-1) male (micronucleus assay,
OECD guideline 474) : negative
11.1.7 Carcinogenicity No data available.
11.1.8 Reproductive toxicity Method : Rat male/female (one generation
screening study, oral: gavage, 0, 100, 300, 1000
mg/kg bw, exposure: 2 weeks before pairing and
continuously thereafter, up to the day before
sacrifice (study day 53, day 4 post partum). (daily),
OECD Guideline 421.
Results : NOAEL (P): 1000 mg/kg bw/day
(nominal) (male/female) (No treatment-related
effects.)
Method : Rat, oral : gavage, 0, 100, 300, 1000
mg/kg bw, exposure : day 6-15 of gestation (daily),
OECD Guideline 414
Results : NOAEL (maternal toxicity): 1000 mg/kg
bw/day (nominal) (no treatment-related effects)
NOAEL (developmental toxicity): 1000 mg/kg
bw/day (nominal) (no treatment-related effects)
11.1.9 STOT-single exposure No data available.
11.1.10 STOT-repeated exposure Method: Rat (male/female), sub chronic (oral:
gavage), 0, 250, 500, 1000 mg/kg bw (nominal in
water), Exposure: 90 days (daily), EU Method B.
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Results: NOAEL: 100 mg/kg bw/day (nominal)
(male/female) (Inflammation and ulcerations of
mucous membrane of the forestomach due to
bolus administration and irritating potential of the
test substance.)
11.1.11 Aspiration hazard No data available.
13.1 Waste treatment methods Small amounts may be diluted with plenty of water
and washed away.
Waste incineration with the approval of the
responsible local authority.
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14. Transport information
14.1 UN number None as product is not classified.
14.2 UN proper shipping name None as product is not classified.
14.3 Transport hazard class(es) None as product is not classified.
14.4 Packing group None as product is not classified.
14.5 Environmental hazard None as product is not classified.
14.6 Special precautions for user None as product is not classified.
14.7 Transport in bulk according to Annex II of MARPOL None as product is not classified.
73/78 and the IBC Code
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OECD SIDS
ECOTOX
NITE
Recommendations on the transport of dangerous goods
Emergency response guide book
EU RAR
The chemical database
HSDB
IARC
ICSC
16.4 Classification for mixtures and used evaluation method according to regulation (EC) 1207/2008 (CLP)
D-Glucopyranose, oligomeric, decyl glycosides
Classification according to Regulation (EC) 1207/2008 Classification procedure
Eye Dam. 1 Calculation method
16.5 Relevant R- and H-phrases (number and full text) R41 Risk of serious damage to eyes.
16.6 Training advice No specific information
16.7 Further information
Original MSDS established April 25, 2020
The (M)SDS is a Hazard Communication tool and should be used to assist in the Risk Assessment.
Many factors determine whether the reported Hazards are Risks in the workplace or other settings. Risks
may be determined by reference to Exposures Scenarios. Scale of use, frequency of use and current or
available engineering controls must be considered.
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