12 - TPP - Nomenclature of Organic Compunds

TOPICAL PRACTICE PROBLEM SHEET
PRACTICE SHEET # 03 (NOMENCLATURE OF ORGANIC CHEMISTRY)

1. Alkanes containing a methyl group on main chain at 2nd carbon are called
a. iso-alkane c. neo-alkane
b. normal-alkane d. branched-alkane
2. While selecting longest possible chains among the organic compounds for nomenclature, when
two or more chains compete each other, which one is selected:
a. Chain with less substitute c. Chain with greater number of substitute
b. Chain near to double bond d. Chain near to triple bond
3. When a double bond and a triple bond compete each other in a single chain, the preference of
giving number 1 carbon will be given to:
a. Double bond c. Triple bond
b. Equally preferred d. None of these
4. The formula of 2-chloro-2-methylpropane is?
a. (CH3)2CH – CI c. (CH3)3C-CI
b. (CH3)2C(CI)2 d. CH3 – (CH2)3 –CI
5. Which one is the name of given compound by IUPAC system of nomenclature?
CH2 = CH – CH = CH2
a. But-2-ene c. 2-methyl-I-ene
b. Buta -1, 3 – diene d. 2, 4 –Butadiene
6. The general formula of alcohol is
a. R ̶ X c. CnH2n+1
b. CnH2n+1 OH d. CnH2n-1 OH
7. The functional group of acid amide is:
a. O c. O
|| ||
̶ C ̶ NH2 ̶ C ̶ X
b. O d. O
|| ||
̶ C ̶ ONH2 ̶ C ̶ NHCl
8. C4H8 is the formula of:
a. Butene c. Both of these
b. Cyclo butane d. None of these
9. (C2H5)3C ̶ OH is an example of:
a. Primary alcohol c. Ter – alcohol
b. Sec – alcohol d. All of these
10. The IUPAC system is also called:
a. Genewa system c. Liege system
b. Amsterdam system d. Greek system
11. Hexanoic acid is also called:
a. Valeric acid c. Palmitic
b. Caproic acid d. Stearic acid
 COMPILED BY: HAFIZ MUHAMMAD SAAD WAQAR

12. The correct IUPAC name of:
CH3
|
CH3 ̶ CH2 ̶ CH2 ̶ CH2 ̶ CH3
|
CH3
a. 2,2 dimethyl pentane c. 3,3 diethyl – propane
b. 3 ,3-dimethyl pentane d. None of these
13. The correct IUPAC name of CH3 – CH = CH – CH2 – C ≡CH :
a. 1 – hexyne – 4-ene c. 4 – hexene – 1-yne
b. 2 – hexyne – 5-yne d. 2 – hexyne – 5-yne
14. If “e” of the saturated hydrocarbon containing seven carbon atoms is replaced by “al” it is
called:
a. Heptenal c. Heptanal
b. Hepatanone d. Hexanal
15. The radical C6H5 is usually named as:
a. Benzyl radical c. Phenyl radical
b. Hexyl radical d. Benzal radical
16. The IUPAC compound given is:
a. Benzophenone c. Phenoxy benzene

b. Diphenyl ether d. Di benzene ether
17. The structure formula of Benzyl chloride is:
a. C6H5 – CH2 – Cl c. C6H5 – CCl3
b. C6H5 – CHCl2 d. C6H5 – Cl
19. The IUPAC name of: CH2 – CH – CH2
| | |
OH OH OH
a. Tripropanol c. 1,2,3 propane – triol
b. 1,2,3 – tripropanal d. Glycerol
20. The IUPAC name of the compound C2H5 – O – Δ is

a. Ethoxy cyclopropane c. Cycloproxy ethane
b. Ethyl – cyclopropane ether d. All of these
21. The correct IUPAC Name of CH3 ̶ CH ̶ CH2 ̶ CH ̶ CH ̶ CH3
| | |
Cl CH3 Br
a 2 ̶chloro̶ 4 methyl ̶ 5 ̶ bromohexane c. 2 ̶ bromo ̶ 3 ̶ methyl ̶ 5 ̶ chloro hexane
b. 2 ̶chloro̶ 5 ̶ bromo ̶ 4 ̶ methyl hexane d. 2 ̶ bromo ̶ 5 ̶ chloro̶ 3 ̶ methyl hexane

22. The correct IUPAC name of the compound given is:
C2H5
|
CH3 ̶ CH ̶ CH ̶ CH3
|
C2H5
a. 2,3 – diethyl – butane c. 3,4 – dimethyl – hexane
b. 2 - ethyl – 3 – methyl – pentane d. 3 – methyl – 4 – ethyl – pentane
24. The correct name of the compound given is:
a. o – ethyl – m – hydroxy chlorobenzene c. o – chloro – o – hydroxy – o – ethyl benzene

b. o – ethyl – m – 1 (Alphatebic Order not d. All are wrong (Best Option)
followed)
25. The chemical formula of urea is
a. NH2COONH4 c. (NH2)2CO
b. C2H2CN d. (NH4)2CO3
26. O
||
R – C – NH2 is called
a. Amino group c. Alcoholic group
b. Amido group d. Ketonic group
27. Which one alcohols is aromatic?
a. Glycerol c. Ethane-1, 2 diol
b. 2-Phenylethanol d. None of these
28. Which one is the name of given compound by IUPAC system of nomenclature?
CH2 = CH – CH = CH2
a. But-2-ene c. 2-methyl-I-ene
b. Buta -1, 3 – diene d. . 2, 4 –Butadiene
29. Which one is not dicarboxylic acid?
a. Terephthalic Acid c. Benzoic Acid
b. Adipic acid d. Oxalic Acid
31. The basic rule of I.U.P.A.C naming for organic compound is the
a. Selection of longest carbon chain c. Alphabetic order for naming of alkyl groups
b. Numbering of the chain d. All of these
32. Which of the following organic compound is not possible?
a. 1.3- pentadiene c. 1.3- pentadiyne
b. 1.2- pentadiene d. 1.2- pentadiyne
33. The saturated alicylic hydrocarbons have the general formula:
a. 𝐶𝑛 𝐻2𝑛+2 -- > Aliphatic c. 𝐶𝑛 𝐻2𝑛 -- > Alicyclic
b. 𝐶𝑛 𝐻2𝑛+1 d. 𝐶𝑛 𝐻2𝑛−1

34. Compounds containing one or more atoms in the ring of heterocylic compounds are called:
a. Aromatic compounds c. Carbocylic compounds
b. Heterocylic compounds d. Aliphatic compounds

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TOPICAL PRACTICE PROBLEM SHEET

PRACTICE SHEET # 03 (NOMENCLATURE OF ORGANIC CHEMISTRY)

 COMPILED BY: HAFIZ MUHAMMAD SAAD WAQAR

a. Benzophenone c. Phenoxy benzene

20. The IUPAC name of the compound C2H5 – O – Δ is

 COMPILED BY: HAFIZ MUHAMMAD SAAD WAQAR

24. The correct name of the compound given is:

a. o – ethyl – m – hydroxy chlorobenzene c. o – chloro – o – hydroxy – o – ethyl benzene

 COMPILED BY: HAFIZ MUHAMMAD SAAD WAQAR

 COMPILED BY: HAFIZ MUHAMMAD SAAD WAQAR

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