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    IR NMR Chart New

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    IR NMR Chart New

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    ashhuuuu777
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    9 views2 pages

    IR NMR Chart New

    Uploaded by

    ashhuuuu777

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    © All Rights Reserved
    Download as PDF, TXT or read online from Scribd
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    Characteristic

     Infrared  Absorption  Frequencies  


     
    Structural  Unit   Wavenumber,  cm   -­‐1 Special  Features  
    O H 3200-­‐3600   ( s,   b r)    
     
    H 3300-­‐3500  (m)   R2N-­‐H  =  one  IR  stretch  
    N H N RNH2  =  two  IR  stretches  
    H
     
    C H ~3300  (s)    
     
    2850-­‐2960  (m)   Look  for  Csp3—H  stretches  just  
    C H
      below  3000  cm-­‐1  
    H-­‐C-­‐H  bending  just  above  1400  cm-­‐1  
    -­‐CH3  bending  just  below  ~1400  cm-­‐1  
    3000-­‐3100  (m)   Look  for  Csp2-­‐H  stretches  just  above  
    C H
      3000  cm-­‐1  
    C N 2200-­‐2300  (s)    
     
    C C ~2150  (v)    
     
    Carbonyl  Groups   1650-­‐1850  (s)   Variable  depending  on  the  carbonyl  
    functionality  (see  below)  
    O
     
    Cl 1750-­‐1850    
    O
     
    RO 1700-­‐1750   Also  look  for  strong  Csp2—O  stretch  
    O between  1200  and  1300  cm-­‐1  
     
    H 1720-­‐1740   Also  look  for  aldehyde  C—H  
    O stretches  at  ~2720  and  ~2820  cm-­‐1  
     
    1680-­‐1750   Generally  around  1720  cm-­‐1;  
    O
      Decreased  when  in  conjugation  
    H 2N 1650-­‐1700    
    O
     
    1600-­‐1700  (v)    
    C C
     
    1450-­‐1600  (v)   Look  for  2  or  3  peaks  in  this  region  
    generally  at  ~1600,  ~1500,  and  
      <1500  cm-­‐1  
    O C
    Csp —O:  1000-­‐1100  (m)    
    3

      Csp2—O:  1200-­‐1300  (s)  


     
      Absorption  strength  abbreviations:  s  =  strong,  m  =  medium,  w  =  weak,  v  =  variable  
    Proton  NMR  Chemical  Shift  Regions  
     
    Z
    H
    O O
    H H
    Z= O,C
    OH H
    H H
    carboxylic aldehyde aromatic vinyl X
    acid

    X = O, N, Halogen saturated

    12 10 8 6 4 2 0
    PPM
     
    Representative  Values  for  the  Saturated  Region  
    Methyl   Methylene   Methine  
    H H
    C H C C H
    H   H    
    ~0.9  ppm   ~1.2  ppm   ~1.7  ppm  
       
    Representative  Values  –  Neighboring  Electronegative  Atom  
    H H H H H
    O C H Cl C H Br C H I C H H 2N C H
    H   H   H   H   H  
    ~3.4  ppm   3.1  ppm   2.7  ppm   2.2  ppm   2.4  ppm  
     
     
    Carbon-­‐13  NMR  Chemical  Shift  Regions  
     
    H
    C
    HC C
    HC CH
    C
    H Aromatics
    O C N
    O C Cl
    C C C
    C C Br
    Alkynes
    O O
    O
    C C C RCH 3 R 3CH
    H C C OR
    N R 2CH 2 R 4C
    Aldehydes Esters, Amides,
    & Keyones Carboxylic Acids Alkenes Alcohols & Ethers Saturated

    220 200 180 160 140 120 100 80 60 40 20 0


    PPM
     

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