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    CHM DPP 23

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    notvivaan1106

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    © All Rights Reserved
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    CHM DPP 23

    Uploaded by

    notvivaan1106
    37 views2 pages

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    chm dpp 23

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    37 views2 pages

    CHM DPP 23

    Uploaded by

    notvivaan1106

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    © All Rights Reserved
    Download as PDF, TXT or read online from Scribd
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    ISOMERISM

    1. CH3CH2CH(CHO)CH2CH3 and CH3CH(CHO) 7. How many alkenes (only structural isomers) are
    CH2CH 2CH3 are :- possible with the molecular formula C4H8
    (1) Chain isomer (2) Positon isomer
    (1) 4 (2) 3 (3) 5 (4) 6
    (3) Metamerism (4) Functional isomer
    2. Find out relation between the following 8. Which of the following is correct :-
    compounds: O O
    O COOH (1) ,
    H
    (1) O and Functional group isomers

    O (2) ; Position isomers


    O C–Cl
    Cl
    (2) and O
    O
    (3) ;
    NH2 H2N H
    (3) CH3CH2CH2CHCH3 and CH3CH2CHCH2CH3
    COOH COOH Position and functional group isomers
    (4) All of these
    O O
    9. Which of the following compounds can show
    (4) O and geometrical isomerism :
    O
    (i) Pent-1-ene
    3. How many amines are possible with the (ii) 1-chloropropene
    molecular formula C4H11N (structural isomers (iii) 2-Methylbut-2-ene
    only) :-
    (iv) CH3–CH=CH–CH3
    (1) 6 (2) 7 (3) 8 (4) 9
    4. How many benzenoid isomers are possible for H H
    molecular formula C7H8O :- Cl Cl
    (1) 3 (2) 4 (3) 5 (4) 6 (v) C C (vi)
    5. The relation between given compound is :- H H COOH COOH

    H CH3
    N CH3 N
    (vii)

    (1) Chain isomerism 10. Assign the configuration E/Z to the following
    (2) Position isomerism compounds.
    (3) Functional isomerism
    (4) Metamerism H2N CH3 H2N OCH3
    6. The structure below are :- C C
    (i) (ii)
    H C C
    CH 3
    H H H H Cl NO2 HS-CH2 F

    H CH3 H CH3
    H CH3 F Cl
    C
    (1) Not isomers (iii) (iv)
    (2) Conformational isomers C
    H D
    (3) Cis-trans isomers
    (4) Structural isomers

    E Your Target is to secure Good Rank in Pre-Medical 2022 3


    11. Which of the following compounds have non zero 13. Which is true for the following isomeric forms
    dipole moment. I & II respectively :

    (1) CCl4 CH3 CH3 CH3


    H
    C=C C=C
    H CH3 H H
    CH3 H
    (2) C=C (I) (II)
    H C2 H 5
    Dipole Boiling Melting Stability
    Cl H moment point point
    (3) C=C
    H Cl (1) I > II I > II II > I I > II
    (2) II > I II > I II > I II > I
    (3) I > II I > II I > II I > II
    (4) Cl Cl
    (4) II > I II > I I > II I > II
    14. In which compound cis-trans nomenclature
    12. Which one of the following is a Z isomer ? cannot be used :
    CH3 Br (1) CH3–CH=CH–COOH
    (1) C=C
    (2) C6H5–CH=CH–C6H5
    H Cl
    (3) C6H5–CH=CHD
    CH3 Cl
    (2) C=C CH3
    H Br (4) C6H5–CH=C
    Cl

    Cl 15. Compare dipole moment of the following


    CH3
    (3) C=C
    Br H Cl Cl H Cl
    (A) C=C ; C=C
    H H Cl H
    CH3 H
    (4) C=C
    H CH3 F CH3 F H
    (B) C=C ; C=C
    H H H CH3
    (C) CH3–CH2–CCH ; CH3–CC–CH3

    ANSWER KEY
    Q ue. 1 3 4 5 6 7 8 11 12 13 14
    Ans . 1 3 3 3 4 2 2 2 1 4 4

    2. (i) Functional Group Isomerism 9. (ii), (iv), (v), (vi), (vii)


    (ii) Functional Group Isomerism 10. (i) Z (ii) Z (iii) Z (iv) 2Z, 4E
    (iii)Chain Isomerism 15. (A) i > ii (B) ii > i (C) i > ii
    (iv)Functional Isomerism

    4 Your Target is to secure Good Rank in Pre-Medical 2022 E

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