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    Review Test-3(Home Assignment)

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    shubhamsurat4

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    Review Test-3(Home Assignment)

    Uploaded by

    shubhamsurat4
    6 views3 pages

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    6 views3 pages

    Review Test-3(Home Assignment)

    Uploaded by

    shubhamsurat4

    Copyright:

    © All Rights Reserved
    Download as PDF, TXT or read online from Scribd
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    ORGANIC CHEMISTRY

    Review test-3(Home assignment) Time:- 45min

    1. Which compound does not form geometrical isomers ?

    (1) (2) (3) (Ph)2C = NOH (4)

    2. CH3 – CH – C – H and CH3 – CH2 – C – Cl represent an example of :


    Cl O O
    (1) Position isomer (2) Geometrical isomer (3) Metamer (4) Functional isomer

    3. Which of the following compounds does not exhibit tautomerism :


    (1) CH3COCH3 (2) CH2 = CHOH
    (3) CH3COCH2COOC2H5 (4) CH 2 = CH – CH2OH

    4. The two structure are :

    H Me Me H

    Me H and H Me

    H Me Me H
    (1) Enantiomers (2) Diastereomers (3) Identical (4) None

    5. CH3CH2 – C – CH2CH3 and CH3 – C – CH(CH3)2 are in fact :


    O O
    (1) Tautomers (2) Functional group isomers
    (3) Metamers (4) Chain isomers

    6. and C – C = C show the isomerism :


    C
    (1)Ring Chain (2) Functional (3) Position (4) None of the above

    7. 'Z' isomer is :
    Cl H Cl CH3
    (1) C=C (2) C=C
    F Br F C2H5
    HOOC COOH H3C Cl
    (3) C=C (4) C=C
    H H H5C2 COOH
    8. Which one is the pair of chain isomers :
    (1) CH3 – CH = CH – CH3, CH2 = CH – CH2 – CH3
    (2) CH2 = C = CH2, CH  C – CH3
    Cl
    (3) CH3 – C – CH2 , CH2 = CH – CH – CH2 – CH3
    CH3
    (4) None of the above

    9. CH 3 – C = CH – COOH , CH3 – C = CH – COOH


    Br Br
    The two acids exhibit :
    (1) Position isomerism (2) Metamerism
    (3) Tautomerism (4) Chain isomerism

    10. Select the correct statement :


    (1) Vinyl alcohol and acetaldehyde are not tautomers
    (2) Pentanal and 2-pentanone are metamers
    (3) Acetone and 1-propen-2-ol are not tautomers
    (4) 2-methylpropene and isobutylene are the same compounds

    11. Cis and trans 4-t-butylcyclohexanol are :


    (1)Structural isomers (2) Enantiomers (3) Diastereomers (4) Homologues
    Br

    12. Configuration of the compound C H is :


    H3C Cl
    (1) E (2) R (3) S (4) Z

    13. Which of the following compound is not chiral :


    (1) 1-Chloropentane (2) 3-Chloro-2-methylpentane
    (3) 1-Chloro-2-methylpentane (4) 2-Chloropentane

    14. Which compound is achiral?


    Cl SH Cl OH Cl COH Cl COH
    (1) (2) (3) (4)
    CH2OH

    15. Which of the following Fischer's projection formula is identical to D-glyceraldehyde :


    CH2OH CH2OH
    (1) HO CHO (2) H OH
    H CHO
    CHO CHO
    (3) HO CH2OH (4) H CH2OH
    H OH
    16. Among the following which can have a meso form ?
    (1) CH3CH(OH)CH(Cl)C2H5 (2*) CH3CH(OH)CH(OH)CH3
    (3) C2H5CH(OH)CH(OH)CH3 (4) HOCH2CH(Cl)CH3

    17. Consider the following representation :


    CH3 CH3
    H Br F H
    F Br
    They are :
    (1) Enantiomer (2) Diastereomers (3) Conformational isomer (4) Identical

    18. The structure of 2R, 3S-dibromocinnamic acid is :

    CO2H CO2H CO2H CO2H


    Br H H Br Br H
    H Br
    (1) (2) H Br (3) Br H (4) Br H
    H Br
    Ph Ph Ph Ph

    19. 2-Pentanone and 3-methyl-2-butanone are a pair of ........... isomers :


    (1) Functional (2) Chain (3) Positional (4) Stereo

    20. What kind of isomerism is possible for 1-chloro-2-nitro-ethene?


    (1) Functional group isomerism (2) Positional isomerism
    (3) E/Z isomerism (4) Optical isomerism

    21. How many optically active stereo isomers of 2,3-butane diol are possible?

    22. Total number of isomers considering both structural and stereoisomers of cyclic ethers with the
    molecular formula C4H8O will be?

    23. Number of geometrical isomers of the following compound?

    24. Find out the number of different structural isomers possible for C4H10O.

    25. How many cyclic structural isomers are possible for C5H10?

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