Avitera® Red Se: Safety Data Sheet

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SAFETY DATA SHEET

AVITERA® RED SE
Version Revision Date: SDS Number: Date of last issue: 01/12/2017
1.2 11/14/2018 400001011534 Date of first issue: 11/07/2016

SECTION 1. IDENTIFICATION

Product name : AVITERA® RED SE

Manufacturer or supplier's details


Company name of supplier : Huntsman International LLC
Address : 2795 Slough Avenue
Mississauga, ON L4T 1G2,
Canada
Telephone : +1 905 678 9150

E-mail address of person : SDS@huntsman.com


responsible for the SDS

Emergency telephone number : Chemtrec: (800) 424-9300 or (703) 527-3887

Recommended use of the chemical and restrictions on use


Recommended use : Textile dye

Restrictions on use : For industrial use only.

SECTION 2. HAZARDS IDENTIFICATION

GHS classification in accordance with the Hazardous Products Regulations


Eye irritation : Category 2A

Skin sensitisation : Category 1

GHS label elements


Hazard pictograms :

Signal word : Warning

Hazard statements : H317 May cause an allergic skin reaction.


H319 Causes serious eye irritation.

Precautionary statements : Prevention:


P261 Avoid breathing dust/ fume/ gas/ mist/ vapours/ spray.
P264 Wash skin thoroughly after handling.
P272 Contaminated work clothing should not be allowed out of
the workplace.
P280 Wear protective gloves/ eye protection/ face protection.
Response:
P302 + P352 IF ON SKIN: Wash with plenty of water.
P305 + P351 + P338 IF IN EYES: Rinse cautiously with water

SDS_CA-TE – EN – 400001011534 1 / 14
SAFETY DATA SHEET

AVITERA® RED SE
Version Revision Date: SDS Number: Date of last issue: 01/12/2017
1.2 11/14/2018 400001011534 Date of first issue: 11/07/2016

for several minutes. Remove contact lenses, if present and easy


to do. Continue rinsing.
P333 + P313 If skin irritation or rash occurs: Get medical advice/
attention.
P337 + P313 If eye irritation persists: Get medical advice/
attention.
P362 + P364 Take off contaminated clothing and wash it before
reuse.
Storage:
Not available
Disposal:
P501 Dispose of contents/container to an approved facility in
accordance with local, regional, national and international
regulations.

Other hazards
None known.

SECTION 3. COMPOSITION/INFORMATION ON INGREDIENTS

Substance / Mixture : Mixture

Chemical nature : Mixture

Hazardous components
Chemical name CAS-No. Concentration (% w/w)
Reactive Red TZ 5978 1198102-85-0 70 - 80

SECTION 4. FIRST AID MEASURES

General advice : Move out of dangerous area.


Show this safety data sheet to the doctor in attendance.
Treat symptomatically.
Get medical attention if symptoms occur.

If inhaled : If inhaled, remove to fresh air.


Get medical attention if symptoms occur.

In case of skin contact : If on skin, rinse well with water.

In case of eye contact : Immediately flush eye(s) with plenty of water.


Remove contact lenses.
Keep eye wide open while rinsing.
If eye irritation persists, consult a specialist.

If swallowed : Keep respiratory tract clear.


Never give anything by mouth to an unconscious person.
If symptoms persist, call a physician.

Most important symptoms : None known.


and effects, both acute and

SDS_CA-TE – EN – 400001011534 2 / 14
SAFETY DATA SHEET

AVITERA® RED SE
Version Revision Date: SDS Number: Date of last issue: 01/12/2017
1.2 11/14/2018 400001011534 Date of first issue: 11/07/2016

delayed

Notes to physician : Treat symptomatically.

SECTION 5. FIREFIGHTING MEASURES

Suitable extinguishing media : Use extinguishing measures that are appropriate to local
circumstances and the surrounding environment.

Unsuitable extinguishing : High volume water jet


media

Specific hazards during : No information available.


firefighting

Hazardous combustion : Carbon oxides


products Sulphur oxides
Oxides of phosphorus
Metal oxides

Specific extinguishing : No data is available on the product itself.


methods

Further information : No action shall be taken involving any personal risk or without
suitable training.

Special protective equipment : Wear self-contained breathing apparatus for firefighting if


for firefighters necessary.

SECTION 6. ACCIDENTAL RELEASE MEASURES

Personal precautions, : Use personal protective equipment.


protective equipment and Avoid dust formation.
emergency procedures Avoid breathing dust.
Refer to protective measures listed in sections 7 and 8.

Environmental precautions : Prevent product from entering drains.


Prevent further leakage or spillage if safe to do so.
If the product contaminates rivers and lakes or drains inform
respective authorities.

Methods and materials for : Keep in suitable, closed containers for disposal.
containment and cleaning up

SECTION 7. HANDLING AND STORAGE

Advice on protection against : Avoid dust formation.


fire and explosion Provide appropriate exhaust ventilation at places where dust
is formed.

Advice on safe handling : Avoid formation of respirable particles.

SDS_CA-TE – EN – 400001011534 3 / 14
SAFETY DATA SHEET

AVITERA® RED SE
Version Revision Date: SDS Number: Date of last issue: 01/12/2017
1.2 11/14/2018 400001011534 Date of first issue: 11/07/2016

Do not breathe vapours/dust.


Avoid exposure - obtain special instructions before use.
Avoid contact with skin and eyes.
For personal protection see section 8.
Smoking, eating and drinking should be prohibited in the
application area.
Dispose of rinse water in accordance with local and national
regulations.
Persons susceptible to skin sensitisation problems or asthma,
allergies, chronic or recurrent respiratory disease should not
be employed in any process in which this mixture is being
used.

Conditions for safe storage : Keep container tightly closed in a dry and well-ventilated place.
Keep in properly labelled containers.

Materials to avoid : For incompatible materials please refer to Section 10 of this


SDS.

Recommended storage : < 40 °C


temperature
Further information on : Keep in a dry place.
storage stability

SECTION 8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Components with workplace control parameters


Contains no substances with occupational exposure limit values.
Personal protective equipment
Respiratory protection : Use respiratory protection unless adequate local exhaust
ventilation is provided or exposure assessment demonstrates
that exposures are within recommended exposure guidelines

Filter type : Particulates type

Hand protection
Material : Neoprene gloves
Break through time : <1h

Remarks : The suitability for a specific workplace should be discussed


with the producers of the protective gloves.

Eye protection : Eye wash bottle with pure water


Tightly fitting safety goggles
Wear face-shield and protective suit for abnormal processing
problems.

Skin and body protection : Dust impervious protective suit


Choose body protection according to the amount and
concentration of the dangerous substance at the work place.

Hygiene measures : When using do not eat or drink.


When using do not smoke.

SDS_CA-TE – EN – 400001011534 4 / 14
SAFETY DATA SHEET

AVITERA® RED SE
Version Revision Date: SDS Number: Date of last issue: 01/12/2017
1.2 11/14/2018 400001011534 Date of first issue: 11/07/2016

Wash hands before breaks and at the end of workday.

SECTION 9. PHYSICAL AND CHEMICAL PROPERTIES

Appearance : powder

Colour : red

Odour : odourless

Odour Threshold : No data is available on the product itself.

pH : 6 - 8 (20 °C)
Concentration: 10 g/l

Melting point/freezing point : No data available

Boiling point/boiling range : No data available

Flash point : No data is available on the product itself.

Evaporation rate : No data is available on the product itself.

Flammability (solid, gas) : No data is available on the product itself.

Flammability (liquids) : No data is available on the product itself.

Upper explosion limit / Upper : No data is available on the product itself.


flammability limit

Lower explosion limit / Lower : No data is available on the product itself.


flammability limit

Vapour pressure : No data is available on the product itself.

Relative vapour density : No data is available on the product itself.

Relative density : No data is available on the product itself.

Density : 1 g/cm3 (20 °C)

Solubility(ies)
Water solubility : > 100 g/l (20 °C)

Solubility in other solvents : No data is available on the product itself.

Partition coefficient: n- : log Pow: -4.2 (20 °C)


octanol/water
pH: 6.3
Method: OECD Test Guideline 107

Auto-ignition temperature : No data is available on the product itself.

Decomposition temperature : > 200 °C

SDS_CA-TE – EN – 400001011534 5 / 14
SAFETY DATA SHEET

AVITERA® RED SE
Version Revision Date: SDS Number: Date of last issue: 01/12/2017
1.2 11/14/2018 400001011534 Date of first issue: 11/07/2016

Self-Accelerating : No data is available on the product itself.


decomposition temperature
(SADT)

Viscosity : No data is available on the product itself.

Explosive properties : No data is available on the product itself.

Oxidizing properties : None.

Molecular weight : No data available

Particle size : No data is available on the product itself.

SECTION 10. STABILITY AND REACTIVITY

Reactivity : No dangerous reaction known under conditions of normal use.


Chemical stability : Stable under normal conditions.
Possibility of hazardous : Dust may form explosive mixture in air.
reactions
Conditions to avoid : None known.

Incompatible materials : None known.

Hazardous decomposition : carbon dioxide


products
carbon monoxide

Sulphur Oxides

Oxides of phosphorus

Metal oxides

SECTION 11. TOXICOLOGICAL INFORMATION

Information on likely routes of : No data is available on the product itself.


exposure
Acute toxicity
Components:
Reactive Red TZ 5978:
Acute oral : LD50 (Rat): > 2,000 mg/kg
toxicityComponents Method: OECD Test Guideline 401
Assessment: The substance or mixture has no acute oral
toxicity

Acute inhalation toxicity : No data available

SDS_CA-TE – EN – 400001011534 6 / 14
SAFETY DATA SHEET

AVITERA® RED SE
Version Revision Date: SDS Number: Date of last issue: 01/12/2017
1.2 11/14/2018 400001011534 Date of first issue: 11/07/2016

Components:
Reactive Red TZ 5978:
Acute dermal toxicity : LD50 (Rat): > 2,000 mg/kg
Method: OECD Test Guideline 402
Assessment: The substance or mixture has no acute dermal
toxicity

Acute toxicity (other routes of : No data available


administration)

Skin corrosion/irritation
No data available

Serious eye damage/eye irritation


Components:
Reactive Red TZ 5978:
Species: Rabbit
Result: Irritation to eyes, reversing after 7 to 21 days
Method: OECD Test Guideline 405

Respiratory or skin sensitisation


Product:
Exposure routes: Skin
Species: Mouse
Method: OECD Test Guideline 429
Result: Causes sensitisation.

Components:
Reactive Red TZ 5978:
Assessment: May cause sensitisation by skin contact.

Germ cell mutagenicity


Components:
Reactive Red TZ 5978:
Genotoxicity in vitro : Metabolic activation: with and without metabolic activation
Method: OECD Test Guideline 473
Result: positive

Method: OECD Test Guideline 476


Result: negative

Components:
Reactive Red TZ 5978:
Genotoxicity in vivo : Method: OECD Test Guideline 474
Result: negative

Carcinogenicity
No data available

SDS_CA-TE – EN – 400001011534 7 / 14
SAFETY DATA SHEET

AVITERA® RED SE
Version Revision Date: SDS Number: Date of last issue: 01/12/2017
1.2 11/14/2018 400001011534 Date of first issue: 11/07/2016

Carcinogenicity - : No data available


Assessment

ACGIH No component of this product present at levels greater than or


equal to 0.1% is identified as a carcinogen or potential
carcinogen by ACGIH.

Reproductive toxicity
Components:
Reactive Red TZ 5978:
Effects on fertility : Species: Rat, male and female
Application Route: Oral
Method: OECD Test Guideline 421
Result: negative

Components:
Reactive Red TZ 5978:
Effects on foetal : Species: Rat, female
development Application Route: Oral
General Toxicity Maternal: No observed adverse effect level:
1,000 mg/kg body weight
Method: OECD Test Guideline 414
Result: No teratogenic effects

Reproductive toxicity - : No data available


Assessment

STOT - single exposure


No data available

STOT - repeated exposure


No data available

Repeated dose toxicity


Components:
Reactive Red TZ 5978:
Species: Rat
NOAEL: 300 mg/kg
Application Route: Ingestion
Exposure time: 672 h
Method: Subacute toxicity

Repeated dose toxicity - : No data available


Assessment

Aspiration toxicity
No data available

SDS_CA-TE – EN – 400001011534 8 / 14
SAFETY DATA SHEET

AVITERA® RED SE
Version Revision Date: SDS Number: Date of last issue: 01/12/2017
1.2 11/14/2018 400001011534 Date of first issue: 11/07/2016

Experience with human exposure


General Information: No data available

Inhalation: No data available

Skin contact: No data available

Eye contact: No data available

Ingestion: No data available

Toxicology, Metabolism, Distribution


No data available

Neurological effects
No data available

Further information
Ingestion: No data available

Other health hazards


No data available

SECTION 12. ECOLOGICAL INFORMATION

Ecotoxicity
Components:
Reactive Red TZ 5978:
Toxicity to fish : LC50 (Brachydanio rerio (zebrafish)): > 110 mg/l
Exposure time: 96 h
Method: OECD Test Guideline 203

Toxicity to daphnia and other : EC50 (Daphnia magna (Water flea)): > 100 mg/l
aquatic invertebrates - Exposure time: 48 h
Product Method: OECD Test Guideline 202

Toxicity to algae - Product : EC50 (Selenastrum capricornutum (green algae)): > 100 mg/l
Exposure time: 72 h
Method: OECD Test Guideline 201

M-Factor (Acute aquatic : No data available


toxicity)

Components:

SDS_CA-TE – EN – 400001011534 9 / 14
SAFETY DATA SHEET

AVITERA® RED SE
Version Revision Date: SDS Number: Date of last issue: 01/12/2017
1.2 11/14/2018 400001011534 Date of first issue: 11/07/2016

Reactive Red TZ 5978:


Toxicity to fish (Chronic : NOEC (Brachydanio rerio (zebrafish)): 158 mg/l
toxicity) Exposure time: 14 d
Test Type: semi-static test
Test substance: Fresh water
Method: OECD Test Guideline 204

Components:
Reactive Red TZ 5978:
Toxicity to daphnia and other : NOEC (Daphnia magna (Water flea)): 4.69 mg/l
aquatic invertebrates Exposure time: 21 d
(Chronic toxicity) Test Type: semi-static test
Test substance: Fresh water
Method: OECD Test Guideline 211

M-Factor (Chronic aquatic : No data available


toxicity)

Toxicity to microorganisms - : IC50 (activated sludge): > 1,000 mg/l


Product Exposure time: 3 h
Method: OECD Test Guideline 209

Toxicity to soil dwelling : No data available


organisms

Plant toxicity : No data available

Sediment toxicity : No data available

Toxicity to terrestrial : No data available


organisms

Ecotoxicology Assessment
Acute aquatic toxicity : No data available

Chronic aquatic toxicity : No data available

Toxicity Data on Soil : No data available

Other organisms relevant to : No data available


the environment

Persistence and degradability


Biodegradability - Product : Result: Not readily biodegradable.
Biodegradation: 0 %
Exposure time: 28 d
Method: OECD Test Guideline 301F

Result: Not readily biodegradable.


Biodegradation: < 10 %
Exposure time: 28 d
Method: OECD Test Guideline 302B

Biochemical Oxygen : 0 mgO2/g

SDS_CA-TE – EN – 400001011534 10 / 14
SAFETY DATA SHEET

AVITERA® RED SE
Version Revision Date: SDS Number: Date of last issue: 01/12/2017
1.2 11/14/2018 400001011534 Date of first issue: 11/07/2016

Demand (BOD) - Product

Chemical Oxygen Demand : 900 mgO2/g


(COD) - Product
BOD/COD : No data available

ThOD : No data available

BOD/ThOD : No data available

Dissolved organic carbon : No data available


(DOC)

Physico-chemical : No data available


removability

Stability in water : No data available

Photodegradation : No data available

Impact on Sewage : No data available


Treatment

Bioaccumulative potential
Components:
Reactive Red TZ 5978:
Bioaccumulation : Species: Brachydanio rerio (zebrafish)
Bioconcentration factor (BCF): 0.16
Remarks: Does not bioaccumulate.

Partition coefficient: n- : log Pow: -4.2 (20 °C)


octanol/water - Product pH: 6.3
Method: OECD Test Guideline 107

Mobility in soil
Mobility : No data available

Components:
Reactive Red TZ 5978:
Distribution among : Koc: < 18
environmental compartments Method: OECD Test Guideline 121

Stability in soil : No data available

Other adverse effects


Environmental fate and : No data available
pathways

Results of PBT and vPvB : No data available


assessment

Endocrine disrupting : No data available

SDS_CA-TE – EN – 400001011534 11 / 14
SAFETY DATA SHEET

AVITERA® RED SE
Version Revision Date: SDS Number: Date of last issue: 01/12/2017
1.2 11/14/2018 400001011534 Date of first issue: 11/07/2016

potential

Adsorbed organic bound : < .1 %


halogens (AOX) - Product Test substance: Chlorine

Hazardous to the ozone layer


Ozone-Depletion Potential Not applicable

Additional ecological : No data available


information

Global warming potential : No data available


(GWP)

SECTION 13. DISPOSAL CONSIDERATIONS

Disposal methods
Waste from residues : Do not dispose of waste into sewer.
Do not contaminate ponds, waterways or ditches with
chemical or used container.
Send to a licensed waste management company.
Dispose of as hazardous waste in compliance with local and
national regulations.
Dispose of contents/ container to an approved waste disposal
plant.

Contaminated packaging : Empty remaining contents.


Dispose of as unused product.
Do not re-use empty containers.

SECTION 14. TRANSPORT INFORMATION

International Regulations

TDG
Not regulated as dangerous goods

IATA
Not regulated as dangerous goods

IMDG
Not regulated as dangerous goods
Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code
Not applicable for product as supplied.

National Regulations

SDS_CA-TE – EN – 400001011534 12 / 14
SAFETY DATA SHEET

AVITERA® RED SE
Version Revision Date: SDS Number: Date of last issue: 01/12/2017
1.2 11/14/2018 400001011534 Date of first issue: 11/07/2016

TDG
Not regulated as dangerous goods

SECTION 15. REGULATORY INFORMATION

The components of this product are reported in the following inventories:


CH INV : The formulation contains substances listed on the Swiss
Inventory, On the inventory, or in compliance with the
inventory
TSCA : On the inventory, or in compliance with the inventory
DSL : This product contains one or several components that are not
on the Canadian DSL nor NDSL.
AICS : Not in compliance with the inventory
NZIoC : Not in compliance with the inventory
ENCS : Low volume exemption, On the inventory, or in compliance
with the inventory
KECI : On the inventory, or in compliance with the inventory
PICCS : On the inventory, or in compliance with the inventory
IECSC : Low volume exemption, On the inventory, or in compliance
with the inventory
TCSI : On the inventory, or in compliance with the inventory
Inventories
AICS (Australia), DSL (Canada), IECSC (China), REACH (European Union), ENCS (Japan),
ISHL (Japan), KECI (Korea), NZIoC (New Zealand), PICCS (Philippines), TCSI (Taiwan), TSCA
(USA)

Canada. CEPA 1999 Significant New Activity (SNAc) List


No substances are subject to a Significant New Activity Notification.

SECTION 16. OTHER INFORMATION

Further information

NFPA 704: HMIS® IV:


Flammability
HEALTH 2
1
FLAMMABILITY 1
Instability
Health

2 0
PHYSICAL HAZARD 0

HMIS® ratings are based on a 0-4 rating


scale, with 0 representing minimal
Special hazard.
hazards or risks, and 4 representing
significant hazards or risks. The "*"
represents a chronic hazard, while the "/"
represents the absence of a chronic
hazard.

Revision Date : 11/14/2018

SDS_CA-TE – EN – 400001011534 13 / 14
SAFETY DATA SHEET

AVITERA® RED SE
Version Revision Date: SDS Number: Date of last issue: 01/12/2017
1.2 11/14/2018 400001011534 Date of first issue: 11/07/2016

The information and recommendations in this publication are to the best of our knowledge,
information and belief accurate at the date of publication, NOTHING HEREIN IS TO BE
CONSTRUED AS A WARRANTY, EXPRESS OR OTHERWISE.

IN ALL CASES, IT IS THE RESPONSIBILITY OF THE USER TO DETERMINE THE


APPLICABILITY OF SUCH INFORMATION AND RECOMMENDATIONS AND THE
SUITABILITY OF ANY PRODUCT FOR ITS OWN PARTICULAR PURPOSE.

THE PRODUCT MAY PRESENT HAZARDS AND SHOULD BE USED WITH CAUTION. WHILE
CERTAIN HAZARDS ARE DESCRIBED IN THIS PUBLICATION, NO GUARANTEE IS MADE
THAT THESE ARE THE ONLY HAZARDS THAT EXIST.

Hazards, toxicity and behaviour of the products may differ when used with other materials and are
dependent upon the manufacturing circumstances or other processes. Such hazards, toxicity and
behaviour should be determined by the user and made known to handlers, processors and end
users.

The trademarks above are the property of Huntsman Corporation or an affiliate thereof.

NO PERSON OR ORGANIZATION EXCEPT A DULY AUTHORIZED HUNTSMAN EMPLOYEE


IS AUTHORIZED TO PROVIDE OR MAKE AVAILABLE DATA SHEETS FOR HUNTSMAN
PRODUCTS. DATA SHEETS FROM UNAUTHORIZED SOURCES MAY CONTAIN
INFORMATION THAT IS NO LONGER CURRENT OR ACCURATE.

SDS_CA-TE – EN – 400001011534 14 / 14

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