Energies 15 05807 v2
Energies 15 05807 v2
Energies 15 05807 v2
Review
Research Progress on Triboelectric Nanogenerator for
Sports Applications
Caixia Li 1 , Yongsheng Zhu 1 , Fengxin Sun 1 , Changjun Jia 1 , Tianming Zhao 2,3 , Yupeng Mao 1, *
and Haidong Yang 1, *
Abstract: Progress in science and technology drives the continuous innovation of energy collection
and utilization. In the field of sports, the information collection and analysis based on Internet
of things have attracted particular attention. Moreover, triboelectric nanogenerator (TENG) has
promising applications in the field of sports. Here, we introduce the working principle of the TENG
then the progress of the TENG as a wearable energy sensor is examined in the two fields of basic
human activities and sports, especially competitive sports. On this basis, it is considered that the
stability of devices, the universality of materials, and the scientificity of application of the TENG
in the future need to be improved. We provide a direction for further upgrading energy collection
technology to promote the high-quality development of human mechanical energy sensing in the
field of sports.
2. Triboelectric Nanogenerator
As a new branch of energy conversion technology, the TENG can convert the me-
chanical energy into electrical energy effectively, with a self-driving system [50,51]. The
operation principle of TENG is based on the coupling effect of contact electrification and
electrostatic induction, and its fundamental physics model can be traced back to Maxwell’s
equations. The TENG has four working modes (Figure 1a): the vertical contact-separation
mode, lateral sliding mode, single electrode mode, and freestanding triboelectric-layer
mode [14]. The principles of different working modes are roughly the same. It is generally
believed that after two different materials come into contact, chemical bonds are formed
between some parts of the two surfaces, which is called adhesion. After separation, some
bound atoms tend to retain additional electrons, and some tend to release electrons, which
may generate friction charges on the surface [52]. In other words, materials with different
electron adsorption capacity generate electric charges through mutual friction, and the
potential difference drives the transfer of electrons, thus forming an electric current.
Here we select the vertical contact-separation mode for detailed description (Figure 1b).
At the original position, there is no charge (Figure 1bI). When two surfaces of different
materials are in contact, frictional charges will be generated on the contact surface due to the
difference in the ability to adsorb electrons (Figure 1bII). Once two surfaces are separated,
a potential difference will occur, causing electrons to flow from the bottom electrode to
the top electrode (Figure 1bIII). When the two surfaces are completely separated to the
initial position, the charge will reach equilibrium (Figure 1bIV). When the two surfaces are
close to each other, the electrons flow from the top electrode to the bottom through the load
Energies 2022, 15, 5807 3 of 15
again (Figure 1bV). The current change during the whole process is shown in the bottom
left of Figure 1.
Figure 1. (a) The TENG’s four working modes. Reprinted with permission from Ref. [50]. Copy-
right 2021 American Chemical Society. (b) Schematic diagram of working principle of TENG in
vertical contact-separation mode. Reprinted with permission from Ref. [1]. Copyright 2021 Wiley
Online Library.
make ITENG. As shown in Figure 2e, the resistance of ITENG increases with the bending
degree of fingers. The bending angle can be identified and distinguished by detecting
the change of resistance. Because the ionic gel has good elasticity, the monitoring of the
device is accurate and repeatable. In the material selection of the TENG, the reuse of
waste material is a hot spot [61–64]. Bhaskar et al. proposed a recycled material-based
triboelectric nanogenerator (TENG) made of plastic waste and carbon-coated paper wipes
(C@PWs) (Figure 2f), and C@PW-Teng has been reshaped into a smart wristband device,
as shown in Figure 2g [65]. However, since this device has no waterproof function, the
moisture in the external environment will affect its working performance. Therefore, the
surface of the wrist strap needs to be wrapped with a layer of polyethylene to prevent
interference in the humid environment. Minglu Zhu et al. developed a self-powered
and self-functional sock (S2-sock) based on a triboelectric nanogenerator (TENG) and
lead zirconate titanate (PZT) piezoelectric chips (Figure 2h) [66]. The S2-sock has diverse
functions for energy harvesting and sensing various physiological signals (gait, contact
force, sweat level, etc.). Figure 2i,j shows the electrical signals under different synchrony
and under the same synchrony, different weights, and different ambient humidity. This
proves that the S2-sock can successfully realize walking pattern recognition and motion
tracking for smart home applications through changes in environmental factors and human
body weight. Textile articles based on TENG can not only contribute to sports monitoring
in the future, but also play a huge role in medical care. X.W. Hu et al. proposed a high-
output flexible ring-structure TENG (FR-TENG) [67]. Since its fabrication materials are
sponge-like porous PDMS and organic flexible hydrogels, it has good tensile properties.
By optimizing the concentration of deionized water, the output performance is greatly
improved. On this basis, a motion monitoring and protection elastic band is made to
monitor human motion data. Wearing the motion monitoring protection elastic band on
the arm, as shown in Figure 2k, the measured voltage can reflect the force of the biceps
when the arm is naturally bent and the arm is bent hard. Experiments compared the
output performance of FR-TENG with pure PDMS and FR-TENG with porous PDMS under
different stress conditions (Figure 2l,m), which further verified that FR-TENG with porous
PDMS has higher sensitivity and output performance can better reflect the strength of
human muscles. Table 1 compares the basic properties of the above five devices in terms
of humidity resistance, self-healing, breathability, and electrical output, as well as their
application scope. The TENGs based on various conductivity and material properties have
different application fields due to their different device characteristics. In a word, the TENG
still has a huge development prospect in the monitoring of basic human activities.
Table 1. Features and application comparison of different TENGs in basic human activity.
Humidity
Devices Self-Healing Breathability Electrical Output Applications
Resistance
Textile-TENG √
~200 V green electronics
(Zhu et al. [59])
ITENG √ wearable electronics,
~115 V
(Sun et al. [60]) E-skin, and soft robotics
C@PW-TENG √ emergency
~174 V
(Bhaskar et al. [65]) communication device
S2-sock √ √ smart home, sports
~196 V
(Zhu et al. [66]) monitoring, healthcare
health monitoring,
FR-TENG √ self-powered system and
~100 V
(Hu et al. [67]) human-machine
interaction
Energies 2022, 15, 5807 5 of 15
Figure 2. (a) Schematic diagram of flexible triboelectric nanogenerator (TENG) based on silicone
rubber. The illustration is a cross-sectional view of the FE-SEM image of TENG. (b,c) Photographic
images and corresponding output performance of TENG fixed at different positions of human body.
(a–c) Reprinted with permission from Ref. [59]. Copyright 2022, Springer Nature Switzerland AG.
(d) Photo of ionic gel fiber woven into fabric. (e) The change of relative resistance of ionic gel
fiber during continuous action and holding test. (d,e) Reprinted with permission from Ref. [60].
Copyright 2022, Highly Transparent, Stretchable, and Self-Healable Ionogel for Multifunctional
Sensors, Triboelectric Nanogenerator, and Wearable Fibrous Electronics. (f) Schematic illustration
and characterization of carbon-coated paper wipes (PWs). (g) C@PW photos of TENG as a wearable
smart wrist strap. (f,g) Reprinted with permission from Ref. [65]. Copyright 2022, ACS Publications.
(h) A diagram of the operating mechanism of S2-sock. (i) Gait characterization with typical voltage
signals under the contact sequences of two motions, forward: heel contact → forefoot contact,
backward: forefoot contact → heel contact. All signals are collected from the sock, with the positive
peak represents separation and negative peak represent the contact. (j) Comparison of TENG gait
characterization with different weights (45, 70, and 90 kg) and humidity levels (70% RH and 90%
RH). (h–j) Reprinted with permission from Ref. [66]. Copyright 2019, American Chemical Society.
(k) Image of a FR-TENG used in testing the strength of the biceps muscle. (l) The output voltage
of FR-TENG with pure PDMS corresponding to different force conditions. (m) The output voltage
of FR-TENG with porous PDMS corresponding to different force conditions. (k–m) Reprinted with
permission from Ref. [67]. Copyright 2021 IEEE.
Energies 2022, 15, 5807 6 of 15
Figure 3. (a) Concept diagram of intelligent saddle mounted on horse, which is used to collect
information and energy. (b) Structural design sectional view of SRE-TENG. (a,b) Reprinted with
permission from Ref. [81]. Copyright 2022 American Chemical Society. (c) Schematic diagram of
long jump monitoring system with its own power supply, electrical signal generated by CC-TENG
and schematic diagram of self-powered reaction system. Reprinted with permission from Ref. [82].
Copyright 2022 Informa UK Limited. (d) Experimental design of big data analysis of the intelligent
sensor with its own power supply in table tennis training. (e) The device for playing table tennis is
integrated with four sensor units. The illustration shows the real-time three electric signals of the four
sensor units. (d,e) Reprinted with permission from Ref. [83]. (f) WS-TENG workflow. (g) Pictures
of athletes’ walking competition. (h) The voltage signal of WS-TENG when there is no foul in the
walking competition. (i) The voltage signal of WS-TENG when an athlete commits a foul in the
walking competition. (f–i) Reprinted with permission from Ref. [87]. Copyright 2022, Informa UK
Limited. (j) A 2 × 3 schematic diagram of integrated electronic skin array on both arms. (k) Display
photos of 2 × 3 integrated electronic skin array. (l) The real-time output voltage signal when the
volleyball impacts the different positions of the electronic skin array. (j–l) Reprinted with permission
from Ref. [88]. Copyright 2021, American Chemical Society.
Energies 2022, 15, 5807 8 of 15
√ intelligent athletic
SRC-TENG
~55 V facilities, and
(Hao et al. [81])
sport safety
CC-TENG √ sports training and
~400 V
(Liu et al. [82]) intelligent sports
√ intelligent athletic
PP-TENG
~6.05 V facilities and big
(Ma et al. [83])
data analytics
WS-TENG √ athlete monitoring
~420 V
(Wang et al. [87]) system
E-Skin √ √ √ wearable sports
no clear data
(Shi et al. [88]) electronic device
Figure 4. (a) Outputting piezoelectric voltage of TSB-PENG on the shoulder that does the bend
and stretch motion. (b) Outputting piezoelectric voltage of TSB-PENG is fixed on the elbow which
protrudes, bends, and stretches. (c) Outputting piezoelectric voltage of TSB-PENG is fixed on the
wrist that protrudes, bends, and stretches. (a–c) Reprinted with permission from Ref. [89]. (d) Output
piezoelectric voltage of speed skating during four sport states. Reprinted with permission from
Ref. [90]. (e) Output piezoelectric voltage of butterfly stroke. (f) Output piezoelectric voltage of
breaststroke. (g) Output piezoelectric voltage of freestyle stroke. (h) Simulating the monitoring of
athlete’s elbow joint angle and heart rate. (i) Simulation of arterial work and biosensor attachment
position. (j) Output piezoelectric voltage of the arterial model monitored by biosensor. (e–j) Reprinted
with permission from Ref. [91]. (k) The output voltage of the canonical table tennis attack technique
with tennis swing action. (l) The output voltage of the incorrect table tennis attack technique
and tennis swing action. (m) The working process of wireless intelligent motion error correction
system. (k–m) Reprinted with permission from Ref. [92]. (n) Unsportsmanlike action monitoring
system. (o) Voltage and waveform generated by punching, elbow blow, knee bump, and palm push.
(n,o) Reprinted with permission from Ref. [93].
Energies 2022, 15, 5807 10 of 15
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