Wires Groups A-C

Safety Data Sheet

according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations
Revision Date: 09/01/2016 Date of issue: 09/29/2016 Version: 1.0

Page 1 of 8
SAFETY DATA SHEET
This Safety Data Sheet (SDS) is for welding consumables and related products and may be used to comply with OSHA’s Hazard Communication standard 29
CFR 1910.1200, and Superfund Amendments and Reauthorization Act (SARA) of 1986 Public Law 99-499. The OSHA standard must be consulted for specific
requirements. This Safety Data Sheet complies with European Commission Directive 89/106/EEC, 91/155/EEC, ISO 11014-1 and ANSI Z400.1. This
document is translated in several languages and available on our Website at www.postle.com, from your sales representative or by calling customer service
at 1(937)332-4000.
SECTION 1 – IDENTIFICATION
Manufacturer/Supplier Name: Postle Industries, Inc. Telephone No: 216-458-0753
Address: 5500 West 164th St., Cleveland, Ohio 44142 Emergency No: 800-424-9300 USA
Website: www.postle.com International: 703-527-3857

Product Type: Group A: Iron base metal-cored and flux-cored hardfacing wires.
Group B: Nickel and Cobalt base metal-cored and flux-cored hardfacing wires, with or without tungsten carbide.
Group C: Bare, solid hardfacing and tool steel wires for Mig and Tig.
SECTION 2 – IDENTIFICATION OF HAZARDS
IMPORTANT – This section covers the hazardous materials from which this product is manufactured. The fumes and gases produced during welding with
normal use of this product are also addressed in Section 8. The term “hazardous” in this section should be interpreted as a term required and defined in OSHA
Hazard Communication Standard (29 CFR Part 1910.1200).

HAZARDOUS CAS EINECS GHS HAZARD STATEMENTS REGULATORY HAZARD IARCE NTP2 OSHAH 65
INGREDIENT CLASSIFICATION/DESIGNATION
67/548/EEC
ALUMINUM 7429-90-5 231-072-3 H228 F-R10, R15, R17 --- --- --- ---
BORON 7440-33-7 231-151-2 None --- --- --- ---
CALCIUM CARBONATE 1317-65-3 215-279-6 H350, H373, H315, H319 None --- --- --- ---
CHROMIUM 7440-47-3 231-157-5 O-R9; Carc 1 – R45; Muta 2 – R46; 1, 3 K X X
Repr 3 – R62; T+ - R26; T – R24/25,
R48/23
C – R35, R42/43; N – R50, R53
COBALT 7440-48-4 231-158-0 H228,H317,H334,H413 Xn; R42/43, R53 2B --- X X
COLUMBIUM 7440-03-1 231-113-5 H250 None --- --- --- ---
COPPER 7440-50-8 231-159-6 None --- --- --- ---
FLUORSPAR 7789-75-5 232-188-7 None --- --- --- ---
IRON 7439-89-6 231-096-4 H228, H251 None --- --- --- ---
MANGANESE 7439-96-5 231-105-1 H260, H412 Xn – R20/22Y --- --- --- ---
MOLYBDENUM 7439-98-7 231-107-2 Xn – R48/20/22; Xi – R36/37X --- --- --- ---
NICKEL 7440-02-0 231-111-4 H228, H317, H351, H372, Carc 3 – R40; T – R43, R48/23 1 K X X
H400, H410
SILICA 14808-60-7 238-878-4 H350, H372 Xn – R48/20, R40/20 1 K X X
(Amorphous Silica Fume) 69012-64-2 273-761-5 None 3 K --- ---
SILICON 7440-21-3 231-130-8 H228 None --- --- --- ---
TITANIUM 7440-32-6 231-142-3 None --- --- --- ---
TITANIUM DIOXIDE 13463-67-7 236-675-5 H351 None 2B --- ---
TUNGSTEN 7440-33-7 231-143-9 None --- --- --- ---
VANADIUM 7440-62-2 231-171-1 Xn – R20, R48/22; Xi – R41; N – R51, 2B --- --- X
R53
ZIRCONIUM H250, H260 7440-67-7 231-176-9 H250, H260 F – R15, R17 --- --- --- ---
TUGSTEN CARBIDE 12070-12-1 235-123-0 None --- --- --- ---

-European Inventory of Existing Chemical Substances Number  - European Union Directive 67/548/EEC – Annex 1 E – International Agency for Research
on Cancer (1-Human Carcinogen, 2A – Probably Carcinogenic to Humans, 2B – Possibly Carcinogenic to Humans, 3 – Unclassifiable as to Carcinogenicity in
Humans, 4 Probably Not Carcinogenic to Humans) Z – US National Toxicology Program (K – Known Carcinogen, S – Suspected Carcinogen) H – OSHA
Known Carcinogen List  - California Proposition 65 (X – On Proposition 65 list) --- Dashes indicate the ingredient is not listed with the IARC, NTP, OSHA or
65  - Carcinogen, Mutagen or Reproductive Category per European Council Directive 67/548/EEC Annex I  - Metal and Chromium III Compounds  -
 Wires Groups A-C
Safety Data Sheet
according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations
Revision Date: 09/01/2016 Date of issue: 09/29/2016 Version: 1.0

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Chromium VI Compounds  - Chromium (VI) Trioxide EU 67/548/EEC Classification/Designation Y – Manganese Dioxide EU 67/548/EEC
Classification/Designation X – Molybdenum Trioxide EU 67/548/EEC Classification/Designation  - Silica Crystalline -Quartz  - Vanadium Pentoxide EU
67/548/EEC Classification/Designation  - Vanadium Pentoxide

The following symbols correspond with the EU 67/548/EEC column above are in European Union Directive 67/548/EEC Annex 1 and EC 1272/2008 Annex VI
– Table 3.2:

F – Flammable Xn – Harmful Xi – Irritant O ‐ Oxidizer

C – Corrosive N – Dangerous for the Environment T – Toxic T+ ‐ Extremely Toxic

WARNING! – Avoid breathing welding fumes and gases, they may be dangerous to your health. Always use adequate ventilation. Always use
appropriate personal protective equipment.

PRIMARY ROUTES OF ENTRY: Respiratory System, Eyes and/or Skin. ARC RAYS: The welding arc can injure eyes and burn skin.
ELECTRIC SHOCK: Arc welding and associated processes can kill. See Section 8. FUMES AND GASES: Can be dangerous to your health.

GHS PICTOGRAMS

GHS HAZARDOUS STATEMENTS

H228-Flammable solid
H250-Catches fire spontaneously if exposed to air
H251-Self heating; may catch fire
H260-In contact with water releases flammable gases, which may ignite spontaneously
H315-Causes skin irritation
H317-May cause an allergic skin reaction
H319-Causes serious eye irritation
H334-May cause allergy or asthma symptoms or breathing difficulties if inhaled
H350-May cause cancer by route of exposure if conclusively proven that no other route applies
H351-Suspected of causing cancer by route of exposure if conclusively proven that no other route applies
H372-Causes damage to organs through prolonged or repeated exposure by route of exposure if conclusively proven that no other route applies
H373-May cause damage to organs through prolonged or repeated exposure by route of exposure if conclusively proven that no other route applies
H400-Very toxic to aquatic life
H410-Very toxic to aquatic life with long lasting effects
H412-harmful to aquatic life with long lasting effects
H413-May cause long lasting harmful effects to aquatic life

GHS PRECAUTIONARY STATEMENTS

P201 - Obtain special instructions before use.
P202 - Do not handle until all safety precautions have been read and understood.
P210 - Keep away from heat.
 Wires Groups A-C
Safety Data Sheet
according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations
Revision Date: 09/01/2016 Date of issue: 09/29/2016 Version: 1.0

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P222 - Do not allow contact with air.
P223 - Keep away from any possible contact with water, because of violent reaction and possible flash fire.
P231 + P232 - Handle under inert gas. Protect from moisture.
P235 + 410 - Keep cool. Protect from sunlight.
P240 - Ground/bond container and receiving equipment.
P241 - Use explosion-proof electrical/ventilating/lighting/equipment.
P260 - Do not breathe fumes.
P261 - Avoid breathing dust/fume/gas/mist/vapors/spray.
P264 - Wash face, hands and any exposed skin thoroughly after handling.
P270 - Do no eat, drink or smoke when using this product.
P272 - Contaminated work clothing should not be allowed out of the workplace.
P273 - Avoid release to the environment.
P280 - Wear protective gloves/protective clothing/eye protection/face protection.
P281 - Use personal protective equipment as required.
P285 - In case of inadequate ventilation wear respiratory protection.
P302 + P334 - IF ON SKIN: Immerse in cool water/wrap in wet bandages.
P302 + P352 - IF ON SKIN: Wash with plenty of soap and water.
P304 + P341 - IF INHALED: If breathing is difficult, remove to fresh air and keep at rest in a position comfortable for breathing.
P305 + P351 + P338 - IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
P308 + P313 - IF exposed or concerned: Get medical advice/attention.
P314 - Get medical advice/attention if you feel unwell.
P321 - Specific treatment (see supplemental first aid instructions on this label).
P332 + P313 - If skin irritation occurs: Get medical advice/attention.
P333 + P313 - If skin irritation or rash occurs: Get medical advice/attention.
P335 + P334 - Brush off loose particles from skin. Immense in cool water/wrap in wet bandages.
P337 + P313 - If eye irritation persists: Get medical advice/attention.
P342 + P311 - If experiencing respiratory symptoms: Call a POISON CENTER or doctor/physician.
P362 - Take off contaminated clothing and wash before reuse.
P363 - Wash contaminated clothing before reuse.
P402 + P404 - Store in a dry place. Store in a closed container.
P370 + P378 - In case of fire: Use Section 5 for extinction.
P391 - Collect spillage.
P405 - Store locked up.
P407 - Maintain air gap between stacks/pallets.
P422 - Store contents according to Section 7 of this document.
P501 - Dispose of contents/container to an approved landfill.

Welding fumes and gases cannot be classified simply. The composition and quantity of both are dependent upon the metal being welded, the process,
procedures and wires used. Most fume ingredients are present as complex oxides and compounds and not as pure metals. When the wire is consumed, the
fume and gas decomposition products generated are different in percent and form from the ingredients listed in Section 3. Decomposition products of normal
operation include those originating from the volatilization, reaction or oxidation of the materials shown in this section, plus those from the base metal and
coating, etc., as noted above. Monitor for the materials identified in the list within this section.

Fumes from the use of this product may contain complex oxides or compounds of the following elements and molecules: amorphous silica fume, calcium
oxide, chromium, cobalt, copper, fluorspar or fluorides, manganese, nickel, silica, vanadium and zirconium. Other reasonably expected constituents of the
fume would also include complex oxides of iron, titanium, silicon and molybdenum. Gaseous reaction products may include carbon monoxide and carbon
dioxide. Ozone and nitrogen oxides may be formed by the radiation from the arc. Other conditions which also influence the composition and quantity of the
fumes and gases to which workers may be exposed include: coatings on the metal being welded (such as paint, plating or galvanizing), the number of welders
and the volume of the work area, the quality and amount of ventilation, the position of the welder’s head with respect to the fume plume, as well as the presence
of contaminants in the atmosphere (such as chlorinated hydrocarbon vapors from cleaning and degreasing activities). One recommended way to determine
the composition and quantity of fumes and gases to which workers are exposed is to take an air sample inside the welder’s helmet if worn or in the worker’s
 Wires Groups A-C
Safety Data Sheet
according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations
Revision Date: 09/01/2016 Date of issue: 09/29/2016 Version: 1.0

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breathing zone. See ANSI/AWS F1.1, available from the “American Welding Society”, P.O. Box 351040, Miami, FL 33135. Also, from AWS is F1.3 “Evaluating
Contaminants in the Welding Environment – A Sampling Strategy Guide”, which gives additional advise on sampling.
SECTION 3 – HAZARDOUS INGREDIENTS
CONTENT PERCENTAGE BY INGREDIENTS
GROUP AND % WEIGHT GROUP AND % WEIGHT
INGREDIENTS CAS EINECS A B C INGREDIENTS CAS EINECS A B C
ALUMINUM 7429-90-5 231-072-3 0-2 --- --- MOLYBDENUM 7439-98-7 231-107-2 0-10 0-20 0-7
BORON 7440-42-8 231-151-2 0-5 0-5 --- NICKEL 7440-02-0 231-111-4 0-10 1-70 0-20
CALCIUM CARBONATE 1317-65-3 215-279-6 0-2 <10 --- SILICA 14808-60-7 238-878-4 0-5 <5 ---
CHROMIUM 7440-47-3 231-157-5 1-40 0-40 1-5 (Amorphous Silica Fume) 69012-64-2 273-761-5
COBALT 7440-48-4 231-158-0 --- 0-50 0-10 SILICON 7440-21-3 231-130-8 <5 --- <1
COLUMBIUM 7440-03-1 231-113-5 0-10 --- --- TITANIUM 7440-32-6 231-142-3 0-10 --- 0-2
COPPER 7440-50-8 231-159-6 0-1 --- <1 TITANIUM DIOXIDE 13463-67-7 236-675-5 0-10 5-15 ---
FLUORSPAR 7789-75-5 232-188-7 0-10 <5 --- TUNGSTEN 7440-33-7 231-143-9 0-10 --- 0-7
IRON 7439-89-6 231-096-4 55-95 <5 60-98 VANADIUM 7440-62-2 231-171-1 0-10 --- <5
MANGANESE 7439-96-5 231-105-1 1-25 --- <1 ZIRCONIUM 7440-67-7 231-176-9 0-3 --- ---
TUNGSTEN CARBIDE 12070-12-1 235-123-0 50-65 50-65 ---
---Dashes indicate the ingredient is not present within the group of products.
SECTION 4 – FIRST AID MEASURES
INHALATION: if breathing is difficult provide fresh air and contact physician. EYE/SKIN INJURIES: For radiation burns, see physician.
Section 11 of this SDS covers the acute effects of overexposure to the various ingredients within the welding consumable. Section 8 of this SDS lists the
exposure limits and Covers methods for protecting yourself and your co-workers.
SECTION 5 – FIRE AND EXPLOSION HAZARD DATA
Welding consumables applicable to this sheet as shipped are nonreactive, nonflammable, nonexplosive and essentially nonhazardous until welded. Welding
arcs and sparks can ignite combustibles and flammable products. Unused welding consumables may remain hot for a period of time after completion of a
welding process. See American National Standard (ANSI) Z49.1 for further general safety information on the use and handling of welding consumable and
associated procedures.
SECTION 6 – ACCIDENTAL RELEASE MEASURES
Solid objects can be picked up and placed into a container. Wear proper personal protective equipment while handling. Do not discard as general trash.
SECTION 7 – HANDLING AND STORAGE
HANDLING: No specific requirements in the form supplied. Handle with care to avoid cuts. Wear gloves when handling welding consumable. Avoid
exposure to dust. Do not ingest. Some individuals can develop an allergic reaction to certain materials. Retain all warning and product labels.
STORAGE: Keep separate from acids and strong bases to prevent possible chemical reactions.
SECTION 8 – EXPOSURE CONTROL AND PERSONAL PROTECTION
Read and understand the instructions and the labels on the packaging. Welding fumes do not have a specific OSHA PEL or ACGIH TLV. The OSHA PEL
for Particulate – Not Otherwise Classified (PNOC) is 5 mg/m3 – Respirable Fraction, 15 mg/m3 - Total Dust. The ACGIH TLV for Particles – Not Otherwise
Specified (PNOS) is 3 mg/m3 – Respirable Particles, 10 mg/m3 – Inhalable Particles. The individual complex compounds within the fume may have a lower
OSHA PEL or ACGIH TLV than the OSHA Particulate – Not Otherwise Classified (PNOC) and ACGIH Particles – Not Otherwise Specified (PNOS). An
Industrial Hygienist, the OSHA Permissible Exposure Limits for Air Contaminants (29 CFR 1910.1000), and the ACGIH Threshold Limit Values should be
consulted to determine the specific fume constituents present and their respective exposure limits. European Union Occupational Exposure Limits (EU OEL)
are listed with the most stringent limit among the EU member nations. All exposure limits are in milligrams per cubic meter (mg/m 3).

INGREDIENT CAS EINECS OSHA PEL ACGIH TLV EU OEL

TUNGSTEN CARBIDE 12070-12-1 235-123-0 5 R* 5, 10 STEL*** (Insol Cpnds) 1.5 R* - Germany
ALUMINUM 7429-90-5 231-072-3 5 R* (Dust) 5 1 R* {A4} 4 I*; 1.5 R* - Germany
BORON 7440-42-8 231-151-2 R*, 15 (As B2O3) 3 R*, 10 (As B2O3) 10 I* (Aerosol as B2O3) - Switzerland
CALCIUM CARBONATE 1317-65-3 215-279-6 5 R*, 5 (as CaO) 3 R*, 2 (as CaO) 10 I* (Aerosol) – UK; 3 R* (Aerosol) - Switzerland
CHROMIUM 7440-47-3 231-157-5 1 (Metal) 0.5 (Metal) {A4}, 0.5 (Cr III Cpnds) 0.1* (Aerosol) - Switzerland
0.5 (Cr II & Cr III Cpnds) {A4}, 0.05 (Cr VI Sol Cpnds) {A1} 0.005; 0.01*** - Denmark
0.005 (Cr VI Cpnds) (Cr VI Insol Cpnds) {A1} 0.005 (Total Aerosol); 0.015***(Total Aerosol)-
Sweden
COBALT 7440-48-4 231-158-0 0.1 (Dust and Fume) .02 {A3} 0.01 I*; 0.02*** - Denmark
 Wires Groups A-C
Safety Data Sheet
according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations
Revision Date: 09/01/2016 Date of issue: 09/29/2016 Version: 1.0

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COLUMBIUM 7440-03-1 231-113-5 5 R* 3 R* 0.5; 1*** - Denmark
COPPER 7440-50-8 231-159-6 0.1(Fume), 1 (Dust) 1.2 (Fume), 1 (Dust) 1.1 I* (Aerosol); 0.2 I*** (Aerosol) – Germany
0.1; 0.2*** - Denmark 1
FLUORSPAR 7789-75-5 232-188-7 2.5 (as F) 2.5 (as F) {A4} 5 I* (Aerosol as F); 4*** (Aerosol as F) – Germany 3
IRON+ 7439-89-6 231-096-4 5 R* R* (Fe2O3) {A4} R* (Aerosol as Fe2O3) – Switzerland
7*** (as Fe2O3) – Denmark
MANGANESE 7439-96-5 231-105-1 5 CL** (Fume) 0.1 I* {A4}  1.2 R*(Aerosol); 0.16 R*** (Aerosol) – Germany
1.3 STEL***◼ 0.02 R* 0.2 I*(Aerosol) – Germany
0.2; 0.4*** - Denmark 3
MOLYBDENUM 7439-98-7 231-107-2 5 R* 3 R*; 10 I* (Ele and Insol) R* - Spain;
0.5 R* (Sol Cpnds( {A3} 4; 10*** - Poland
NICKEL# 7440-02-0 231-111-4 1 (Metal) 1 1.5 I* (Ele) {A5} 0.05; 0.1*** - Denmark
(Sol Cpnds) 1 1.1 I* (Sol Cpnds) {A4}
(Insol Cpnds) 1.2 I* (Insol Cpnds) {A1}
SILICA++ 14808-60-7 238-878-4 0.1 R* 0.025 R* {A2} 0.1 (Fused, Respirable Dust) – Denmark
0.2*** (Fused, Respirable Dust) – Denmark
(Amorphous Silica Fume) 69012-64-2 273-761-5 0.8 3 R* 2 I*; 4 I*** - Denmark 4
SILICON+ 7440-21-3 231-130-8 5 R* 3 R* R* (Aerosol); 10 I* (Aerosol) – Denmark
TITANIUM+ 7440-32-6 231-142-3 5 R* 3 R* 1.5 R* (as TiO2) – Germany
TITANIUM DIOXIDE 13463-67-7 236-675-5 15 (Dust) 10 {A4} 1.5 R* - Germany 1
TUNGSTEN 7440-33-7 231-143-9 5 R* 5, 10 STEL*** (Insol Cpnds) I* (Aerosol); 2 I**** (Aerosol) – Austria
1, 3 STEL*** (Sol Cpnds)
VANADIUM 7440-62-2 231-171-1 0.1 CL** (Fume as V2O5) 0.05 I* (as V) {A3} 0.5 I* (Aerosol); 1 I*** (Aerosol) - Austria
0.5 R* CL** (Dust as V2O5) 0.01 (as V2Os); 0.03*** (as V2Os) – Netherlands
ZIRCONIUM 7440-67-7 231-176-9 5 (Zr Cpnds) 5, 10 STEL*** (Zr Cpnds) {A4} 1 I* (Aerosol); 0.1 I*** (Aerosol) - Germany

R* - Respirable Fraction R*** - Respirable Fraction – Short Term Exposure Limit I* - Inhalable Fraction I*** - Inhalable Fraction – Short Term Exposure Limit
** - Ceiling Limit *** - Short Term Exposure Limit + - As a nuisance particulate covered under “Particulates Not Otherwise Regulated” by OSHA or
“Particulates Not Otherwise Classified” by ACGIH ++ - Crystalline silica is bound within the product as it exists in the package. However, research indicates
silica is present in welding fume in the amorphous (non-crystalline) form # - Reportable material under Section 313 of SARA ### - Reportable material
under Section 313 SARA as dust or fume ◼ - NIOSH REL TWA and STEL  - Limit of 0.1 mg/m3 is for inhalable Mn in 2013 by ACGIH  - Limit of 0.02
mg/m3 is for Respirable Mn in 2013 by ACGIH Ele - Element Sol – Soluble Insol – Insoluble Inorg – Inorganic Cpnds – Compounds NOS – Not Otherwise
Specified {A1} – Confirmed Human Carcinogen per ACGIH {A2} – Suspected Human Carcinogen per ACGIH {A3} – Confirmed Animal Carcinogen with
Unknown Relevance to Humans per ACGIH {A4} – Not Classifiable as a Human Carcinogen per ACGIH {A5} – Not Suspected as a Human Carcinogen per
ACGIH (non-crystalline) form

VENTILATION: Use enough ventilation, local exhaust at the arc or both to keep the fumes and gases below the PEL/TLV/OELs in the worker’s breathing
zone and the general area. Train the welder to keep his head out of the fumes.
RESPIRATORY PROTECTION: Use NIOSH approved or equivalent fume respirator or air supplied respirator when welding in confined space or where local
exhaust or ventilation does not keep exposure below the regulatory limits.
EYE PROTECTION: Wear helmet or use face shield with filter lens. As a rule of thumb begin with Shade Number 14. Adjust if needed by selecting the next
lighter and/or darker shade number. Provide protective screens and flash goggles, if necessary, to shield others from the weld arc flash.
PROTECTIVE CLOTHING: Wear hand, head and body protection which help to prevent injury from radiation, sparks and electrical shock. See ANSI Z49.1.
At a minimum this includes welder’s gloves and a protective face shield, and may include arm protectors, aprons, hats, shoulder protection as well as dark
non-synthetic clothing. Train the welder not to touch live electrical parts and to insulate himself from work and ground.
PROCEDURE FOR CLEANUP OF SPILLS OR LEAKS: Not applicable.
SPECIAL PRECAUTIONS (IMPORTANT): Maintain exposure below the PEL/TLV/OEL. Use industrial hygiene monitoring to ensure that your use of this
material does not create exposures which exceed PEL/TLV/OEL. Always use exhaust ventilation. Refer to the following sources for important additional
information: American National Standard (ANSI) Z49.1; Safety in Welding and Cutting published by the American Welding Society, P.O. Box 351040, Miami,
FL 33135 and OSHA Publication 2206 (29 CFR 1910), U.S. Government Printing Office, Washington, DC 20402.
SECTION 9 – PHYSICAL AND CHEMICAL PROPERTIES
Welding consumables applicable to this sheet as shipped are nonreactive, nonflammable, nonexplosive and essentially nonhazardous until welded.
PHYSICAL STATE: Cored Wire ODOR: N/A
COLOR: Gray FORM: Round Wire
 Wires Groups A-C
Safety Data Sheet
according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations
Revision Date: 09/01/2016 Date of issue: 09/29/2016 Version: 1.0

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SECTION 10 – STABILITY AND REACTIVITY
GENERAL: Welding consumables applicable to this sheet are solid and nonvolatile as shipped. This product is only intended for use per the welding
parameters it was designed for. When this product is used for welding, hazardous fumes may be created. Other factors to consider include the base metal,
base metal preparation and base metal coatings. All of these factors can contribute to the fume and gases generated during welding. The amount of fume
varies with the welding parameters
STABILITY: This product is stable under normal conditions.
REACTIVITY: Contact with acids or strong bases may cause generation of gas.
SECTION 11 – TOXICOLOGICAL INFORMATION
SHORT-TERM (ACUTE) OVEREXPOSURE EFFECTS: Welding Fumes – May result in discomfort such as dizziness, nausea or dryness or irritation of
nose, throat or eyes. Aluminum Oxide – Irritation of the respiratory system. Boron Oxide – irritation of the nose, throat, eyes and skin. Calcium Oxide –
Dust or fumes may cause irritation of the respiratory system, skin and eyes. Chromium – Inhalation of fume with chromium (VI) compounds can cause
irritation of the respiratory tract, lung damage and asthma-like symptoms. Swallowing chromium (VI) salts can cause severe injury or death. Dust on skin
can form ulcers. Eyes may be burned by chromium (VI) compounds. Allergic reactions may occur in some people. Cobalt – Pulmonary irritation, cough,
dermatitis, weight loss. Columbium – Dust or fumes may cause irritation of the respiratory system, skin and eyes. Copper – Metal fume fever
characterized by metallic taste, tightness of chest and fever. Symptoms may last 24 to 48 hours following overexposure. Fluorides – Fluoride compounds
evolved may cause skin and eye burns, pulmonary edema and bronchitis. Iron, Iron Oxide – None are known. Treat as nuisance dust or fume.
Manganese – Metal fume fever characterized by chills, fever, upset stomach, vomiting, irritation of the throat and aching of body. Recovery is generally
complete within 48 hours of the overexposure. Molybdenum – Irritation of the eyes, nose and throat. Nickel, Nickel Compounds – Metallic taste, nausea,
tightness in chest, metal fume fever, allergic reaction. Silica (Amorphous) – Dust and fumes may cause irritation of the respiratory system, skin and eyes.
Titanium Dioxide – Irritation of respiratory system. Tungsten – Dust may cause irritation of the skin and eyes. Inhalation of dust may cause acute airways
obstructive asthma which is reversible following overexposure. Symptoms are tightening chest and productive cough. Vanadium – Overexposure to the
oxide causes green tongue, cough, metallic taste, throat irritation and eczema. Zirconium – May cause irritation of the eyes, nose and throat due to
mechanical effects.
LONG-TERM (CHRONIC) OVEREXPOSURE EFFECTS: Welding Fumes – Excess levels may cause bronchial asthma, lung fibrosis, pneumoconiosis or
“Siderosis.” Aluminum Oxide - Pulmonary fibrosis and emphysema. Boron Oxide – No chronic effects are known. Calcium Oxide – Prolonged
overexposure may cause ulceration of the skin and perforation of the nasal septum, dermatitis and pneumonia. Chromium – Ulceration and perforation of
nasal septum. Respiratory irritation may occur with symptoms resembling asthma. Studies have shown that chromate production workers exposed to
hexavalent chromium compounds have an excess of lung cancers. Chromium (VI) compounds are more readily absorbed through the skin than chromium
(III) compounds. Good practice requires the reduction of employee exposure to chromium (III) and (VI) compounds. Cobalt – Repeated overexposure to
cobalt compounds can produce reduced pulmonary function, diffuse nodular fibrosis of lungs and respiratory hypersensitivity. Columbium – No adverse
long term health effects have been reported in the literature. Copper – Copper poisoning has been reported in the literature from exposure to high levels of
copper. Liver damage can occur due to copper accumulating in the liver characterized by cell destruction and cirrhosis. High levels of copper may cause
anemia and jaundice. High levels of copper may cause central nervous system damage characterized by nerve fiber separation and cerebral degeneration.
Fluorides - Serious bone erosion (Osteoporosis) and mottling of teeth. Iron, Iron Oxide Fumes – Can cause Siderosis (deposits of iron in lungs) which
some researchers believe may affect pulmonary function. Lungs will clear in time when exposure to iron and its compounds ceases. Iron and magnetite
(Fe3O4) are not regarded as fibro-genic materials. Manganese- Long-term overexposure to manganese compounds may affect the central nervous system.
Symptoms may be similar to Parkinson’s disease and can include slowness, changes in handwriting, gait impairment, muscle spasms and cramps and less
commonly, tremor and behavioral changes. Employees who are overexposed to manganese compounds should be seen by a physician for early detection
of neurologic problems. Overexposure to manganese and manganese compounds above safe exposure limits can cause irreversible damage to the central
nervous system, including the brain, symptoms of which may include slurred speech, lethargy, tremor, muscular weakness, psychological disturbances and
spastic gait. Molybdenum – Prolonged overexposure may result in loss of appetite, weight loss, loss of muscle coordination, difficulty in breathing and
anemia. Nickel, Nickel Compounds – Lung fibrosis or pneumoconiosis. Studies of nickel refinery workers indicated a higher incidence of lung and nasal
cancers. Silica (Amorophous) – Research indicates that silica is present in welding fume in the amorphous form. Long term overexposure may cause
pneumoconiosis. Non-crystalline forms of silica (amorphous silica) are considered to have little fibrotic potential. Titanium Dioxide – Pulmonary irritation
and slight fibrosis. Tungsten – Long term overexposure may cause pulmonary fibrosis characterized by a rapid onset of cough, sputum and dyspnea on
 Wires Groups A-C
Safety Data Sheet
according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations
Revision Date: 09/01/2016 Date of issue: 09/29/2016 Version: 1.0

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exertion. Vanadium – Prolonged overexposure to vanadium pentoxide can cause nasal catarrh or nose bleeds and chronic respiratory problems.
Zirconium – May cause pulmonary fibrosis and pneumoconiosis.
MEDICAL CONDITIONS AGGRAVATED BY EXPOSURE: Persons with pre-existing impaired lung functions (asthma-like conditions). Persons with a
pacemaker should not go near welding and cutting operations until they have consulted their doctor and obtained information from the manufacturer of the
devise. Respirators are to be worn only after being medically cleared by the company-designated physician.
EMERGENCY AND FIRST AID PROCEDURES: Call for medical aid. Employ first aid techniques recommended by American Red Cross. If irritation or
flash burns develop after exposure, consult a physician.
CARCINOGENICITY: Chromium VI compounds, nickel compounds and silica (crystalline quartz) are classified as IARC Group 1 and NTP Group K
carcinogens. Titanium dioxide compounds, vanadium (V2O5) and cobalt compounds are classified as IARC Group 28 carcinogens. Chromium VI
compounds, cobalt compounds, nickel compounds, silica (crystalline quartz) and welding fumes must be considered as carcinogens under OSHA (29 CFR
1910.1200).
CALIFORNIA PROPOSITION 65: WARNING: These products contain or produce a chemical known to the State of California to cause cancer and birth
defects (or other reproductive harm). (California Health & Safety Code Section 25249.5 et seq.)
SECTION 12 – ECOLOGICAL INFORMATION
Welding processes can release fumes directly to the environment. Welding wire can degrade if left outside and unprotected. Residues from welding
consumables and processes could degrade and accumulate in the soil and groundwater.
SECTION 13 – DISPOSAL CONSIDERATIONS
Use recycling procedures if available. Discard any product, residue, packaging, disposable container or liner in an environmentally acceptable manner, in
full compliance with federal, state and local regulations.
SECTION 14 – TRANSPORT INFORMATION
No international regulations or restrictions are applicable. No special precautions are necessary.
SECTION 15 – REGULATORY INFORMATION
Read and understand the manufacturer’s instructions, your employer’s safety practices and the health and safety instructions on the label and the safety
data sheet. Observe all local and federal rules and regulations. Take all necessary precautions to protect yourself and others.
United States EPA Toxic Substance Control Act: All constituents of these products are on the TSCA inventory list or are excluded from listing.

CERCLA/SARA TITLE III: Reportable Quantities (RQs) and/or Threshold Planning Quantities (TPQs):

Ingredient name RQ (lbs.) TPQ (lbs.)

Products on this MSDA are a solid solution in the form of a solid article. -- --

Spills or releases resulting in the loss of any ingredient at or above its RQ require immediate notification to the National Response Center and to your Local
Emergency Planning Committee.

Section 311 Hazard Class

As shipped: Immediate In use: Immediate delayed

EPCRA/SARA TITLE III 313 TOXIC CHEMICALS: The following metallic components are listed as SARA 313 “Toxic Chemicals” and potentially subject to
annual SARA 312 reporting: Chromium, Cobalt, Copper, Manganese, Nickel and Vanadium. See Section 3 for weight percentage.

CANADIAN WHMIS CLASSIFICATION: Class D; Division 2, Subdivision A

CANADIAN ENVIRONMENTAL PROTECTION ACT (CEPA): All constituents of these products are on the Domestic Substance List (DSL).
SECTION 16 – OTHER INFORMATION
The following Risk and Safety Phrase Texts and Hazard Statements correspond with the columns labeled – EU 67/548/EEC within Section 2 of this safety
data sheet. Take appropriate precautions and protective measures to eliminate or limit the associated hazard.
 Wires Groups A-C
Safety Data Sheet
according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations
Revision Date: 09/01/2016 Date of issue: 09/29/2016 Version: 1.0

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EU Directive 67/548/EEC – Risk Phrase Texts

R9 – Explosive when mixed with combustible material R45 – May cause cancer
R10 – Flammable R46 – May cause heritable genetic damage
R15 – Contact with water liberates extremely flammable gases R48/20 – Harmful: danger of serious damage to health by prolonged
R17 – Spontaneously flammable in air exposure through inhalation
R20 – Harmful by inhalation R48/20/22 – Harmful: danger of serious damage to health by
R20/22 – Harmful by inhalation and if swallowed prolonged exposure through inhalation and if swallowed
R24/25 – Toxic in contact with skin and if swallowed R48/22 – Harmful: danger of serious damage to health by
R26 – Very toxic by inhalation prolonged exposure if swallowed
R35 – Causes severe burns R48/23 – Toxic: danger of serious damage to health by prolonged
R36/37 – Irritating to eyes and respiratory system exposure through inhalation
R40 - Limited evidence of a carcinogenic effect R50 – Very toxic to aquatic organisms
R40/20 – Harmful: possible risk of irreversible effects through inhalation R51 – Toxic to aquatic organisms
R41 – Risk of serious damage to eyes R53 – May cause long-term adverse effects in the aquatic environment
R42/43 – May cause sensitization by inhalation and skin contact R62 – Possible risk of impaired fertility
R43 – May cause sensitization by skin contact

For additional information please refer to the following sources:

USA: American National Standard (ANSI) Z49.1 “Safety in Welding and Cutting”, ANSI/American Welding Society (AWS) F1.5 “Methods for
Sampling and Analyzing Gases from Welding and Allied Processes”, ANSI/AWS F1.1 “Method for Sampling Airborne Particles Generated by
Welding and Allied Processes”, AWSF3.2M/F3.2 “Ventilation Guide for Weld Fume”, American Welding Society, 550 North Le Jeune Road, Miami,
Florida, 33135. Safety and Health Fact Sheets available from AWS at www.aws.org. OSHA Publication 2206 (29 C.F.R. 1910), U.S. Government
Printing Office, Superintendent of Documents, P.O. Box 371954, Pittsburg, PA 15250-7954. Threshold Limit Values and Biological Exposure
Indices, American Conference of Governmental Hygienists (ACGIH), 6500 Glenway Ave., Cincinnati, Ohio 45211, USA. NFPA 51B “Standard for
Fire Prevention during Welding, Cutting and Other Hot Work” published by the National Fire Protection Association, 1 Batterymarch Park, Quincy,
MA 02169.
UK: WMA Publication 236 and 237, “Hazards from Welding Fume”, “The arc welder at work, some general aspects of health and safety”.
Canada: CSA Standard CAN/CSA-W117.2-01 “Safety In Welding, Cutting and Allied Processes”.

Postle Industries, Inc. strongly recommends the users of this product study this SDS, the product label information and become aware of all hazards
associated with welding. Postle industries, Inc. believes this data to be accurate and to reflect qualified expert opinion regarding current research. However,
Postle Industries, Inc. cannot make any expressed or implied warranty as to this information.