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Inorganic Chemistry Part 18 - Triads Part 2

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TRIADS

PART 2
Module 1
Inorganic Chemistry - Part 18 - Triads 2

Group VIII-B: Triads


B. Cobalt
Deficiency:
• Name from German word “_______” • ______________ and ______________
meaning “a _____ or _____”.
• Essential in development of ______________ ______________ reaction: When a concentrated
and ______________ solution of ammonium thiocyanate is added
• Component of Vitamin ___ to a cobaltous solution, ammonium cobaltous
thiocyanate ( __________ ) is formed.
Compounds of Cobalt
Compound Name Other Name Use
1. Cobaltous Chloride -
CoCl2

2. Cobalt meta-aluminate

3. Cobalt zincate

C. Nickel E. Platinum
• Aka: _______________ • Low oxidation metal and low reactivity noble
• Fossil fuel metal
• Component of fancy jewelry • Catalyst in finely divided steel
• Alloy of nickel:
-Raney nickel: _______________ F. Paladium
• Catalyst in finely divided steel
-Monel nickel and Constantan: _______________
-German silver: _______________
• Nickel Hydroxide in solution is __________

D. Osmium
• __________ metal
TRIADS - PART 2

Quick Quiz
1. Platinum metals are called noble metals because: 4. It is considered as the densest element in the
A. Shows low oxidation potential periodic table

B. Shows low reactivity A. Pb C. Os

C. Shows high reactivity B. Pd D. At

D. A and B 5. The ion that gives positive result to Thenard’s Blue


Test:
2. Cobalt meta-aluminate is: A. Aluminum C. Manganese
A. Rinman’s green B. Chromium D. Zinc
B. Azure crystals
C. Thenard’s blue
D. Emerald blue crystals

3. Nickel ion in solution is colored:


A. Colorless C. Green
B. Blue D. Yellow

Additional Practice Questions


1. Iron sorbitex is a chemical complex of: 4. Crude metal iron that is obtained from the blast
A. Iron D. Dextrin furnace:

B. Sorbitol E. All of the above A. cast iron C. pig iron

C. Citric acid B. wrought iron D. a and c

2. Gray cast iron is also known as 5. Blood red colorization with SCN but a blue
precipitate with hexacyanoferrate(II):
A. graphite scales C. wrought iron
A. Ferric C. Magnesium
B. graphite fines D. none of these
B. Ferric D.Cobalt

Ratonale: Addition of ferric salts to solution of thiocyanates


3. Solid solution of hard, brittle iron carbide when causes the formation of a blood-red color which has
molten iron is rapidly cooled: been variously ascribed to the formation of Fe(CNS)3,
Fe(CNS)6 and Fe(CNS).
A. Cementite C. a and b
B. white cast iron D. gray cast iron

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