The document provides information about triads in inorganic chemistry, focusing on iron. It discusses the properties, uses, and compounds of iron. It also provides example identification tests for ferrous and ferric salts and concludes with practice questions.
The document provides information about triads in inorganic chemistry, focusing on iron. It discusses the properties, uses, and compounds of iron. It also provides example identification tests for ferrous and ferric salts and concludes with practice questions.
The document provides information about triads in inorganic chemistry, focusing on iron. It discusses the properties, uses, and compounds of iron. It also provides example identification tests for ferrous and ferric salts and concludes with practice questions.
The document provides information about triads in inorganic chemistry, focusing on iron. It discusses the properties, uses, and compounds of iron. It also provides example identification tests for ferrous and ferric salts and concludes with practice questions.
A. Iron • Aka: _______ • Cast Iron aka _______- crude metal iron from blast furnace (92-94%) Present in proteins: • Cementite or White Cast Iron- solid solution • Hemoglobin of hard, brittle iron carbide • Transferrin • Gray Cast Iron aka __________; liquid iron is • Ferritin run into sand molds and allowed to cool • Cytochrome-oxidase enzyme • Wrought Iron- Product obtained by removing most of the impurities from cast iron. Enhance absorption of Iron: • Reduced Iron- made from ferric oxide with • Vitamin C the addition of hydrogen • Copper • Steel- Made up of Iron and _______ • Iron Pyrite: aka __________ is a native iron • Most important element in engineering sulfide • Iron is best absorbed in the __________. • Misch metal” is 70% _______ and 30% Iron • Mucosal block postulation by Hahn is the best known hypothesis of iron absorption. Identification Test: 1. Ferric salts Use: _______ • Acid ferric salt solutions give a dark blue precipitate with potassium ferrocyanide T.S. ADR: Black stool • Excess NaOH T.S. produces a reddish brown precipitate of ferric hydroxide. • With ammonium thiocyanate (SCN) T.S. a Deficiency: _______________ deep red color is formed.
Toxicity: 2. Ferrous salts
• GIT distress • Solutions of ferrous salts give a dark blue • Cardiac collapse precipitate with potassium ferricyanide T.S. • Hemochromatosis • The precipitate is insoluble in diluted HCl but is decomposed by NaOH T.S. Antidote: __________ ( S. pilosus)
Compounds of Iron Compound Name Other Name Use Hematinic Most economical and most satisfactory form 1. Ferrous sulfate- FeSO4 __________ of iron preparation S/E: Constipation
8. Ferric oxide- Fe2O3 ___________________ • Makes calamine PINK
9. Ferrous ammonium ___________________ • Used in analytical chemistry sulfate
All rights reserved. Copyright 2020
Practice Questions 1. Misch metal” is 70% cerium and 30%: 8. It contains iron in solution or in suspension and are A. magnesium C. iron characterized by a ferruginous taste.
B. calcium D. holmium A. Carbonated water
B. Chalybeate water 2. This is obtained from the removal of most of the C. Saline water impurities in a cast iron D. Lithia water A. wrought iron C. A and B B. reduced iron D. none of this 9. Iron sorbitex is a chemical complex of: 3.Reduced iron is made from ferric oxide with the A. Iron D. Dextrin addition of: B. Sorbitol E. All of the above A. hydrogen C. chlorine C. Citric acid B. electron D. oxygen
4. Gray cast iron is also known as 10. Blood red colorization with SCN but a blue precipitate with hexacyanoferrate(II): A. graphite scales C. wrought iron A. Ferrous salt C. Magnesium B. graphite fines D. none of these B. Ferric salt D.Cobalt 5. Solid solution of hard, brittle iron carbide when molten iron is rapidly cooled: 11. The ion that gives a Turnbulls’ blue precipitate A. Cementite C. A and B with potassium ferricyanide: B. white cast iron D. gray cast iron A. Ferrous C. Cobalt B. Ferric D. Nickel 6. Crude metal iron that is obtained from the blast furnace: A. cast iron C. pig iron 12. The ion that produces an intense blue colored B. wrought iron D. A and C solution with an excess ammonia and a reddish brown precipitate with potassium ferrocyanide: 7. After oral administration, the greatest amount of A. Cuprous C. Cadmium iron absorption occurs in the: B. Cupric D. Zinc A. Duodenum B. Stomach C. Sigmoid portion of the large intestine D. Ascending portion of the large intestine
