JEE (Main + Advanced) 2024

ENTHUSE COURSE

INORGANIC CHEMISTRY QUIZ # 01 TIME : 30 Min.

SECTION–I (i) : (Maximum Marks : 18)
This section contains SIX questions. Marking scheme : +3(–1)
Each question has FOUR options (A), (B), (C) and (D). ONLY ONE of these four option(s) is correct.
1. Dipole-induced dipole interaction depends upon
(A) size of polarisable particle (B) dipole moment of permanent dipole
(C) Both (A) and (B) (D) None of these

2. Which of the following has INCORRECT order of their boiling point ?

(A) H3BO3 > B(OCH3) 3 (B) HF > HCl

(C) ICl > Br2 (D) NH3 > SbH3

3. PBr5(s) ® PBr4+ + Br¯

Br¯ + Br2 ® Br¯
3

Which of the following force is responsible for the interaction of X¯ and X2 to form coordinate bond
in between X¯ and X2 :
(A) Keesom force (B) Debye force
(C) London force (D) Ion-induced dipole attraction
4. Which of the following molecular interactions include not only London dispersion forces but also
dipole-dipole interaction -
(A) PF3( ) (B) BF3( ) (C) AlF3(s) (D) SiF4( )
5. Which of the following statement(s) is/are correct :

(A) For fatty molecules, head-tail arrangement is more preferred than antiparallel
arrangement in context of dipole-dipole interaction

(B) Debye forces can act between a pair of non-polar molecules

(C) Formation of noble gas clathrates is due to London-forces

(D) Boiling point of H2O > Boiling point of D2O

6. Among the following, the most soluble in water is

OH Cl OH
CHO
(A) (B) (C) (D) CCl4

CHO
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 JEE (Main + Advanced) 2024
ENTHUSE COURSE
SECTION–I(ii) : (Maximum Marks : 16)
This section contains FOUR questions. Marking scheme : +4(0)
Each question has FOUR options (A), (B), (C) and (D). ONE OR MORE THAN ONE of these
four option(s) is (are) correct.

7. Which of the following option(s) is/are CORRECT ?

Type of interaction distance-energy function
1 1
(A) dipole-dipole (B) H-bonding
r3 r3
1 1
(C) Ion-dipole 2 (D) London force
r r6
8. The correct order of the boiling point is /are -
(A) He < Ne < Ar < Kr < Xe (B) H2 < He
(C) H2 < D2 < T2 (D) BF3 < BMe3
9. Which of the following statement is/are CORRECT :-
(A) In noble gases helium has lowest boiling point
(B) In NaHCO3(s) hydrogen bonding takes place
(C) Boiling point of SiCl4 is greater than the boiling point of CCl4
(D) Boiling point of H2O is greater than the boiling point of HF.
10. Which of the following order(s) is/are correct
(A) SiH4 > CH4 (boiling point order)
(B) Deby forces are responsible for formation of condense phase of H2O
(C) London forces exist between all molecules
(D) Boiling point of Cis-1,2-dichloroethene is more than trans-1,2-dichloroethene
SECTION–I(iii) : (Maximum Marks : 12)
This section contains TWO paragraphs. Marking scheme : +3(0)
Based on each paragraph, there will be TWO questions
Each question has FOUR options (A), (B), (C) and (D) ONLY ONE of these four option(s) is correct.
Paragraph for Q.11 to Q.12
Atoms within a covalent molecule are bound firmly together by covalent bonds, but the molecules usually
are attracted very weakly to other molecules by vanderwaals forces. Contribution to the vanderwaals
forces can be pictured as the attraction exerted by positive nucleus on electrons beyond its own radius.
11. Which of the following consist of discrete covalent molecules and only London forces holding the
molecules-
(A) SiC(solid) (B) NF3(liq.)
(C) Hydrated Noble gases (D) Liq. halogens
12. Momentary dipole of a non polar molecule polarize the adjacent non polar molecule during
(A) Liquifacation of chlorobenzene (B) Liquifaction of C(CH3)4
(C) Clathrate formation of Xe (D) Hydration of K+

E-2 / 3 INORGANIC CHEM. / QUIZ # 01

 JEE (Main + Advanced) 2024
ENTHUSE COURSE

Paragraph for Q.13 & Q.14

Various forces acting on chemical species are ionic, covalent and Vanderwaal forces. In general, the
importance of a particular force affect chemical and Physical properties of chemicals.
13. London force is the only operational force between -
(A) Ions of NaF (B) Molecules of fluorobenzene
(C) Molecules of fluorine (D) Molecules of water & fluoride ion
14. Select the correct order of the strength of intermolecular forces -
(A) n-butane > n-butylchloride > n-butanol (B) n-butanol > n-butylchloride > n-butane
(C) n-butanol > n-butane > n-butylchloride (D) n-butylchloride > n-butane > n-butanol
SECTION–II : Matrix-Match Type (Maximum Marks : 16)
This Section contains TWO questions. Each question has four statements (A, B, C and D) given in
Column I and five statements (P, Q, R, S & T) in Column II. Any given statement in Column I can have
correct matching with ONE or MORE statement(s) given in Column II. For example, if for a given
question, statement B matches with the statements given in Q and R, then for the particular question, against
statement B, darken the bubbles corresponding to Q and R in the ORS.

1. Column-I (Types of weak forces) Column-II(Characteristics)

1
(A) Dipole-dipole interactions (P) Interaction energy
r3
(between rotating polar molecule)
1
(B) Dipole-induced dipole interactions (Q) Interaction energy
r6
(C) London force (R) Liquid-He
(between non-polar particles)
1
(D) Ion-dipole interactions (S) Interaction energy
r2
(T) KHF2
2. Column (I) Column (II)
Molecules Interaction that can exist between
molecules of any type
(A) HF and H2O (P) Dipole-dipole interaction
(B) Br2 and H2O (Q) Ion-Dipole interaction
(C) KCl and Cl2 (R) London-forces
(D) Xe(l) (S) Ion-induced dipole interaction
(T) Dipole-induced dipole interaction

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 JEE (Main + Advanced) 2024
ENTHUSE COURSE
SECTION–IV : (Maximum Marks : 12)
This section contains THREE questions. Marking scheme : +4(–1)
The answer to each question is a SINGLE DIGIT INTEGER ranging from 0 to 9, both inclusive
1. Which of the following pairs have dipole-dipole interaction
(BF3 + BF3), (CCl4 + Na+) (HCl + HCl), (CHCl3 + CHCl3), (K+ + HCl), (Na+ + Cl–)
2. Find the total number of following molecules which are polar.
P(CH3)3, XeO3, PCl3F2, O3, SiF4, XeF4, XeO2F4
3. Number of molecules in which only London force is responsible for inter particle interactions.
HCN, CCl4, RbCl, H3BO3, HCl, PCl5(s)

E-4 / 3 INORGANIC CHEM. / QUIZ # 01