Eporip - MSDS
Eporip - MSDS
Eporip - MSDS
EPORIP comp.A
Safety Data Sheet dated: 15/09/2023 - version 6
Warning
Hazard statements
H315 Causes skin irritation.
H317 May cause an allergic skin reaction.
H319 Causes serious eye irritation.
H411 Toxic to aquatic life with long lasting effects.
Precautionary statements
P261 Avoid breathing mist/vapours/spray.
P264 Wash hands thoroughly after handling.
P273 Avoid release to the environment.
P280 Wear protective gloves/clothing and eye/face protection.
P333+P313 If skin irritation or rash occurs: Get medical advice/attention.
P391 Collect spillage.
Special Provisions:
EUH208 Contains 1,6-Hexanediol Diglycidyl Ether. May produce an allergic reaction.
EUH208 Contains Formaldehyde, oligomeric reaction products with 1-chloro-2,3-epoxypropane and phenol. May
produce an allergic reaction.
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EUH208 Contains Formaldehyde, oligomeric reaction products with 1-chloro-2,3-epoxypropane and phenol. May
produce an allergic reaction.
Contains
bis-[4-(2,3-epoxipropoxi)phenyl]propane
Special provisions according to Annex XVII of REACH and subsequent amendments:
Restricted to professional users.
2.3. Other hazards
This preparation contains low molecular weight epoxy resins. Cross sensitisation to other epoxies is possible. Avoid also exposure to spray
mist and vapour.
Hazardous components within the meaning of the CLP regulation and related classification:
Qty Name Ident. Numb. Classification Registration Number
≥25 - <50 bis-[4-(2,3- CAS:1675-54-3, Skin Irrit. 2, H315 Skin Sens. 1, 01-2119456619-26-XXXX
% epoxipropoxi)phenyl]propane 25085-99-8 H317 Eye Irrit. 2, H319 Aquatic
EC:216-823-5 Chronic 2, H411
Index:603-073-
00-2 Specific Concentration Limits:
C ≥ 5%: Skin Irrit. 2 H315
C ≥ 5%: Eye Irrit. 2 H319
≥10 - <20 1,6-Hexanediol Diglycidyl Ether CAS:933999-84- Skin Irrit. 2, H315; Eye Irrit. 2, 01-2119463471-41-0005
% 9, 16096-31-4 H319; Skin Sens. 1, H317; Aquatic
EC:618-939-5 Chronic 3, H412
≥5 - <10 Formaldehyde, oligomeric reaction CAS:9003-36-5 Skin Irrit. 2, H315; Aquatic 01-2119454392-40-XXXX
% products with 1-chloro-2,3- EC:701-263-0 Chronic 2, H411; Skin Sens. 1,
epoxypropane and phenol H317
≥0.25 - ethylene glycol monobutyl ether CAS:111-76-2 Acute Tox. 3, H331 Acute Tox. 4, 01-2119475108-36-XXXX
<0.49 % EC:203-905-0 H302 Skin Irrit. 2, H315 Eye Irrit.
Index:603-014- 2, H319
00-0
Acute Toxicity Estimate:
ATE - Oral: 1200mg/kg bw
NDS NETHERLAND Long Term: 100 mg/m3; Short Term: 246 mg/m3
S
National ESTONIA Long Term: 98 mg/m3 - 20 ppm; Short Term: 246 mg/m3 - 50 ppm
National LATVIA Long Term: 98 mg/m3 - 20 ppm; Short Term: 246 mg/m3 - 50 ppm
National CZECH Short Term: Ceiling - 200 mg/m3
REPUBLIC
National BULGARIA Long Term: 98 mg/m3 - 20 ppm; Short Term: 246 mg/m3 - 50 ppm
National ROMANIA Long Term: 98 mg/m3 - 20 ppm; Short Term: 246 mg/m3 - 50 ppm
TUR TURKEY Long Term: 98 mg/m3 - 20 ppm; Short Term: 246 mg/m3 - 50 ppm
National LITHUANIA Long Term: 50 mg/m3 - 10 ppm; Short Term: 100 mg/m3 - 20 ppm
National CROATIA Long Term: 98 mg/m3 - 20 ppm; Short Term: 246 mg/m3 - 50 ppm
EU Long Term: 98 mg/m3 - 20 ppm; Short Term: 246 mg/m3 - 50 ppm
Behaviour Indicative
Possibility of significant uptake through the skin;
National SLOVENIA Long Term: 98 mg/m3 - 20 ppm; Short Term: 246 mg/m3 - 50 ppm
Exposure Route: Human Inhalation; Exposure Frequency: Long Term, systemic effects
Worker Industry: 4.9 mg/m3
Formaldehyde, oligomeric a) acute toxicity LD50 Oral Rat > 5000 mg/kg
reaction products with 1-
chloro-2,3-epoxypropane
and phenol
Formaldehyde, oligomeric reaction CAS: 9003-36-5 a) Aquatic acute toxicity : LC50 Fish = 5.7 mg/L 96h
products with 1-chloro-2,3- - EINECS: 701-
epoxypropane and phenol 263-0
a) Aquatic acute toxicity : EC50 Daphnia Daphnia magna > 1000 mg/L 48h
EPA
a) Aquatic acute toxicity : LC50 Fish Lepomis macrochirus = 2950 mg/L 96h
IUCLID
N.A.
12.3. Bioaccumulative potential
N.A.
12.4. Mobility in soil
N.A.
12.5. Results of PBT and vPvB assessment
IATA-Erg: 9L
IATA-Special Provisions: A97 A158 A197
Sea (IMDG):
IMDG-Stowage Code: Category A
IMDG-Stowage Note: -
IMDG-Subsidiary hazards: -
Seveso III category according Lower-tier threshold (tonnes) Upper-tier threshold (tonnes)
to Annex 1, part 1
Product belongs to category: E2 200 500
Restrictions related to the product or the substances contained according to Annex XVII Regulation (EC) 1907/2006 (REACH)
and subsequent modifications:
Restrictions related to the product: 3
Restrictions related to the substances contained: 28, 29, 40, 75
SVHC Substances:
SVHC substances not present in a concentration ≥ 0.1% (w/w)
National regulations
Produktregisteret Norge: 52874
MAL-kode: 0-5; A+B (3:1)=3-5 (1993)
Lagerklasse (TRGS-510): 12 - Non-combustible liquids, that cannot be assigned to any of the aforementioned LGK
German Water Hazard Class.
Class 2: hazardous for water.
15.2. Chemical safety assessment
No Chemical Safety Assessment has been carried out for the mixture.
Code Description
H302 Harmful if swallowed.
H315 Causes skin irritation.
H317 May cause an allergic skin reaction.
H319 Causes serious eye irritation.
H331 Toxic if inhaled.
H411 Toxic to aquatic life with long lasting effects.
H412 Harmful to aquatic life with long lasting effects.
Classification and procedure used to derive the classification for mixtures according to Regulation (EC) 1272/2008
[CLP]:
Classification according to Regulation Classification procedure
(EC) Nr. 1272/2008
Skin Irrit. 2, H315 Calculation method
Eye Irrit. 2, H319 Calculation method
Skin Sens. 1, H317 Calculation method
Aquatic Chronic 2, H411 Calculation method
If appropriate, specific provisions in relation to possible training for workers are mentioned in section 2. Any training related to safety in the
workplace must in any case refer to a risk assessment that must be carried out by a company safety officer taking into account the specific
operating and environmental conditions in which the products are used.
This document was prepared by a competent person who has received appropriate training.
Main bibliographic sources:
ECDIN - Environmental Chemicals Data and Information Network - Joint Research Centre, Commission of the European
Communities
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ECDIN - Environmental Chemicals Data and Information Network - Joint Research Centre, Commission of the European
Communities
SAX's DANGEROUS PROPERTIES OF INDUSTRIAL MATERIALS - Eight Edition - Van Nostrand Reinold
The information contained herein is based on our state of knowledge at the above-specified date. It refers solely to the product indicated and
constitutes no guarantee of particular quality.
It is the duty of the user to ensure that this information is appropriate and complete with respect to the specific use intended.
This SDS cancels and replaces any preceding release.
Legend to abbreviations and acronyms used in the safety data sheet:
ACGIH: American Conference of Governmental Industrial Hygienists
ADR: European Agreement concerning the International Carriage of Dangerous Goods by Road.
AND: European Agreement concerning the International Carriage of Dangerous Goods by Inland Waterways
ATE: Acute Toxicity Estimate
ATEmix: Acute toxicity Estimate (Mixtures)
BCF: Biological Concentration Factor
BEI: Biological Exposure Index
BOD: Biochemical Oxygen Demand
CAS: Chemical Abstracts Service (division of the American Chemical Society).
CAV: Poison Center
CE: European Community
CLP: Classification, Labeling, Packaging.
CMR: Carcinogenic, Mutagenic and Reprotoxic
COD: Chemical Oxygen Demand
COV: Volatile Organic Compound
CSA: Chemical Safety Assessment
CSR: Chemical Safety Report
DMEL: Derived Minimal Effect Level
DNEL: Derived No Effect Level.
DPD: Dangerous Preparations Directive
DSD: Dangerous Substances Directive
EC50: Half Maximal Effective Concentration
ECHA: European Chemicals Agency
EINECS: European Inventory of Existing Commercial Chemical Substances.
ES: Exposure Scenario
GefStoffVO: Ordinance on Hazardous Substances, Germany.
GHS: Globally Harmonized System of Classification and Labeling of Chemicals.
IARC: International Agency for Research on Cancer
IATA: International Air Transport Association.
IATA-DGR: Dangerous Goods Regulation by the "International Air Transport Association" (IATA).
IC50: half maximal inhibitory concentration
ICAO: International Civil Aviation Organization.
ICAO-TI: Technical Instructions by the "International Civil Aviation Organization" (ICAO).
IMDG: International Maritime Code for Dangerous Goods.
INCI: International Nomenclature of Cosmetic Ingredients.
IRCCS: Scientific Institute for Research, Hospitalization and Health Care
KAFH: KAFH
KSt: Explosion coefficient.
LC50: Lethal concentration, for 50 percent of test population.
LD50: Lethal dose, for 50 percent of test population.
LDLo: Leathal Dose Low
N.A.: Not Applicable
N/A: Not Applicable
N/D: Not defined/ Not available
NA: Not available
NIOSH: National Institute for Occupational Safety and Health
NOAEL: No Observed Adverse Effect Level
OSHA: Occupational Safety and Health Administration
PBT: Persistent, Bioaccumulative and Toxic
PGK: Packaging Instruction
PNEC: Predicted No Effect Concentration.
PSG: Passengers
RID: Regulation Concerning the International Transport of Dangerous Goods by Rail.
STEL: Short Term Exposure limit.
STOT: Specific Target Organ Toxicity.
TLV: Threshold Limiting Value.
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TLV: Threshold Limiting Value.
TWATLV: Threshold Limit Value for the Time Weighted Average 8 hour day. (ACGIH Standard).
vPvB: Very Persistent, Very Bioaccumulative.
WGK: German Water Hazard Class.
Paragraphs modified from the previous revision:
- SECTION 2: Hazards identification
- SECTION 3: Composition/information on ingredients
- SECTION 5: Firefighting measures
- SECTION 6: Accidental release measures
- SECTION 7: Handling and storage
- SECTION 8: Exposure controls/personal protection
- SECTION 11: Toxicological information
- SECTION 12: Ecological information
- SECTION 14: Transport information
- SECTION 15: Regulatory information
- SECTION 16: Other information