Eporip - MSDS

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Safety Data Sheet

EPORIP comp.A
Safety Data Sheet dated: 15/09/2023 - version 6

SECTION 1: Identification of the substance/mixture and of the company/undertaking


1.1. Product identifier
Mixture identification:
Trade name: EPORIP comp.A
Trade code: 901521
UFI: J3C0-70JR-500M-046J
1.2. Relevant identified uses of the substance or mixture and uses advised against
Recommended use: Epoxy adhesive
Uses advised against: Data not available.
1.3. Details of the supplier of the safety data sheet
Company: MAPEI U.K. Ltd - Mapei House Steel Park Road
Halesowen - West Midlands B62 8HD
phone: +44(0)121 508 6970 - fax: +44(0)121 5086 960 - www.mapei.co.uk (office hour 8:30-17:30)
Responsible: sicurezza@mapei.it
1.4. Emergency telephone number
call NHS 111 or a doctor/OHES Environmental Ltd +44(0)333 333 9962

SECTION 2: Hazards identification

2.1. Classification of the substance or mixture

Regulation (EC) n. 1272/2008 (CLP)


Skin Irrit. 2 Causes skin irritation.
Eye Irrit. 2 Causes serious eye irritation.
Skin Sens. 1 May cause an allergic skin reaction.
Aquatic Chronic 2 Toxic to aquatic life with long lasting effects.
Adverse physicochemical, human health and environmental effects:
No other hazards
2.2. Label elements
Regulation (EC) No 1272/2008 (CLP):

Hazard pictograms and Signal Word

Warning

Hazard statements
H315 Causes skin irritation.
H317 May cause an allergic skin reaction.
H319 Causes serious eye irritation.
H411 Toxic to aquatic life with long lasting effects.

Precautionary statements
P261 Avoid breathing mist/vapours/spray.
P264 Wash hands thoroughly after handling.
P273 Avoid release to the environment.
P280 Wear protective gloves/clothing and eye/face protection.
P333+P313 If skin irritation or rash occurs: Get medical advice/attention.
P391 Collect spillage.

Special Provisions:
EUH208 Contains 1,6-Hexanediol Diglycidyl Ether. May produce an allergic reaction.
EUH208 Contains Formaldehyde, oligomeric reaction products with 1-chloro-2,3-epoxypropane and phenol. May
produce an allergic reaction.
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EUH208 Contains Formaldehyde, oligomeric reaction products with 1-chloro-2,3-epoxypropane and phenol. May
produce an allergic reaction.

EUH205 Contains epoxy constituents. May produce an allergic reaction.

Contains
bis-[4-(2,3-epoxipropoxi)phenyl]propane
Special provisions according to Annex XVII of REACH and subsequent amendments:
Restricted to professional users.
2.3. Other hazards

No PBT, vPvB or endocrine disruptor substances present in concentration >= 0.1%


Other Hazards: No other hazards

This preparation contains low molecular weight epoxy resins. Cross sensitisation to other epoxies is possible. Avoid also exposure to spray
mist and vapour.

SECTION 3: Composition/information on ingredients


3.1. Substances
Not Relevant
3.2. Mixtures
Mixture identification: EPORIP comp.A

Hazardous components within the meaning of the CLP regulation and related classification:
Qty Name Ident. Numb. Classification Registration Number
≥25 - <50 bis-[4-(2,3- CAS:1675-54-3, Skin Irrit. 2, H315 Skin Sens. 1, 01-2119456619-26-XXXX
% epoxipropoxi)phenyl]propane 25085-99-8 H317 Eye Irrit. 2, H319 Aquatic
EC:216-823-5 Chronic 2, H411
Index:603-073-
00-2 Specific Concentration Limits:
C ≥ 5%: Skin Irrit. 2 H315
C ≥ 5%: Eye Irrit. 2 H319

≥10 - <20 1,6-Hexanediol Diglycidyl Ether CAS:933999-84- Skin Irrit. 2, H315; Eye Irrit. 2, 01-2119463471-41-0005
% 9, 16096-31-4 H319; Skin Sens. 1, H317; Aquatic
EC:618-939-5 Chronic 3, H412

≥5 - <10 Formaldehyde, oligomeric reaction CAS:9003-36-5 Skin Irrit. 2, H315; Aquatic 01-2119454392-40-XXXX
% products with 1-chloro-2,3- EC:701-263-0 Chronic 2, H411; Skin Sens. 1,
epoxypropane and phenol H317

≥0.25 - ethylene glycol monobutyl ether CAS:111-76-2 Acute Tox. 3, H331 Acute Tox. 4, 01-2119475108-36-XXXX
<0.49 % EC:203-905-0 H302 Skin Irrit. 2, H315 Eye Irrit.
Index:603-014- 2, H319
00-0
Acute Toxicity Estimate:
ATE - Oral: 1200mg/kg bw

SECTION 4: First aid measures


4.1. Description of first aid measures
In case of skin contact:
Immediately take off all contaminated clothing.
Areas of the body that have - or are only even suspected of having - come into contact with the product must be rinsed immediately
with plenty of running water and possibly with soap.
Wash thoroughly the body (shower or bath).
Remove contaminated clothing immediately and dispose of safely.
After contact with skin, wash immediately with soap and plenty of water.
In case of eyes contact:
After contact with the eyes, rinse with water with the eyelids open for a sufficient length of time, then consult an opthalmologist
immediately.
Protect uninjured eye.
In case of Ingestion:
Do not induce vomiting, get medical attention showing the SDS and the hazard label.
In case of Inhalation:
Remove casualty to fresh air and keep warm and at rest.
4.2. Most important symptoms and effects, both acute and delayed
Eye irritation
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Eye irritation
Eye damages
Skin Irritation
Erythema
4.3. Indication of any immediate medical attention and special treatment needed
In case of accident or unwellness, seek medical advice immediately (show directions for use or safety data sheet if possible).
Treatment:
(see paragraph 4.1)

SECTION 5: Firefighting measures


5.1. Extinguishing media
Suitable extinguishing media:
Water.
Carbon dioxide (CO2).
Extinguishing media which must not be used for safety reasons:
None in particular.
5.2. Special hazards arising from the substance or mixture
Do not inhale explosion and combustion gases.
Burning produces heavy smoke.
5.3. Advice for firefighters
Use suitable breathing apparatus.
Collect contaminated fire extinguishing water separately. This must not be discharged into drains.
Move undamaged containers from immediate hazard area if it can be done safely.

SECTION 6: Accidental release measures


6.1. Personal precautions, protective equipment and emergency procedures
For non emergency personnel:
Wear personal protection equipment.
Remove persons to safety.
See protective measures under point 7 and 8.
For emergency responders:
Wear personal protection equipment.
6.2. Environmental precautions
Do not allow to enter into soil/subsoil. Do not allow to enter into surface water or drains.
Limit leakages with earth or sand.
In case of gas escape or of entry into waterways, soil or drains, inform the responsible authorities.
6.3. Methods and material for containment and cleaning up
Suitable material for taking up: absorbing material, organic, sand
Wash with plenty of water.
Retain contaminated washing water and dispose it.
6.4. Reference to other sections
See also section 8 and 13

SECTION 7: Handling and storage


7.1. Precautions for safe handling
Avoid contact with skin and eyes, inhalation of vapours and mists.
Don't use empty container before they have been cleaned.
Before making transfer operations, assure that there aren't any incompatible material residuals in the containers.
Contaminated clothing should be changed before entering eating areas.
Do not eat or drink while working.
See also section 8 for recommended protective equipment.
Advice on general occupational hygiene:
7.2. Conditions for safe storage, including any incompatibilities
Keep away from food, drink and feed.
Incompatible materials:
None in particular.
Instructions as regards storage premises:
Adequately ventilated premises.
7.3. Specific end use(s)
Recommendation(s)
None in particular
Industrial sector specific solutions:
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Industrial sector specific solutions:
None in particular

SECTION 8: Exposure controls/personal protection


8.1. Control parameters

Community Occupational Exposure Limits (OEL)


OEL Country Occupational Exposure Limit
Type
ethylene glycol monobutyl DFG GERMANY Short Term: Ceiling - 98 mg/m3 - 20 ppm
ether
CAS: 111-76-2

ACGIH Long Term: 20 ppm


A3 - Confirmed Animal Carcinogen with Unknown Relevance to Humans;eye and upper
respiratory tract irritation;

National SWEDEN Long Term: 50 mg/m3 - 10 ppm


National FRANCE Long Term: 49 mg/m3 - 10 ppm; Short Term: 246 mg/m3 - 50 ppm
National SPAIN Long Term: 98 mg/m3 - 20 ppm; Short Term: 245 mg/m3 - 50 ppm
National GREECE Long Term: 120 mg/m3 - 25 ppm
National DENMARK Long Term: 98 mg/m3 - 20 ppm
National FINLAND Long Term: 98 mg/m3 - 20 ppm; Short Term: 250 mg/m3 - 50 ppm
National GERMANY Long Term: 49 mg/m3 - 10 ppm
National PORTUGAL Long Term: 98 mg/m3 - 20 ppm; Short Term: 246 mg/m3 - 50 ppm
National NORWAY Long Term: 50 mg/m3 - 10 ppm; Short Term: 75 mg/m3 - 15 ppm
National BELGIUM Long Term: 98 mg/m3 - 20 ppm; Short Term: 246 mg/m3 - 50 ppm
NDS POLAND Long Term: 98 mg/m3
NDSCh POLAND Short Term: 200 mg/m3
CHE SWITZERLAN Short Term: 98 mg/m3 - 20 ppm
D

NDS NETHERLAND Long Term: 100 mg/m3; Short Term: 246 mg/m3
S

National CZECH Long Term: 100 mg/m3


REPUBLIC

National HUNGARY Long Term: 98 mg/m3; Short Term: 246 mg/m3


Malaysi MALAYSIA Long Term: 96.7 mg/m3 - 20 ppm
a OEL Skin notation;

National ESTONIA Long Term: 98 mg/m3 - 20 ppm; Short Term: 246 mg/m3 - 50 ppm
National LATVIA Long Term: 98 mg/m3 - 20 ppm; Short Term: 246 mg/m3 - 50 ppm
National CZECH Short Term: Ceiling - 200 mg/m3
REPUBLIC

National SLOVAKIA Short Term: Ceiling - 246 mg/m3


National SLOVAKIA Long Term: 98 mg/m3 - 20 ppm
National SLOVENIA Long Term: 98 mg/m3 - 20 ppm; Short Term: 245 mg/m3 - 50 ppm
National UNITED Long Term: 123 mg/m3 - 25 ppm; Short Term: 246 mg/m3 - 50 ppm
KINGDOM

National BULGARIA Long Term: 98 mg/m3 - 20 ppm; Short Term: 246 mg/m3 - 50 ppm
National ROMANIA Long Term: 98 mg/m3 - 20 ppm; Short Term: 246 mg/m3 - 50 ppm
TUR TURKEY Long Term: 98 mg/m3 - 20 ppm; Short Term: 246 mg/m3 - 50 ppm
National LITHUANIA Long Term: 50 mg/m3 - 10 ppm; Short Term: 100 mg/m3 - 20 ppm
National CROATIA Long Term: 98 mg/m3 - 20 ppm; Short Term: 246 mg/m3 - 50 ppm
EU Long Term: 98 mg/m3 - 20 ppm; Short Term: 246 mg/m3 - 50 ppm
Behaviour Indicative
Possibility of significant uptake through the skin;

ACGIH Long Term: 20 ppm


A3 - Confirmed Animal Carcinogen with Unknown Relevance to Humans;eye and upper
respiratory tract irritation

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Malaysi MALAYSIA Long Term: 96.7 mg/m3 - 20 ppm
a OEL Skin notation

EU Long Term: 98 mg/m3 - 20 ppm; Short Term: 246 mg/m3 - 50 ppm


Behaviour Indicative
Possibility of significant uptake through the skin

National SLOVENIA Long Term: 98 mg/m3 - 20 ppm; Short Term: 246 mg/m3 - 50 ppm

Biological limit values


ethylene glycol monobutyl Biological Indicator: Butoxyacetic acid ( BAA ); Sampling Period: End of turn
ether Value: 200 MGGCREAT; Medium: Urine
CAS: 111-76-2

Predicted No Effect Concentration (PNEC) values


1,6-Hexanediol Diglycidyl Exposure Route: Microorganisms in sewage treatments; PNEC Limit: 1 mg/l
Ether
CAS: 933999-84-9,
16096-31-4

Exposure Route: Fresh Water; PNEC Limit: 0.0115 mg/l


Exposure Route: Freshwater sediments; PNEC Limit: 0.283 mg/kg
Exposure Route: Marine water; PNEC Limit: 0.00115 mg/l
Exposure Route: Marine water sediments; PNEC Limit: 0.0283 mg/kg
Exposure Route: Soil; PNEC Limit: 0.223 mg/kg
Formaldehyde, oligomeric Exposure Route: Microorganisms in sewage treatments; PNEC Limit: 10 mg/l
reaction products with 1-
chloro-2,3-epoxypropane
and phenol
CAS: 9003-36-5

Exposure Route: Fresh Water; PNEC Limit: 0.003 mg/l


Exposure Route: Freshwater sediments; PNEC Limit: 0.294 mg/kg
Exposure Route: Marine water; PNEC Limit: 0.0003 mg/l
Exposure Route: Marine water sediments; PNEC Limit: 0.0294 mg/kg
Exposure Route: Soil; PNEC Limit: 0.237 mg/kg

Derived No Effect Level (DNEL) values


1,6-Hexanediol Diglycidyl Exposure Route: Human Dermal; Exposure Frequency: Long Term, systemic effects
Ether Worker Industry: 2.8 mg/kg
CAS: 933999-84-9,
16096-31-4

Exposure Route: Human Inhalation; Exposure Frequency: Long Term, systemic effects
Worker Industry: 4.9 mg/m3

8.2. Exposure controls


Eye protection:
Use close fitting safety goggles, don't use eye lens.
Protection for skin:
Use clothing that provides comprehensive protection to the skin, e.g. cotton, rubber, PVC or viton.
Protection for hands:
Suitable materials for safety gloves; EN ISO 374:
Polychloroprene - CR: thickness >=0,5mm; breakthrough time >=480min.
Nitrile rubber - NBR: thickness >=0,35mm; breakthrough time >=480min.
Butyl rubber - IIR: thickness >=0,5mm; breakthrough time >=480min.
Fluorinated rubber - FKM: thickness >=0,4mm; breakthrough time >=480min.
Neoprene gloves are suggested (0,5 mm) not recommended gloves: not waterproof gloves
Respiratory protection:
Personal Protective Equipment should comply with relevant CE standards (as EN ISO 374 for gloves and EN ISO 166 for goggles),
correctly maintained and stored. Consult the supplier to check the suitability of equipment against specific chemicals and for user
information.
Respiratory protection must be used where exposure levels exceed workplace exposure limits. Refer to appropriate EN standards,
like EN 136, 140, 143, 149, 14387 for information on selection and use of appropriate respiratory protection equipment.
In case of insufficient ventilation use mask with ABEKP filters (EN 14387).
Hygienic and Technical measures
Not available
Appropriate engineering controls:
Not available
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Not available

SECTION 9: Physical and chemical properties


9.1. Information on basic physical and chemical properties
Physical state: Liquid
Appearance: liquid
Color: Grey
Odour: Characteristic
Odour threshold: Not available
Melting point / freezing point: Not available
Initial boiling point and boiling range: Not available
Flammability: N.A.
Lower and upper explosion limit: Not available
Flash point: Not available
Auto-ignition temperature: Not available
Decomposition temperature: Not available
pH: Not Relevant
Viscosity: 20,000.00 cPs
Kinematic viscosity: Not available
Solubility in water: Insoluble
Solubility in oil: soluble
Partition coefficient (n-octanol/water): Not available
Vapour pressure: 0.01
Relative density: 1.55 g/cm3
Vapour density: Not available
Particle characteristics:
Particle size: Not available
9.2. Other information
Miscibility: Not available
Conductivity: Not available
Explosive properties: ==
No other relevant information

SECTION 10: Stability and reactivity


10.1. Reactivity
Stable under normal conditions
10.2. Chemical stability
Stable under normal conditions
10.3. Possibility of hazardous reactions
None.
10.4. Conditions to avoid
Stable under normal conditions.
10.5. Incompatible materials
None in particular.
10.6. Hazardous decomposition products
None.

SECTION 11: Toxicological information


11.1. Information on hazard classes as defined in Regulation (EC) No 1272/2008
Toxicological Information of the Preparation
a) acute toxicity Not classified
Based on available data, the classification criteria are not met
b) skin corrosion/irritation The product is classified: Skin Irrit. 2(H315)
c) serious eye damage/irritation The product is classified: Eye Irrit. 2(H319)
d) respiratory or skin sensitisation The product is classified: Skin Sens. 1(H317)
e) germ cell mutagenicity Not classified
Based on available data, the classification criteria are not met
f) carcinogenicity Not classified
Based on available data, the classification criteria are not met

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g) reproductive toxicity Not classified
Based on available data, the classification criteria are not met
h) STOT-single exposure Not classified
Based on available data, the classification criteria are not met
i) STOT-repeated exposure Not classified
Based on available data, the classification criteria are not met
j) aspiration hazard Not classified
Based on available data, the classification criteria are not met
Toxicological information on main components of the mixture:
bis-[4-(2,3- a) acute toxicity LD50 Skin Rabbit = 20 mg/kg
epoxipropoxi)phenyl]
propane

LD50 Oral Rat = 11300 µL/kg

1,6-Hexanediol Diglycidyl a) acute toxicity LD50 Oral Rat = 3010 mg/kg


Ether

LD50 Skin Rabbit > 4900 mg/kg


i) STOT-repeated NOAEL Oral = 200 mg/kg
exposure

NOAEL Inhalation = 16 mg/m3

Formaldehyde, oligomeric a) acute toxicity LD50 Oral Rat > 5000 mg/kg
reaction products with 1-
chloro-2,3-epoxypropane
and phenol

LD50 Skin Rat > 2000 mg/kg


i) STOT-repeated NOAEL Oral = 250 mg/kg
exposure

ethylene glycol monobutyl a) acute toxicity ATE - Oral : 1200 mg/kg bw


ether

LD50 Oral Guineapig = 1414 mg/kg

11.2. Information on other hazards


Endocrine disrupting properties:
No endocrine disruptor substances present in concentration >= 0.1%

SECTION 12: Ecological information


12.1. Toxicity
Adopt good working practices, so that the product is not released into the environment.
Eco-Toxicological Information:
Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment.
List of Eco-Toxicological properties of the product
The product is classified: Aquatic Chronic 2(H411)
List of Eco-Toxicological properties of the components
Component Ident. Numb. Ecotox Data
bis-[4-(2,3- CAS: 1675-54-3, a) Aquatic acute toxicity : LC50 Fish = 2 mg/L 96h
epoxipropoxi)phenyl]propane 25085-99-8 -
EINECS: 216-
823-5 - INDEX:
603-073-00-2

a) Aquatic acute toxicity : EC50 Daphnia = 1.8 mg/L 48h


1,6-Hexanediol Diglycidyl Ether CAS: 933999- a) Aquatic acute toxicity : EC50 Daphnia = 47 mg/L 48
84-9, 16096-31-
4 - EINECS:
618-939-5

a) Aquatic acute toxicity : LC50 Fish = 30 mg/L 96

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a) Aquatic acute toxicity : EC50 Algae = 23.1 mg/L 48
a) Aquatic acute toxicity : LC50 Fish Oncorhynchus mykiss = 30 mg/L 96h
ECHA

Formaldehyde, oligomeric reaction CAS: 9003-36-5 a) Aquatic acute toxicity : LC50 Fish = 5.7 mg/L 96h
products with 1-chloro-2,3- - EINECS: 701-
epoxypropane and phenol 263-0

a) Aquatic acute toxicity : EC50 Daphnia = 2.55 mg/L 48h


a) Aquatic acute toxicity : EC50 Algae = 1.8 mg/L 72h
ethylene glycol monobutyl ether CAS: 111-76-2 - a) Aquatic acute toxicity : LC50 Fish Lepomis macrochirus = 1490 mg/L 96h
EINECS: 203- EPA
905-0 - INDEX:
603-014-00-0

a) Aquatic acute toxicity : EC50 Daphnia Daphnia magna > 1000 mg/L 48h
EPA

a) Aquatic acute toxicity : LC50 Fish Lepomis macrochirus = 2950 mg/L 96h
IUCLID

12.2. Persistence and degradability

N.A.
12.3. Bioaccumulative potential

N.A.
12.4. Mobility in soil

N.A.
12.5. Results of PBT and vPvB assessment

No PBT, vPvB or endocrine disruptor substances present in concentration >= 0.1%


12.6. Endocrine disrupting properties
No endocrine disruptor substances present in concentration >= 0.1%
12.7. Other adverse effects
Not available

SECTION 13: Disposal considerations


13.1. Waste treatment methods
The generation of waste should be avoided or minimized wherever possible. Recover if possible.
A waste code (EWC) according to European List of Waste (LoW) cannot be specified, due to dependence on the usage. Contact and
send to an authorized waste disposal service.
Methods of disposal:
Disposal of this product, solutions, packaging and any by-products should at all times comply with the requirements of
environmental protection and waste disposal legislation and any regional local authority requirements.
Dispose of surplus and nonrecyclable products via a licensed waste disposal contractor.
Do not dispose of waste into sewers.
Hazardous waste: Yes
Disposal considerations:
Do not allow to enter drains or watercourses.
Dispose of product according to all federal, state and local applicable regulations.
If this product is mixed with other wastes, the original waste product code may no longer apply and the appropriate code should be
assigned.
Dispose of containers contaminated by the product in accordance with local or national legal provisions. For further information,
contact your local waste authority.
Special precautions:
This material and its container must be disposed of in a safe way. Care should be taken when handling untreated empty containers.
Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains and sewers.
Empty containers or liners may retain some product residues. Do not re-use empty containers.

SECTION 14: Transport information


14.1. UN number or ID number
3082
14.2. UN proper shipping name
ADR-Shipping Name: ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S. (epoxy resins)
IATA-Technical name: ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S. (epoxy resins)
IMDG-Technical name: ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S. (epoxy resins)
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IMDG-Technical name: ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S. (epoxy resins)
14.3. Transport hazard class(es)
ADR-Class: 9
IATA-Class: 9
IMDG-Class: 9
14.4. Packing group
ADR-Packing Group: III
IATA-Packing group: III
IMDG-Packing group: III
14.5. Environmental hazards
Marine pollutant: Yes
Environmental Pollutant: Yes
IMDG-EMS: F-A, S-F
14.6. Special precautions for user
Road and Rail (ADR-RID):
ADR exempt: No
ADR-Label: 9
ADR-Hazard identification number: 90
ADR-Special Provisions: 274 335 375 601
ADR-Transport category (Tunnel restriction code): 3 (-)
ADR-Limited Quantity threshold: 5 L
Air (IATA):
IATA-Passenger Aircraft: 964
IATA-Cargo Aircraft: 964
IATA-Label: 9
IATA-Subsidiary hazards: -

IATA-Erg: 9L
IATA-Special Provisions: A97 A158 A197
Sea (IMDG):
IMDG-Stowage Code: Category A
IMDG-Stowage Note: -

IMDG-Subsidiary hazards: -

IMDG-Special Provisions: 274 335 969


IMDG-EMS: F-A, S-F
14.7. Maritime transport in bulk according to IMO instruments
Not Applicable
These substances, when carried in single or combination packagings containing a net quantity per single or inner packaging of 5 l or less for
liquids, or having a net mass per single or inner packaging of 5 kg or less for solids, are not subject to provisions of ADR, IMDG and IATA
DGR.

SECTION 15: Regulatory information


15.1. Safety, health and environmental regulations/legislation specific for the substance or mixture
VOC (2004/42/EC) : N.A. g/l
Dir. 98/24/EC (Risks related to chemical agents at work)
Dir. 2000/39/EC (Occupational exposure limit values)
Regulation (EC) n. 1907/2006 (REACH)
Regulation (EU) n. 2020/878
Regulation (EC) n. 1272/2008 (CLP)
Regulation (EC) n. 790/2009 (ATP 1 CLP) and (EU) n. 758/2013
Regulation (EU) n. 286/2011 (ATP 2 CLP)
Regulation (EU) n. 618/2012 (ATP 3 CLP)
Regulation (EU) n. 487/2013 (ATP 4 CLP)
Regulation (EU) n. 944/2013 (ATP 5 CLP)
Regulation (EU) n. 605/2014 (ATP 6 CLP)
Regulation (EU) n. 2015/1221 (ATP 7 CLP)
Regulation (EU) n. 2016/918 (ATP 8 CLP)
Regulation (EU) n. 2016/1179 (ATP 9 CLP)
Regulation (EU) n. 2017/776 (ATP 10 CLP)
Regulation (EU) n. 2018/669 (ATP 11 CLP)
Regulation (EU) n. 2019/521 (ATP 12 CLP)
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Regulation (EU) n. 2019/521 (ATP 12 CLP)
Regulation (EU) n. 2018/1480 (ATP 13 CLP)
Regulation (EU) n. 2020/217 (ATP 14 CLP)
Regulation (EU) n. 2020/1182 (ATP 15 CLP)
Regulation (EU) n. 2021/643 (ATP 16 CLP)
Regulation (EU) n. 2021/849 (ATP 17 CLP)
Regulation (EU) n. 2022/692 (ATP 18 CLP)

Provisions related to directive EU 2012/18 (Seveso III):

Seveso III category according Lower-tier threshold (tonnes) Upper-tier threshold (tonnes)
to Annex 1, part 1
Product belongs to category: E2 200 500
Restrictions related to the product or the substances contained according to Annex XVII Regulation (EC) 1907/2006 (REACH)
and subsequent modifications:
Restrictions related to the product: 3
Restrictions related to the substances contained: 28, 29, 40, 75
SVHC Substances:
SVHC substances not present in a concentration ≥ 0.1% (w/w)
National regulations
Produktregisteret Norge: 52874
MAL-kode: 0-5; A+B (3:1)=3-5 (1993)
Lagerklasse (TRGS-510): 12 - Non-combustible liquids, that cannot be assigned to any of the aforementioned LGK
German Water Hazard Class.
Class 2: hazardous for water.
15.2. Chemical safety assessment
No Chemical Safety Assessment has been carried out for the mixture.

SECTION 16: Other information

Code Description
H302 Harmful if swallowed.
H315 Causes skin irritation.
H317 May cause an allergic skin reaction.
H319 Causes serious eye irritation.
H331 Toxic if inhaled.
H411 Toxic to aquatic life with long lasting effects.
H412 Harmful to aquatic life with long lasting effects.

Code Hazard class and hazard category Description


3.1/3/Inhal Acute Tox. 3 Acute toxicity (inhalation), Category 3
3.1/4/Oral Acute Tox. 4 Acute toxicity (oral), Category 4
3.2/2 Skin Irrit. 2 Skin irritation, Category 2
3.3/2 Eye Irrit. 2 Eye irritation, Category 2
3.4.2/1 Skin Sens. 1 Skin Sensitisation, Category 1
4.1/C2 Aquatic Chronic 2 Chronic (long term) aquatic hazard, category 2
4.1/C3 Aquatic Chronic 3 Chronic (long term) aquatic hazard, category 3

Classification and procedure used to derive the classification for mixtures according to Regulation (EC) 1272/2008
[CLP]:
Classification according to Regulation Classification procedure
(EC) Nr. 1272/2008
Skin Irrit. 2, H315 Calculation method
Eye Irrit. 2, H319 Calculation method
Skin Sens. 1, H317 Calculation method
Aquatic Chronic 2, H411 Calculation method
If appropriate, specific provisions in relation to possible training for workers are mentioned in section 2. Any training related to safety in the
workplace must in any case refer to a risk assessment that must be carried out by a company safety officer taking into account the specific
operating and environmental conditions in which the products are used.
This document was prepared by a competent person who has received appropriate training.
Main bibliographic sources:
ECDIN - Environmental Chemicals Data and Information Network - Joint Research Centre, Commission of the European
Communities
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ECDIN - Environmental Chemicals Data and Information Network - Joint Research Centre, Commission of the European
Communities
SAX's DANGEROUS PROPERTIES OF INDUSTRIAL MATERIALS - Eight Edition - Van Nostrand Reinold
The information contained herein is based on our state of knowledge at the above-specified date. It refers solely to the product indicated and
constitutes no guarantee of particular quality.
It is the duty of the user to ensure that this information is appropriate and complete with respect to the specific use intended.
This SDS cancels and replaces any preceding release.
Legend to abbreviations and acronyms used in the safety data sheet:
ACGIH: American Conference of Governmental Industrial Hygienists
ADR: European Agreement concerning the International Carriage of Dangerous Goods by Road.
AND: European Agreement concerning the International Carriage of Dangerous Goods by Inland Waterways
ATE: Acute Toxicity Estimate
ATEmix: Acute toxicity Estimate (Mixtures)
BCF: Biological Concentration Factor
BEI: Biological Exposure Index
BOD: Biochemical Oxygen Demand
CAS: Chemical Abstracts Service (division of the American Chemical Society).
CAV: Poison Center
CE: European Community
CLP: Classification, Labeling, Packaging.
CMR: Carcinogenic, Mutagenic and Reprotoxic
COD: Chemical Oxygen Demand
COV: Volatile Organic Compound
CSA: Chemical Safety Assessment
CSR: Chemical Safety Report
DMEL: Derived Minimal Effect Level
DNEL: Derived No Effect Level.
DPD: Dangerous Preparations Directive
DSD: Dangerous Substances Directive
EC50: Half Maximal Effective Concentration
ECHA: European Chemicals Agency
EINECS: European Inventory of Existing Commercial Chemical Substances.
ES: Exposure Scenario
GefStoffVO: Ordinance on Hazardous Substances, Germany.
GHS: Globally Harmonized System of Classification and Labeling of Chemicals.
IARC: International Agency for Research on Cancer
IATA: International Air Transport Association.
IATA-DGR: Dangerous Goods Regulation by the "International Air Transport Association" (IATA).
IC50: half maximal inhibitory concentration
ICAO: International Civil Aviation Organization.
ICAO-TI: Technical Instructions by the "International Civil Aviation Organization" (ICAO).
IMDG: International Maritime Code for Dangerous Goods.
INCI: International Nomenclature of Cosmetic Ingredients.
IRCCS: Scientific Institute for Research, Hospitalization and Health Care
KAFH: KAFH
KSt: Explosion coefficient.
LC50: Lethal concentration, for 50 percent of test population.
LD50: Lethal dose, for 50 percent of test population.
LDLo: Leathal Dose Low
N.A.: Not Applicable
N/A: Not Applicable
N/D: Not defined/ Not available
NA: Not available
NIOSH: National Institute for Occupational Safety and Health
NOAEL: No Observed Adverse Effect Level
OSHA: Occupational Safety and Health Administration
PBT: Persistent, Bioaccumulative and Toxic
PGK: Packaging Instruction
PNEC: Predicted No Effect Concentration.
PSG: Passengers
RID: Regulation Concerning the International Transport of Dangerous Goods by Rail.
STEL: Short Term Exposure limit.
STOT: Specific Target Organ Toxicity.
TLV: Threshold Limiting Value.
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TLV: Threshold Limiting Value.
TWATLV: Threshold Limit Value for the Time Weighted Average 8 hour day. (ACGIH Standard).
vPvB: Very Persistent, Very Bioaccumulative.
WGK: German Water Hazard Class.
Paragraphs modified from the previous revision:
- SECTION 2: Hazards identification
- SECTION 3: Composition/information on ingredients
- SECTION 5: Firefighting measures
- SECTION 6: Accidental release measures
- SECTION 7: Handling and storage
- SECTION 8: Exposure controls/personal protection
- SECTION 11: Toxicological information
- SECTION 12: Ecological information
- SECTION 14: Transport information
- SECTION 15: Regulatory information
- SECTION 16: Other information

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