SR MPC DATE: 30-09-2024 TO 05-10-2024

CHEMISTRY ASSIGNMENT
1. The product formed when ethyl chloride reacts with dry Ag2O
1) Ethene 2) Ethyne
3) Etheneoxide 4) Diethyl ether
2. Incorrect statement is
1) Ethers are inert toward most of the reagents, due to this they act as solvent in organic
synthesis.
2) Ethers have much lower boiling points than alcohols of similar molecular mass.
3) p-nitro phenol is more acidic than o-nitrophenol
4) p-nitro phenol is more volatile than o-nitrophenol
3. Phenol is also known as
1) Carbonic acid 2) Carbolic acid 3) Wood spirit 4) Marsh gas
4.

1) 18 2)
O O
CH 3 CH 3
OH CH3

3) 4)
O 18
CH 3 O

5. Which alcohol is obtained when 2 -methoxy-2-methyl propane reacts with one

equivalent of concentrated HBr?

1) methanol 2) isopropyl alcohol 3) ter-butyl alcohol 4) iso-butyl alcohol

CH 3OH
H+
6. O Major product formed is
 CH3 CH3
O O
O
CH3
O O

1) O 2) CH3 3) O 4) O

7. Choose the correct acidic order for the compounds

OH OH
OH
OH
NO2
NO2

NO2
NO2 NO2
(I) ( II ) ( III ) ( IV )

1) II  IV  I  III 2) II  I  IV  III

3) II  III  I  IV 4) I  II  III  IV

8. The number of moles of HI consumed if 1 mole of anisole reacts with excess of HI

1) 0 2) 1 3) 2 4) 3

9. Diethyl ether and methyl propyl ether are

1) Chain isomers 2) Position isomers 3) metamers 4) Tautomers

C H O− Na+ (excess)
OH + C2H5 I ⎯⎯ ⎯⎯⎯⎯⎯→
2 5
C2H5OH (anhydrous)
10.
Predict the major product formed in the above reaction

OC2 H5 I C6 H5 OC6H5
1) 2) 3) 4) C2H5OC2H5

18
O H + / H 2O
A

OH − / H 2 O

11. B Products A & B respectively are

18
OH OH
&
18 &
OH OH OH
1) OH 2) OH OH
 OH 18
OH 18 &
18 & 18 OH OH
3) OH OH 4) OH OH
1
CH3 − CH = CH 2 ⎯⎯⎯⎯→( A) ⎯⎯⎯⎯ →( B )( Major ) the product ‘B’ is
O
2 2
i ) LiA H 4
12. ii ) H O+
Ag − powder 3

OH
CH 3 − CH − CH 3
1) CH3 − CH2 − CH2 − OH 2)

OH
CH 3 − CH − CH 3 O
OH CH 3 − CH − CH 2
3) 4)

13. Most acidic one is

O S
O S

1) O 2) O 3) S 4) S

CH3
H3C
O
O
14. The byproduct formed when (cumene hydroperoxide) H treated with

dilute acid is

1) Ethanol 2) Acetaldehyde 3) Acetone 4) Dimethyl ether

15. The compounds A & B are respectively

 OH OH OH OH
Br Br Br Br
and and

1) Br Br 2) Br

OH OH OH
OH
Br Br
Br Br
and and

Br Br Br Br
3) 4)
16. Electrophile in Reimer-Tiemann reaction is
1) Trychloro carbanion 2) Dichloro carbine
3) Tetrachloro carbon 4) All of these
17. Ph − O − Ph ⎯⎯⎯
HI
Excess
→ product (s) formed are

1) Ph − OH & Ph − I 2) Ph − OH ( 2moles)

3) Ph − I ( 2moles) 4) Cleavage of ether does not takes place

O − CH 3
18. The best method to prepare is

Br + CH 3 − O − ⎯⎯
→ O − + CH 3 Br ⎯⎯
→
1) 2)

Br + CH 3 − OH ⎯⎯

→ Br + CH 3 − OH ⎯ ⎯
→
3) 4)

19. Phenol reacts with

1) Na-metal 2) NaNH2 3) NaOH 4) all the above

20. Which has maximum boiling point?

 OH OH

OH OH
CHO NO2

1) 2) 3) CHO 4) NO2

21. The major product formed in the following reaction is

O
+
H


H3C H
1) o-cresol 2) m-cresol 3) p-cresol 4) Anisole
22. White precipitate among the following is
1) Picric acid 2) 2, 4, 6- tribromo phenol
3) Phenol 4) Anisole
23. Convertion of Phenol to benzene is achieved by
1) Li-metal 2) Na-metal
3) Ag-powder 4) Zn-dust
24. Which gives tribromo derivative upon reaction with 3eq of Br2 in H2O
1) o-cresol 2) m-cresol 3) p-cresol 4) All of these

25. Electrophile in Kolb’s reaction is

1) CO2 2) SO3 3) AlCl3 4) ZnCl2

26. Which of the following reaction wouldn’t yield anisole?
1) C6 H5OH + CH2 N2 → 2) C6 H5ONa + CH3 − I ⎯⎯
→

3) C6 H5OH + (CH3 )2 SO4 ⎯⎯⎯

NaOH
→ 4) C6 H5OH + CH3MgBr ⎯⎯
→

27. Which of the following ethers can be prepared by williamson’s synthesis

1) Ph − O − Ph 2) CH2 = CH − O − CH = CH2
O − CH 3 O − CH = CH 2

3) 4)
28. The product formed when ethyl alcohol reacts with concentrated H2SO4 at 1400 C

1) Ethene 2) Diethyl ether

 3) Etheneoxide 4) 1,4-dioxane

29. Characteristic colouration with neutral FeCl3 solution is given by

1) Phenol 2) Anisole 3) Toluene 4) Diphenyl ether

30. Phenol and anisole can be distinguish by

1) Neutral FeC 3 test
2) 10% aqueous NaHCO3
3) Anhydrous ZnCl2 and concentrated HCl
4) All the above
 CHEMISTRY:-
1) 4 2) 4 3) 2 4) 1 5) 1 6) 2 7) 2 8) 2 9) 3 10) 4

11) 3 12) 2 13) 3 14) 3 15) 4 16) 2 17) 4 18) 2 19) 4 20) 4

21) 3 22) 2 23) 4 24) 2 25) 1 26) 4 27) 3 28) 2 29) 1 30) 1

CHEMISTRY
1 to 30 Conceptual