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12th exams

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15 views

Selfstudys Com File

12th exams

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manuhamu143
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© © All Rights Reserved
We take content rights seriously. If you suspect this is your content, claim it here.
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Thi Question Paper contains 20, ma ‘o a Part= B) Printed pages SLNo. wn dure Az cra? tell add ada OME afer 082 (E) ons . (MARCH, 2024) Sci STREAM (CLASS - XH) 21 Hour/ Marts : 59 e: 2 Hours / Marke : 59 (Part - A) Time : 1 Hour] [Maximum Marks : 50 S = 1) There are 50 objective type (M.C.Q,) questions in Part - A and all questions are compulsory. 2) The een are serially numbered from 1 to 50 and cach carries 1 mark. 3) Read eacl question carefully, sele i in the OMAR sheet ly, select proper alternative and answer 4) The OMR sheet is given for answering the questions. The answer of each question is represented by (A) O, (B) O, (C) O, (D) O. Darken the circle @ of the correct answer with ball-pen. .5) Rough work is to be done in the space provided for this purpose in the Test Booklet only. 6) Set No. of Question Paper printed on the upper-most right side of the Question Paper is to be written in the column provided in the OMR sheet. 7) Use of Simple Calculator and log table is allowed, if required. used in question Paper have usual meaning. 1) Cannizaro reaction is not. given by. (A) HCHO Rough Work (D) CH,CHO UHB62 (12) 1 G-3013 (PT.0.) cact: 2) Whieh Product is obtain when eyelopentanane reels with Hydroxyl amine in acidic medium? (A) Cyclopentanoncoxime (3) Cyclopentanol (C) Cyclopentanone Hydrazone , ’ (D) Cyclopentenamide 3) Which of the following compound gives Iodoform reaction? (A) Propanal (B) Acetone (C) Pent -3- one (D) Benzophenone 4) Which of the following compound has highest K, Value? (A) NO,CH,COOH (B) BrCH,COOH (C) CCl,COOH (D) CH,COOH 5) Which product is obtained on heating sodium acetate with sodalime? (A) Butane (B) Propane (C) Ethane (D) Methane UHB6z2 (12) 2 which of the following compound gives carbyl amine test? ” (B) () (Dp) Isopropylamine Methylamine Ethanamide Trimethylamine which reagent is used to distingui dary and n tertiary amines? 0 distinguish between secondary (A) (B) «c) @) 8) “A @®) ©) @) 9) (A) (B) () (D) ~-UHB62 (12) Nessler reagent Tollens reagent Hinsberg’s reagent Schiff’s reagent Which order for solubility in water of the following compounds is correct? C,H,NH, < C,H,NH, <(C,H,),NU C,H,NH, <(C,H,),NH < C,H,NH, (C,H),NH iyric K, (D) AT,=K, 20) Which one is an example of Ideal solution of the following? (A) Chloroform and acetone (B) Benzene and Toluene (C) Ethanol and Acetone (D) Water and Ethanol 21) An unripe mango placed in a concentrated salt solution to prepare pickle, shrivels because (A) , It gains water due to reverse osmosis (B)* It loses water due to reverse osmosis (Q Itgains water due to osmosis (D) It loses water due to osmosis UHB62 (12) 6 An clectrochemical cel] when can b i ” ¢ behave like an electrolytic cell 22) (A) Bes? Boy (B) Bren > Bay (C) Bey = (D) The standard electy, Til be the value rot Potential for Daniel cell is 1.1. What standard Gibbs energy for the reaction : 23, 2 Zi + Cty —> Zn85, + Cuyy (IF = 96487 C mol) (A) -106.14 KImor"! (B) 212.27 KJmort (C) -212.27 KImor! (D) 106.14 KImor" featoe of charge required to obtain 2mole of aluminium (A) 3F (B) 6F (C) IF (D) 2F 24) 25) InMercury cell which of the following acts as a Cathode? (A) Paste of. ‘ZnO and Carbon (B) () @) Zinc and mercury amalgam Paste of HgO and Carbon Paste of NH,Cl and ZnCl, ‘HB62 (12) re 126.4, 425.9 and o HCl a Aca 26) A‘, for NaCl, HCI and Na ‘A? for HAc. 91.0 Sem’mol-! respectively. Calculate (A) 461.3 Sem?molt (B) 208.5 Sen?molt (C) 643.3 Sem’mol"! (D) 390.5 Sem’mol'! 27) Which Nernst equation is correct for the following cell? Aly | Ales || 20% | Zr (oa) A) By =Eta — ge 108 0.059 B) Bey =Eta ~ log 6 0.059 (©) Boy =Eta — 3 08 0.059 @) Bear =Eea ~ > ee 28) Ifvalue of rate constant K = 2.3 x 10° L moIS", then identity! the reaction order : 3¢ (A) Second order (B) Third order (C) First order (DP) Zero order UHB62 (12) 8 | 1 + 29) What is the slop of plot between IK. > TT according to ‘Arshenius equation? -2.303E, (A) R _ ®) 3303 c) —s (c) R (D) na 30) Areaction is first order in A and second order in B, How many times the rate constant affected on increasing the concentration of B three times. (A) 9 times decreases (B) 9 times increases (C) 6 times increases (D) 6 times decreases 31) Which statement is true with respect to catalyst? (A) Does not alter Gibbs energy (B) Itincreases equillibrium constant (C) Itincreases value of activation energy (D). It increases potential energy barrier UHB62 (12) 9 ‘ . ion? 32) Which of the relation is correct for zero order reaction’ () t < IRI z 1 © 4° RE oc [Rl], nia (c) viet @) 4 @IRh 33) What is the magnetic moment of a solution if its atomic number is 28 (A) 3.87BM (B) 284BM () 1.73BM @) 4.90BM divalent ion in aqueous 34) Which transition element does not exhibit variable oxidation states? (A) Chromium (B) Nickel (C) Copper (D) Scandium 35) What is the formula of Manganate ion? (A) Mnoz (B) MnO; (c) Mnoz @) Mn* L UHB62 (12) 10 36) When acidified Kcr " changes to 1.Cr,0, solution is added to Sn? salt then $17 (AD Sn (B) Sn «C) Sn «D) Sn‘ Primary and Secondary valancy of Coin the complex compound (Co(en),]Cl,is respectively. A 2,3 ®) 3,6 (CC) 3,3 @) 4,6 we a i of 38) [Co(NH,),CI]SO, and [Co(NH,),SO,ICI are which tyPS isomers? (A) _Ionisation isomer (B) Linkage isomer (C) Solvate isomer (D) Coordination isomer in comple: many number of unpaired electrons are there 39) How ion [Ni(CN),]> (A) 4 (B) 3 (c) 2 @) 0 11 aR&2 (12) antate igen? 40) Which othe following is an ambiente 8 (Ay TO ay C404 (C) SCN wD) tEp Tray 41) Amongest the following, the most stable complex is ___— A) [Fe (C,0,)31" (B) [Fe (NH,),]* (©) [Fe (H,0),]* @) [FeCi,]>- 42) Predict the order of reactivity of the following compounds in S,.1 reaction (@) CH,CH,CH (Br) CH, Gi) (CH,), CHCH,Br Gii) (CH,),C Br A did xX+¥ (A) (CH,),C-OH+C,H.I (B) (CH,),C-1+C,H,OH () CH,+C,H, (@) (CH,),C—-I+ CH,OH 50) Which reagent is used in preparation of benzene to benzaldehyde by Gatterman - Koch reaction? (A) CH,COCIand anhydrous AICI, (B) SnCl, and HCI (C) CO,HCland anhydrous AICI, @) CrO,Cl,andcs, 52 (EO. a 4 Marks : (Part B) (Masionun “ and total 1 to 25 Time s 2 Hours} seation paper Anstructions ; 1) Write ina clear legible handwritiee 2) the a! ve giver ns a . stion- There are three sections in Part - Bo al optio' fern fthe gv questions are there. All the questions are compulsory. 17 pulsory. arks 0} » The numbers at right side represent the ™ 4) $) Start new section on new page. 6) Maintain sequence. ii uired. 7)__Use of Simple Calculator and log table is allowed, o_ ——t SECTION-A in brief. 1 to 12 in brie [16] ™ Answer any 8 Questions from the following Q.No- (2 marks for each question) 1) Write reaction equation occurs at anode and cathode in Dry Cell 2) The initial concentration of N,O, in the following first order reaction 0 mol L*! at 318 K. The N,Oyq) —>2NO ye ++Oygy was 1.24 * 1 2 molL7. Calculate concentration of N,O, after 60 minutes was 0.20 * 107 the rate constant of the reaction at 318K. 3) Explain Lanthanoid contraction. What are iterstitial compounds. Write its any two characteristics. 4) 5) Write main postulates of Wemer’s theory of coordination compounds. Write the IUPAC names of the following coordination compounds. ) i) Kcr(C,o,)] if) [CoCl, (en),] Cl 2(12) 16 2 Explain Finkelstein reaction, G-3013 8) . %» 10) Write two step eo, sion fri to Dipheny . Version from Benzene to Dipheny’ Explain production m Cumene. ?0f of phenol fror Explain reactiv; ‘it - ° of aldchyde and Ketones in nucleophilic addition reaction. 11) Explain presence of Five 12) ~OH group i . p in structure of glucose. Differentiate between Globular Protein and fibrous protein. A SECTION-B a. nswer . ANY 6 Questions from the following Q.No. 13 to 21 in detail. G marks for each question) 118) 13) Derive equation of Raouit’s law for vapour pressure of liquid-liquid solution and give its conclusion, 14) Write the Nemst equation and calculate emf of the following cell at 298K = Preo| Hao] HW eoay [BF worse [pr,,| PLy Ibar 0 Eg ya = 1-09 volt 15) The rate constants ofa reaction at 500 K and 700K are 0.02 S*' and 0.078" 7 respectively. Calculate the values of E, and A [R=8.314 JK"'mol"] 16) Describe the preparation of potassium dichromate from iron chromite orc. 7 Whatis the effect of increasing pH on a solution of potassium dichromate. 17) Primary alky! halide C,H,Br (a) reacted with alcoholic KOH to give compound _ (b). Compound (b) is reacted with HBr to give (c) which is an isomer of (a). When (a)is reacted with sodium metal it gives compound (4), C,H, which is different from the compound formed when n-buty! bromide is reacted with sodium. Give the structural formula of (a) and write the equations for all the reactions. 18) Write only chemical equation of method of preparation of 1°, 2° and 3° alcohol “from Grignard reagent. UHB62 (12) 7 (P.T.O.) & J oN write structural formula an dame of fo ¢ from Propanal and Ethal aldol condensatic 19) WhatisC possible aldol condensation prod’ mine and Primary plain Gabrict pthalimide synthesis: primary aliphetic © 20). 1: 21) Explain rea aromatic amine. on of nitrous acid with in detail. SECTION-C 22 to 27 {6} Answer any four Questions from the following Q.No- (4 marks for each question) in 50g of benzene shows a jepression constant for sociation of acid if it is = 122 gmol") give its 4g of benzoic acid (C,H,COOH) dissolved ii 22) “depression in freezing point equal to 1.62K. Molal d benzene is 4.9 K Kgmol~'. What is the percentage as forms dimer in solution? (Molar mass of benzoic acid i What is corrosion. Explain chemistry of corrosion of iron and prevention. Derive the formula for Rate constant (K) and half life period (t,) for first "order reaction. [CoF,]* is paramagnetic while [Ni(CN),]* is diamagnetic, explain on the 25) basis of valance bond theory. Give equations of the following reactions When tertiary alcohol heated at 573K inpresence of Copper (Cu) i) ii) Bromine in CS, with phenol iii) Dilute HNO, with phenol iv) Oxidation of phenol with chromic acid. 27), Write short note on : i) Fehling Test ii) Hell - Volhard - Zelinsky reaction. UHB62 (12) 18

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