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    KML QUEST PSPM Trial DK014

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    Muhammad Haziq

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    KML QUEST PSPM Trial DK014

    Uploaded by

    Muhammad Haziq
    24 views2 pages

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    KML QUEST Pspm trial DK014

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    24 views2 pages

    KML QUEST PSPM Trial DK014

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    Muhammad Haziq

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    DK014 Chemistry 1

    Labuan Matriculation College


    PSPM TRIAL

    QUESTION 1

    (a) Glucose contains 40.00% C, 6.67% H and 53.33% O by mass.


    (i) What is the empirical formula of glucose?
    (ii) If the molar mass of glucose is 180 g, what is the molecular formula of glucose?
    (7 marks)

    (b) A student is asked to prepare 1.25 M aqueous solution of glucose using 50.5 g of glucose.
    (i) Define molarity.
    (ii) Calculate the number of moles of glucose.
    (iii) What is the volume of water in litre (L) needed to prepare the solution?
    (5 marks)

    (c) Estrone is a female sexual hormone containing carbon, hydrogen, and oxygen with a
    molar mass of 270.36 g mol -1. The combustion analysis of 1.893 g of estrone produces 5.545
    g of CO2 and 1.388 g of H2O. Write a balanced chemical equation for the combustion of
    estrone. (10 marks)

    QUESTIONS 2

    a) Between 4s,5f and 2d, which orbital represents impossible combinations of n


    and l ? Explain. (2 marks)
    b) Phosphorus is an element in period 3.
    (i) Write the electronic configuration of phosphorus.
    (ii) Draw its orbital diagram.
    (iii) How many unpaired electrons does it have?
    (3 marks)

    c) Given the set of quantum number for one electron in Calcium atom;
    (n, l, m, s) = (2, 1, -1, -1/2)
    (i) Define orbital.
    (ii) Draw the orbital shape occupied by this electron.
    (iii) State the magnetic quantum number for this electron.
    (iv) Name the quantum number represented by -1/2. (5 marks)
    DK014 Chemistry 1
    Labuan Matriculation College
    PSPM TRIAL

    QUESTION 3

    Hydrogen sulphide, H 2S reacts with excess oxygen to produce sulphur dioxide, SO 2 and water.

    a. Write the balanced equation for the above reaction.

    b. Calculate the number of moles of H 2S required to form 8.20 mol of SO 2.

    c. Calculate the volume of oxygen consumed if 1.00 mol of H 2S was reacted at STP.

    d. Calculate the percentage yield if 12.0 g SO 2 was produced from the reaction of 7.98 g of H 2S.

    (8 marks)

    QUESTIONS 4

    Draw all 3 Lewis structure for COCl2


    a) Calculate the formal charge for all 3 structures
    b) Which structure is the most plausible? Explain
    c) Predict the shape of COCl2 (20 marks)
    QUESTION 5

    (a) The reaction between N 2 and O2 at 250C is represented by the following equation:

    N2(g) + O2(g) ⇌ 2NO(g) Kp = 1 x 10-25


    If the partial pressures of N 2 and O2 at equilibrium are 0.75 atm and 0.24 atm
    respectively, calculate the partial pressure of NO under this condition.
    (b) The equilibrium constant, Kc, for the decomposition of COF 2 is 4.98 at 25 0C. The
    equation of the reaction is given as follows:

    2COF2(g) ⇌ CF4(g) + CO2(g)


    The initial concentrations of COF2 is 0.17 mol L-1, calculate the concentration of CF4 and
    CO2 at equilibrium? (10 marks)

    QUESTION 6
    The Ka for formic acid, HCOOH is 1.8 x 10 - 4. Determine the pH, [H+], [HCOO-] and [HCOOH]
    at equilibrium for 0.010 M solution of formic acid ? (10 marks)

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