Safety Data Sheet

COLEMANITE

Section 1 - Chemical Product and Company Identification

GHS Name: COLEMANITE

Chemical Name: Hydrated Calcium Borate, Di-Calcium Hexaborate Pentahydrate, Boro-

Calcite

Company Identification:

Manufacturer: ETI MADEN MINES AND PRODUCTS, Turkey

Bahçekapı Mah. Fatih Sultan Mehmet Bulvarı No:179 Postcode:06377

Etimesgut / ANKARA, TÜRKİYE
PHONE : + 90 312 397 41 14

Supplied By: Etimine USA, Inc; One Penn Center West; Suite# 400
Pittsburgh, PA 15276
Telephone: (412) 809-8215; Fax: (412) 809-8217

Emergency Number: CHEMTREC 1-800-262-8200/ (703) 741-5500

Section 2 – Hazard Identification

EMERGENCY OVERVIEW

Appearance: Crystalline, Ground or Tan-grey Powder forms

Caution!
Colemanite is considered as a non-hazardous material and it has not been tested
for detailed occupational and toxicological studies. However, human study of
occupationally exposed borate worker population showed no adverse
reproductive effects.
Target Organs: None.
Potential Health Effects
Eye: Not Available

Skin: Not Available

Ingestion: Not Available
Inhalation: Not Available
Chronic: Not Available

Hazard Symbols: NA

Risk Phrase(s): None

Section 3 – Product Identification/Composition

Common Name Chemical name CAS# %

Di-calcium Hexaborate
Colemanite 12291-65-5 65-95
Pentahydrate
Calcite/Dolomite Dolomitic Limestone 16389-88-1 7-20
Sodium-Calcium Pentaborate 1319-33-1 2-6
Ulexite
Octahydrate
Moisture Water 7732-18-5 1 max
Realgar Arsenic Sulphide 12044-30-3 50 ppm
Orpiment Arsenic Trisulphide 12255-89-9 (as As2O3)

Section 4 - First Aid Measures

HAZARDS TO HUMANS AND DOMESTIC ANIMALS

CAUTION: Harmful if swallowed or inhaled. Causes moderate eye irritation. Avoid

contact with eyes or clothing. Avoid breathing dust. Wash thoroughly
with soap and water after handling. Remove contaminated clothing and
wash clothing before reuse.

STATEMENT OF PRACTICAL TREATMENT:

If swallowed: Call a physician or poison control center. Do not induce vomiting.

If Inhaled: Remove victim to fresh air. If not breathing, give artificial respiration,
preferably by mouth-to-mouth. Get medical attention.

If in Eyes: Flush eyes with plenty of water. Call a physician if irritation persists.
Notes to Physician: Treat symptomatically and supportively.

Section 5 - Fire Fighting Measures

General Hazard: Colemanite is not flammable, combustible, or explosive. Borates

present no unusual hazards when involved in a fire. This product
is an inherent fire retardant.

UEL/LEL: Not Applicable

Flash Point: Not Applicable

Auto-ignition: Not Applicable

Flammability: Non-flammable solid.

Class: Flammability Classification (29 CFR 1910.1200)

Extinguishing Media: Any fire extinguishing media may be used on nearby fires.

NFPA Rating Health 0 Flammability 0 Reactivity 0 Phys Haz N/A

Section 6 - Accidental Release Measures

ENVIRONMENTAL HAZARD:

Personal Precautions: Use personal protective equipment. Ensure adequate

ventilation. Avoid dust formation. Do not get in eyes, on
skin, or on clothing.

Environmental Precautions: Should not be released into the environment.

Methods for Containment Sweep up or vacuum up spillage and collect in suitable
and Clean Up container for disposal. Avoid dust formation.

Do not discharge effluent containing this product to sewer

systems without previously notifying the local sewage
treatment plant authority. For guidance, contact your
State Water Board or Regional Office of the EPA.
 Section 7 - Handling and Storage

[It is a violation of Federal Law to use this product in a manner inconsistent with
its labeling]

Caution: Keep out of Reach of Children

Hygenic Practices: Wash hands thoroughly with soap and water after handling, and
before eating, drinking, or smoking.

Storage & Disposal: No special storage or handling procedures are required for this
material. However, for any query contact local authority and
State Water Board or Regional Office of the EPA for guidance.

Container Disposal: There is no special requirement for this product. However, for
disposal of empty bags and containers observe all Federal, state
and local regulations.

FORMULATORS AND REPACKAGERS USING THIS PRODUCT ARE RESPONSIBLE FOR

OBTAINING ENVIRONMENTAL PROTECTION AGENCY (EPA) REGISTRATION FOR
THEIR PRODUCTS. [Refer to PR Notice 95-1 for the applicability of the Environmental
Hazards statement to your product]

This product is a soluble mineral powder which may be used for the formulation of products
for the following registered end-use patterns:

i. Algaecides for water treatment in swimming pools.

ii. Bacteriostats for use in impregnating or otherwise applying to absorbent
material(s) to inhibit the growth of odor-causing bacteria when applied at a rate of
0.015 to 0.37% w/w (approximately) equivalent boron.
iii. Insecticides for mop, spot and crack and crevice treatment in homes, residential,
industrial, institutional and commercial buildings and in transportation equipment.
iv. Insecticide/fungicide for wood treatment.
 Section 8 - Exposure Controls, Personal Protection

Personal protection:

Respiratory Protection : Not required unless there is heavy dust occurrence

in which case a protective mask is recommended.

Skin Protection : Use of gloves recommended.

Eye Protection : Safety goggles recommended in dusty areas.

Other Information : Not absorbed when in contact with healthy skin or

eye. Wash with plenty of water.

Engineering Controls: General dilution ventilation and/or local exhaust

ventilation should be provided as necessary to maintain
exposures below regulatory limits. Dust collection
systems may be necessary in some operations.

Eye Protection: Use goggles or vented safety glasses in excessively

dusty conditions.

Skin Protection: (Not required under normal conditions.) Use protection if

excessively dusty or if skin is damaged.

Respiratory Protection: Use appropriate NIOSH/MSHA certified respirators when

levels are expected to exceed exposure limits (see
Section 15).

Personal Protective Equipment:

Eyes: Wear appropriate protective eyeglasses or chemical safety goggles as

described by OSHA's eye and face protection regulations in 29 CFR 1910.133
or European Standard EN166.
Skin: Wear appropriate protective gloves to prevent skin exposure.
Clothing: Wear appropriate protective clothing to prevent skin exposure.
Respirators: A respiratory protection program that meets OSHA's 29 CFR §1910.134
must be followed whenever workplace conditions warrant a respirator's use.
 Section 9 - Physical and Chemical Properties
Appearance : Ground, light grey to tan stones granulate (80% -75 micron
or 80% -45 micron)

Odor : Odorless

pH : 9.1

Boiling point : Not applicable

Freezing point : Not applicable.

Melting point : 986oC

Vapour Pressure : Not applicable.

Bulk density : 1460-1520 kg/m3

Solubility in water : 0.81 g/l (25oC)

Chemical formula : Ca2B6O11.5H2O,(2CaO.3B2O3.5H2O)

Section 10 - Stability and Reactivity

Stability : Stable under ordinary conditions of use and storage.

Incompatible Materials and Conditions to avoid : None.

Hazardous Decomposition Products : None.

Hazardous Polymerization : Will not occur.

Thermal Decomposition : When heated above 260oC in the oven, it starts losing water
of hydration. On continued heating, dehydration proceeds until
all the water is removed at around 415oC.

Section 11 - Toxicological Information

Not tested. Similar inorganic borate compounds are low in acute oral toxicity; LD50 of
Colemanite in rats is expected to be greater than 5,000 mg/kg of body weight.

EYES: Long occupational exposure history indicates no human

eye injury from exposure to Colemanite.
SKIN: Not known as a skin irritant. As per the data on other pure
form of borates, Colemanite must be of very low acute
dermal toxicity; LD50 for rabbits is expected to be >>
2,000 mg/kg of body weight (test conducted per 16 CFR
1500.41). Boron Oxide is not absorbed through intact
skin.

INHALATION: Not tested. Human epidemiological studies show no

increase in pulmonary disease in occupational populations
with chronic exposure to Boron Oxide and Sodium Borate
dust (See Section 4 also).

INGESTION: Low acute oral toxicity; LD50 for Sprague-Dawley rats is

Expected to be >>4000 mg/kg of body weight.

CARCINOGENICITY: Colemanite, being a Boron Oxide, is not listed as a

carcinogen by the Environmental Protection Agency
(EPA), the State of California, or the International Agency
for Research on Cancer (IARC). A report issued by the
National Toxicology Program showed "no evidence of
carcinogenicity" from a full two-year bioassay on Boron
Oxide on mice at feed doses of 2,500 to 5,000 ppm in the
diet. No mutagenic activity was observed for Boron Oxide
in a recent battery of four short-term mutagenicity
assays.

REPRODUCTIVE: Colemanite has not been tested. However, human study

of occupationally exposed borate worker population
showed no adverse reproductive effects.

Realgar & Orpiment: Colemanite has a very low level of arsenic sulfide content
(<50ppm). However, awareness on Arsenic toxicity is
important to know. Toxicity of arsenic ranges from very
low to extremely high depending on chemical state.
Metallic arsenic and arsenious sulfide have low toxicity;
arsine, a gas, is extremely toxic. The toxicity of other
organic and inorganic arsenic compounds varies.
Although metallic arsenic and arsenic sulfides may be
handled safely without special precautions, skin contact
with all arsenical compounds should be avoided.
Inorganic arsenic is a documented human carcinogen and
has been classified by IARC in Group 1.
 Section 12 - Ecological Information

The environmental effects of boron are minimal and most noticeable in the world of plants.
Minimal quantities of this element is essential for plant growth and hence boron is added to
fertilizers used in boron deficient soils. However concentrations as low as 1 ppm boron could
be critical for sensitive plants (lemon. etc.) and 10 ppm for semi tolerant plants (mustard,
radish). There is no permanent effect as boron gradually soluble in water. In diluted aqueous
solutions the predominant boron species present is undissociated boric acid.
Phytotoxicity: Boron is an essential micronutrient for plants. However, it can be harmful to
boron sensitive plants in higher quantities. Acute toxicity (72-hr EC50) for algae (selenastrum
capricornutum) was determined as 53 mg B/l.
Environmental Fate: Boron and calcium are both ubiquitous in the environment and occur
naturally in various mineral forms. Colemanite should be expected to decompose in the
environment to stable calcium and boron containing mineral species.
Fish Toxicity: Boron naturally occurs in sea water and average concentration of 5 mg B/l.
Acute toxicity (96-hr LC50) for under-yearling Coho salmon (oncorhynchus kisutch) in fresh
water was determined as 447 mg B/l.
Bioaccumulation:
Species : Crassostrea gigas
Exposure Period : 47 days at 8°C
Concentration : 40.5 B mg/l
BCF : ca 4.5-8.5
Test Substance : Sodium Metaborate

Low BCFs and reduction of tissue concentrations during exposures suggest regulation

Section 13 - Disposal Considerations

Danger Class DOT/ADR/RID : Non-hazardous material.

Section 14 - Transport Information

IATA-DGR : Not applicable.

IMDG-Code : Not applicable.

Packing : Not applicable.

Labelling/Marking
(Acc. to EEC regulations) : Not applicable.
 Section 15 - Regulatory Information

US Regulations:

TSCA: Colemanite CAS#12291-65-5 & CAS# 1318-3-8 is listed

on the TSCA inventory.
RCRA (40CFR 261): None listed under any section.
CERCLA (SUPERFUND): None listed under any section.
Health & Safety Reporting List: Not on the Health & Safety Reporting List.

Chemical Test Rules: Not under a Chemical Test Rule.

TSCA 12(b) Chemical Weapons Convention: TSCA 12(b): No

CDTA: No

SARA 311/312: Fire: No Pressure: No

Reactivity: No (Mixture / Solid)

TSCA Significant New Use Rule:Not a SNUR under TSCA.

SARA Section 302 (RQ): None of the chemicals in this material have an RQ.

Section 302 (TPQ): None of the chemicals in this product have a TPQ.

SARA Codes: CAS # 12291-65-5 / 1318-633-8:

Section 313 No chemicals are reportable under Section 313.
Clean Air Act: This material does not contain any hazardous air
pollutants. This material does not contain any Class 1
Ozone depletory substance. This material does not
contain any Class 2 Ozone depletory substance.

Clean Water Act: Colemanite is not regulated by any water quality criteria
under Section 304, is not listed as priority pollutant under
Section 307, and is not listed as a hazardous substance
under Section 311.

SAFE DRINKING WATER ACT: Not regulated under SDWA, 42 USC 300g-1, 40 CFR 141
et seq. Consult state and local regulations for possible
water quality advisories involving boron.

OCCUPATIONAL EXPOSURE LIMITS: Colemanite is not listed/regulated by OSHA, CAL

OSHA, or ACGIH as "Particulate Not Otherwise
 classified" or "Nuisance Dust".

OSHA: NA

ACGIH: NA
CALIFORNIA OSHA: NA

STATE: CAS# 12291-65-5/1318-33-8 can be found on the

following state right to know lists: California, New Jersey,
Florida, Pennsylvania, Minnesota, Massachusetts.
California No Significant Risk Level: None of the chemicals
in this product are listed.
Other Regulations:

Canada: CAS#12291-65-5 is listed on Canada's DSL List.

This is not a WHMIS regulated product.

Exposure Limits
CAS#12291-65-5 : OEL-AUSTRALIA:NA
OEL-BELGIUM:NA
OEL-DENMARK:NA
OEL-FRANCE:NA
OEL-THE NETHERLANDS:NA
OEL-SWEDEN:NA
OEL-SWITZERLAND:NA
OEL-UNITED KINGDOM:NA
OEL IN BULGARIA, COLOMBIA, KOREA,
NEW ZEALAND, SINGAPORE, VIETNAM check ACGIH TLV

INTERNATIONAL AGENCY for CANCER RESEARCH: Not listed as a carcinogen.

NTP ANNUAL REPORT ON CARCINOGENS: Not listed as a carcinogen.
OSHA CARCINOGEN: Not listed as an OSHA carcinogen.

CONEG MODEL LEGISLATION: Meets all CONEG requirements relating to heavy metal
limitations on components of packaging materials.

CALIFORNIA PROPOSITION 65: Not listed as carcinogen or reproductive toxin.

FEDERAL DRUG AGENCY (FDA): NA

WORKPLACE HAZARDOUS MATERIALS INFORMATION SYSTEMS (WHMIS): NA

 Section 16 - Additional Information
OTHER INFORMATION:

Label Hazard Warning: May be harmful if swallowed or inhaled.

Causes irritation if absorbed through damaged skin.

Label Precautions :  Avoid breathing dust.

 Use with adequate ventilation.

 Avoid contact with eyes and damaged skin.

 Wash after handling.

Label First Aid :  Do not ingest.

 If inhaled, remove to fresh air.

 In case of contact with eyes and skin, flush with plenty of water.
If irritation develops, get medical attention.

National Fire Protection Association (NFPA) Classification:

4 = Severe, 3 = Serious, 2 = Moderate, 1 = Slight, 0 = Minimal

Health 0
Flammability 0
Reactivity 0

Hazardous Materials Information Systems (HMIS):

4 = Extreme, 3 = High, 2 = Moderate, 1 = Slight, 0 = Insignificant

Blue: (Acute Health) 0

Red: (Flammability) 0
Yellow: (Reactivity) 0

MSDS Creation Date: 01/02/2014 Updated on: February 25, 2016

This SDS has been compiled for safety information only and does not form part of any selling specification.
Information contained in this Safety Data Sheet is correct to the best of ETIMINE’s knowledge and understanding
based on available information. However, no warranty of merchantability or any other warranty, express or implied,
with respect to such information can be made, and no liability resulting from its use can be assumed. Users should
make their own investigations to determine the suitability of the information for their particular purposes. In no event
shall ETIMINE USA, INC be liable for any claims, losses, or damages of any third party or for lost profits or any
special, indirect, incidental, consequential or exemplary damages, howsoever arising, even if ETIMINE USA has been
advised of the possibility of such damages.

Per the 2012 revision of the OSHA Hazard Communication Standard (HCS), Material Safety
Data Sheets (MSDS) have been reformatted and renamed Safety Data Sheets (SDS).