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Energetics-SL-Paper1-SET 1
1. [1 mark]
Which processes are exothermic?
I.
II.
III.
A. I and II only
B. I and III only
C. II and III only
D. I, II and III
Markscheme
2. [1 mark]
Which equation corresponds to the bond enthalpy of the H–I bond?
A.
B.
C.
D.
Markscheme
3. [1 mark]
Which combination is correct for the standard enthalpy change of neutralization?
1 Markscheme
4. [1 mark]
Which statement is correct for the reaction with this enthalpy level diagram?
A. Heat energy is released during the reaction and the reactants are more stable than the products.
B. Heat energy is absorbed during the reaction and the reactants are more stable than the products.
C. Heat energy is released during the reaction and the products are more stable than the reactants.
D. Heat energy is absorbed during the reaction and the products are more stable than the reactants.
Markscheme 2 B
5a. [1 mark]
The enthalpy changes of three reactions are given below.
What is the enthalpy change for the following reaction?
A.
B.
C.
D.
Markscheme
5b. [1 mark]
The specific heat capacities of two substances are given in the table below.
Which statement is correct?
A. More heat is needed to increase the temperature of 50 g of water by 50 °C than 50 g of ethanol by 50
°C.
B. If the same heat is supplied to equal masses of ethanol and water, the temperature of the water increases more. 3 C. If equal masses of water at 20 °C and ethanol at 50 °C are mixed, the final temperature is 35 °C .
D. If equal masses of water and ethanol at 50 °C cool down to room temperature, ethanol liberates more heat.
Markscheme
6. [1 mark]
The enthalpy change for the reaction between zinc metal and copper(II) sulfate solution is . Which statement about this reaction is correct?
A. The reaction is endothermic and the temperature of the reaction mixture initially rises.
B. The reaction is endothermic and the temperature of the reaction mixture initially drops.
C. The reaction is exothermic and the temperature of the reaction mixture initially rises.
D. The reaction is exothermic and the temperature of the reaction mixture initially drops.
Markscheme
7. [1 mark]
Consider the following equations.
What is the enthalpy change of the reaction below?
A.
B.
C.
D.
4 Markscheme
8. [1 mark]
Which processes are exothermic?
I.
II.
III.
A. I and II only
B. I and III only
C. II and III only
D. I, II and III
Markscheme
9. [1 mark]
Consider the following two equations.
What is , in kJ, for the following reaction?
A.
B.
C.
D.
Markscheme 5 A
10. [1 mark]
Which statement is correct for the enthalpy level diagram shown?
A. The reaction is exothermic and the products are more stable than the reactants.
B. The reaction is exothermic and the sign of the enthalpy change is positive.
C. The reaction is endothermic and the sign of the enthalpy change is negative.
D. The reaction is endothermic and the products are more stable than the reactants.
Markscheme
11. [1 mark]
Which combination is correct about the energy changes during bond breaking and bond formation?
6 Markscheme
12. [1 mark]
Which combination is correct for the exothermic reaction that occurs between zinc and copper sulfate solution.
Markscheme
13. [1 mark]
A 5.00 g sample of a substance was heated from 25.0 °C to 35.0 °C using of energy. What
is the specific heat capacity of the substance in ?
A.
B. 7 C. 2.00
D. 4.00
Markscheme
14. [1 mark]
Using the equations below:
what is , in kJ, for the following reaction?
A. –214
B. –72
C. +72
D. +214
Markscheme
15. [1 mark]
Which statement is correct given the enthalpy level diagram below?
8 A. The reaction is endothermic and the products are more thermodynamically stable than the reactants.
B. The reaction is exothermic and the products are more thermodynamically stable than the reactants.
C. The reaction is endothermic and the reactants are more thermodynamically stable than the products.
D. The reaction is exothermic and the reactants are more thermodynamically stable than the products.
Markscheme
16. [1 mark]
Identical pieces of magnesium are added to two beakers, A and B, containing hydrochloric acid. Both acids have the same initial temperature but their volumes and concentrations differ.
9 Which statement is correct?
A. The maximum temperature in A will be higher than in B.
B. The maximum temperature in A and B will be equal.
C. It is not possible to predict whether A or B will have the higher maximum temperature.
D. The temperature in A and B will increase at the same rate.
Markscheme
17. [1 mark]
Which equation best represents the bond enthalpy of HCl?
A.
B.
C.
D.
Markscheme
18. [1 mark]
Which is true for a chemical reaction in which the products have a higher enthalpy than the reactants?
10 Markscheme
19. [1 mark]
In a reaction that occurs in 50 g of aqueous solution, the temperature of the reaction mixture increases by 20 °C. If 0.10 mol of the limiting reagent is consumed, what is the enthalpy change (in ) for the reaction? Assume the specific heat capacity of the solution .
A.
B.
C.
D.
Markscheme
20. [1 mark]
Use the average bond enthalpies below to calculate the enthalpy change, in kJ, for the following reaction.
A. +290
B. +10
C. –10
11 D. –290
Markscheme
21. [1 mark]
When some solid barium hydroxide and solid ammonium thiosulfate were reacted together, the temperature of the surroundings was observed to decrease from 15 °C to –4 °C. What can be deduced from this observation?
A. The reaction is exothermic and is negative.
B. The reaction is exothermic and is positive.
C. The reaction is endothermic and is negative.
D. The reaction is endothermic and is positive.
Markscheme
22. [1 mark]
Which process represents the C–Cl bond enthalpy in tetrachloromethane?
A.
B.
C.
D.
Markscheme
23. [1 mark]
Some water is heated using the heat produced by the combustion of magnesium metal. Which values are needed to calculate the enthalpy change of reaction?
I. The mass of magnesium
12 II. The mass of the water
III. The change in temperature of the water
A. I and II only
B. I and III only
C. II and III only
D. I, II and III
Markscheme
24. [1 mark]
When of HCl is mixed with of NaOH, the
temperature of the resulting solution increases by 5.0 °C. What will be the temperature change, in °C, when of these two solutions are mixed?
A. 2.5
B. 5.0
C. 10
D. 20
Markscheme
25. [1 mark]
Which statement about bonding is correct?
A. Bond breaking is endothermic and requires energy.
B. Bond breaking is endothermic and releases energy.
C. Bond making is exothermic and requires energy.
D. Bond making is endothermic and releases energy.
Markscheme 13 A
26. [1 mark]
Consider the following reactions.
What is the value of , in kJ, for this reaction?
A.
B.
C.
D.
Markscheme
27. [1 mark]
A student measured the temperature of a reaction mixture over time using a temperature probe. By considering the graph, which of the following deductions can be made?
14 I. The reaction is exothermic.
II. The products are more stable than the reactants.
III. The reactant bonds are stronger than the product bonds.
A. I and II only
B. I and III only
C. II and III only
D. I, II and III
Markscheme
28. [1 mark]
Which process is endothermic?
A.
B.
C. 15 D.
Markscheme
29. [1 mark]
Consider the following enthalpy of combustion data.
