Periodic Table
Periodic Table
Periodic Table
2. According to Mendeleeve's periodic law, physical and chemical properties are function of
(A) Atomic number (B) Atomic weight (C) Atomic volume (D) Number of neutron
3. According to modern periodic law the elements with similar chemical and physical properties repeat at
regular intervals when the elements are arranged in order of :
(A) decreasing atomic number (B) increasing atomic weight.
(C) increasing atomic number. (D) decreasing atomic weight
7. An element has 56 nucleons in nucleus and if it is isotonic with 30Y60. Which group and period does it belong to?
(A) 8th group, 4th period (B) 14th group, 3rd period
(C) 12th group, 3rd period (D) 12th group, 4th period
10. Select the INCORRECT match for the element with its outer most electronic configuration
(A) Pd(46) : [Kr]4d10 (B) Mo(42) : [Kr]4d55s1
(C) Ag(47) : [Kr]4d105s1 (D) Rh(45) : [Kr]5s24d9
11. Element in periodic table with electronic configuration as [18Ar] 3d5 4s1 is placed in :
(A) IA, s-block (B) VIA, s-block (C) VIB, s-block (D) VIB, d-block
12. Atomic number of Ag is 47. In the same group the atomic number of elements placed above and below Ag
will be :
(A) 37, 67 (B) 29, 79 (C) 39, 69 (D) 18, 28
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13. Which of the following statement is wrong for the transition elements ?
(A) Transition elements are placed from 3rd to 6th period.
(B) Last electron enters in (n – 1) d subshell.
(C) Exhibits variable valency.
(D) General electronic configuration is (n – 1) d1–10 ns1–2.
14. The statement that is not correct for the periodic classification of elements is :
(A) the properties of elements are the periodic functions of their atomic numbers.
(B) non-metallic elements are lesser in number than metallic elements.
(C) the third period contains 8 elements and not 18 as 4th period contains.
(D) None of these
16. The statements that are true for the long form of the periodic table are :
(A) it reflects the sequence of filling the electrons in the order of sub energy levels s, p, d & f
(B) it helps to predict the stable valency states of the elements
(C) it reflects trends in physical & chemical properties of elements
(D) All of these
21. Which of the following elements do not belong to the family indicated ?
(A) 29Cu - Coinage metal (B) 56Ba - Alkaline earth metal
(C) 30Zn - Alkaline earth metal (D) 54Xe - Noble gas
25. The period number in the long form of the periodic table is equal to
(A) Magnetic quantum number of any element of the period.
(B) Atomic number of any element of the period.
(C) Maximum Principal quantum number of any element of the period.
(D) Maximum Azimuthal quantum number of any element of the period.
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26. The elements in which electrons are progressively filled in 4f-orbital are called
(A) actinoids (B) transition elements (C) lanthanoids (D) halogens
27. Uub is the symbol for the element with atomic number
(A) 102 (B) 108 (C) 110 (D) 112
I. +CH
3 II. H3O+ III. NH3 IV. CH3
(A) I and II (B) III and IV (C) I and III (D) II, III and IV
34. In a given energy level, the order of penetration effect of different orbitals is :
(A) f < d < p < s (B) s = p = d = f (C) s < p < d < f (D) p > s > d > f
35. The order of screening effect of electrons of s, p, d and f orbitals of a given shell of an atom on its outer shell
electrons is
(A) s > p > d > f (B) f > d > p > s (C) p < d < s > f (D) f > p > s > d
40. Element Hg has two oxidation states Hg+1 & Hg+2, the right order of radii of these ions.
(A) Hg+1 > Hg+2 (B) Hg+2 > Hg+1 (C) Hg+1 = Hg+2 (D) Hg+2 Hg+1
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41. The incorrect order of radius is
(A) K+ > Li+ > Mg+2 > Al+3 (B) Sc+3 < K+ < S2–
(C) Ni > Cu < Zn (D) All are correct
42. Which of the following is the correct order of size of the given species
(A) I > I– > I+ (B) I+ > I– > I (C) I > I+ > I– (D) I– > I > I+
46. When the following five anions are arranged in order of decreasing ionic radius, the correct sequence is :
(A) Se2–, –, Br–, O2–, F– (B) –, Se2–, O2–, Br–, F– (C) Se2–, –, Br–, F–, O2– (D) –, Se2–, Br–, O2–, F–
49. Consider the isoelectronic species, Na+, Mg2+, F– and O2–. The correct order of increasing length of their radii
is ________.
(A) F– < O2– < Mg2+ < Na+ (B) Mg2+ < Na+ < F– < O2–
(C) O2– < F– < Na+ < Mg2+ (D) O2– < F– < Mg2+ < Na+
Ionisation Energy :
50. The value of IE(I), IE(II), IE(III), and IE(IV), of an atom are respectively 7.5 eV, 25.6 eV, 48.6 eV and 170.6
eV. The electronic configuration of the atom will be :
(A) 1s2, 2s2, 2p6, 3s1 (B) 1s2, 2s2, 2p6, 3s2, 3p1
(C) 1s2, 2s2, 2p6, 3s2, 3p3 (D) 1s2, 2s2, 2p6, 3s2
51. Element in which maximum ionization energy of following electronic configuration would be
(A) [Ne] 3s2 3p1 (B) [Ne] 3s2 3p2 (C) [Ne] 3s2 3p3 (D) [Ar] 3d10 4s2 4p3
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54. Decreasing ionization potential for Cs, Ca & Ba is
(A) Ba > Cs > Ca (B) Ca > Ba > Cs (C) Cs > Ba > Ca (D) Cs > Ca > Ba
58. Which represents alkali metals (i.e. 1 group metals) based on (IE)1 and (IE)2 values ?
(IE)1 (IE)2 (IE)1 (IE)2
(A) X 100 110 (B) Y 95 120
(C) Z 195 500 (D) M 200 250
62. Which of the following relation is correct with respect to first (I) and second (II) ionisation energies of sodium
and magnesium ?
(A) mg = Na (B) Na > Mg (C) Mg > Na (D) IINa > Mg
63. Which of the following isoelectronic ion has the lowest 1st ionisation energy ?
(A) Na+ (B) F– (C) Mg2+ (D) O2–
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68. The first ionisation potentials of Na, Mg, Al and Si are in the order
(A) Na < Mg > Al < Si (B) Na < Mg < Al > Si (C) Na > Mg > Al > Si (D) Na > Mg > Al < Si
69. Which among the following elements has the highest value for third ionisation energy ?
(A) Mg (B) Al (C) Na (D) Ar
73. A sudden large jump between the values of second and third ionisation energies of an element would be
associated with the electronic configuration
(A) 1s2, 2s2p6, 3s1 (B) 1s2, 2s2p6, 3s2p1 (C) 1s2, 2s2p6, 3s2p2 (D) 1s2, 2s2p6, 3s2
74. Which of the following orders are correct for the ionization energies ?
(1) Ba < Sr < Ca (2) S2– < S < S2+ (3) C < O < N (4) Mg < Al < Si
(A) 1, 2 and 4 (B) 1, 3 and 4 (C) 1, 2 and 3 (D) 1, 2, 3 and 4
77. Which of the following configuration is associated with the biggest jump between first and second ionization
energy ?
(A) 1s22s22p5 (B) 1s22s22p63s1 (C) 1s22s22p4 (D) 1s22s1
80. Among halogens, the correct order of amount of energy released in electron gain (electron gain enthalpy) is
(A) F > Cl > Br > I (B) F < Cl < Br < I (C) F < Cl > Br > I (D) F < Cl < Br < I
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82. For electron affinity of halogens which of the following is correct ?
(A) Br > F (B) F > Cl (C) Br < Cl (D) F < l
83. Which one of the following statements is incorrect ?
(A) Greater is the nuclear charge, greater is the negative electron gain enthalpy.
(B) Nitrogen has almost zero electron affinity
(C) Negative electron gain enthalpy decreases from fluorine to iodine in the group.
(D) Chlorine has highest negative electron gain enthalpy.
85. The electronic affinity values (in kJ mol–1) of three halogens X, Y and Z are respectively – 349, – 333 and
– 325. Then X, Y and Z respectively are
(A) F2, Cl2 and Br2 (B) Cl2, F2 and Br2 (C) Cl2, Br2 and F2 (D) Br2, Cl2 and F2
87. In which of the following arrangements, the order is NOT according to the property indicated against it.
(A) Al3+ < Mg2+ < Na+ < F– : Increasing ionic size
(B) B < C < N < O : Increasing first ionization enthalpy
(C) I < Br < F < Cl : Increasing electron gain enthalpy (with negative sign)
(D) Li < Na < K < Rb : increasing metallic radius
89. How many given species have negative electron gain enthalpy
F, N, C, Be, Ar, Ne, Ca, Cl–, S, O–
(A) 4 (B) 3 (C) 5 (D) 2
Electronegativity :
94. Out of following, which have the highest electronegativity ?
(A) H (B) Li (C) Na (D) Be
97. The first element of a group in many ways differs from the other heavier members of the group. This is due to:
(A) the small size
(B) the high electronegativity and high ionisation potential
(C) the unavailability of d-orbitals
(D) all of the above
99. If x, y and z are electronegativity, ionisation potential and electron-affinity respectively. Then the electron
affinity (z) in the terms of electronegativity (x) and ionisation potential (y) will be :
xy x–y x2 – y2
(A) z (B) Z (C) Z (D) z = 2x – y
z z 2
100. A molecule H—X will be 50% ionic if electronegativity difference of H and X is : (In mulliken scale)
(A) 1.2 (B) 1.4 (C) 1.5 (D) 1.7
102. Electronegativity of an element is 1.0 on the Pauling scale. Its value on Mulliken scale
(A) 2.8 (B) 1 (C) 2.0 (D) 1.5
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103. The formation of the oxide ion, O2– (g), from oxygen atom requires first an exothermic and then an endothermic
step as shown below :
O(g) + e– O–(g) ; H = –141 kJ mol–1
O–(g) + e– O2–(g) ; H = +780 kJ mol–1
Thus process of formation of O2– in gas phase is unfavourable even though O2– is isoelectronic with neon. It
is due to the fact that.
(A) Oxygen is more electronegative.
(B) Addition of electron in oxygen results in larger size of the ion.
(C) Electron repulsion outweighs the stability gained by achieving noble gas configuration.
(D) O– ion has comparatively smaller size than oxygen atom.
104. Which of the following is affected by the stable electron configuration of an atom ?
(a) electronegativity (b) Ionisation energy (c) Electron affinity
Correct answer is :
(A) Only electronegativity (B) only ionisation potential
(C) electron affinity and ionisation energy both (D) All of the above
110. Which one of the following oxide have highest acidic character ?
(A) CO2 (B) ClO2 (C) SiO2 (D) SO2
111. If an element A show two oxidation states +2 and +3 and form oxide in such a way that ratio of the elemen
showing +2 and +3 state is 1 : 3 in compound. Formula of the compound will be
(A) A8O11 (B) A4O11 (C) A9O11 (D) A5O11
115. Among Al2O3, SiO2, P2O5 and SO3 the correct order of acid strength is
(A) Al2O3 < SiO2 < P2O5 < SO3 (B) SO3 < P2O5 < SiO2 < Al2O3
(C) SiO2 < SO3 < Al2O3 < P2O5 (D) Al2O3 < SiO2 < SO3 < P2O5
116. Which of the following orders are correct for property indicated in brackets ?
(A) Cl > S > O > N (electron affinity) (B) Si > Mg > Al > Na (first ionisation enthalpy)
(C) HClO4 > HBrO4 > HIO4 (acidic nature) (D) All of these
117. Which of the following gradation in the properties is false, as we move from Left to right in the periodic table ?
(A) Metallic to nonmetallic character
(B) Oxidising to reducing properties
(C) Metallic solids through network solids to molecular solids
(D) Base forming to acid forming character
120. If the same element is forming oxides in different oxidation states then :
(A) that oxide will be neutral in nature in which element will be in its highest oxidation state.
(B) that oxide will be highest acidic in nature in which element will be in its highest oxidation state.
(C) that oxide will be amphoteric in nature in which element will be in its highest oxidation state.
(D) that oxide will be highly basic in nature in which element will be in its highest oxidation state.
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