CLASS TEST P BLOCK B and C

CLASS TEST
INORGANIC CHEMISTRY ADVANCED LEVEL DATE: 08-11-24

BORON CARBON FAMILY
Single Choice Questions :
1. In the following reaction, compound (X) is :
B2H6 + 2X  2BH3X.
(A) NH3 (B) R3N (C) RNH2 (D) R2NH
2. BX3 + NH3  BX3.NH3 + Heat of adduct formation (H)

R.T.
The numerical value of H is found to be maximum for :

(A) BF3 (B) BCl3 (C) BBr3 (D) BI3
3. The incorrect statement regarding 'X' in given reaction is :

ether 
BF3 + LiAlH4  (X) + LiF + AlF3
(A) 'X' is a toxic gas

(B) On hydrolysis 'X' produces boric acid
(C) 'X' is electron deficient and behaves as lewis acid
(D) Structure of 'X' in similar to C2H6
4. Which of the following molecular species does not act Lewis acid.
(A) B2H6 (B) BeF2 (C) AlCl3 (D) BF4–
5. H3BO3 
T1
 X 
T2 Y red

hot
 B2O3
if T1 < T2 then X and Y respectively are
(A) X = Metaboric acid and Y = Tetraboric acid (B) X = Tetraboric acid and Y = Metaboric acid
(C) X = Borax and Y = Metaboric acid (D) X = Tetraboric acid and Y = Borax
6. Incorrect order of Lewis-acid character :

(A) BF3 > BCl3 > BBr3 > BI3 (B) SiF4 > SiCl4 > SiBr4 > SiI4
(C) AlCl3 > AlBr3 > AlI3 (D) SO3 > SO2
7. Borax is actually made of two tetrahedra and two triangular units joined together and should be written
as: Na2[B4O5(OH)4]·8H2O
Consider the following statements about borax :
a. Each boron atom has four B–O bonds
b. Each boron atom has three B–O bonds
c. Two boron atoms have four B–O bonds while other two have three B–O bonds
d. Each boron atom has one –OH groups
Select correct statement(s) :
(A) a, b (B) b, c (C) c, d (D) a, c
8. Consider given reaction : B(OH)3 + NaOH  Na[B(OH)4] + H2O

This reaction can be made to proceed for completion by adding.
(A) Glycerol (B) Salicylic acid (C) Glucose (*D) All
9. RCl + Si 
Cu

R2SiCl2 
HO
 R2Si(OH)2 
2 Condensation
 P
Substance (P) is :
(A) Chain silicone (B) Chlorosilane (C) Linear silane (D) Network silane
Page No. 1
10. Which of the following organo silicon chloride can produce cross linked 3D silicone polymer :
(A) R3SiCl (B) R4Si (C) RSiCl3 (D) R2SiCl2
11. Correct order of melting point is :

(A) Diamond > Graphite > C60 (B) Graphite > Diamond > C60
(C) C60 > Graphite > Diamond (D) Diamond > C60 > Graphite
12. PbI4 does not exist because :

(A) Iodine is not reactive (B) Pb(IV) is oxidising and I– is a strong reducing agent
(C) Pb(IV) is less stable than Pb(II) (D) Pb4+ is not easily formed
13. Which metal bicarbonates do not exist in solid state?

(i) LiHCO3 (ii) Ca(HCO3)2 (iii) Zn(HCO3)2 (iv) AgHCO3
(A) (i), (ii), (iii), (iv) (B) (i), (ii), (iii) (C) (i), (ii), (iv) (D) (ii), (iii), (iv)
14. Which of the following gives propyne gas on hydrolysis?

(A) Al4C3 (B) Be4C (C) Mg2C3 (D) SiC
15. An aqueous solution of SnCl2 does not reduce which of the following metal cation into its respective metallic
form.
(A) Bi3+(aq) (B) Hg2+(aq) (C) Au3+(aq) (D) Fe3+(aq)
Multiple Choice Questions :

16. Which of the following statements is/are correct regarding B2H6?
(A) Banana bonds are longer but stronger than terminal B–H bonds
(B) B2H6 is also known as electron deficient compound
(C) Hybridisation of boron in B2H6 is sp3
(D) It cannot be prepared by reacting BF3 with LiAlH4 in the presence of dry ether
17. Select correct statement(s) for orthoboric acid :

(A) It exists in layered structure form in solid state.
(B) It is used in manufacturing of optical glasses.
(C) It is tri-basic acid
(D) It can be used in preparation of buffer solution by mixing it with borax
18. Select correct statement(s):

(A) Aquaous solution of Borax is used as a buffer
(B) 1 M borax solution reacts with equal volumes of 2 M HCl solution
(C) Titration of borax with dil. HCl can be made using methyl orange as the indicator
(D) Coloured bead obtained in borax-bead test contains metaborate
19. The correct statement(s) related to allotropes of carbon is/are
(A) Graphite is thermodynamically most stable allotrope of carbon.
(B) Diamond is the hardest allotrope of carbon
(C) Fullerene (C60) is recently discovered non-crystalline allotrope of carbon having a soccer ball-like
structure.
(D) Vander Waal's force of attraction acts among layers of graphite.
20. Which of the following is correct about silicones?

(A) Silicones are organo silicon compounds containing Si – O – Si linkage
(B) R3SiCl on hydrolysis followed by subsequent polymerisation gives liner silicones
Page No. 2
(C) RSiCl3 on hydrolysis followed by subsequent polymerisation gives linear silicones
(D) When water is eliminated from the terminal –OH groups of linear silicone then cross linked silicone is
formed
INTEGER
180 º C
21. 2BF3(g) + 6NaH   P(g) + Q(solid).
Find out maximum number of atom(s) that can lie in a plane of covalent molecule 'P'.
22. Consider given condensation reaction for formation of silicone :
R
n HO – Si – OH –3H 2O
  Cyclic silicone,
R
and find the value of expression |x – n|

where, x = total number of Si – C bonds in the Cyclic silicone.
ANSWER KEY
1. B 2. D 3. D 4. D 5. A 6. A 7. C
8. D 9. A 10. C 11. A 12. B 13. A 14. C
15. D 16. ABC 17. ABD 18. ABCD 19. ABD 20. A 21. 6
22. 3
Page No. 3

CLASS TEST P BLOCK B and C

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CLASS TEST

INORGANIC CHEMISTRY ADVANCED LEVEL DATE: 08-11-24

2. BX3 + NH3  BX3.NH3 + Heat of adduct formation (H)

The numerical value of H is found to be maximum for :

3. The incorrect statement regarding 'X' in given reaction is :

(A) 'X' is a toxic gas

6. Incorrect order of Lewis-acid character :

8. Consider given reaction : B(OH)3 + NaOH  Na[B(OH)4] + H2O

11. Correct order of melting point is :

12. PbI4 does not exist because :

13. Which metal bicarbonates do not exist in solid state?

14. Which of the following gives propyne gas on hydrolysis?

Multiple Choice Questions :

17. Select correct statement(s) for orthoboric acid :

18. Select correct statement(s):

20. Which of the following is correct about silicones?

and find the value of expression |x – n|

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